{"id":163589,"date":"2019-01-06T06:33:47","date_gmt":"2019-01-05T22:33:47","guid":{"rendered":"\/\/m.iemloyee.com\/?p=163589"},"modified":"2019-01-05T19:33:58","modified_gmt":"2019-01-05T11:33:58","slug":"%e4%ba%ba%e6%b0%91%e5%a4%a7%e5%ad%a6%e6%85%95%e6%88%90%e5%8c%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e5%be%90%e4%b8%9c%e5%8d%87adv-funct-mater-%ef%bc%9a%e7%94%a8fai%e5%a4%84%e7%90%86mapbi3%e8%96%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=163589","title":{"rendered":"\u4eba\u6c11\u5927\u5b66\u6155\u6210&\u5317\u4eac\u5927\u5b66\u5f90\u4e1c\u5347Adv. Funct. Mater.\uff1a\u7528FAI\u5904\u7406MAPbI3\u8584\u819c\u5bf9\u9ad8\u6027\u80fd\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7f3a\u9677\u51cf\u5c11"},"content":{"rendered":"

\u3010\u7814\u7a76\u80cc\u666f\u3011<\/strong><\/p>\n

\u6709\u673a\u94c5\u4e09\u5364\u9499\u949b\u77ff\u7531\u4e8e\u5177\u6709\u826f\u597d\u7684\u5149\u5e26\u8fb9\u7f18\u3001\u957f\u8f7d\u6d41\u5b50\u6269\u6563\u957f\u5ea6\u3001\u5f31\u6fc0\u5b50\u7ed3\u5408\u80fd\u548c\u9ad8\u5438\u6536\u7cfb\u6570\u7b49\u4f18\u5f02\u7684\u5149\u7535\u6027\u80fd\uff0c\u6210\u4e3a\u4e00\u79cd\u5177\u6709\u5e7f\u9614\u53d1\u5c55\u524d\u666f\u7684\u5149\u7535\u538b\u6750\u6599\u3002\u5728\u8fc7\u53bb\u51e0\u5e74\u4e2d\uff0c\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7684\u529f\u7387\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u4ece3.8%\u5230\u8d85\u8fc723%\uff0c\u4e3a\u540e\u7eed\u5e94\u7528\u5e26\u6765\u5de8\u5927\u6f5c\u529b\u3002\u901a\u8fc7\u591a\u79cd\u52a0\u5de5\u65b9\u6cd5\u5236\u9020\u9ad8\u8d28\u91cf\u7684\u9499\u949b\u77ff\u8584\u819c\uff08PSC\uff09\uff0c\u4f7f\u5f97PSC\u7684\u5feb\u901f\u53d1\u5c55\u6210\u4e3a\u53ef\u80fd\u3002\u800c\u8868\u9762\u8986\u76d6\u5747\u5300\u3001\u7ed3\u6676\u8d28\u91cf\u9ad8\u7684\u9499\u949b\u77ff\u8584\u819c\u662f\u4fdd\u8bc1\u5145\u5206\u91c7\u5149\u548c\u51cf\u5c11\u590d\u5408\u5149\u635f\u5931\u7684\u5173\u952e\u3002\u4e3a\u4e86\u4ece\u6eb6\u5242\u4e2d\u83b7\u5f97\u9ad8\u8d28\u91cf\u7684\u9499\u949b\u77ff\u5c42\uff0c\u4eba\u4eec\u5f00\u53d1\u4e86\u5927\u91cf\u7684\u5236\u5907\u65b9\u6cd5\uff0c\u5982\u524d\u9a71\u6eb6\u5242\u6cd5\u3001\u6297\u6eb6\u5242\u6d17\u6da4\u3001\u8bbe\u8ba1\u6210\u5206\u6539\u53d8\u7b49\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u901a\u8fc7\u8c03\u6574\u7684\u4e00\u6b65\u65cb\u6d82\u6cd5\u53ef\u4ee5\u65b9\u4fbf\u5730\u751f\u4ea7\u5177\u6709\u518d\u73b0\u6027\u548c\u826f\u597d\u6548\u7387\u7684PSC\u3002\u7136\u800c\uff0c\u5176\u6d4b\u91cf\u5f97\u5230PSC\u591a\u6676\u7ebf\u8584\u819c\u7684\u5149\u81f4\u53d1\u5149\u