{"id":162524,"date":"2018-12-26T06:30:13","date_gmt":"2018-12-25T22:30:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=162524"},"modified":"2018-12-25T18:26:37","modified_gmt":"2018-12-25T10:26:37","slug":"%e5%8d%8e%e4%b8%9c%e5%b8%88%e8%8c%83%e5%a4%a7%e5%ad%a6macromolecules%ef%bc%9a%e4%b8%b2%e8%81%94%e6%98%93%e4%bd%8d%e8%81%9a%e5%90%88%e8%af%b1%e5%af%bc%e8%87%aa%e7%bb%84%e8%a3%85%e6%88%90%e7%ba%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=162524","title":{"rendered":"\u534e\u4e1c\u5e08\u8303\u5927\u5b66Macromolecules\uff1a\u4e32\u8054\u6613\u4f4d\u805a\u5408\u8bf1\u5bfc\u81ea\u7ec4\u88c5\u6210\u7eb3\u7c73\u7ed3\u6784\u5d4c\u6bb5\u5171\u805a\u7269\u53ca\u53ef\u63a7\u4e09\u5511\u4e8c\u916e\u6539\u6027\u589e\u5f3a\u4ecb\u7535\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u683c\u62c9\u5e03\u50ac\u5316\u5242\u5f15\u53d1\u7684\u5f00\u73af\u6613\u4f4d\u805a\u5408\uff08ROMP\uff09\u548c\u6613\u4f4d\u73af\u5316\u805a\u5408\uff08MCP\uff09\u662f\u5b9e\u7528\u3001\u9ad8\u6548\u7684\u53ef\u63a7\u805a\u5408\u6280\u672f\uff0c\u5176\u5e7f\u6cdb\u7528\u4e8e\u5408\u6210\u5404\u79cd\u7ed3\u6784\u660e\u786e\u7684\u805a\u5408\u7269\u3002\u7531\u805a\u964d\u51b0\u7247\u70ef\u94fe\u6bb5\u548c\u805a\u4e59\u7094\u94fe\u6bb5\u7ec4\u6210\u7684\u5d4c\u6bb5\u5171\u805a\u7269\uff0c\u5c31\u5f88\u5bb9\u6613\u901a\u8fc7\u4e00\u9505\u4e32\u8054ROMP-MCP\u5408\u6210\uff0c\u5e76\u4e14\u5c55\u73b0\u51fa\u4e0e\u5546\u7528\u805a\u5408\u7269\u7535\u5bb9\u5668\u8584\u819c\u76f8\u6bd4\u8f83\u9ad8\u7684\u4ecb\u7535\u5e38\u6570\u548c\u50a8\u5b58\/\u91ca\u653e\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u8fd9\u4e9b\u5171\u805a\u7269\u80fd\u591f\u81ea\u7ec4\u88c5\u6210\u4e0d\u540c\u7684\u7eb3\u7c73\u7ed3\u6784\uff0c\u5982\u7eb3\u7c73\u6bdb\u7ec6\u7ba1\u3001\u7a7a\u5fc3\u7403\u7eb3\u7c73\u7ed3\u6784\u3001\u8d85\u87ba\u65cb\u7eb3\u7c73\u7ba1\u548c\u6838-\u58f3\u7eb3\u7c73\u7c92\u5b50\u7b49\uff0c\u800c\u4e14\u5bfc\u7535\u805a\u4e59\u7094\u5d4c\u6bb5\u662f\u5305\u88f9\u5728\u7edd\u7f18\u805a\u964d\u51b0\u7247\u70ef\u5d4c\u6bb5\u4e2d\u7684\uff0c\u6709\u5229\u4e8e\u5236\u5907\u805a\u5408\u7269\u5206\u5b50\u590d\u5408\u6750\u6599\u4ee5\u8fdb\u4e00\u6b65\u6539\u5584\u4ecb\u7535\u6027\u80fd\u3002\u4f46\u662f\u4e0e\u4f20\u7edf\u7684\u6709\u673a\/\u65e0\u673a\u590d\u5408\u6750\u6599\u76f8\u6bd4\uff0c\u591a\u6570\u60c5\u51b5\u4e0b\u57fa\u4e8e\u8fd9\u4e9b\u81ea\u7ec4\u88c5\u7ed3\u6784\u7684\u805a\u5408\u7269\u6750\u6599\u7684\u4ecb\u7535\u5e38\u6570\u4ecd\u8f83\u4f4e\uff0c\u96be\u4ee5\u6ee1\u8db3\u8bbe\u5907\u7684\u6700\u4f73\u64cd\u4f5c\u8981\u6c42\u3002\u4e3a\u4e86