{"id":163512,"date":"2019-01-01T08:30:29","date_gmt":"2019-01-01T00:30:29","guid":{"rendered":"\/\/m.iemloyee.com\/?p=163512"},"modified":"2018-12-31T16:02:46","modified_gmt":"2018-12-31T08:02:46","slug":"nano-energy-%e9%80%9a%e8%bf%87%e5%a2%9e%e5%bc%ba%e9%93%81%e7%94%b5%e6%9e%81%e5%8c%96%e4%bf%83%e8%bf%9b%e5%85%89%e7%94%9f%e7%94%b5%e8%8d%b7%e5%88%86%e7%a6%bb%e5%92%8cco2%e8%bf%98%e5%8e%9f%e6%b4%bb","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=163512","title":{"rendered":"Nano Energy: \u901a\u8fc7\u589e\u5f3a\u94c1\u7535\u6781\u5316\u4fc3\u8fdb\u5149\u751f\u7535\u8377\u5206\u79bb\u548cCO2\u8fd8\u539f\u6d3b\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/span><\/p>\n

\u592a\u9633\u80fd\u9a71\u52a8\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u53ef\u518d\u751f\u71c3\u6599\u5728\u8fd1\u5e74\u6765\u663e\u793a\u4e86\u5de8\u5927\u6f5c\u529b\uff0c\u7136\u800c\u5149\u751f\u7535\u8377\u5728\u50ac\u5316\u5242\u4f53\u76f8\u7684\u5feb\u901f\u590d\u5408\u4e25\u91cd\u5236\u7ea6\u4e86\u5149\u50ac\u5316\u6d3b\u6027\u7684\u63d0\u9ad8\u3002\u901a\u8fc7\u5efa\u7acb\u7535\u573a\u6291\u5236\u5149\u751f\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u590d\u5408\uff0c\u52a0\u5feb\u8f7d\u6d41\u5b50\u6cbf\u4e0d\u540c\u65b9\u5411\u8fc1\u79fb\u5bf9\u4e8e\u63d0\u5347\u5149\u50ac\u5316\u6548\u7387\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u8fd1\u671f\u4f5c\u8005\u8bfe\u9898\u7ec4\u5df2\u7ecf\u901a\u8fc7\u589e\u5f3a\u5b8f\u89c2\u6781\u5316Angew. Chem. Int. Ed. 2017, 56, 11860\u3001\u6784\u5efa\u8584\u5c42\u6676\u9762\u7ed3Adv.\u00a0Funct. Mater. 2018, 28, 1804284\u3001\u589e\u5f3a\u538b\u7535\u6781\u5316Nano Energy\u00a02018, 53, 513\u548c\u8868\u9762\u6781\u5316Nano Energy 2018, 50, 383\u6765\u63d0\u9ad8\u7535\u8377\u5206\u79bb\u6548\u7387\u548c\u5149\u50ac\u5316\u6d3b\u6027\u3002\u94c1\u7535\u6750\u6599\u7531\u4e8e\u5176\u81ea\u53d1\u6781\u5316\u7279\u6027\u53ef\u5728\u6750\u6599\u5185\u90e8\u5f62\u6210\u5f3a\u7684\u6781\u5316\u7535\u573a\uff0c\u4ece\u800c\u8bf1\u5bfc\u5149\u751f\u7535\u8377\u7684\u9ad8\u6548\u5206\u79bb\uff0c\u5177\u6709\u5f88\u5927\u7684\u5149\u50ac\u5316\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/span><\/p>\n

