{"id":163501,"date":"2019-01-03T06:20:40","date_gmt":"2019-01-02T22:20:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=163501"},"modified":"2019-01-02T18:50:41","modified_gmt":"2019-01-02T10:50:41","slug":"%e3%80%90%e6%a0%a1%e7%a8%bf%e5%b7%b2%e5%9b%9e%e5%a4%8d%e3%80%91%e5%b8%85%e5%bf%97%e5%88%9a%e5%bd%ad%e8%b0%a6jacs-%e9%ab%98%e6%95%88%e9%95%bf%e5%af%bf%e5%91%bd%e6%9c%89%e6%9c%ba%e5%ae%a4%e6%b8%a9","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=163501","title":{"rendered":"\u5e05\u5fd7\u521a&amp;\u5f6d\u8c26JACS: \u9ad8\u6548\u957f\u5bff\u547d\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u6750\u6599\u8bbe\u8ba1\u7684\u5206\u5b50\u63cf\u8ff0\u7b26"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u957f\u4f59\u8f89\u6709\u673a\u5ba4\u6e29\u78f7\u5149\uff08RTP\uff09\u6750\u6599\u7531\u4e8e\u5728\u751f\u7269\u6210\u50cf\u3001\u6570\u5b57\u52a0\u5bc6\u548c\u5149\u7535\u5668\u4ef6\u7b49\u65b9\u9762\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7531\u4e8e\u7eaf\u6709\u673a\u5206\u5b50\u7684\u65cb\u8f68\u8026\u5408\u6bd4\u8f83\u5f31\u548c\u4e09\u7ebf\u6001\u5bf9\u6e29\u5ea6\u548c\u6c27\u6c14\u9ad8\u5ea6\u654f\u611f\uff0c\u957f\u671f\u4ee5\u6765\u6709\u673a\u6750\u6599\u88ab\u8ba4\u4e3a\u662f\u6ca1\u6709\u78f7\u5149\u7684\u3002\u6700\u8fd1\uff0c\u6709\u7814\u7a76\u8bc1\u660e\u4e00\u4e9b\u7eaf\u6709\u673a\u5316\u5408\u7269\u8868\u73b0\u51fa\u9ad8\u6548\u7684\u56fa\u6001RTP\uff0c\u4f46\u5176\u53d1\u5149\u6548\u7387\u548c\u5bff\u547d\u4e0d\u53ef\u517c\u5f97\u3002\u7eb5\u89c2\u76ee\u524d\u7684\u7eaf\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u6750\u6599\uff0c\u6709\u4e9b\u662f\u6548\u7387\u9ad8\u4f46\u5bff\u547d\u77ed\uff0c\u6709\u4e9b\u662f\u6548\u7387\u4f4e\u4f46\u5bff\u547d\u957f\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u96be\u9898\uff0c\u51e0\u4e2a\u8bfe\u9898\u7ec4\u8bbe\u8ba1\u82b3\u9999\u7c7b\u7fb0\u57fa\u5316\u5408\u7269\uff0c\u671f\u671b\u5229\u7528\u6df7\u5408\u7684n\/p\u57fa\u56e2\u6765\u4e0d\u540c\u7a0b\u5ea6\u5730\u8c03\u63a7\u78f7\u5149\u6548\u7387\u548c\u5bff\u547d\u3002\u4f46\u8fd9\u79cd\u65b9\u6848\u4e5f\u662f\u90e8\u5206\u6210\u529f\uff0c\u90e8\u5206\u5931\u8d25\u3002\u6240\u4ee5\uff0c\u9610\u660e\u6709\u673aRTP\u6750\u6599\u7684\u53d1\u5149\u673a\u5236\uff0c\u6784\u5efa\u666e\u9002\u7684\u78f7\u5149\u5206\u5b50\u8bbe\u8ba1\u89c4\u5219\u662f\u6b64\u9886\u57df\u9762\u4e34\u7684\u4e00\u9879\u5de8\u5927\u6311\u6218\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p><strong>\u00a0<\/strong><strong>\u6e05\u534e\u5927\u5b66\u5e05\u5fd7\u521a\u6559\u6388\u548c