{"id":163716,"date":"2019-01-05T06:24:15","date_gmt":"2019-01-04T22:24:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=163716"},"modified":"2019-01-04T11:24:28","modified_gmt":"2019-01-04T03:24:28","slug":"%e7%ba%af%e5%87%80%e9%93%9c%e7%ba%b3%e7%b1%b3%e5%9b%a2%e7%b0%87%e7%94%9f%e9%95%bf%e5%8f%8a%e5%85%b6%e7%94%b5%e5%82%ac%e5%8c%96%e6%80%a7%e8%83%bd%e7%a0%94%e7%a9%b6%e5%8f%96%e5%be%97%e8%bf%9b%e5%b1%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=163716","title":{"rendered":"\u7eaf\u51c0\u94dc\u7eb3\u7c73\u56e2\u7c07\u751f\u957f\u53ca\u5176\u7535\u50ac\u5316\u6027\u80fd\u7814\u7a76\u53d6\u5f97\u8fdb\u5c55"},"content":{"rendered":"<p>\u50ac\u5316\u53cd\u5e94\u5728\u80fd\u6e90\u3001\u73af\u5883\u3001\u5316\u5de5\u3001\u98df\u54c1\u3001\u533b\u836f\u7b49\u9886\u57df\u626e\u6f14\u7740\u91cd\u8981\u7684\u89d2\u8272\u3002\u5177\u6709\u591a\u53d8\u5316\u5408\u4ef7\u6001\u7684\u94dc\uff08Cu\uff09\u662f\u4e00\u79cd\u91cd\u8981\u7684\u50ac\u5316\u5242\u6750\u6599\uff0c\u5728\u70ed\u50ac\u5316\u548c\u7535\u50ac\u5316\u7b49\u65b9\u9762\u90fd\u5177\u6709\u975e\u5e38\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002\u4f17\u6240\u5468\u77e5\uff0c\u50ac\u5316\u5242\u6750\u6599\u7684\u5fae\u89c2\u7ed3\u6784\u5bf9\u53cd\u5e94\u8fc7\u7a0b\u5177\u6709\u5de8\u5927\u7684\u5f71\u54cd\u3002\u964d\u4f4e\u91d1\u5c5e\u7eb3\u7c73\u6750\u6599\u7684\u5c3a\u5bf8\uff0c\u83b7\u5f97\u66f4\u5927\u7684\u6bd4\u8868\u9762\u79ef\uff0c\u6709\u53ef\u80fd\u63d0\u9ad8\u5176\u50ac\u5316\u6d3b\u6027\u3002\u5f53\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92\u5c3a\u5bf8\u964d\u52303 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srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u72477-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u72477-1-300x114.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u5e7f\u5dde\u5927\u5b66\u7269\u7406\u4e0e\u7535\u5b50\u5de5\u7a0b\u5b66\u9662\u6f58\u4e66\u751f\u6559\u6388<\/strong>\uff0c<strong>\u4e0e\u9999\u6e2f\u7406\u5de5\u5927\u5b66\u548c\u4e2d\u56fd\u79d1\u5b66\u9662\u56fa\u4f53\u7269\u7406\u7814\u7a76\u6240\u7b49<\/strong>\u7814\u7a76\u4eba\u5458\u5408\u4f5c\uff0c\u63d0\u51fa\u4e00\u79cd\u8868\u9762\u7b49\u79bb\u6fc0\u5143\u8bf1\u5bfc\u9006\u7f6e\u6362\u53cd\u5e94\uff08Plasmon-engineered Anti-Replacement Reaction\uff09\u7684\u65b9\u6cd5\uff0c\u751f\u957f\u51fa\u65e0\u914d\u4f53\u4fdd\u62a4\u3001\u201c\u7eaf\u51c0\u201dCu\u7eb3\u7c73\u56e2\u7c07\u3002\u91c7\u7528\u8109\u51b2\u6fc0\u5149\u8f90\u7167Au\u7eb3\u7c73\u9897\u7c92\u4e0eCuCl<sub>2<\/sub>\u6df7\u5408\u6eb6\u6db2\uff0c\u5728\u8868\u9762\u7b49\u79bb\u6fc0\u5143\u5149\u6fc0\u53d1\u4e0b\uff0cAu\u7eb3\u7c73\u9897\u7c92\u4ea7\u751f\u80fd\u91cf\u9ad8\u4e8e\u8d39\u7c73\u80fd\u7ea7\u7684\u201c\u70ed\u7535\u5b50\u201d\uff0c\u90e8\u5206\u80fd\u91cf\u5927\u4e8eCu<sup>2+<\/sup>\/Cu\u8fd8\u539f\u7535\u4f4d\u201c\u70ed\u7535\u5b50\u201d\uff0c\u5c06Cu<sup>2+<\/sup>\u79bb\u5b50\u8fd8\u539f\u6210Cu\u7eb3\u7c73\u56e2\u7c07\u3002\u7531\u4e8e\u7edd\u5927\u90e8\u5206\u70ed\u7535\u5b50\u5c40\u57df\u5206\u5e03\u5728\u91d1\u9897\u7c92\u8868\u97621~10nm\u9644\u8fd1\uff0c\u4ec5\u6709\u8fd9\u4e9b\u5c40\u57df\u7a7a\u95f4\u7684Cu<sup>2+<\/sup>\u79bb\u5b50\u80fd\u591f\u63a5\u6536\u5230\u201c\u70ed\u7535\u5b50\u201d\u5e76\u88ab\u8fd8\u539f\uff0c\u6700\u7ec8\u5f62\u6210\u5c3a\u5bf8\u4e3a2 