\u5f25\u8865\u8fd9\u4e00\u7f3a\u9677\uff0c\u4e00\u79cd\u65b9\u6cd5\u662f\u901a\u8fc7\u5316\u5b66\u4fee\u9970\u5c06\u6781\u6027\u5206\u5b50\u76f4\u63a5\u8fde\u63a5\u5230\u7eb3\u7c73\u7ed3\u6784\u7684\u8868\u9762\uff0c\u4ee5\u589e\u52a0\u5076\u6781\u5b50\u6781\u5316\u800c\u4e0d\u635f\u574f\u7ec4\u88c5\u4f53\u5185\u7684\u5bfc\u7535\u533a\u57df\u30021,2,4-\u4e09\u5511\u5549-3,5-\u4e8c\u916e\uff08TAD\uff09\u662f\u4e00\u79cd\u5178\u578b\u7684\u6781\u6027\u5206\u5b50\uff0c\u7136\u800c\u76ee\u524d\u57fa\u4e8eTAD\u7684\u70b9\u51fb\u5316\u5b66\u53cd\u5e94\u5f88\u5c11\u7528\u4e8e\u4fee\u9970\u81ea\u7ec4\u88c5\uff0c\u5c24\u5176\u662f\u5168\u805a\u5408\u7269\u7eb3\u7c73\u7ed3\u6784\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u4e1c\u5e08\u8303\u5927\u5b66\u8c22\u7f8e\u7136\u6559\u6388<\/strong>\u4e0e\u674e\u4e9a\u5dcd\u526f\u6559\u6388<\/strong>\u5408\u4f5c\uff0c\u901a\u8fc7\u4e32\u8054ROMP-MCP\u5408\u6210\u5f97\u5230\u5d4c\u6bb5\u5171\u805a\u7269\uff0c\u8be5\u805a\u5408\u7269\u80fd\u591f\u5728\u9009\u62e9\u6027\u6eb6\u5242\u4e2d\u81ea\u7ec4\u88c5\u6210\u6838-\u58f3\u7eb3\u7c73\u7ed3\u6784\u3002\u901a\u8fc7\u8c03\u8282TAD\u8fdb\u6599\u91cf\u53ef\u4ee5\u5bf9\u5d4c\u6bb5\u5171\u805a\u7269\u8fdb\u884c\u53ef\u63a7\u4fee\u9970\uff0c\u4f7f\u5f97\u5728\u58f3\u4e2d\u7684\u805a\u964d\u51b0\u7247\u70ef\u9aa8\u67b6\u4e0a\u9996\u5148\u53d1\u751fTAD\u4e0e\u53cc\u952e\u7684Alder-ene\u53cd\u5e94\uff0c\u7136\u540e\u5728\u6838\u4e2d\u5e26\u6709\u4e94\u5143\u73af\u7684\u805a\u4e59\u7094\uff08PA\uff09\u4e3b\u94fe\u4e0a\u53d1\u751f\u7ea7\u8054Alder-ene\u548cDiels-Alder\u53cd\u5e94\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u542b\u6709\u4e0d\u540c\u91cf\u7684\u8132\u5511\u57fa\u56e2\u7684\u6539\u6027\u5d4c\u6bb5\u5171\u805a\u7269\u5c55\u73b0\u51fa\u589e\u5f3a\u7684\u4ecb\u7535\u5e38\u6570\uff0816.2\u523020.3\uff09\u548c\u66f4\u4f4e\u7684\u4ecb\u7535\u635f\u8017\uff08\u4ece0.031 \u52300.009\uff09\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Tandem Metathesis Polymerization-Induced Self-Assembly to Nanostructured Block Copolymer and the Controlled Triazolinedione Modification for Enhancing Dielectric Properties<\/strong>“\u53d1\u8868\u5728\u9ad8\u5206\u5b50\u9886\u57df\u8457\u540d\u671f\u520aMacromolecules<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u5171\u805a\u7269\u7684\u5408\u6210\u3001TAD\u6539\u6027\u548c\u81ea\u7ec4\u88c5\u6838-\u58f3\u7eb3\u7c73\u7ed3\u6784\u7684\u53ef\u63a7TAD\u4fee\u9970<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u65e0\u89c4\u5171\u805a\u7269\u7684\u5408\u6210\u53ca\u5176TAD\u6539\u6027\uff1b<\/p>\n