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u5f6d\u8c26\u526f\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u7b49\u4eba\u63d0\u51fa\u4e86\u4e00\u5bf9\u5206\u5b50\u63cf\u8ff0\u7b26\u6765\u8868\u5f81\u78f7\u5149\u6548\u7387\u548c\u5bff\u547d\u3002\u7531\u7fb0\u57fa\u548c\u03c0-\u5171\u8f6d\u7247\u6bb5\u7ec4\u6210\u7684\u5178\u578bRTP\u4f53\u7cfb\uff0c\u5176\u6fc0\u53d1\u6001\u53ef\u4ee5\u89c6\u4e3an\u2192\u03c0*\u8dc3\u8fc1\uff08\u03b1\uff09\u548c\u03c0\u2192\u03c0*\u8dc3\u8fc1\uff08\u03b2\uff09\u4e24\u7ec4\u5206\u7684\u7ec4\u5408\uff0c\u5373\u03b1 + \u03b2 = 1\u3002\u4ed6\u4eec\u57fa\u4e8e\u5149\u81f4\u78f7\u5149\u7684\u57fa\u672c\u5149\u7269\u7406\u8fc7\u7a0b\uff0c\u7279\u522b\u662f\u5355\u7ebf\u6001\u4e0e\u4e09\u7ebf\u6001\u76f8\u4e92\u8f6c\u5316\u6240\u9075\u5faa\u7684El-Sayed\u89c4\u5219\uff0c\u5f15\u5165\u4e86\u5206\u5b50\u63cf\u8ff0\u7b26\u03b3\u548c\u03b2\uff0c\u5176\u6570\u503c\u7684\u5927\u5c0f\u4e0e\u5206\u5b50\u5355\/\u4e09\u7ebf\u6001\u6fc0\u53d1\u6001\u7684\uff08n\uff0c\u03c0*\uff09\u548c\uff08\u03c0\uff0c\u03c0*\uff09\u8dc3\u8fc1\u6210\u5206\u6709\u5173\u3002\u7ed3\u5408\u91cf\u5b50\u529b\u5b66\/\u5206\u5b50\u529b\u5b66\uff08QM\/MM\uff09\u65b9\u6cd5\uff0c\u4ed6\u4eec\u63ed\u793a\u4e86\u5206\u5b50\u63cf\u8ff0\u7b26\uff08\u03b3\uff0c\u03b2\uff09\u4e0e\u78f7\u5149\u6548\u7387\u548c\u5bff\u547d\u4ee5\u53ca\u65cb\u8f68\u8026\u5408\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u4ed6\u4eec\u63d0\u51fa\uff0c\u5927\u7684\u03b3\u548c\u03b2\u503c\u6709\u5229\u4e8e\u6709\u673a\u6750\u6599\u4e2d\u5f3a\u7684\u3001\u957f\u5bff\u547d\u7684RTP\u3002\u8fd9\u4e9b\u5206\u5b50\u8bbe\u8ba1\u539f\u5219\uff0c\u5df2\u88ab\u5b9e\u9a8c\u6240\u8bc1\u5b9e\u548c\u62a5\u9053\u3002\u8be5\u7814\u7a76\u53d1\u8868\u4e8e<strong>Journal of the American Chemical Society<\/strong>\uff0c\u9898\u4e3a<strong>\u201c<\/strong><strong>Efficient and Long-lived Room Temperature Organic Phosphorescence: Theoretical Descriptors for Molecular Designs\u201d<\/strong>\u3002\u7b2c\u4e00\u4f5c\u8005\u4e3a\u5357\u4eac\u5de5\u4e1a\u5927\u5b66\u7684\u9a6c\u4f1a\u5229\u526f\u7814\u7a76\u5458\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u00a0<\/strong><strong>\u56fe<\/strong><strong>1. <\/strong><strong>\u56db\u7c7b\u6709\u673a<\/strong><strong>RTP<\/strong><strong>\u5206\u5b50\u7684\u5316\u5b66\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-163502\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/1-10.png\" alt=\"\" width=\"600\" height=\"492\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/1-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/1-10-300x246.