590d\u5408\u5bff\u547d\u8fdc\u8fdc\u77ed\u4e8e\u5355\u4e00\u9499\u949b\u77ff\u6676\u4f53\uff0c\u8fd9\u8868\u660e\u4e0e\u5355\u6676\u76f8\u6bd4\u5176\u6676\u4f53\u7f3a\u9677\u5bc6\u5ea6\u4ecd\u7136\u5f88\u5927\u3002\u56e0\u6b64\uff0c\u964d\u4f4e\u8fd9\u4e9b\u7f3a\u9677\u662f\u5236\u5907\u9ad8\u8d28\u91cf\u9499\u949b\u77ff\u8584\u819c\u5fc5\u987b\u9762\u4e34\u7684\u95ee\u9898\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4eba\u6c11\u5927\u5b66\u6155\u6210&\u5317\u4eac\u5927\u5b66\u5f90\u4e1c\u5347\u901a\u8fc7\u4f7f\u7528\u7532\u8112\u7898\u5316\u7269\uff08FAI\uff09\u7684CH3<\/sub>NH3<\/sub>PbI3<\/sub>(MAPbI3<\/sub>)\u4e00\u6b65\u6c89\u79ef\u6cd5\u5bf9\u9499\u949b\u77ff\u7684\u8868\u9762\u8fdb\u884c\u5904\u7406\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u540e\u5904\u7406\u7b56\u7565\u6765\u4f18\u5316\u9499\u949b\u77ff\u7ed3\u6676\u3002\u901a\u8fc7\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u3001\u5f00\u8def\u5149\u7535\u538b\u8870\u51cf\u548c\u65f6\u95f4\u5206\u8fa8\u7535\u8377\u63d0\u53d6\u7814\u7a76\u7684\u8f7d\u6d41\u5b50\u52a8\u529b\u5b66\u8868\u660e\uff0cFAI\u540e\u5904\u7406\u53ef\u4ee5\u63d0\u9ad8\u9499\u949b\u77ff\u7684\u6676\u4f53\u8d28\u91cf\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u9499\u949b\u77ff\u8584\u819c\u4e2d\u7684\u6676\u4f53\u7f3a\u9677\u3002\u4e0e\u5bf9\u7167\u7ec4\u592a\u9633\u80fd\u7535\u6c60\u76f8\u6bd4\uff0c\u901a\u8fc7FAI\u5904\u7406\u7684\u5149\u4f0f\u5668\u4ef6\u663e\u793a\u51fa\u7684\u6027\u80fd\u5f97\u5230\u4e86\u6781\u5927\u6539\u5584\u3002\u7531\u4e8e\u586b\u5145\u56e0\u5b50\u7684\u663e\u8457\u6539\u5584\uff0c\u4f7f\u5f97\u592a\u9633\u80fd\u7535\u6c60\u83b7\u5f97\u4e86\u5177\u670920.25\uff05\u7684\u6781\u4f73\u529f\u7387\u8f6c\u6362\u6548\u7387\u3002\u540c\u65f6\u8fd9\u9879\u7814\u7a76\u4e3a\u591a\u76f8\u7ed3\u6784\u7684\u8bbe\u8ba1\u3001\u751f\u957f\u548c\u5e94\u7528\u5f00\u8f9f\u4e86\u65b0\u7684\u53ef\u80fd\u6027\uff0c\u5e76\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\u6765\u8bbe\u8ba1\u590d\u6742\u7684\u7eb3\u7c73\u590d\u5408\u7cfb\u7edf\u3002\u8be5\u6210\u679c\u8fd1\u65e5\u4ee5\u9898\u4e3a\u201cReduced Defects of MAPbI3<\/sub> Thin Films Treated by FAI for High-Performance Planar Perovskite Solar Cells<\/strong>\u201d\u53d1\u8868\u5728\u77e5\u540d\u671f\u520aAdv. Funct. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1a\u91c7\u7528\u53cd\u6eb6\u5242\u6cd5\u548cFAI\u540e\u5904\u7406\u6cd5\u5236\u5907\u9499\u949b\u77ff\u5c42\u7684\u5b9e\u9a8c\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\uff1a\u4e0d\u540cFAI\u6d53\u5ea6\u5904\u7406MAPbI3<\/sub>\u8584\u819c\u7684SEM\u56fe\u50cf\u3002<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u672a\u5904\u7406\uff1b
