{"id":162934,"date":"2018-12-31T06:07:21","date_gmt":"2018-12-30T22:07:21","guid":{"rendered":"\/\/m.iemloyee.com\/?p=162934"},"modified":"2018-12-30T21:08:09","modified_gmt":"2018-12-30T13:08:09","slug":"%e6%a2%b3%e7%90%86%ef%bc%9a2018%e5%b9%b4%e7%a2%b3%e5%9f%baorr%e5%82%ac%e5%8c%96%e5%89%82%e7%83%ad%e7%82%b9%e7%a0%94%e7%a9%b6%e8%bf%9b%e5%b1%95%e6%b1%87%e6%80%bb","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=162934","title":{"rendered":"\u68b3\u7406\uff1a2018\u5e74\u78b3\u57faORR\u50ac\u5316\u5242\u70ed\u70b9\u7814\u7a76\u8fdb\u5c55\u6c47\u603b"},"content":{"rendered":"<p>\u6c27\u8fd8\u539f\u53cd\u5e94\uff08Oxygen Reduction Reaction\uff0cORR\uff09\u662f\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u4ee5\u53ca\u71c3\u6599\u7535\u6c60\u5b9e\u73b0\u80fd\u6e90\u8f6c\u5316\u7684\u91cd\u8981\u53cd\u5e94\u3002\u6c27\u6c14\u7ecf\u8fc7\u4e8c\u7535\u5b50\u8fc7\u7a0b\u5f62\u6210\u8fc7\u6c27\u5316\u7269\u6216\u7ecf\u8fc7\u56db\u7535\u5b50\u8fc7\u7a0b\u5f62\u6210\u6c34\u5b8c\u6210\u7535\u5b50\u8f6c\u79fb\u3002\u6c27\u8fd8\u539f\u53cd\u5e94\u8def\u5f84\u8f83\u590d\u6742\uff0c\u4e2d\u95f4\u4f53\u751f\u6210\u8f83\u591a\uff0c\u53cd\u5e94\u6d3b\u5316\u80fd\u8f83\u9ad8\uff0c\u672c\u5f81\u52a8\u529b\u5b66\u901f\u7387\u7f13\u6162\uff0c\u56e0\u800c\u6c27\u8fd8\u539f\u53cd\u5e94\u6548\u7387\u6210\u4e3a\u9650\u5236\u4e24\u7c7b\u5668\u4ef6\u6027\u80fd\u7684\u5173\u952e\u56e0\u7d20\u3002\u4f20\u7edf\u7684\u94c2\u3001\u94c2\u5408\u91d1\u4ee5\u53ca\u5176\u4ed6\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u5177\u6709\u826f\u597d\u7684\u6c27\u8fd8\u539f\u50ac\u5316\u6d3b\u6027\u4f46\u6210\u672c\u9ad8\u6602\u3001\u50a8\u91cf\u7a00\u7f3a\uff0c\u4e14\u5728\u5de5\u4f5c\u73af\u5883\u4e2d\u6613\u53d1\u751f\u6bd2\u5316\u73b0\u8c61\uff08\u5982\u53d7\u5230\u7532\u9187\u3001CO\u5f71\u54cd\uff09\uff0c\u4ece\u800c\u4f7f\u5176\u89c4\u6a21\u5316\u5e94\u7528\u53d7\u5230\u9650\u5236\uff0c\u4ece\u6210\u672c\u548c\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u89d2\u5ea6\u6765\u770b\uff0c\u53d1\u5c55\u9ad8\u6027\u80fd\uff08\u517c\u5177\u9ad8\u6d3b\u6027\u548c\u9ad8\u7a33\u5b9a\u6027\uff09\u3001\u4f4e\u6210\u672c\u7684\u6c27\u8fd8\u539f\u7535\u50ac\u5316\u5242\u662f\u63a8\u52a8\u71c3\u6599\u7535\u6c60\u4ee5\u53ca\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u53d1\u5c55\u7684\u91cd\u8981\u65b9\u5411\u4e4b\u4e00\u3002\u5176\u4e2d\u78b3\u57fa\u50ac\u5316\u5242\u79cd\u7c7b\u4e30\u5bcc\uff0c\u884d\u751f\u6750\u6599\u591a\u6837\uff0c\u53d7\u5230\u4e86\u76f8\u5f53\u5e7f\u6cdb\u7684\u7814\u7a76\u3002<\/p>\n<p>2018\u5e74\uff0c\u79d1\u7814\u5de5\u4f5c\u8005\u5728\u78b3\u57fa\u6c27\u8fd8\u539f\u7535\u50ac\u5316\u5242\u9886\u57df\u6301\u7eed\u53d6\u5f97\u8fdb\u5c55\u3002\u672c\u6587\u64b7\u53d6\u90e8\u5206\u56fd\u5185\u5916\u8be5\u9886\u57df\u70ed\u70b9\u6587\u732e\uff0c\u7814\u7a76\u5305\u542b\u78b3\u57fa\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\u3001\u5355\u539f\u5b50\/\u53cc\u539f\u5b50\u91d1\u5c5e-\u6c2e-\u78b3\u6750\u6599\u3001\u78b3\u57fa\u975e\u91d1\u5c5e\u50ac\u5316\u6750\u6599\u7b49\u4e3b\u8981\u65b9\u9762\u3002\u5e0c\u671b\u5bf9\u4ece\u4e8b\u76f8\u5173\u6750\u6599\u5f00\u53d1\u7684\u7814\u7a76\u8005\u6709\u6240\u542f\u53d1\u3002<\/p>\n<p><strong>1.\u78b3\u57fa\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269<\/strong><\/p>\n<p>\uff081\uff09\u78f7\u5316\u94dc\u7eb3\u7c73\u9897\u7c92<\/p>\n<p>\u91d1\u5c5e-\u6709\u673a\u9aa8\u67b6(MOF)\u662f\u8fd1\u5e74\u6765\u53d1\u5c55\u8d77\u6765\u7684\u4e00\u79cd\u5316\u5b66\u53cd\u5e94\u524d\u9a71\u4f53\u548c\u9ad8\u6548\u7684\u81ea\u727a\u7272\u6a21\u677f\uff0c2\u6708\uff0c\u90d1\u5dde\u5927\u5b66\u81e7\u53cc\u5168\u56e2\u961f\u5229\u7528\u7528\u4e8e\u5236\u5907\u5c42\u72b6\u591a\u5b54\u78b3\u7eb3\u7c73\u7ed3\u6784\u529f\u80fd\u6750\u6599\u3002\u56e2\u961f\u4ee5\u542b\u6c2e\u6742\u539f\u5b50\u548c\u78f7\u6742\u539f\u5b50\u7684\u94dc\u57faMOF(Cu-NPMOF)\u4e3a\u524d\u9a71\u4f53\uff0c\u4ee5Cu-NPMOF\u4e3a\u6a21\u677f\uff0c\u5236\u5907\u4e86N\uff0cP\u5171\u63ba\u6742\u78b3\u58f3\u5305\u8986\u7684\u65b0\u578bCu<sub>3<\/sub>P\u7eb3\u7c73\u7c92\u5b50(NPs)\uff0c\u8fdb\u4e00\u6b65\u5236\u5907\u4e86\u6c2e\u78f7\u53cc\u63ba\u6742(Cu3P@NPPC)\u7684\u591a\u5b54\u78b3\u57fa\u7535\u50ac\u5316\u5242\u3002Cu<sub>3<\/sub>P@NPPC\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\uff0c\u540c\u65f6\u5f97\u76ca\u4e8eCu<sub>3<\/sub>P NPs\u5c55\u73b0\u51fa\u534f\u540c\u6548\u5e94\uff0c\u6750\u6599\u5728\u6c27\u8fd8\u539f\u53cd\u5e94\u4e2d\u663e\u793a\u51fa\u4f18\u5f02\u7684\u6d3b\u6027\u3002<\/p>\n<p>\u56fe1.Cu<sub>3<\/sub>P@NPPC\u6750\u6599\u5236\u5907\u56fe\u793a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162935 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72476-16.png\" alt=\"\" width=\"600\" height=\"388\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72476-16.