{"id":162597,"date":"2018-12-29T06:30:20","date_gmt":"2018-12-28T22:30:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=162597"},"modified":"2018-12-28T19:56:17","modified_gmt":"2018-12-28T11:56:17","slug":"%e3%80%90%e6%9c%aa%e5%9b%9e%e5%a4%8d%e3%80%91%e6%ae%b5%e9%95%b6%e9%94%8b%e9%bb%84%e6%98%b1%e5%9b%a2%e9%98%9fadv-mater-%ef%bc%9a%e9%ab%98%e6%80%a7%e8%83%bdpt%e5%9f%baorr%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=162597","title":{"rendered":"\u6bb5\u9576\u950b&amp;\u9ec4\u6631\u56e2\u961fAdv. Mater.\uff1a\u9ad8\u6027\u80fdPt\u57faORR\u50ac\u5316\u5242\u7684\u7eb3\u7c73\u7ed3\u6784\u8bbe\u8ba1"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u968f\u7740\u5168\u7403\u4eba\u53e3\u7684\u589e\u957f\u548c\u80fd\u6e90\u9700\u6c42\u7684\u589e\u52a0\uff0c\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\uff08PEMFCs\uff09\u4f5c\u4e3a\u9ad8\u6548\u76f4\u63a5\u5316\u5b66\u80fd-\u7535\u80fd\u8f6c\u6362\u7684\u66ff\u4ee3\u80fd\u6e90\u8f6c\u6362\u88c5\u7f6e\uff0c\u6b63\u5f15\u8d77\u4eba\u4eec\u7684\u5e7f\u6cdb\u5174\u8da3\u3002PEMFCs\u4e2d\u5173\u952e\u7684\u5316\u5b66\u80fd-\u7535\u80fd\u8f6c\u6362\u8fc7\u7a0b\u53ef\u7528\u7b80\u5355\u7684\u516c\u5f0f\u63cf\u8ff0\uff1a2H<sub>2<\/sub>\u00a0+ O<sub>2<\/sub>\u21922H<sub>2<\/sub>O\uff0c\u5176\u4e2dH<sub>2<\/sub>\u5728\u8d1f\u6781\u88ab\u6c27\u5316\uff0c\u5e76\u4e14O<sub>2<\/sub>\u5728\u6b63\u6781\u5904\u88ab\u8fd8\u539f\u3002\u867d\u7136\u6b63\u6781\u548c\u8d1f\u6781\u90fd\u9700\u8981\u50ac\u5316\u5242\u6765\u964d\u4f4e\u7535\u5316\u5b66\u8fc7\u7535\u4f4d\uff0c\u5e76\u83b7\u5f97\u66f4\u9ad8\u7684\u7535\u538b\u8f93\u51fa\uff0c\u4f46\u6b63\u6781\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u662f\u4e00\u4e2a\u591a\u7535\u5b50\u3001\u591a\u6b65\u53cd\u5e94\u3001\u53cd\u5e94\u52a8\u529b\u5b66\u7f13\u6162\u3002\u56e0\u6b64\uff0cORR\u53cd\u5e94\u662f\u5173\u952e\u7684\u9650\u5236\u6b65\u9aa4\u3002\u4e3a\u6b64\uff0c\u4e3a\u4e86\u964d\u4f4ePEMFCs\u7684\u6210\u672c\uff0c\u5f00\u53d1\u9ad8\u6548\u3001\u9ad8\u6027\u80fd\u7684\u7535\u50ac\u5316\u5242\u6765\u6539\u5584ORR\u52a8\u529b\u5b66\u81f3\u5173\u91cd\u8981\u3002\u94c2\uff08Pt\uff09\u56e0\u5176\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\uff08\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\uff09\uff0c\u662f\u76ee\u524d\u7814\u7a76\u6700\u5e7f\u6cdb\u7684ORR\u7535\u50ac\u5316\u5242\u3002Pt\u57fa\u50ac\u5316\u5242\u7684\u7a00\u7f3a\u6027\u548c\u9ad8\u6210\u672c\u662f\u76ee\u524dPEMFCs\u9ad8\u6210\u672c\u7684\u91cd\u8981\u539f\u56e0\u4e4b\u4e00\u3002\u6839\u636e\u7f8e\u56fd\u80fd\u6e90\u90e8\uff08DOE\uff09\u71c3\u6599\u7535\u6c60\u6280\u672f\u529e\u516c\u5ba4\u7684\u9884\u6d4b\uff0c\u5728\u5927\u89c4\u6a21\u751f\u4ea7\u9636\u6bb5\uff0cPt\u57fa\u50ac\u5316\u5242\u7684\u6210\u672c\u7ea6\u5360\u71c3\u6599\u7535\u6c60\u603b\u6210\u672c\u768441%\u3002\u4e3a\u6b64\uff0c\u7f8e\u56fd\u80fd\u6e90\u90e8\u5df2\u8bbe\u5b9a\u4e00\u4e2a\u7279\u5b9a\u7684\u76ee\u6807\uff0c\u51cf\u5c11PEMFCs\u7684\u603bPt\u8d1f\u8f7d\u91cf\u4e3a0.125 