\n (b) 0.5 mg mL\u22121<\/sup> FAI\uff1b
\n (c) 1 mg mL\u22121<\/sup> FAI\uff1b
\n (d) 2 mg mL\u22121<\/sup> FAI\u3002<\/p>\n

\u56fe\u4e09\uff1a\u4e0d\u540cFAI\u6d53\u5ea6\u5904\u7406\u524d\u540eMAPbI3<\/sub>\u8584\u819c\u7684UV-vis\u5438\u6536\u5149\u8c31\u548cXRD\u56fe<\/strong>
\n \"\"
\n (a) \u7528FAI\u5904\u7406\u53ca\u672a\u5904\u7406\u5bf9\u7167MAPbI3<\/sub>\u8584\u819c\u7684UV-vis\u5438\u6536\u5149\u8c31\uff1b
\n (b) \u9760\u8fd1\u5438\u6536\u8fb9\u7f18\u7684\u653e\u5927\u89c6\u56fe\uff1b
\n (c) \u4e0d\u540cFAI\u6d53\u5ea6\u5904\u7406\u7684MAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u7684XRD\u56fe\u8c31\uff1b
\n (d) MAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c(110)\u6676\u683cXRD\u7684\u5e73\u9762\u653e\u5927\u56fe\u3002<\/p>\n

\u56fe\u56db\uff1a\u57fa\u4e8eFAI\u5904\u7406MAPbI3<\/sub>\u9499\u949b\u77ff\u8584\u819c\u7684\u592a\u9633\u80fd\u7535\u6c60\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a-d) \u5bf9\u7167\u7ec4\u4e0eFAI\u5904\u7406\u7ec4\u592a\u9633\u80fd\u7535\u6c60\u7684V<\/em>OC<\/sub>, J<\/em>SC<\/sub> , FF and PCE\u7edf\u8ba1\u5b66\u5206\u5e03\uff0c\u4ece100\u4e2a\u592a\u9633\u80fd\u7535\u6c60\u6536\u96c6\u7684\u6570\u636e\uff08\u6bcf\u79cd\u7c7b\u578b50\u4e2a\u592a\u9633\u80fd\u7535\u6c60\uff09\uff1b
\n (e) \u57fa\u4e8e\u539f\u59cbMAPbI3<\/sub>\u819c\u548c1 mg mL-1<\/sup> FAI\u5904\u7406\u819c\u7684\u592a\u9633\u80fd\u7535\u6c60\u7684J-V<\/em>\u66f2\u7ebf\uff1b
\n (f) \u57fa\u4e8e\u539f\u59cbMAPbI3<\/sub>\u819c\u548c1 mg mL-1<\/sup> FAI\u5904\u7406\u819c\u7684\u592a\u9633\u80fd\u7535\u6c60\u7684EQE\u5149\u8c31\u3002<\/p>\n

\u56fe\u4e94\uff1a\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u5149\u5b66\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5bf9\u7167\u7ec4\u4e0e1 mg mL-1<\/sup> FAI\u5904\u7406MAPbI3<\/sub>\u819c\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\uff1b
\n (b) \u57fa\u4e8e\u539f\u59cbMAPbI3<\/sub>\u819c\u548c1 mg mL-1<\/sup> FAI\u5904\u7406\u819c\u7684\u592a\u9633\u80fd\u7535\u6c60\u7684\u5f00\u8def\u7535\u538b\u8870\u51cf\u66f2\u7ebf\uff1b
\n (c) \u5149\u7535\u538b\u7ea6\u4e3a1 V\u65f6\u7684\u7279\u5f81\u7535\u8377\u63d0\u53d6\u52a8\u529b\u5b66\u56fe\uff1b