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72476-16-300x194.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe2.\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162936 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72477-16.png\" alt=\"\" width=\"600\" height=\"478\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72477-16.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72477-16-300x239.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<em><i>Adv.Mater.<\/i><\/em>2018, 30, 1703711<\/p>\n<p>\uff082\uff09\u6c34\u51dd\u80f6\u57fa\u954d\/\u6c27\u5316\u9530<\/p>\n<p>\u6c27\u8fd8\u539f\u50ac\u5316\u5242\u4e0e\u6790\u6c27\u53cd\u5e94\u50ac\u5316\u5242\u5bf9\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u6027\u80fd\u6709\u91cd\u8981\u5f71\u54cd\u3002\u94c2\u5408\u91d1\u5e38\u7528\u4f5c\u6c27\u8fd8\u539f\u50ac\u5316\u5242\uff0cIr\/RuO<sub>2<\/sub>\u5e38\u7528\u4f5c\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u50ac\u5316\u5242\u30022\u6708\uff0c\u5357\u4eac\u5e08\u8303\u5927\u5b66\u5510\u4e9a\u6587\u56e2\u961f\u901a\u8fc7\u7b80\u5355\u6613\u884c\u7684\u6c34\u51dd\u80f6\u6cd5\u5236\u5907\u4e86\u4e09\u7ef4\u591a\u5b54\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\u8d1f\u8f7dNi\/MnO(Ni-MnO\/rGO\u6c14\u51dd\u80f6)\u53cc\u529f\u80fd\u50ac\u5316\u5242\uff0c\u6210\u679c\u53d1\u8868\u4e8eAdvanced Materials\u3002\u6c34\u51dd\u80f6\u5141\u8bb8\u5728\u70ed\u89e3\u4e4b\u540e\u9ad8\u6548\u5730\u6355\u83b7\u9ad8\u6d3b\u6027\u7684Ni\/MnO\u9897\u7c92\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u6240\u5f97\u5230\u7684Ni-MnO\/rGO\u6c14\u51dd\u80f6\u5728\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u5bf9ORR\u548cOER\u90fd\u8868\u73b0\u51fa\u4e0e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u53ef\u6bd4\u7684\u4f18\u5f02\u7684\u53cc\u529f\u80fd\u50ac\u5316\u6027\u80fd\u3002MnO\u5bf9ORR\u7684\u9ad8\u6d3b\u6027\u8d77\u4e3b\u8981\u4f5c\u7528\uff0c\u800c\u91d1\u5c5eNi\u5bf9OER\u7684\u6d3b\u6027\u8d77\u4e3b\u8981\u4f5c\u7528\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u53cc\u529f\u80fd\u50ac\u5316\u5242\u6bd4\u6df7\u5408Pt\/C+RuO2\u50ac\u5316\u5242\u5177\u6709\u66f4\u597d\u7684\u529f\u7387\u5bc6\u5ea6\u3001\u6bd4\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u8bc1\u660e\u4e86\u5176\u5e94\u7528\u4e8e\u53ef\u5145\u7535\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u7684\u6f5c\u5728\u53ef\u884c\u6027\u3002<\/p>\n<p>\u56fe3.\u6750\u6599\u5236\u5907\u6d41\u7a0b\u4ee5\u53ca\u6d3b\u6027\u4f4d\u70b9\u56fe\u793a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162937 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72478-14.png\" alt=\"\" width=\"600\" height=\"379\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72478-14.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72478-14-300x190.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe4.\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162938 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72479-11.png\" alt=\"\" width=\"600\" height=\"461\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72479-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u72479-11-300x231.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<em><i>Adv.Mater.