mg<sub>Pt<\/sub>\u00a0cm<sup>-2<\/sup>\u3002\u56e0\u6b64\uff0c\u65e2\u8981\u4fdd\u8bc1Pt\u57fa\u50ac\u5316\u5242\u7684\u6700\u5c11\u91cf\u4e14\u4e0d\u727a\u7272\u50ac\u5316\u6027\u80fd\uff0c\u6240\u4ee5\u9700\u8981\u5f00\u53d1\u9ad8\u6027\u80fdPt\u57faORR\u50ac\u5316\u5242\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5728<strong><b>\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u6d1b\u6749\u77f6\u5206\u6821<\/b><\/strong><strong><b>\u6bb5\u9576\u950b<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong><strong><b>\u3001\u9ec4\u6631<\/b><\/strong><strong><b>\u6559\u6388\u56e2\u961f\uff08<\/b><\/strong><strong><b>\u5171\u540c<\/b><\/strong><strong><b>\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u5e26\u9886\u4e0b\uff0c\u4e0e<strong><b>\u6e56\u5357\u5e08\u8303\u5927\u5b66<\/b><\/strong>\u5408\u4f5c\uff0c\u57fa\u4e8ePt\u57faORR\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u5f97\u5230\u4e86\u5f88\u5927\u7684\u63d0\u9ad8\uff0c\u5305\u62ec\u5f00\u53d1\u548c\u8bbe\u8ba1\u5404\u79cd\u5c3a\u5bf8\u548c\u5316\u5b66\u7ec4\u6210\u7684\u5404\u79cdPt\u7eb3\u7c73\u7ed3\u6784\u3001\u901a\u8fc7\u6676\u4f53\u8868\u9762\u63a7\u5236\u5f62\u72b6\u3001\u8868\u9762\u5e94\u53d8\u3001\u8868\u9762\u63ba\u6742\u3001\u51e0\u4f55\u5de5\u7a0b\u548c\u754c\u9762\u5de5\u7a0b\u7b49\u65b9\u9762\u8c03\u63a7\u3002\u5728\u6b64\uff0c\u56e2\u961f\u7b80\u8981\u4ecb\u7ecd\u4e86\u71c3\u6599\u7535\u6c60\u548cORR\u50ac\u5316\u5242\u7684\u4e00\u4e9b\u57fa\u672c\u539f\u7406\u548c\u6027\u80fd\u6307\u6807\uff0c\u7136\u540e\u8be6\u7ec6\u63cf\u8ff0\u4e86\u4e00\u7cfb\u5217\u7b56\u7565\uff0c\u4ee5\u63a8\u52a8\u9ad8\u6027\u80fdPt\u57fa\u50ac\u5316\u5242\u7684\u6781\u9650\u3002\u7b80\u8981\u4ecb\u7ecd\u4e86\u71c3\u6599\u7535\u6c60\u4e2dPt\u57faORR\u50ac\u5316\u5242\u9762\u4e34\u7684\u6311\u6218\u53ca\u672a\u6765\u53d1\u5c55\u65b9\u5411\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong><b>Nanoscale Structure Design for High<\/b><\/strong><strong><b>&#8211;<\/b><\/strong><strong><b>Performance Pt<\/b><\/strong><strong><b>&#8211;<\/b><\/strong><strong><b>Based ORR Catalysts<\/b><\/strong><strong><b>\u201d<\/b><\/strong>\u53d1\u8868\u5728\u4e86<strong><b>Adv. Mater.<\/b><\/strong>\u4e0a\u3002<img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-162598\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/0-1.jpg\" alt=\"\" width=\"600\" height=\"530\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/0-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/0-1-300x265.