nm\u7684Cu\u7eb3\u7c73\u56e2\u7c07\uff0c\u56fe1\u6240\u793a\u3002\u6574\u4e2a\u53cd\u5e94\u8fc7\u7a0b\u4e0d\u9700\u8981\u6709\u673a\u914d\u4f53\u53c2\u4e0e\u3002\u8fc7\u5269\u201c\u70ed\u7535\u5b50\u201d\u6709\u6548\u5730\u907f\u514d\u4e86Cu\u7eb3\u7c73\u56e2\u7c07\u4e4b\u95f4\u76f8\u4e92\u805a\u96c6\u3002\u5728350 nm\u7d2b\u5916\u5149\u6fc0\u53d1\u4e0b\uff0cCu\u7eb3\u7c73\u56e2\u7c07\u53d1\u51fa450 nm\u6ce2\u957f\u84dd\u8272\u8367\u5149\uff0c\u56fe2\u6240\u793a\u3002\u6240\u83b7\u5f97\u7684\u94dc\u7eb3\u7c73\u56e2\u7c07\u8868\u73b0\u51fa\u5178\u578b\u7684\u91d1\u5c5e\u56e2\u7c07\u7279\u6027\uff0c\u6709\u671b\u5728\u8367\u5149\u6807\u8bb0\u7b49\u65b9\u9762\u83b7\u5f97\u5e94\u7528\u3002<\/p>\n<p><strong><b>\u56fe1<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\uff08a<\/b><\/strong><strong><b>\uff09<\/b><\/strong><strong><b>\u94dc\u7eb3\u7c73\u56e2\u7c07\u7684HRTEM\u56fe\u7247\uff0c<\/b><\/strong><strong><b>\uff08<\/b><\/strong><strong><b>b<\/b><\/strong><strong><b>\uff09<\/b><\/strong><strong><b>\u94bc\u78b3\u7f51\u4e0a\u94dc\u7eb3\u7c73\u56e2\u7c07\u7684\u80fd\u8c31<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-163719 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u72478-1.png\" alt=\"\" width=\"600\" height=\"213\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u72478-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u72478-1-300x107.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u56fe2<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\uff08a<\/b><\/strong><strong><b>\uff09<\/b><\/strong><strong><b>\u94dc\u7eb3\u7c73\u56e2\u7c07\u5149\u5438\u6536\u8c31\uff081<\/b><\/strong><strong><b>\uff09<\/b><\/strong><strong><b>\uff0c<\/b><\/strong><strong><b>\u6fc0\u53d1<\/b><\/strong><strong><b>\u8c31\uff082<\/b><\/strong><strong><b>\uff09<\/b><\/strong><strong><b>\u548c\u53d1\u5c04\u8c31\uff083<\/b><\/strong><strong><b>\uff09<\/b><\/strong><strong><b>\uff0c<\/b><\/strong><strong><b>\uff08<\/b><\/strong><strong><b>b<\/b><\/strong><strong><b>\uff09440 nm<\/b><\/strong><strong><b>\u6ce2\u957f\u8367\u5149\u5bff\u547d\u8c31<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-163720 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u72479-1.png\" alt=\"\" width=\"600\" height=\"238\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u72479-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u72479-1-300x119.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u8fdb\u4e00\u6b65\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u5b9e\u9a8c\u7814\u7a76\u8868\u660e\uff0c\u7535\u538b\u4e3a0.9\u4f0f\u65f6\uff0c\u5355\u4f4d\u8d28\u91cfCu\u7eb3\u7c73\u56e2\u7c07\u50ac\u5316\u5242\u7684\u8fd8\u539f\u7535\u6d41\u4e3a0.73 A\/g\uff0c\u663e\u8457\u9ad8\u4e8e\u76ee\u524d\u8868\u9762\u914d\u4f53\u4fdd\u62a4Cu\u7eb3\u7c73\u56e2\u7c07\u7684\u7535\u50ac\u5316\u5242\uff0c\u4f18\u4e8e\u76ee\u524d\u5546\u7528\u7684\u94c2\uff08Pt\uff09\u50ac\u5316\u5242\uff080.17 A\/g\uff09\uff0c\u56fe3\u6240\u793a\u3002\u8d35\u91d1\u5c5ePt\u662f\u6700\u597d\u7684ORR\u50ac\u5316\u5242\uff0c\u7136\u800c\u5176\u9ad8\u6602\u7684\u6210\u672c\u5236\u7ea6\u4e86\u71c3\u6599\u7535\u6c60\u6280\u672f\u53d1\u5c55\u548c\u5546\u4e1a\u5316\u8fdb\u7a0b\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u7eaf\u51c0Cu\u7eb3\u7c73\u56e2\u7c07\u5728\u71c3\u6599\u7535\u6c60\u4e2d\u5c55\u73b0\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cPlasmon-engineered anti-replacement synthesis of naked Cu nanoclusters with ultrahigh electrocatalytic activity\u201d\u4e3a\u9898\u53d1\u8868\u5728Journal of Materials Chemistry A\uff08DOI: 