<\/i><\/em>2018, 30, 1704609<\/p>\n<p>\uff083\uff09 \u94b4\u7eb3\u7c73\u9897\u7c92<\/p>\n<p>8\u6708\uff0c\u4e2d\u4f5b\u7f57\u91cc\u8fbe\u5927\u5b66\u6768\u9633\u6559\u6388\u56e2\u961f\u5f00\u53d1\u4e86\u4e00\u79cd\u517c\u5177\u4ea7\u6c27\uff08OER\uff09\u4e0e\u6c27\u8fd8\u539f\uff08ORR\uff09\u50ac\u5316\u6d3b\u6027\u7684\u53cc\u529f\u80fd\u94b4\u786b\u63ba\u6742\u7684\u591a\u5b54\u6c2e\u5316\u78b3\/\u77f3\u58a8\u70ef\u6750\u6599\uff08CoS<sub>x<\/sub>@-PCN\/rGO\uff09\uff0c\u6210\u679c\u53d1\u8868\u4e8eAdvan ced Energy Materials\u3002\u56e2\u961f\u4f7f\u7528\u4e09\u805a\u6c30\u80fa\u4e3a\u539f\u6599\uff0c\u7ecf\u94b4\u79bb\u5b50\u914d\u5408\u540e\uff0c\u5728\u7a7a\u6c14\u4e2d\u4e0e\u6c27\u6c14\u53cd\u5e94\u53d1\u751f\u53cd\u5e94\u805a\u5408\u5f62\u6210\u94b4\u63ba\u6742\u7684\u591a\u5b54\u6c2e\/\u78b3\u6750\u6599\uff1b\u4e4b\u540e\uff0c\u6750\u6599\u5728\u6c2e\u6c14\u73af\u5883\u4e0b\u4e0e\u786b\u78fa\u3001\u6c27\u5316\u77f3\u58a8\u70ef\u4f5c\u7528\uff0c\u6700\u7ec8\u5f97\u5230CoS<sub>x<\/sub>@-PCN\/rGO\u6750\u6599\u3002\u77f3\u58a8\u70ef\u7684\u5f15\u5165\u589e\u5f3a\u4e86\u6750\u6599\u7684\u7535\u5b50\u4f20\u8f93\u6027\u80fd\uff0c\u800c\u591a\u5b54\u78b3\u7ed3\u6784\u589e\u6dfb\u4e86\u66f4\u591a\u50ac\u5316\u6d3b\u6027\u5fae\u5e97\u3002\u6700\u7ec8\uff0c\u6750\u6599\u5c55\u73b0\u51fa\u4f18\u4e8e\u5546\u7528\u94c2\u3001RuO<sub>2<\/sub>\u50ac\u5316\u5242\u4ee5\u53ca\u5176\u4ed6\u78b3\u6c2e\u5316\u7269\u7684\u50ac\u5316\u6d3b\u6027\u4e0e\u7a33\u5b9a\u6027\u3002\u540c\u65f6\uff0c\u7531\u6b64\u6750\u6599\u6784\u6210\u7684\u950c-\u7a7a\u6c14\u7535\u6781\u6750\u6599\u6709\u7740\u66f4\u4f18\u7684\u5145\u7535\u6027\u80fd\u3002<\/p>\n<p>\u56fe5.CoS<sub>x<\/sub>@-PCN\/rGO\u6750\u6599\u5236\u5907\u8fc7\u7a0b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162939 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724710-11.png\" alt=\"\" width=\"600\" height=\"106\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724710-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724710-11-300x53.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe6.CoS<sub>x<\/sub>@-PCN\/rGO\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162940 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724711-10.png\" alt=\"\" width=\"600\" height=\"590\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724711-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724711-10-300x295.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<em><i>Adv. Energy Mater.<\/i><\/em>2018, 8, 1701642<\/p>\n<p><strong>2.\u91d1\u5c5e-\u6c2e-\u78b3\u6750\u6599<\/strong><\/p>\n<p>\uff081\uff09\u5355\u539f\u5b50\u94b4<\/p>\n<p>1\u6708\uff0c\u51ef\u65af\u897f\u50a8\u5927\u5b66\u6234\u9ece\u660e\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u7c7b\u65b0\u578b\u94b4\u63ba\u6742\u7684\u91d1\u5c5e-\u6c2e-\u78b3\u6750\u6599(C-MOF-C2-T)\uff0c\u56e2\u961f\u5229\u7528MOF\u4f5c\u524d\u9a71\u4f53\uff0c\u5bf9\u6750\u6599\u7ed3\u6784\u8fdb\u884c\u4e86\u7cbe\u7ec6\u8bbe\u8ba1\uff0c\u6210\u679c\u53d1\u8868\u4e8eAdvanced Materials\u3002\u65b0\u7814\u5236\u7684C-MOF-C2-900\u5177\u6709\u72ec\u7279\u7684\u4e09\u7ef4\u5206\u7ea7\u68d2\u72b6\u7ed3\u6784\uff0c\u7531\u6cbf\u68d2\u957f\u7684\u90e8\u5206\u77f3\u58a8\u5316\u6c2e\u63ba\u6742\u78b3\u73af\u5305\u8986\u7684\u5747\u5300\u5206\u5e03\u7684\u94b4\u7eb3\u7c73\u9897\u7c92\u7ec4\u6210\u3002\u4e0e\u94b4\u76f8\u6bd4\uff0cCo@N-C\u5177\u6709\u66f4\u9ad8\u7684\u6c27\u8fd8\u539f\u548c\u4ea7\u6c27\u53cd\u5e94\u7684\u7535\u50ac\u5316\u6d3b\u6027(ORR\u548cOER)\u3002\u57fa\u4e8eC-MOF-900\u7684\u6c27\u8fd8\u539f\u53cd\u5e94(ORR)\u521d\u7ea7\u950c\u7a7a\u6c14\u7535\u6c60\uff0c\u653e\u7535\u7535\u4f4d\u4e3a1.30V\uff0c\u6bd4\u5bb9\u91cf\u4e3a741mA h g(Zn)<sup>-1<\/sup>\uff0810mA cm<sup>-2<\/sup>\uff09\u3002\u4ee5C-MOF-C2-900\u4e3aORR\u548cOER\u53cc\u529f\u80fd\u50ac\u5316\u5242\u7684\u53ef\u5145\u7535\u950c-\u7a7a\u6c14\u7535\u6c60\u5728\u5c55\u73b0\u51fa\u826f\u597d\u7684\u521d\u59cb\u5145\u653e\u7535\u7535\u4f4d\uff0c\u4e14\u5728120\u5c0f\u65f6\u540e\u4ecd\u5177\u6709\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u4e14\u6781\u5316\u7a0b\u5ea6\u6ca1\u6709\u589e\u52a0\uff0c\u4f18\u4e8e\u57fa\u4e8e\u8d35\u91d1\u5c5e\u7a7a\u6c14\u7535\u6781\u3002\u7531\u6b64\u6750\u6599\u5f97\u5230\u7684\u53ef\u5145\u7535\u950c\u7a7a\u6c14\u7535\u6c60\u53ef\u4ee5\u6709\u6548\u5730\u4e3a\u7535\u5316\u5b66\u6c34\u5206\u79bb\u7cfb\u7edf\u4f9b\u7535\uff0c\u5c55\u73b0\u51fa\u5b9e\u9645\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<p>\u56fe15.Co@N-C\u6750\u6599\u5206\u7ea7\u7ed3\u6784\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162949 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724720-5.png\" alt=\"\" width=\"600\" height=\"572\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724720-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724720-5-300x286.