\u4e2d\u56fd\u5730\u8d28\u5927\u5b66\uff08\u5317\u4eac\uff09\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u8d44\u6e90\u7efc\u5408\u5229\u7528\u4e0e\u73af\u5883\u80fd\u6e90\u65b0\u6750\u6599\u521b\u65b0\u56e2\u961f\u5f20\u4ee5\u6cb3\u6559\u6388<\/b><\/strong>\u3001<\/b><\/strong>\u9ec4\u6d2a\u4f1f\u6559\u6388<\/b><\/strong>\u4e0e\u7ebd\u5361\u7d22\u5927\u5b66\u9a6c\u5929\u7ffc\u535a\u58eb\u6307\u5bfc\u535a\u58eb\u751f\u6d82\u59dd\u81e3<\/b><\/strong>\uff0c\u8fd1\u671f\u5728Nano Energy<\/b><\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3aFerroelectric Polarization Promoted Bulk Charge Separation for Highly Efficient CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u00a0Photoreduction of SrBi<\/b><\/strong>4<\/b><\/sub><\/strong>Ti<\/b><\/strong>4<\/b><\/sub><\/strong>O<\/b><\/strong>15<\/b><\/sub><\/strong>\u7684\u6587\u7ae0\u3002\u6587\u4e2d\u9009\u62e9\u540c\u65f6\u5177\u6709\u5149\u54cd\u5e94\u548c\u94c1\u7535\u6027\u7684\u5c42\u72b6\u94cb\u7cfb\u534a\u5bfc\u4f53SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u4e3a\u7814\u7a76\u5bf9\u8c61\uff0c\u9996\u6b21\u901a\u8fc7\u6c34\u70ed\u6cd5\u5408\u6210\u4e86[001]\u6676\u9762\u4f18\u52bf\u66b4\u9732\u4e14\u6cbf[100]\u6781\u5316\u65b9\u5411\u5b9a\u5411\u751f\u957f\u7684SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u7eb3\u7c73\u7247\uff0c\u7531\u4e8e\u94c1\u7535\u6781\u5316\u6cbf[100]\u65b9\u5411\u7d2f\u79ef\u5f62\u6210\u5f3a\u7684\u5b8f\u89c2\u6781\u5316\u7535\u573a\uff0c\u4ece\u800c\u4f7f\u5176\u5728\u5149\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u5177\u6709\u66f4\u9ad8\u6548\u7684\u4f53\u76f8\u7535\u8377\u5206\u79bb\u6548\u7387\uff0c\u6700\u7ec8\u5927\u5e45\u63d0\u5347SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u5728\u5149\u50ac\u5316\u4e0b\u7684CO2<\/sub>\u8fd8\u539f\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/span><\/p>\n

\u56fe\u4e00\uff1a<\/b><\/strong>SrBi<\/b><\/strong>4<\/b><\/sub><\/strong>Ti<\/b><\/strong>4<\/b><\/sub><\/strong>O<\/b><\/strong>15<\/b><\/sub><\/strong>\u7eb3<\/b><\/strong>\u7c73<\/b><\/strong>\u7247\u5f62\u8c8c\u53ca\u5149\u5438\u6536\u8868\u5f81<\/b><\/strong><\/span><\/p>\n

\"\" \uff08a\uff09SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u7eb3\u7c73\u7247\u7684\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09XRD\u56fe\u8c31\uff1b<\/p>\n

\uff08c\uff0cd\uff09\u9ad8\u5206\u8fa8TEM\u548c\u9009\u533a\u7535\u5b50\u884d\u5c04\u56fe\u50cf\uff1b<\/p>\n

\uff08e\uff09\u5143\u7d20\u80fd\u8c31\u56fe\u50cf\uff1b<\/p>\n

\uff08f\uff09\u7d2b\u5916-\u53ef\u89c1\u5149\u5438\u6536\u5149\u8c31\u548c\u5e26\u9699\u3002<\/p>\n

\u56fe\u4e8c\uff1a<\/b><\/strong>\u5149\u50ac\u5316CO<\/b><\/strong>2<\/b><\/sub><\/strong>\u8fd8\u539f\u6027\u80fd<\/b><\/strong><\/span><\/p>\n

\"\"<\/p>\n

\uff08a\u3001b\uff09CH4<\/sub>\u548cCO\u4ea7\u91cf\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09CH4<\/sub>\u548cCO\u4ea7\u7387\u67f1\u72b6\u56fe\uff1b<\/p>\n

\uff08d\u3001e\uff09SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u5bf9\u7167\u5b9e\u9a8c\u4ea7CH4<\/sub>\u548cCO\u7684\u901f\u7387\u67f1\u72b6\u56fe\u548c\u8272\u8c31\u56fe\uff1b<\/p>\n