\n (d) \u7531TRCE\u6d4b\u91cf\u5f97\u5230\u7684Q-V<\/em>\u5173\u7cfb\u56fe\uff0c\u6563\u70b9\u662f\u5b9e\u9a8c\u6570\u636e\uff0c\u5b9e\u7ebf\u662f\u62df\u5408\u7ed3\u679c\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u4f18\u5316\u6d53\u5ea6\u7684FAI\u6eb6\u6db2\u540e\u5904\u7406\u5de5\u827a\uff0c\u5c06MAPbI3<\/sub>\u8584\u819c\u8f6c\u5316\u4e3a\u9ad8\u8d28\u91cf\u7684PSC\u8584\u819c(\u65e0\u9488\u5b54\u3001\u5927\u6676\u7c92)\u3002\u7531\u4e8eFAI\u7684\u9009\u62e9\u6027\uff0c\u9664\u5bf9\u5176\u5f62\u6001\u5b66\u5177\u6709\u660e\u663e\u7684\u4fee\u9970\u5916\uff0c\u8fd8\u5bf9\u5176\u8fdb\u884c\u4e86\u5904\u7406\u5927\u9897\u7c92\u7684MAPbI3<\/sub>\u8584\u819c\u5728\u7535\u8377\u5206\u79bb\u3001\u7535\u8377\u6536\u96c6\u548c\u8868\u9762\u949d\u5316\u6027\u80fd\u65b9\u9762\u5747\u6709\u6240\u6539\u5584\u3002\u7ecf\u8fc7FAI\u5904\u7406\u7684MAPbI3<\/sub>\u4e0e\u539f\u59cb\u7684MAPbI3<\/sub> PSC\u592a\u9633\u80fd\u7535\u6c60\u76f8\u6bd4\uff0c\u663e\u793a\u51fa\u8d85\u8fc720%\u7684\u6548\u7387\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u7b80\u5355\u7684FAI\u5904\u7406\u5de5\u827a\u80fd\u5236\u5907\u5177\u6709\u8f83\u597d\u91cd\u73b0\u6027\u53ca\u9ad8\u6027\u80fdPSC\uff0c\u662f\u4e00\u79cd\u975e\u5e38\u6709\u524d\u666f\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Reduced Defects of MAPbI3<\/sub> Thin Films Treated by FAI for High-Performance Planar Perovskite Solar Cells<\/a> (Adv. Funct. Mater.<\/em> 2018,<\/strong> 1805810)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7535\u5b50\u7ec4\u6211\u4ea6\u662f\u884c\u4eba\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u7814\u7a76\u80cc\u666f\u3011 \u6709\u673a\u94c5\u4e09\u5364\u9499\u949b\u77ff\u7531\u4e8e\u5177\u6709\u826f\u597d\u7684\u5149\u5e26\u8fb9\u7f18\u3001\u957f\u8f7d\u6d41\u5b50\u6269\u6563\u957f\u5ea6\u3001\u5f31\u6fc0\u5b50\u7ed3\u5408\u80fd\u548c\u9ad8\u5438\u6536\u7cfb\u6570\u7b49\u4f18\u5f02\u7684\u5149\u7535\u6027\u80fd\uff0c\u6210\u4e3a\u4e00\u79cd\u5177\u6709\u5e7f\u9614\u53d1\u5c55\u524d\u666f\u7684\u5149\u7535\u538b\u6750\u6599\u3002\u5728\u8fc7\u53bb\u51e0…<\/p>\n","protected":false},"author":11455,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2990],"class_list":["post-163589","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2990"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163589"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/11455"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=163589"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163589\/revisions"}],"predecessor-version":[{"id":163946,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163589\/revisions\/163946"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=163589"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=163589"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=163589"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}