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe16.Co@N-C\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162950 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724721-5.png\" alt=\"\" width=\"600\" height=\"803\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724721-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724721-5-224x300.png 224w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5<em><i>Adv.Mater.<\/i><\/em>2018, 30, 1705431<\/p>\n<p>\uff082\uff09\u5355\u539f\u5b50\u94b4<\/p>\n<p>5\u6708\uff0c\u7ebd\u7ea6\u5dde\u7acb\u5927\u5b66\u5e03\u6cd5\u7f57\u5206\u6821\u7684\u6b66\u521a\u6559\u6388\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u6c2e\u914d\u4f4d\u7684\u5355\u539f\u5b50\u94b4\u78b3\u57fa\u50ac\u5316\u5242\u3002\u94c1\u7684Fenton\u6548\u5e94\u4ee5\u53ca\u70ed\u5904\u7406\u8fc7\u7a0b\u4e2d\u7684\u56e2\u805a\u95ee\u9898\u56f0\u6270\u4e86\u94c1\u57fa\u91d1\u5c5e-\u6c2e-\u78b3\u6750\u6599\u5236\u5907\u4e0e\u5e94\u7528\uff0c\u7535\u6781\u4e2d\u94c1\u81ea\u7531\u57fa\u3001\u8fc7\u6c27\u5316\u7269\u7684\u5b58\u5728\u6709\u53ef\u80fd\u5bfc\u81f4\u6709\u673a\u8d28\u5b50\u4ea4\u6362\u819c\u964d\u89e3\u3002\u56e0\u6b64\uff0c\u65e0\u94c2\u548c\u65e0\u94c1\u9634\u6781\u50ac\u5316\u5242\u662f\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60(PEMFC)\u7684\u91cd\u70b9\u7814\u7a76\u65b9\u5411\u3002\u56e2\u961f\u5229\u7528\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u524d\u9a71\u4f53\uff0c\u7ecf\u8fc7\u4e00\u6b65\u70ed\u5316\u5b66\u53cd\u5e94\u591f\u9020\u4e86\u4e00\u79cd\u542bCo-N<sub>4<\/sub>\u6d3b\u6027\u4f4d\u70b9\u7684\u50ac\u5316\u6750\u6599\u3002\u50cf\u5dee\u6821\u6b63\u7535\u5b50\u663e\u5fae\u6280\u672f\u7ed3\u5408X\u5c04\u7ebf\u5438\u6536\u5149\u8c31\u5b66\u5b9e\u9645\u4e0a\u8bc1\u5b9e\u4e86Co-N<sub>4<\/sub>\u6d3b\u6027\u4f4d\u70b9\u7684\u5b58\u5728\u3002\u540c\u65f6\uff0c\u5747\u5300\u5206\u6563\u7684\u6d3b\u6027\u4f4d\u70b9\u5927\u5927\u589e\u5f3a\u4e86\u6750\u6599\u7684\u50ac\u5316\u6d3b\u6027\u3002\u6700\u7ec8\u5f97\u5230\u4e86\u6027\u80fd\u4e0eFe-N\/C\u6750\u6599\u3001\u5546\u7528\u94c2\u9ed1\u6750\u6599\u53ef\u6bd4\u7684\u94b4\u50ac\u5316\u6750\u6599\u3002<\/p>\n<p>\u56fe7.\u50ac\u5316\u6750\u6599\u7ed3\u6784\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162941 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724712-10.png\" alt=\"\" width=\"600\" height=\"420\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724712-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724712-10-300x210.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe8.\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162942 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724713-10.png\" alt=\"\" width=\"600\" height=\"501\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724713-10.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724713-10-300x251.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<em><i>Adv.Mater.<\/i><\/em>2018, 30, 1706758<\/p>\n<p>\uff083\uff09 \u53cc\u539f\u5b50\u94b4<\/p>\n<p>6\u6708\uff0c\u4e2d\u79d1\u9662\u957f\u6625\u6240\u90a2\u5dcd\u8bfe\u9898\u7ec4\u4e8eNano Energy\u62a5\u9053\u4e86\u4e00\u79cd\u53cc\u539f\u5b50\u4e2d\u5fc3\u578b\u78b3\u57fa\u50ac\u5316\u5242\u3002\u8be5\u5de5\u4f5c\u5229\u7528\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4f5c\u4e3a\u524d\u9a71\u4f53\uff0c\u901a\u8fc7\u8c03\u8282\u94b4\u542b\u91cf\uff0c\u7cbe\u51c6\u5236\u5907\u4e86\u53cc\u539f\u5b50\u4e2d\u5fc3\u94b4\u50ac\u5316\u5242\u3002\u7403\u5dee\u6821\u6b63\u7535\u955c\u548c\u6269\u5c55\u7684X-\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u8c31\u8bc1\u5b9e\u4e86\u53cc\u539f\u5b50Co\u4e2d\u5fc3\u6d3b\u6027\u4f4d\u7ed3\u6784\u7684\u5b58\u5728\u3002\u800c\u53cc\u539f\u5b50\u50ac\u5316\u5242\u6d3b\u6027\u76f8\u6bd4\u5355\u539f\u5b50\u63d0\u5347\u4e00\u4e2a\u6570\u91cf\u7ea7\uff0813\u500d\uff09\uff0c\u5e94\u7528\u524d\u666f\u5f97\u4ee5\u6539\u5584\u3002<\/p>\n<p>\u56fe9.\u53cc\u4e2d\u5fc3\u539f\u5b50Co<sub>2<\/sub>N<sub>5<\/sub>\u50ac\u5316\u8fc7\u7a0b\u56fe\u793a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162943 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724714-11.png\" alt=\"\" width=\"600\" height=\"362\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724714-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724714-11-300x181.