\uff08f\uff09\u9000\u706b\u5904\u7406\u7684SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u4ea7CH4<\/sub>\u548cCO\u7684\u7a7a\u767d\u5b9e\u9a8c\u8272\u8c31\u56fe\u3002<\/p>\n

\u56fe\u4e09\uff1a<\/b><\/strong>\u540c\u4f4d\u7d20\u68c0\u6d4b\u3001\u4ea7\u6c27\u68c0\u6d4b<\/b><\/strong>\u53ca\u539f\u4f4d<\/b><\/strong>\u6f2b\u53cd\u5c04\u7ea2\u5916\u5085\u7acb\u53f6\u53d8\u6362\u5149\u8c31<\/b><\/strong>\u5206\u6790<\/b><\/strong><\/span><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u901a\u516512<\/sup>CO2 \u300113<\/sup>CO2 \u53cd\u5e94\u65f6\u7684\u8272\u8c31\u56fe\u548c\uff08b\uff09\u8d28\u8c31\u4fe1\u53f7\uff1b<\/p>\n

\uff08c\uff09\u6c27\u5316\u8fd8\u539f\u4ea7\u91cf\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u7684\u539f\u4f4d\u6f2b\u53cd\u5c04\u7ea2\u5916\u5085\u7acb\u53f6\u53d8\u6362\u5149\u8c31\u3002<\/p>\n

\u56fe\u56db\uff1a<\/b><\/strong>\u80fd\u5e26\u7ed3\u6784\u53caDFT\u8ba1\u7b97<\/b><\/strong><\/span><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u83ab\u7279\u8096\u7279\u57fa\u56fe\u8c31\uff1b<\/p>\n

\uff08b\uff09\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08c\u3001d\uff09SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u6001\u5bc6\u5ea6\u8ba1\u7b97\u53ca\uff08e\uff09\u7535\u5b50\u7a7a\u7a74\u5206\u79bb\u4e0e\u8fc1\u79fb\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe\u4e94\uff1a<\/b><\/strong>\u6781\u5316\u7d2f\u79ef\u4e0e<\/b><\/strong>\u94c1\u7535\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/span><\/p>\n

\"\"\uff08a\uff09\u6cbf\u03b1 \u8f74\u7684\u65b9\u5411\u4e0a\u94c1\u7535\u6781\u5316\uff1b<\/p>\n

\uff08b\u3001c\uff09\u538b\u7535\u529b\u663e\u5fae\u955c\u6d4b\u5f97\u76842D\u548c3D \u94c1\u7535\u76f8\u56fe\u548c\u5bf9\u5e94\u7684\u7ffb\u8f6c\u66f2\u7ebf\u548c\uff08e\uff09\u94c1\u7535\u76f8\u4f4d\u56de\u7ebf\uff1b<\/p>\n

\uff08f\uff09\u4e0d\u540c\u9000\u706b\u6e29\u5ea6\u5904\u7406SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u7684\u7535\u6ede\u56de\u7ebf\u3002<\/p>\n

\u56fe\u516d\uff1a<\/b><\/strong>\u94c1\u7535\u6781\u5316\u4e0e\u7535\u8377\u5206\u79bb\u673a\u5236\u53ca\u5173\u7cfb\u5206\u6790<\/b><\/strong><\/span><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u6781\u5316\u573a\u589e\u5f3a\u5149\u751f\u8f7d\u6d41\u5b50\u5206\u79bb\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\u3001c\uff09\u4e0d\u540c\u6e29\u5ea6\u9000\u706b\u6837\u54c1\u7684CH4<\/sub>\u00a0\u548cCO \u4ea7\u91cf\u66f2\u7ebf\uff1b<\/p>\n

\uff08d\uff09\u7eb3\u79d2\u7ea7\u65f6\u95f4\u5206\u8fa8\u8367\u5149\u5149\u8c31\u4ee5\u53ca\uff08e\uff09\u7a33\u6001\u8367\u5149\u5149\u8c31\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u4e0e\u5c55\u671b\u3011<\/b><\/strong><\/span><\/p>\n