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u5217\u4e3e\u4e86\u56db\u7c7b\u6709\u673aRTP\u5206\u5b50\u7684\u5316\u5b66\u7ed3\u6784\uff0c\u540c\u65f6\u8fd8\u5217\u51fa\u4e86\u78f7\u5149\u5bff\u547d\uff08\u03c4<sub>p<\/sub>\uff09\u548c\u91cf\u5b50\u4ea7\u7387\uff08\u03a6<sub>p<\/sub>\uff09\u3002\uff08a\uff09\u548c\uff08c\uff09\u7684\u4e0d\u540c\u4e4b\u5904\u5728\u4e8e\uff08a\uff09\u4e2d\u6ca1\u6709\u5e38\u89c1\u7684\u7fb0\u57fa\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>2. <\/strong><strong>\u53c2\u8003\u7406\u8bba\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-163503\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/2-13.png\" alt=\"\" width=\"600\" height=\"306\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/2-13.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/2-13-300x153.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09Jablonski\u793a\u610f\u56fe\uff0c\uff08b\uff09El-Sayed\u89c4\u5219\uff0c\uff08c\uff09\u8f68\u9053\u89d2\u52a8\u91cf\u7684\u65cb\u8f6c\u7279\u6027\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>3.<\/strong> <strong>\u6a21\u578b\u5efa\u7acb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-163504\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/3-10.png\" alt=\"\" width=\"600\" height=\"467\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/3-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/3-10-300x234.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>QM\/MM\u6a21\u578b\uff08\u4ee5DPhCzT\u4e3a\u4f8b\uff0c\u9690\u85cf\u4e86\u6c22\u539f\u5b50\uff09\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u56fe<\/strong><strong>4. <\/strong><strong>\u80fd\u7ea7\u56fe\u548c<\/strong><strong>SOC<\/strong><strong>\u7cfb\u6570<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-163505\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/4-13.png\" alt=\"\" width=\"447\" height=\"600\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/4-13.png 447w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/4-13-224x300.png 224w\" sizes=\"(max-width: 447px) 100vw, 447px\" \/><\/p>\n<p>\u5229\u7528QM\/MM\u65b9\u6cd5\u8ba1\u7b97\u768412\u4e2a\u5206\u5b50\u805a\u96c6\u4f53\u7684\u80fd\u7ea7\u56fe\u548cSOC\u7cfb\u6570\uff08\u03be\uff09\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong>5. <\/strong><strong>\u5404\u53c2\u6570\u95f4\u7684\u76f8\u4e92\u5173\u7cfb<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-163506\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/5-8.png\" alt=\"\" width=\"600\" height=\"400\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/5-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/5-8-300x200.