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe10.\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81\u5bf9\u6bd4<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162944 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724715-11.png\" alt=\"\" width=\"600\" height=\"286\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724715-11.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724715-11-300x143.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5 <em><i>;<\/i><\/em><em><i>Nano Energy<\/i><\/em>, 2018, 46: 396-403<\/p>\n<p>\uff084\uff09\u5355\u539f\u5b50\u94c1<\/p>\n<p>6\u6708\uff0c\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u9662\u58eb\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u786b\u548c\u6c2e\u5171\u63ba\u78b3\uff08Fe-ISA\/SNC\uff09\u6750\u6599\uff0c\u6210\u679c\u53d1\u8868\u4e8eAdvanced Materials\u3002\u6742\u539f\u5b50\u63ba\u6742\u7684Fe-NC\u50ac\u5316\u5242\u662f\u53d6\u4ee3\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u7684\u6700\u6709\u5e94\u7528\u524d\u666f\u7684\u50ac\u5316\u5242\u4e4b\u4e00\u3002\u7136\u800c\uff0c\u5bf9\u5176\u7ed3\u6784\u53c2\u6570\u7684\u7cbe\u7ec6\u63a7\u5236\u4ee5\u4f18\u5316\u50ac\u5316\u6548\u7387\u548c\u5bf9\u50ac\u5316\u673a\u7406\u7684\u5206\u5b50\u6c34\u5e73\u7406\u89e3\u4ecd\u7136\u662f\u5177\u6709\u6311\u6218\u6027\u3002\u56e2\u961f\u521b\u9020\u6027\u8bbe\u8ba1\u51fa\u4e00\u79cd\u65b0\u7684\u5421\u54af-\u567b\u5429\u5171\u805a\u7269\u70ed\u89e3\u5408\u6210\u65b9\u6848\uff0c\u5728\u786b\u548c\u6c2e\u5171\u63ba\u78b3\uff08Fe-ISA\/SNC\uff09\u4e0a\u4ee5\u53ef\u63a7\u7684S\uff0cN\u63ba\u6742\u65b9\u5f0f\u5408\u6210Fe\u5b64\u7acb\u7684\u5355\u539f\u5b50\u4f4d\u70b9\u3002Fe-ISA\/SNC\u7684\u50ac\u5316\u6548\u7387\u968f\u786b\u63ba\u6742\u91cf\u7684\u589e\u52a0\u5448\u706b\u5c71\u578b\u66f2\u7ebf\u53d8\u5316\u3002\u4f18\u5316\u540e\u7684Fe-ISA\/SNC\u534a\u6ce2\u7535\u4f4d\u4e3a0.896V(vs RHE)\uff0c\u76f8\u6bd4\u94c1\u6c2e\u5171\u63ba\u6742\u78b3(Fe-ISA\/NC\uff0c0.839V)\u3001\u5de5\u4e1aPt\/C(0.841V)\u548c\u5927\u591a\u6570\u5176\u4ed6\u94c1\u5355\u539f\u5b50\u975e\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u6709\u66f4\u9ad8\u7684\u534a\u6ce2\u7535\u4f4d\u3002Fe-ISA\/SNC\u6709\u826f\u597d\u7532\u9187\u8010\u53d7\u6027\uff0c\u7ecf\u538615000\u626b\u63cf\u5faa\u73af\uff0c\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u8868\u73b0\u51fa\u53ef\u5ffd\u7565\u7684\u6d3b\u6027\u8870\u51cf\u3002X\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u5206\u6790\u4ee5\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u63ba\u5165\u7684\u786b\u589e\u52a0\u4e86\u73af\u7ed5\u5728\u94c1\u539f\u5b50\u5468\u56f4\u7684\u6c2e\u539f\u5b50\u5904\u7535\u8377\u3002\u5bcc\u96c6\u7684\u7535\u8377\u4fc3\u8fdb\u4e86\u53cd\u5e94\u4e2d\u95f4\u4f53OH*\u7684\u8fd8\u539f\u91ca\u653e\uff0c\u56e0\u6b64\u63d0\u9ad8\u4e86\u603b\u7684ORR\u6548\u7387\u3002<\/p>\n<p>\u56fe11.\u50ac\u5316\u5242\u5236\u5907\u4e0e\u5f62\u8c8c\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162945 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724716-8.png\" alt=\"\" width=\"600\" height=\"605\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724716-8.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724716-8-150x150.png 150w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724716-8-298x300.png 298w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe12.\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162946 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724717-6.png\" alt=\"\" width=\"600\" height=\"608\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724717-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724717-6-296x300.png 296w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aLi\u00a0et al.\/<em><i>Adv.Mater.