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe1<\/b><\/strong><strong><b>\u00a0\u5404\u79cdPt\u57fa\u7eb3\u7c73\u7ed3\u6784ORR\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u7b56\u7565<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-162599\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/1-30.jpg\" alt=\"\" width=\"600\" height=\"301\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/1-30.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/1-30-300x151.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u7528\u4e8e\u4ea7\u751f\u5177\u6709\u589e\u5f3a\u7684\u6bd4\u6d3b\u6027\u3001\u7535\u5316\u5b66\u6d3b\u6027\u8868\u9762\u79ef\u548c\u8d28\u91cf\u6d3b\u6027\u7684\u5404\u79cdPt\u57fa\u7eb3\u7c73\u7ed3\u6784ORR\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u7b56\u7565\u3002<\/p>\n<p><strong><b>\u56fe2<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u5404\u79cdPt\u57faORR\u7eb3\u7c73\u50ac\u5316\u5242\u7684\u4ee3\u8868\u6027\u56fe\u50cf<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-162600\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/2-32.jpg\" alt=\"\" width=\"600\" height=\"199\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/2-32.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/2-32-300x100.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>A\uff0cB\uff09Pd@Pt\u6838-\u58f3\u51f9\u5341\u9762\u4f53\u3002<\/p>\n<p>C\uff0cD\uff09Pt-Ni\u516b\u9762\u4f53\u3002<\/p>\n<p>E\uff0cF\uff09Mo-Pt<sub>3<\/sub>Ni\u516b\u9762\u4f53\u7eb3\u7c73\u6676\u4f53\u3002<\/p>\n<p>G\uff0cH\uff09J-PtNWs\u3002<\/p>\n<p>I\uff0cJ\uff09PtPb\u516d\u8fb9\u5f62\u7eb3\u7c73\u7247\u3002<\/p>\n<p>K\uff0cL\uff093D Pt<sub>3<\/sub>Ni\u7eb3\u7c73\u6846\u67b6\u3002<\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u5404\u79cdPt\u57faORR\u7eb3\u7c73\u50ac\u5316\u5242\u7684<\/b><\/strong><strong><b>SA\u3001ECSA\u548cMA\u6bd4\u8f83<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-162601\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/3-34.jpg\" alt=\"\" width=\"600\" height=\"317\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/3-34.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/12\/3-34-300x159.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\u901a\u8fc7\u6539\u8fdbSA\u548cECSA\u63d0\u5347Pt\u57faORR\u50ac\u5316\u5242MA\u7684\u4e00\u4e9b\u4ee3\u8868\u6027\u50ac\u5316\u5242\uff08SA\u3001MA\u57280.9V\u00a0vs RHE\u4e0b\u8fdb\u884c\u6bd4\u8f83\uff09\u3002\u9664\u4e86PtPb NPs\u548cPtNi CS\u5916\uff0c\u4e0a\u8ff0\u7eb3\u7c73\u50ac\u5316\u5242\u7684ECSA\u548cSA\u503c\u662f\u6839\u636eCO-stripping\u4f30\u7b97\u7684\u8868\u9762\u79ef(\u8868\u9762\u79ef\u4f30\u7b97\u91c7\u7528H<sub>upd<\/sub>)\u3002TKK 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href=\"https:\/\/onlinelibrary.wiley.com\/doi\/full\/10.1002\/adma.201802234\" target=\"_blank\" rel=\"noopener\"><u>Nanoscale Structure Design for High<\/u><u>&#8211;<\/u><u>Performance Pt<\/u><u>&#8211;<\/u><u>Based ORR Catalysts<\/u><\/a>\uff08Adv. 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