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u78f7\u5149\u91cf\u5b50\u4ea7\u7387\uff08\u03a6<sub>p<\/sub>\uff09\uff0c\u5bff\u547d\uff08\u03c4<sub>p<\/sub>\uff09\uff0cSOC\u7cfb\u6570\uff08\u03be\uff09\u548c\u5206\u5b50\u63cf\u8ff0\u7b26\uff08\u03b3\uff0c\u03b2\uff09\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\uff08a\uff09\u03a6<sub>p<\/sub>\u5bf9\u03b3\uff1b\uff08b\uff09\u03c4<sub>p<\/sub>\u4e0e\u03b2\uff1b\uff08c\uff09\u03be\uff08S<sub>1<\/sub>\uff0cT<sub>n<\/sub>\uff09\u4e0e\u03b3\uff1b\uff08d\uff09\u03be\uff08T<sub>1<\/sub>\uff0cS<sub>0<\/sub>\uff09\u4e0e\u03b2\u3002\u03a6<sub>p<\/sub>\u548c\u03c4<sub>p<\/sub>\u4e3a\u5b9e\u9a8c\u503c\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u8be5\u9879\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u5bf9\u7b80\u5355\u7684\u5206\u5b50\u63cf\u8ff0\u7b26\uff08\u03b3\uff0c\u03b2\uff09\u6765\u6709\u6548\u8bc4\u4f30\u6709\u673aRTP\u6750\u6599\u7684\u78f7\u5149\u6548\u7387\u548c\u5bff\u547d\u3002\u901a\u5e38\uff0c\u78f7\u5149\u6548\u7387\u548c\u4f59\u8f89\u65f6\u95f4\u4e4b\u95f4\u76f8\u4e92\u77db\u76fe\uff0c\u5373\uff0c\u957f\u5bff\u547d\u610f\u5473\u7740\u7f13\u6162\u7684\u6fc0\u53d1\u6001\u8870\u51cf\u901f\u7387\uff0c\u6548\u7387\u5c31\u4f4e\u3002\u7136\u800c\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\uff0c\u53ef\u4ee5\u901a\u8fc7\u5206\u5b50\u8bbe\u8ba1\uff0c\u72ec\u7acb\u4f18\u5316\u8fd9\u4e24\u4e2a\u53c2\u6570\uff0c\u6765\u89e3\u51b3\u8fd9\u4e00\u56fd\u9645\u96be\u9898\u3002\u4ed6\u4eec\u57fa\u4e8e\u4ea7\u751f\u78f7\u5149\u7684\u6fc0\u53d1\u6001\u8f6c\u5316\u548c\u8870\u51cf\u8fc7\u7a0b\u53caEl-Sayed\u89c4\u5219\uff0c\u63d0\u51fa\uff1a\u7b80\u5355\u7684\u5206\u5b50\u63cf\u8ff0\u7b26\uff08\u03b3\uff0c\u03b2\uff09\u53ef\u4ee5\u6709\u6548\u8868\u5f81\u6709\u673a\u6750\u6599\u7684RTP\u3002\u4ed6\u4eec\u4f7f\u7528QM\/MM\u65b9\u6cd5\uff0c\u9009\u62e9\u8bf8\u591a\u4e0d\u540c\u7c7b\u578b\u7684\u6709\u673aRTP\u6750\u6599\u5206\u5b50\uff0c\u8fdb\u884c\u591a\u4e2a\u4f4e\u6fc0\u53d1\u6001\u6027\u8d28\u548c\u65cb\u8f68\u8026\u5408\u7cfb\u6570\u7684\u5927\u91cf\u8ba1\u7b97\uff0c\u5e76\u5c06\u8fd9\u4e9b\u4e0e\u5b9e\u9a8c\u78f7\u5149\u6548\u7387\u548c\u5bff\u547d\u76f8\u5173\u8054\u3002\u7136\u540e\uff0c\u7ed9\u51fa\u5206\u5b50\u63cf\u8ff0\u7b26\uff08\u03b3\uff0c\u03b2\uff09\u4e0e\u78f7\u5149\u6548\u7387\u548c\u5bff\u547d\u4e4b\u95f4\u7684\u4f9d\u5b58\u5173\u7cfb\u3002\u6b63\u5982\u9884\u671f\uff0c\u7406\u6027\u8bbe\u8ba1\u542b\u6709n\/\u03c0-\u57fa\u56e2\u7684\u6709\u673a\u5316\u5408\u7269\u4e2d\uff0c\u589e\u5927\u03b3\u548c\u03b2\u503c\u4f1a\u4f7f\u5f97\u6709\u673aRTP\u5206\u5b50\u540c\u65f6\u517c\u5177\u9ad8\u6548\u7387\u548c\u957f\u5bff\u547d\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/jacs.8b11224\"> Efficient