<\/i><\/em><em><i>\u00a0<\/i><\/em>2018\u00a0(30) 1800588<\/p>\n<p>\uff085\uff09\u5355\u539f\u5b50\u94dc<\/p>\n<p>10\u6708\uff0c\u674e\u4e9a\u680b\u9662\u58eb\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u79cd\u5177\u6709\u5927\u89c4\u6a21\u5236\u5907\u524d\u666f\u7684\u78b3\u57fa\u94dc\u5355\u539f\u5b50\u5206\u6563\u50ac\u5316\u5242\u3002\u5355\u539f\u5b50\u50ac\u5316\u5242\u56e0\u5176\u5728\u4fc3\u8fdb\u5404\u79cd\u50ac\u5316\u53cd\u5e94\u65b9\u9762\u7684\u9ad8\u6548\u6027\u800c\u9887\u53d7\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5408\u6210\u8fd9\u4e9b\u6750\u6599\u7684\u5e38\u7528\u65b9\u6cd5\u901a\u5e38\u9700\u8981\u7e41\u7410\u7684\u6b65\u9aa4\uff0c\u5e76\u4e14\u91d1\u5c5e\u539f\u5b50\u4e0e\u8f7d\u4f53\u4e4b\u95f4\u7f3a\u4e4f\u9002\u5f53\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u56e2\u961f\u521b\u9020\u6027\u5229\u7528\u94dc\u539f\u5b50\u4e0e\u6c28\u6c14\u7684\u8def\u6613\u65af\u9178\u78b1\u76f8\u4e92\u4f5c\u7528\uff0c\u5728\u6c28\u6c14\u73af\u5883\u4e0b\u5c06\u94dc\u539f\u5b50\u5f15\u5165\u5230MOF\u524d\u9a71\u4f53\uff08ZIF-8\uff09\u4e0a\uff0c\u5f97\u5230\u6c2e\u63ba\u6742\u7684\u5355\u539f\u5b50\u5206\u6563\u7684\u94dc\u50ac\u5316\u5242\uff0c\u6210\u679c\u53d1\u8868\u4e8eNature Catalysis\u3002\u6b64\u5de5\u4f5c\u5b9e\u73b0\u4e86\u5355\u539f\u5b50\u5206\u6563\u50ac\u5316\u5242\u7684\u5927\u5c3a\u5ea6\u5236\u5907\uff0c\u540c\u65f6\u6750\u6599\u5c55\u73b0\u51fa\u826f\u597d\u7684\u6c27\u8fd8\u539f\u50ac\u5316\u6d3b\u6027\uff0c\u57285000\u6b21CV\u626b\u63cf\u540e\u5e76\u672a\u51fa\u73b0\u8f83\u5927\u7684\u7535\u5316\u5b66\u6027\u80fd\u4e0b\u964d\u3002<\/p>\n<p>\u56fe13.\u5355\u539f\u5b50\u5206\u6563\u94dc\u50ac\u5316\u5242\u5408\u6210\u8def\u5f84\u56fe\u793a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162947 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724718-6.png\" alt=\"\" width=\"600\" height=\"434\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724718-6.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724718-6-300x217.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe14.\u5355\u539f\u5b50\u5206\u6563\u94dc\u50ac\u5316\u5242\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162948 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724719-5.png\" alt=\"\" width=\"600\" height=\"476\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724719-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724719-5-300x238.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aYunteng Qu et al.\u00a0\/<em><i>Nature Catalysis<\/i><\/em>\u00a02018 (1) 781\u2013786<\/p>\n<p>\uff086\uff09\u5355\u539f\u5b50\u94b4<\/p>\n<p>1\u6708\uff0c\u51ef\u65af\u897f\u50a8\u5927\u5b66\u6234\u9ece\u660e\u56e2\u961f\u62a5\u9053\u4e86\u4e00\u7c7b\u65b0\u578b\u94b4\u63ba\u6742\u7684\u91d1\u5c5e-\u6c2e-\u78b3\u6750\u6599(C-MOF-C2-T)\uff0c\u56e2\u961f\u5229\u7528MOF\u4f5c\u524d\u9a71\u4f53\uff0c\u5bf9\u6750\u6599\u7ed3\u6784\u8fdb\u884c\u4e86\u7cbe\u7ec6\u8bbe\u8ba1\uff0c\u6210\u679c\u53d1\u8868\u4e8eAdvanced Materials\u3002\u65b0\u7814\u5236\u7684C-MOF-C2-900\u5177\u6709\u72ec\u7279\u7684\u4e09\u7ef4\u5206\u7ea7\u68d2\u72b6\u7ed3\u6784\uff0c\u7531\u6cbf\u68d2\u957f\u7684\u90e8\u5206\u77f3\u58a8\u5316\u6c2e\u63ba\u6742\u78b3\u73af\u5305\u8986\u7684\u5747\u5300\u5206\u5e03\u7684\u94b4\u7eb3\u7c73\u9897\u7c92\u7ec4\u6210\u3002\u4e0e\u94b4\u76f8\u6bd4\uff0cCo@N-C\u5177\u6709\u66f4\u9ad8\u7684\u6c27\u8fd8\u539f\u548c\u4ea7\u6c27\u53cd\u5e94\u7684\u7535\u50ac\u5316\u6d3b\u6027(ORR\u548cOER)\u3002\u57fa\u4e8eC-MOF-900\u7684\u6c27\u8fd8\u539f\u53cd\u5e94(ORR)\u521d\u7ea7\u950c\u7a7a\u6c14\u7535\u6c60\uff0c\u653e\u7535\u7535\u4f4d\u4e3a1.30V\uff0c\u6bd4\u5bb9\u91cf\u4e3a741mA h g(Zn)<sup>-1<\/sup>\uff0810mA cm<sup>-2<\/sup>\uff09\u3002\u4ee5C-MOF-C2-900\u4e3aORR\u548cOER\u53cc\u529f\u80fd\u50ac\u5316\u5242\u7684\u53ef\u5145\u7535\u950c-\u7a7a\u6c14\u7535\u6c60\u5728\u5c55\u73b0\u51fa\u826f\u597d\u7684\u521d\u59cb\u5145\u653e\u7535\u7535\u4f4d\uff0c\u4e14\u5728120\u5c0f\u65f6\u540e\u4ecd\u5177\u6709\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u4e14\u6781\u5316\u7a0b\u5ea6\u6ca1\u6709\u589e\u52a0\uff0c\u4f18\u4e8e\u57fa\u4e8e\u8d35\u91d1\u5c5e\u7a7a\u6c14\u7535\u6781\u3002\u7531\u6b64\u6750\u6599\u5f97\u5230\u7684\u53ef\u5145\u7535\u950c\u7a7a\u6c14\u7535\u6c60\u53ef\u4ee5\u6709\u6548\u5730\u4e3a\u7535\u5316\u5b66\u6c34\u5206\u79bb\u7cfb\u7edf\u4f9b\u7535\uff0c\u5c55\u73b0\u51fa\u5b9e\u9645\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n<p>\u56fe15.Co@N-C\u6750\u6599\u5206\u7ea7\u7ed3\u6784\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162949 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724720-5.png\" alt=\"\" width=\"600\" height=\"572\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724720-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724720-5-300x286.