(b) \u5d4c\u6bb5\u5171\u805a\u7269\u7684\u5408\u6210\u53ca\u5176TAD\u6539\u6027\uff1b<\/p>\n

(c) \u81ea\u7ec4\u88c5\u6838-\u58f3\u7eb3\u7c73\u7ed3\u6784\u7684\u53ef\u63a7TAD\u4fee\u9970\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 \u6539\u6027\u524d\u540e\u65e0\u89c4\u5171\u805a\u7269\u4e0e\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

(a) CHCl3<\/sub>\u4e2d\u6539\u6027\u524d\u540e\u65e0\u89c4\u5171\u805a\u7269\uff080.01 mg mL-1<\/sup>\uff09\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

(b) CHCl3<\/sub>\u4e2d\u6539\u6027\u524d\u540e\u5d4c\u6bb5\u5171\u805a\u7269\uff080.01 mg mL-1<\/sup>\uff09\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\u3002<\/p>\n

\u56fe3 \u5171\u805a\u7269\u76841<\/sup>H NMR\u8c31<\/strong><\/p>\n

\"\"<\/p>\n

(a) PTNP50<\/sub>–b<\/em>-PSHD25<\/sub>\u76841<\/sup>H NMR\u8c31\uff1b<\/p>\n

(b) (PTNP50<\/sub>-25%FTAD)-b<\/em>-PSHD25<\/sub>\u76841<\/sup>H NMR\u8c31\uff1b<\/p>\n

(c) (PTNP50<\/sub>–b<\/em>-PSHD25<\/sub>)-50%FTAD\u76841<\/sup>H NMR\u8c31\u3002<\/p>\n

\u56fe4 PA\u9aa8\u67b6\u4e2d\u5171\u8f6d\u591a\u70ef\u7684\u53ef\u80fd\u4e0e\u975e\u53ef\u80fdTAD\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5177\u6709\u4e94\u5143\u73af\u7684PA\u9aa8\u67b6\u4e2d\u5171\u8f6d\u591a\u70ef\u7684\u53ef\u80fdTAD\u53cd\u5e94\u7684\u56fe\u793a\uff1b<\/p>\n

(b, c) \u5177\u6709\u4e94\u5143\u73af\u7684PA\u9aa8\u67b6\u4e2d\u5171\u8f6d\u591a\u70ef\u7684\u975e\u53ef\u80fdTAD\u53cd\u5e94\u7684\u56fe\u793a\u3002<\/p>\n

\u56fe5 PTNP50<\/sub>–b<\/em>-PSHD25<\/sub>\u548c(PTNP50<\/sub>-25%FTAD)-b<\/em>-PSHD25<\/sub>\u7684TEM\u56fe\u50cf<\/strong><\/p>\n

\"\"<\/p>\n

(a-c) PTNP50<\/sub>–b<\/em>-PSHD25<\/sub>\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

(e, f) (PTNP50<\/sub>-25%FTAD)-b<\/em>-PSHD25<\/sub>\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe6 \u805a\u5408\u7269\u8584\u819c\u6539\u6027\u524d\u540e\u7684\u4ecb\u7535\u5e38\u6570\u548c\u4ecb\u7535\u635f\u8017\u7684\u9891\u7387\u4f9d\u8d56\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5728\u5ba4\u6e29\u4e0b\u6d4b\u91cf\u4e0d\u540cFTAD\u542b\u91cf\u7684\u805a\u5408\u7269\u8584\u819c\u6539\u6027\u524d\u540e\u7684\u4ecb\u7535\u5e38\u6570\u7684\u9891\u7387\u4f9d\u8d56\u6027\uff1b<\/p>\n

(b) \u5728\u5ba4\u6e29\u4e0b\u6d4b\u91cf\u4e0d\u540cFTAD\u542b\u91cf\u7684\u805a\u5408\u7269\u8584\u819c\u6539\u6027\u524d\u540e\u7684\u4ecb\u7535\u635f\u8017\u7684\u9891\u7387\u4f9d\u8d56\u6027\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u4e2d\uff0c\u4f5c\u8005\u901a\u8fc7MCP\u548c\u4e32\u8054ROMP-MCP\u5206\u522b\u5408\u6210\u5f97\u5230\u4e86\u65e0\u89c4\u5171\u805a\u7269PSHD-co<\/em>-PEHD\u548c\u5d4c\u6bb5\u5171\u805a\u7269PTNP-b<\/em>-PSHD\u3002\u5bf9\u4e8ePSHD-co<\/em>-PEHD\u805a\u5408\u7269\uff0c\u5229\u75284-(3-\u4e09\u6c1f\u7532\u57fa\u82ef\u57fa)-1,2,4-\u4e09\u5511\u5549-3,5-\u4e8c\u916e\uff08FTAD\uff09\u8fdb\u884c\u6539\u6027\u65f6\uff0c\u80fd\u591f\u5f97\u5230\u542b\u6709\u4e0d\u9971\u548c\u516d\u5143\u73af\u7684\u7ea7\u8054Alder-ene\u548cDiels-Alder\u52a0\u6210\u7269\u3002\u5bf9\u4e8ePTNP-b<\/em>-PSHD\u805a\u5408\u7269\uff0c\u5f53FTAD\/\u53cc\u952e\u6bd4\u7387\u589e\u52a0\u52300.5\u4ee5\u4e0a\u65f6\uff0c\u624d\u80fd\u591f\u5f15\u53d1\u7ea7\u8054\u7684Alder-ene\u548cDiels-Alder\u53cd\u5e94\u3002\u5f53\u5229\u7528FTAD\u6539\u6027\u5171\u805a\u7269\u540e\uff0c\u4ecb\u7535\u5e38\u6570\u4ece16.2\u589e\u52a0\u523020.3\uff0c\u800c\u4ecb\u7535\u635f\u8017\u4ece0.031\u964d\u4f4e\u52300.009\u3002\u56e0\u6b64\uff0c\u8868\u660e\u57fa\u4e8eTAD\u70b9\u51fb\u53cd\u5e94\u7684\u9009\u62e9\u6027\u540e\u529f\u80fd\u5316\u4f5c\u4e3a\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u4e00\u79cd\u53ef\u9760\u5408\u6210\u9014\u5f84\uff0c\u5728\u8bbe\u8ba1\u529f\u80fd\u6750\u6599\u65b9\u9762\u5177\u6709\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aTandem Metathesis Polymerization-Induced Self-Assembly to Nanostructured Block Copolymer and the Controlled Triazolinedione Modification for Enhancing Dielectric Properties<\/a>\u00a0(Macromolecules 2018, DOI: 10.1021\/acs.macromol.8b01645)<\/strong><\/p>\n