\u8be5\u5de5\u4f5c\u9996\u6b21\u62a5\u9053\u4e86\u901a\u8fc7\u8f6f\u5316\u5b66\u65b9\u6cd5\u5408\u6210\u5c42\u72b6\u94c1\u7535\u9499\u949b\u77ff\u7ed3\u6784\u7684SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u7eb3\u7c73\u7247\u4f5c\u4e3a\u9ad8\u6548\u5149\u50ac\u5316\u5242\u8fd8\u539fCO2<\/sub>\u3002\u6cbf[100]\u65b9\u5411\u5f3a\u7684\u94c1\u7535\u6781\u5316\u4f7f\u5f97SrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u5149\u751f\u7535\u5b50\u548c\u7a7a\u7a74\u5728\u8be5\u65b9\u5411\u4e0a\u5f97\u5230\u6709\u6548\u5206\u79bb\u3002\u540c\u65f6\u7406\u8bba\u8ba1\u7b97\u8868\u660e\u7535\u5b50\u548c\u7a7a\u7a74\u5206\u522b\u8fc1\u79fb\u81f3TiO6<\/sub>\u516b\u9762\u4f53\u548cBi2<\/sub>O2<\/sub>2+<\/sup>\u5c42\uff0c\u4e14\u8f7d\u6d41\u5b50\u6cbfa\u8f74\u5177\u6709\u6700\u5c0f\u7684\u6709\u6548\u8d28\u91cf\uff0c\u5341\u5206\u6709\u5229\u4e8e\u7535\u8377\u6cbf\u8be5\u65b9\u5411\u7684\u5feb\u901f\u8fc1\u79fb\u548c\u5206\u79bb\u3002\u57fa\u4e8e\u4ee5\u4e0a\u4f18\u52bf\uff0cSrBi4<\/sub>Ti4<\/sub>O15<\/sub>\u5c55\u793a\u4e86\u6781\u9ad8\u7684\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u6d3b\u6027\uff0cCH4<\/sub>\u4ea7\u7387\u8fbe\u523019.8\u00a0\u03bcmol\u00b7h-1<\/sup>\u00b7g-1<\/sup>\u3002\u8fd9\u9879\u5de5\u4f5c\u8868\u660e\u94c1\u7535\u534a\u5bfc\u4f53\u53ef\u4f5c\u4e3a\u4e00\u7c7b\u9ad8\u6d3b\u6027\u5149\u50ac\u5316\u6750\u6599\uff0c\u5c06\u5728\u5149\uff08\u7535\uff09\u50ac\u5316\u80fd\u6e90\u8f6c\u5316\u8fc7\u7a0b\u4e2d\u5c55\u73b0\u5de8\u5927\u5e94\u7528\u524d\u666f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Ferroelectric Polarization Promoted Bulk Charge Separation for Highly Efficient CO2<\/sub>\u00a0Photoreduction of SrBi4<\/sub>Ti4<\/sub>O15<\/sub>.\u00a0Nano Energy 56 (2019) 840-850.<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u592a\u9633\u80fd\u9a71\u52a8\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4e3a\u53ef\u518d\u751f\u71c3\u6599\u5728\u8fd1\u5e74\u6765\u663e\u793a\u4e86\u5de8\u5927\u6f5c\u529b\uff0c\u7136\u800c\u5149\u751f\u7535\u8377\u5728\u50ac\u5316\u5242\u4f53\u76f8\u7684\u5feb\u901f\u590d\u5408\u4e25\u91cd\u5236\u7ea6\u4e86\u5149\u50ac\u5316\u6d3b\u6027\u7684\u63d0\u9ad8\u3002\u901a\u8fc7\u5efa\u7acb\u7535\u573a\u6291\u5236\u5149\u751f\u7535\u5b50\u548c\u7a7a\u7a74…<\/p>\n","protected":false},"author":4695,"featured_media":163526,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-163512","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163512"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4695"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=163512"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163512\/revisions"}],"predecessor-version":[{"id":163527,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163512\/revisions\/163527"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/163526"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=163512"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=163512"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=163512"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}