and Long-lived Room Temperature Organic Phosphorescence: Theoretical Descriptors for Molecular Designs <\/a>(Journal of the American Chemical Society 2018, DOI: 10.1021\/jacs.8b11224)<\/p>\n<p>\u4f5c\u8005\u7b80\u4ecb\uff1a<\/p>\n<p>\u5e05\u5fd7\u521a\uff1a<\/p>\n<p>\u6e05\u534e\u5927\u5b66\u767e\u4eba\u8ba1\u5212\u3001\u957f\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\u3002\u4ece\u4e8b\u7406\u8bba\u8ba1\u7b97\u5316\u5b66\u7814\u7a76, \u9488\u5bf9\u590d\u6742\u529f\u80fd\u6750\u6599\u7684\u7535\u5b50\u6fc0\u53d1\u6001\u7684\u7ed3\u6784\u4e0e\u52a8\u6001\u8fc7\u7a0b\u53d1\u5c55\u4e86\u5bc6\u5ea6\u77e9\u9635\u91cd\u6b63\u5316\u7fa4\u3001\u70ed\u632f\u52a8\u5173\u8054\u51fd\u6570\u4ee5\u53ca\u8026\u5408\u7c07\u8fd0\u52a8\u65b9\u7a0b\u7b49\u8ba1\u7b97\u65b9\u6cd5, \u5e76\u5e94\u7528\u4e8e\u5171\u8f6d\u805a\u5408\u7269\u548c\u5206\u5b50\u805a\u96c6\u4f53\u7684\u53d1\u5149\u73b0\u8c61; \u63d0\u51fa\u4e86\u6709\u673a\u534a\u5bfc\u4f53\u4e2d\u8f7d\u6d41\u5b50\u4f20\u8f93\u7684\u91cf\u5b50\u6838\u96a7\u7a7f\u6a21\u578b; \u6240\u5f00\u53d1\u7684\u8ba1\u7b97\u5316\u5b66\u8f6f\u4ef6MOMAP\u5f97\u5230\u4e86\u8f83\u5e7f\u6cdb\u7684\u5e94\u7528\u5e76\u5b9e\u73b0\u4e86\u5546\u4e1a\u5316\u30022004\u5e74\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\uff1b2006\u5e74\u56fd\u5bb6\u4eba\u4e8b\u90e8\u7b497\u90e8\u59d4\u201c\u65b0\u4e16\u7eaa\u767e\u5343\u4e07\u4eba\u624d\u56fd\u5bb6\u7ea7\u4eba\u9009\u201d\uff1b2008\u5e74\u5f53\u9009\u4e3a\u56fd\u9645\u91cf\u5b50\u5206\u5b50\u79d1\u5b66\u9662\u9662\u58eb\uff1b2011\u5e74\u5f53\u9009\u4e3a\u6b27\u6d32\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb\uff1b2013\u5e74\u5f53\u9009\u4e3a\u6bd4\u5229\u65f6\u7687\u5bb6\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb\uff1b2018\u5e74\u5f53\u9009\u4e3a\u56fd\u9645\u91cf\u5b50\u5206\u5b50\u79d1\u5b66\u9662\u526f\u9662\u957f, 2015~2018\u5e74\u4efb\u4e2d\u56fd\u5316\u5b66\u4f1a\u7406\u8bba\u5316\u5b66\u59d4\u5458\u4f1a\u4e3b\u4efb\u3002<\/p>\n<p>\u4efbJournal of Materials Chemistry