\u3010\u8c22\u7f8e\u7136\u6559\u6388\u4ee3\u8868\u6027\u8bba\u6587\u3011<\/strong><\/p>\n

[1] Jie Chen, Hongfei Li, Hengchen Zhang, Xiaojuan Liao, Huijing Han, Lidong Zhang, Ruyi Sun* and Meiran Xie<\/strong>*. Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology, Nat. Commun<\/em>., 2018<\/strong>, 9<\/em>, 5310.<\/p>\n

[2] Jie Chen, Yuxin Wang, Hongfei Li, Huijing Han, Xiaojuan Liao, Ruyi Sun, Xingyi Huang*, and Meiran Xie<\/strong>*. Rational Design and Modification of High-k<\/em> Bis(double-stranded) Block Copolymer for High Electrical Energy Storage Capability, Chem. Mater.<\/em>, 2018<\/strong>, 30<\/em>, 1102-1112.<\/p>\n

[3] Jie Chen, Cheng Long, Hongfei Li, Huijing Han*, Ruyi Sun, Meiran Xie<\/strong>*. Double-stranded block copolymer with dual-polarized linker for improving dielectric and electrical energy storage performance, Polymer<\/em>, 2017<\/strong>, 127<\/em>, 259-268.<\/p>\n

[4] Wenmei Liu, Jie Chen, Dandan Zhou, Xiaojuan Liao, Meiran Xie<\/strong>* and Ruyi Sun*. A high-performance dielectric block copolymer with a self-assembled superhelical nanotube morphology, Polym. Chem<\/em>., 2017<\/strong>, 8<\/em>, 725-734<\/strong>.<\/p>\n

[5] Jianhua Wu, Cuifang Wang, Dandan Zhou, Xiaojuan Liao, Meiran Xie<\/strong>,* Ruyi Sun*. Branched 1,2,3-Triazolium-Functionalized Polyacetylene with Enhanced Conductivity, Macromol. Rapid Commun.<\/em>, 2016<\/strong>, <\/em>37<\/em>,<\/em> 2017-2022.\u00a0<\/p>\n

[6] Junfang Wang, Hongfei Li, Xiaojuan Liao, Meiran Xie<\/strong>* and Ruyi Sun*. Synthesis of triazole-dendronized polyacetylenes by metathesis cyclopolymerization and their conductivity, Polym. Chem<\/em>., 2016<\/strong>, 7<\/em>, 4912-4923.<\/p>\n

[7] Huijing Han, Sha Zhang, Ruyi Sun, Jianhua Wu, Meiran Xie<\/strong>* and Xiaojuan Liao*. Photocrosslinkable Polynorbornene-based Block Copolymer with Enhanced Dielectric and Thermal Properties, Chinese J. Polym. Sci<\/em>., 2016<\/strong>, 34<\/em>, 378-389.<\/p>\n

[8] Jianhua Wu, Jie Chen, Junfang Wang, Xiaojuan Liao, Meiran Xie<\/strong>* and Ruyi Sun*. Synthesis and conductivity of hyperbranched poly(triazolium)s with various end-capping groups, Polym. Chem.<\/em>, 2016<\/strong>, 7<\/em>, 633-642.<\/p>\n

 <\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u751f\u7269\u5b66\u672f\u7ec4biotech\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u5ba1\u6838\u6574\u7406\u3002<\/p>\n

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