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe16.Co@N-C\u6750\u6599\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162950 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724721-5.png\" alt=\"\" width=\"600\" height=\"803\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724721-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724721-5-224x300.png 224w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5<em><i>Adv.Mater.<\/i><\/em>2018, 30, 1705431<\/p>\n<p><strong>3.\u975e\u91d1\u5c5e\u50ac\u5316\u5242<\/strong><\/p>\n<p>\uff081\uff09\u4e09\u7ef4\u6c2e\u63ba\u6742\u50ac\u5316\u5242<\/p>\n<p>1\u6708\uff0c\u6e56\u5357\u5927\u5b66\u738b\u53cc\u5370\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u5229\u7528\u5bcc\u7f3a\u9677\u7eb3\u7c73\u7247\u548c\u591a\u9762\u4f53\u539f\u4f4d\u6784\u5efa\u7684\u4e09\u7ef4\u6c2e\u63ba\u6742\u7684\u78b3\u57fa\u7535\u50ac\u5316\u5242\uff0c\u6210\u679c\u53d1\u8868\u4e8eAdvanced Functional Materials\u3002\u56e2\u961f\u901a\u8fc7\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u7684\u9ad8\u6e29\u70ed\u89e3\uff0c\u5728\u76d0\u5c01\u53cd\u5e94\u5668\u4e2d\u539f\u4f4d\u8fde\u63a5\u78b3\u591a\u9762\u4f53\u4e0e\u7eb3\u7c73\u7247\uff0c\u5236\u5907\u4e86\u4e09\u7ef4\u78b3\u7535\u50ac\u5316\u5242\u3002MOF\u5728\u5411\u591a\u9762\u4f53\u7684\u8f6c\u5316\u8fc7\u7a0b\u4e2d\uff0c\u6709\u673a\u7269\u88ab\u9650\u5236\u5728\u76d0\u5c01\u53cd\u5e94\u5668\u4e2d\uff0c\u90e8\u5206\u5206\u89e3\u5e76\u5f62\u6210\u78b3\u7eb3\u7c73\u7247\u3002\u539f\u4f4d\u5f62\u6210\u7684\u78b3\u7eb3\u7c73\u7247\u56f4\u7ed5\u7740\u78b3\u591a\u9762\u4f53\u5f62\u6210\u4e09\u7ef4\u78b3\u7f51\u7edc\u3002\u7531\u4e8e\u9650\u5236\u6548\u5e94\uff0cMOFs\u5728\u76d0\u53cd\u5e94\u5668\u4e2d\u5411\u78b3\u7f51\u7edc\u7684\u8f6c\u5316\u5177\u6709\u9ad8\u4ea7\u7387\uff0c\u800c\u6d3b\u6027\u78b3\u6ca1\u6709\u663e\u8457\u635f\u5931\uff0c\u8fd9\u589e\u5f3a\u4e86\u6750\u6599\u7684\u7535\u5b50\u548c\u8d28\u91cf\u4f20\u8f93\u6027\u80fd\u3002\u6240\u5f97\u6750\u6599\u7f3a\u9677\u4e30\u5bcc\uff0c\u8fd9\u63d0\u4f9b\u4e86\u66f4\u591a\u7535\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u3002\u6750\u6599\u5c55\u73b0\u5904\u826f\u597d\u7684ORR\u50ac\u5316\u6d3b\u6027\uff0c\u751a\u81f3\u4e0ePt\/C\u76f8\u5f53\u3002\u7531\u6b64\u6784\u5efa\u7684\u950c-\u7a7a\u6c14\u7535\u6c60\u4e5f\u5c55\u73b0\u51fa\u826f\u597d\u6027\u80fd\u3002<\/p>\n<p>\u56fe17.NLPC\u6750\u6599\u5236\u5907\u56fe\u793a<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162951 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724722-5.png\" alt=\"\" width=\"600\" height=\"417\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724722-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724722-5-300x209.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe18.NLPC\u6027\u80fd\u8868\u5f81<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162952 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724723-2.png\" alt=\"\" width=\"600\" height=\"670\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724723-2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724723-2-269x300.png 269w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<em><i>Advanced Functional Materials<\/i><\/em>.2018,28,1705356<\/p>\n<p>\uff082\uff09\u6c2e\u63ba\u6742\u591a\u5b54\u78b3<\/p>\n<p>11\u6708\uff0c\u4e2d\u79d1\u9662\u5408\u80a5\u7269\u8d28\u79d1\u5b66\u7814\u7a76\u6240\u8d75\u60e0\u519b\u6559\u6388\u4e0e\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u5510\u667a\u52c7\u6559\u6388\u56e2\u961f\u5408\u4f5c\u62a5\u9053\u4e86\u4e00\u79cd\u8d85\u8584\u7684\u77f3\u58a8\u70ef\u590d\u5408\u7684\u6c2e\u63ba\u6742\u591a\u5b54\u78b3\u6750\u6599\uff0c\u6210\u679c\u53d1\u8868\u4e8eAngewandte