A\u3001\u300a\u5316\u5b66\u5b66\u62a5\u300b\u3001\u300a\u5927\u5b66\u5316\u5b66\u300b\u7b49\u6742\u5fd7\u7684\u526f\u4e3b\u7f16\u3002<\/p>\n<p>\u5f6d\u8c26<\/p>\n<p>\u5f6d\u8c26\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u526f\u7814\u7a76\u5458\u3002\u7814\u7a76\u65b9\u5411\uff1a\u590d\u6742\u4f53\u7cfb\u7684\u5206\u5b50\u6fc0\u53d1\u6001\u52a8\u529b\u5b66\u7406\u8bba\u7684\u53d1\u5c55\u548c\u8f6f\u4ef6\u5f00\u53d1\uff1b\u6709\u673a\u5149\u7535\u9886\u57df\u65b0\u73b0\u8c61\u548c\u65b0\u673a\u5236\u7684\u7406\u8bba\u7814\u7a76\u548c\u6750\u6599\u8bbe\u8ba1\u3002\u5728\u6709\u673a\u53d1\u5149\u6750\u6599\u6fc0\u53d1\u6001\u8fc7\u7a0b\u7684\u7406\u8bba\u8ba1\u7b97\u65b9\u6cd5\u3001\u6027\u80fd\u9884\u6d4b\u548c\u5206\u5b50\u8bbe\u8ba1\u7b49\u65b9\u9762\u5f62\u6210\u4e86\u72ec\u5177\u7279\u8272\u7684\u201c\u7406\u8bba\u9884\u6d4b\u2192\u5206\u5b50\u8bbe\u8ba1\u2192\u5b9e\u9a8c\u5408\u6210\u201d\u7684\u7814\u7a76\u6a21\u5f0f\uff0c\u53d6\u5f97\u4e86\u7cfb\u5217\u539f\u521b\u6027\u6210\u679c\uff1a\u53d1\u5c55\u4e86\u591a\u6a21\u8026\u5408\u6fc0\u53d1\u6001\u901f\u7387\u7406\u8bba\uff0c\u5f00\u53d1\u4e86\u5149\u7269\u7406\u6027\u80fd\u9884\u6d4b\u7a0b\u5e8f\u5305\uff1b\u9996\u6b21\u5b9e\u73b0\u4e86\u590d\u6742\u4f53\u7cfb\u53d1\u5149\u91cf\u5b50\u6548\u7387\u7684\u5b9a\u91cf\u9884\u6d4b\uff0c\u9610\u8ff0\u201c\u65e0\u8f90\u5c04\u8dc3\u8fc1\u53d7\u963b\u201d\u7684AIE\u673a\u7406\uff1b\u7406\u8bba\u8bbe\u8ba1\u4e86\u591a\u79cdOLED\u8367\u5149\u3001\u91d1\u5c5e\u914d\u5408\u7269\u78f7\u5149\u3001\u7eaf\u6709\u673a\u957f\u5bff\u547d\u5ba4\u6e29\u78f7\u5149\u3001\u53cc\u78f7\u5149\u767d\u5149\u53ca\u5149\u523a\u6fc0\u54cd\u5e94\u7b49\u6709\u673a\u53d1\u5149\u6750\u6599\u3002\u5171\u53d1\u8868\u8bba\u6587129\u7bc7\uff0c\u5305\u62ecPhys. Reports\u3001J Am. Chem. Soc.\u3001Nat. Commun.\u3001Angew. Chem. Int. Ed.\u7b49\uff0c\u7814\u7a76\u6210\u679c\u76f8\u7ee7\u88abC&amp;Ens\u7b49\u7f51\u7ad9\u4eae\u70b9\u62a5\u9053\u30022013\u5e74\u83b7\u4e2d\u56fd\u5316\u5b66\u4f1a\u5510\u6556\u5e86\u7406\u8bba\u5316\u5b66\u9752\u5e74\u5956\u3002<\/p>\n<p>&nbsp;<\/p>\n<p>\u4f5c\u8005\u5173\u4e8e\u7eaf\u6709\u673a\u5ba4\u6e29\u78f7\u5149\u7684\u76f8\u5173\u7814\u7a76\u5de5\u4f5c<\/p>\n<ol>\n<li>Weijun Zhao#, Zikai He#*, Qian Peng*, Jacky W.Y. Lam, Huili Ma, Zijie Qiu, Yuncong Chen, Zheng Zhao, Zhigang Shuai, Yongqiang Dong*, BenZhong Tang*, Highly sensitive switching of solid-state luminescence by controlling intersystem crossing, Nat. Commun. 2018, 9, 3044.<\/li>\n<li>Yu Xiong#, Zheng Zhao#,Weijun Zhao, Huili Ma, Qian Peng*, Zikai He, Xuepeng Zhang, Yuncong Chen, Xuewen He, Jacky W. Y. Lam, and Ben Zhong Tang*, Designing Efficient and Ultralong Pure Organic Room-Temperature Phosphorescent Materials by Structural Isomerism, Angew. Chem. Int. Ed. 2018, 57, 7997-8001.<\/li>\n<li>Cai, H. Shi, D. Tian, H. Ma, Z. Cheng, Q. Wu, M. Gu, L. Huang, Z. An*, Q. Peng*, W. Huang*, Enhancing Ultralong Organic Phosphorescence by Effective \u03c0-Type Halogen Bonding. Adv. Funct. Mater. 