10.1039\/c8ta06789a\uff09\uff0c\u5e76\u7533\u8bf7\u56fd\u5bb6\u53d1\u660e\u4e13\u5229\uff08\u7533\u8bf7\u53f7201810389351.4\uff09\u3002<\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>. <\/b><\/strong><strong><b>\uff08a<\/b><\/strong><strong><b>\uff09<\/b><\/strong><strong><b>\u94dc\u7eb3\u7c73\u56e2\u7c07\/\u73bb\u78b3\u7535\u6781\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff0c\uff08b\uff09\u8fd8\u539f\u7535\u6d41\u968f\u7740\u65f6\u95f4\u53d8\u5316\uff0c<\/b><\/strong><strong><b>\u63d2\u56fe<\/b><\/strong><strong><b>\uff0c<\/b><\/strong><strong><b>\u4e0d\u540c<\/b><\/strong><strong><b>\u91d1\u5c5e\u56e2\u7c07\u7684\u5355\u4f4d\u8d28\u91cf\u8fd8\u539f\u7535\u6d41\u5bc6\u5ea6\u6bd4\u8f83\u3002<\/b><\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-163721 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u724710-1.png\" alt=\"\" width=\"508\" height=\"191\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u724710-1.png 508w, \/\/m.iemloyee.com\/wp-content\/uploads\/2019\/01\/\u56fe\u724710-1-300x113.png 300w\" sizes=\"(max-width: 508px) 100vw, 508px\" \/><\/p>\n<p><strong>\u4e3b\u8981\u4eae\u70b9\u5728\u4e8e\uff1a<\/strong><\/p>\n<p>\uff081\uff09\u53d1\u5c55\u4e86\u4e00\u79cd\u65b0\u7684\u6750\u6599\u5408\u6210\u65b9\u6cd5plasmon-driven anti-replacement reaction\uff1a\u8868\u9762\u7b49\u79bb\u6fc0\u5143\u9a71\u52a8\u7684\u9006\u7f6e\u6362\u53cd\u5e94\uff1b\uff082\uff09\u5229\u7528\u4e0a\u8ff0\u53cd\u5e94\uff0c\u751f\u957f\u51fa\u201d\u7eaf\u51c0\u201c\uff0c\u4e0d\u542b\u8868\u9762\u914d\u4f53\u7b49\u6709\u673a\u7269\u7684\u94dc\u7eb3\u7c73\u56e2\u7c07<\/p>\n<p>\u8be5\u9879\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9762\u4e0a\u9879\u76ee\uff0c\u5e7f\u5dde\u5927\u5b66\u201c\u767e\u4eba\u8ba1\u5212\u201d\u542f\u52a8\u9879\u76ee\uff0c\u201c\u9999\u6c5f\u5b66\u8005\u201d\u8ba1\u5212\uff0c\u6df1\u5733\u5e02\u79d1\u6280\u8ba1\u5212\u7b49\u7ecf\u8d39\u652f\u6301\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"   https:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/2018\/TA\/C8TA06789A#!divAbstract\"> https:\/\/pubs.rsc.org\/en\/Content\/ArticleLanding\/2018\/TA\/C8TA06789A#!divAbstract<\/a><\/p>\n<p>\u672c\u6587\u7531<strong>\u5e7f\u5dde\u5927\u5b66\u7269\u7406\u4e0e\u7535\u5b50\u5de5\u7a0b\u5b66\u9662\u6f58\u4e66\u751f\u6559\u6388\u7814\u7a76\u56e2\u961f<\/strong>\u4f9b\u7a3f\uff0c\u7f16\u8f91\u90e8\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u50ac\u5316\u53cd\u5e94\u5728\u80fd\u6e90\u3001\u73af\u5883\u3001\u5316\u5de5\u3001\u98df\u54c1\u3001\u533b\u836f\u7b49\u9886\u57df\u626e\u6f14\u7740\u91cd\u8981\u7684\u89d2\u8272\u3002\u5177\u6709\u591a\u53d8\u5316\u5408\u4ef7\u6001\u7684\u94dc\uff08Cu\uff09\u662f\u4e00\u79cd\u91cd\u8981\u7684\u50ac\u5316\u5242\u6750\u6599\uff0c\u5728\u70ed\u50ac\u5316\u548c\u7535\u50ac\u5316\u7b49\u65b9\u9762\u90fd\u5177\u6709\u975e\u5e38\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-163716","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163716"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=163716"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163716\/revisions"}],"predecessor-version":[{"id":163780,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163716\/revisions\/163780"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=163716"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=163716"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=163716"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}