Chemie\u3002\u56e2\u961f\u5229\u7528\u6c34\u70ed\u6cd5\u5c06\u6c27\u5316\u77f3\u58a8\u70ef\u4e0e\u8461\u8404\u7cd6\u9178\u950c\u5728\u6c28\u6c34\u7684\u4f5c\u7528\u4e0b\u590d\u5408\uff0c\u5e76\u7ecf\u8fc7\u9ad8\u6e29\u70ed\u5904\u7406\u5b9e\u73b0\u53bb\u9664\u950c\u5f97\u5230\u6c2e\u63ba\u6742\u591a\u5b54\u78b3\u6750\u6599\uff08N-HC@G-x\uff09\u3002\u6750\u6599\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\u5c55\u73b0\u51fa\u826f\u597d\u7684\u6027\u80fd\u4e0e\u7a33\u5b9a\u6027\uff0c\u5728\u9178\u73af\u5883\u4e0b\u7ecf\u8fc7\u591a\u5468\u671f\u7535\u5316\u5b66\u626b\u63cf\u540e\u6027\u80fd\u4ec5\u7565\u6709\u4e0b\u964d\u3002\u77f3\u58a8\u70ef\u589e\u5f3a\u4e86\u4f53\u7cfb\u7684\u7535\u5b50\u4f20\u8f93\u80fd\u529b\uff0c\u8fdb\u800c\u5927\u5e45\u63d0\u9ad8\u591a\u5b54\u78b3\u6750\u6599\u50ac\u5316\u6027\u80fd\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u6750\u6599\u8fd8\u5c55\u73b0\u51fa\u8f83\u597d\u7684\u4ea7\u6c27\uff08OER\uff09\u53cd\u5e94\u6027\u80fd\u3002<\/p>\n<p>\u56fe19.N-HC@G-x\u6750\u6599\u5408\u6210\u8def\u5f84<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162953 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724724-3.png\" alt=\"\" width=\"600\" height=\"166\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724724-3.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724724-3-300x83.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u56fe20.\u6750\u6599\u6027\u80fd\u8868\u5f81\uff0c\u5176\u4e2da\u3001b\u3001c\u56fe\u4e3a\u78b1\u6027\u73af\u5883\u4e0b\u6027\u80fd\uff0cd\u3001e\u3001f\u4e3a\u9178\u73af\u5883\u4e0b\u6027\u80fd<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-162954 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724725-2.png\" alt=\"\" width=\"600\" height=\"747\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724725-2.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/\u56fe\u724725-2-241x300.png 241w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1aHuijun Zhao, Zhiyong Tang \u00a0<em><i>Angew. Chem. Int. Ed. <\/i><\/em>10.1002\/anie.201811573<\/p>\n<p><strong>4.\u5c0f\u7ed3<\/strong><\/p>\n<p>2018\u5e74\uff0c\u79d1\u7814\u5de5\u4f5c\u8005\u5728\u78b3\u57fa\u6c27\u8fd8\u539f\u50ac\u5316\u9886\u57df\u53d6\u5f97\u4e86\u4e30\u5bcc\u7684\u6210\u679c\u3002\u603b\u7684\u6765\u770b\uff0c\u91d1\u5c5e-\u6c2e-\u78b3\u6750\u6599\uff08\u542b\u78b3\u57fa\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\u6750\u6599\uff09\u65b9\u9762\u7814\u7a76\u6700\u4e3a\u5145\u5206\uff0c\u94b4\u3001\u94dc\u3001\u9530\u7684\u78b3\u57fa\u50ac\u5316\u6750\u6599\u5747\u5f97\u5230\u4e86\u76f8\u5f53\u591a\u5173\u6ce8\uff1b\u78b3\u57fa\u7eaf\u975e\u91d1\u5c5e\u50ac\u5316\u5242\u62a5\u9053\u91cf\u6709\u9650\u4f46\u8fdb\u6b65\u5341\u5206\u663e\u8457\uff0c\u90e8\u5206\u6750\u6599\u50ac\u5316\u6027\u80fd\u5df2\u7ecf\u63a5\u8fd1\u5546\u7528Pt\/C\u6750\u6599\u3002\u50ac\u5316\u5242\u7684\u6548\u7387\u63d0\u5347\u3001\u6d3b\u6027\u4f4d\u70b9\u6570\u91cf\u63d0\u5347\u4e0e\u7a33\u5b9a\u6027\u63d0\u5347\u662f\u76ee\u524d\u975e\u8d35\u91d1\u5c5e\u6c27\u8fd8\u539f\u50ac\u5316\u5242\u9700\u8981\u89e3\u51b3\u7684\u4e3b\u8981\u95ee\u9898\u3002\u800c\u50ac\u5316\u5242\u8bbe\u8ba1\u4e0e\u7406\u8bba\u8ba1\u7b97\u76f8\u7ed3\u5408\u662f\u672a\u6765\u7684\u91cd\u8981\u6f5c\u5728\u65b9\u5411\u4e4b\u4e00\u3002<\/p>\n<p>\u672c\u6587\u7531<strong>\u6750\u6599\u4eba\u79d1\u6280\u987e\u95ee\u5434\u540c\u5b66<\/strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7f16\u8f91\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6c27\u8fd8\u539f\u53cd\u5e94\uff08Oxygen Reduction Reaction\uff0cORR\uff09\u662f\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u4ee5\u53ca\u71c3\u6599\u7535\u6c60\u5b9e\u73b0\u80fd\u6e90\u8f6c\u5316\u7684\u91cd\u8981\u53cd\u5e94\u3002\u6c27\u6c14\u7ecf\u8fc7\u4e8c\u7535\u5b50\u8fc7\u7a0b\u5f62\u6210\u8fc7\u6c27\u5316\u7269\u6216\u7ecf\u8fc7&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2810],"tags":[],"class_list":["post-162934","post","type-post","status-publish","format-standard","hentry","category-huizong"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/162934"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=162934"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/162934\/revisions"}],"predecessor-version":[{"id":163482,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/162934\/revisions\/163482"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=162934"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=162934"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=162934"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}