2018, 1705045.<\/li>\n<li>Zikai He, Weijun Zhao, Jacky W. Y. Lam, Qian Peng*, Huili Ma, Guodong Liang, Zhigang Shuai &amp; Ben Zhong Tang*, White Light Emission from a Single Organic Molecule with Dual Phosphorescence at Room Temperature, Nat. Commun., 2017, 8, 416.<\/li>\n<li>Weijun Zhao, Zikai He, Jacky W. Y. Lam, Qian Peng*, Huili Ma, Zhigang Shuai. Gongxun Bai, Jianhua Hao, Benzhong Tang*, Rational Molecular Design for Achieving Persistent and Efficient Pure Organic Room-Temperature Phosphorescence Chem., 2016, 1, 592-602;<\/li>\n<li>Huili Ma, Wen Shi, Jiajun Ren, Wenqiang Li, Qian Peng*, Zhigang Shuai*, Electrostatic Interaction-Induced Room-Temperature Phosphorescence in Pure Organic Molecules from QM\/MM Calculations, J. Phys. Chem. Lett. 2016, 7, 2893-2898.<\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u8ba1\u7b97\u6750\u6599\u7ec4Annay\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c<a href=\"mailto:\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\">\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n<p><strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong><strong>cailiaokefu<\/strong><strong>\u3002<\/strong><\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u957f\u4f59\u8f89\u6709\u673a\u5ba4\u6e29\u78f7\u5149\uff08RTP\uff09\u6750\u6599\u7531\u4e8e\u5728\u751f\u7269\u6210\u50cf\u3001\u6570\u5b57\u52a0\u5bc6\u548c\u5149\u7535\u5668\u4ef6\u7b49\u65b9\u9762\u5177\u6709\u6f5c\u5728\u7684\u5e94\u7528\u800c\u5907\u53d7\u5173\u6ce8\u3002\u7531\u4e8e\u7eaf\u6709\u673a\u5206\u5b50\u7684\u65cb\u8f68\u8026\u5408\u6bd4\u8f83\u5f31\u548c\u4e09\u7ebf\u6001\u5bf9\u6e29\u5ea6\u548c\u6c27\u6c14\u9ad8&#8230;<\/p>\n","protected":false},"author":5415,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[2865,3499,97],"class_list":["post-163501","post","type-post","status-publish","format-standard","hentry","category-keji","tag-2865","tag-3499","tag-computation"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163501"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/5415"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=163501"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163501\/revisions"}],"predecessor-version":[{"id":163680,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/163501\/revisions\/163680"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=163501"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=163501"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=163501"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}