{"id":162257,"date":"2018-12-24T08:00:19","date_gmt":"2018-12-24T00:00:19","guid":{"rendered":"\/\/m.iemloyee.com\/?p=162257"},"modified":"2018-12-23T19:30:36","modified_gmt":"2018-12-23T11:30:36","slug":"%e5%8d%8e%e4%b8%9c%e5%b8%88%e8%8c%83%e5%a4%a7%e5%ad%a6j-mater-chem-a%ef%bc%9a%e9%80%9a%e8%bf%87%e9%85%8d%e4%bd%8d%e6%a1%86%e6%9e%b6%e5%ae%9e%e7%8e%b0%e7%ba%b3%e7%b1%b3%e5%a4%9a%e5%ad%94%e7%a2%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=162257","title":{"rendered":"\u534e\u4e1c\u5e08\u8303\u5927\u5b66J. Mater. Chem. A\uff1a\u901a\u8fc7\u914d\u4f4d\u6846\u67b6\u5b9e\u73b0\u7eb3\u7c73\u591a\u5b54\u78b3\u7684\u53ef\u63a7\u6c2e\u63ba\u6742"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7eb3\u7c73\u591a\u5b54\u78b3\u662f\u4e00\u7c7b\u9664\u91d1\u521a\u77f3\u3001\u5bcc\u52d2\u70ef\u3001\u77f3\u58a8\u3001\u78b3\u7eb3\u7c73\u7ba1\u548c\u77f3\u58a8\u70ef\u4e4b\u5916\u4e00\u79cd\u91cd\u8981\u7684\u78b3\u6750\u6599\u3002\u5c3d\u7ba1\u7eb3\u7c73\u591a\u5b54\u78b3\u5177\u6709\u5de8\u5927\u6f5c\u529b\uff0c\u5728\u5177\u4f53\u5e94\u7528\u65f6\u4e5f\u9700\u8981\u8c03\u6574\u5176\u90e8\u5206\u7406\u5316\u6027\u8d28\uff0c\u5176\u4e2d\u6c2e\u63ba\u6742\u5c31\u662f\u4e00\u79cd\u80fd\u591f\u663e\u8457\u6539\u53d8\u7eb3\u7c73\u591a\u5b54\u78b3\u6027\u8d28\u7684\u6709\u6548\u7b56\u7565\u3002N\u63ba\u6742\u5242\u901a\u5e38\u5305\u62ec\u5421\u54af-N\u3001\u5421\u5576-N\u548c\u77f3\u58a8-N\uff0c\u8fd9\u4e9bN\u6784\u578b\u80fd\u591f\u5bf9\u78b3\u539f\u5b50\u5e26\u6765\u663e\u8457\u5f71\u54cd\u3002\u901a\u5e38\uff0c\u5c06N\u63ba\u6742\u5230\u7eb3\u7c73\u591a\u5b54\u78b3\u4e2d\u662f\u57fa\u4e8e\u540e\u5904\u7406\u6216\u539f\u4f4d\u53d6\u4ee3\uff0c\u800c\u6700\u8fd1\u914d\u4f4d\u5316\u5b66\u4e3a\u5b9e\u73b0\u660e\u786e\u7684\u7eb3\u7c73\u591a\u5b54\u78b3\u63d0\u4f9b\u4e86\u673a\u4f1a\uff0c\u76ee\u524d\u56fa\u6001\u70ed\u89e3\u7531\u5bcc\u542bN\u7684\u6709\u673a\u914d\u4f53\u6784\u5efa\u5f97\u5230\u7684\u914d\u4f4d\u6846\u67b6\u5df2\u88ab\u516c\u8ba4\u4e3a\u662f\u4e00\u79cd\u5b9e\u73b0\u7eb3\u7c73\u591a\u5b54\u78b3N\u63ba\u6742\u7684\u6709\u6548\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u5c3d\u7ba1\u4f7f\u7528\u914d\u4f4d\u6846\u67b6\u4f5c\u4e3a\u524d\u4f53\u5177\u6709\u5f88\u5927\u7684\u4f18\u52bf\uff0c\u4f46\u662f\u4ee5\u53ef\u9884\u6d4b\u7684\u65b9\u5f0f\u63a7\u5236N\u6784\u578b\u4f9d\u7136\u6ca1\u6709\u65e0\u6cd5\u5b9e\u73b0\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u4e1c\u5e08\u8303\u5927\u5b66\u80e1\u9e23\u7814\u7a76\u5458<\/strong>\u3001\u8881\u6e05\u7ea2\u7814\u7a76\u5458\u4e0e<\/strong>AIST<\/strong>\u7684\u5f90\u5f3a\u6559\u6388<\/strong>\u5408\u4f5c\uff0c\u5728\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u7684\u6307\u5bfc\u4e0b\u901a\u8fc7\u914d\u4f4d\u6846\u67b6\u7684\u70ed\u89e3\u8bc1\u660e\u4e86\u5728\u7eb3\u7c73\u591a\u5b54\u78b3\u4e2d\u5b9e\u73b0N-\u63ba\u6742\u7684\u53ef\u63a7\u3001\u539f\u4f4d\u7684\u7b56\u7565\u3002\u7814\u7a76\u53d1\u73b0\uff0cN\u63ba\u6742\u6784\u578b\u7684\u4e0d\u540c\u70ed\u7a33\u5b9a\u6027\u4f7f\u5f97N\u63ba\u6742\u5242\u7684\u542b\u91cf\u53ef\u4ee5\u5229\u7528\u9000\u706b\u6e29\u5ea6\u6765\u8fdb\u884c\u8c03\u8282\uff0c\u800c\u4e14N\u63ba\u6742\u6784\u578b\u5bf9\u7eb3\u7c73\u591a\u5b54\u78b3\u7684K\u79bb\u5b50\u5b58\u50a8\u5bb9\u91cf\u6709\u663e\u8457\u5f71\u54cd\u3002\u4f18\u5316\u7684N\u63ba\u6742\u6784\u578b\u80fd\u591f\u663e\u8457\u63d0\u9ad8K\u79bb\u5b50\u7535\u6c60\u7535\u6781\u7684\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u8fd9\u4e00\u7ed3\u679c\u4e0e\u7406\u8bba\u9884\u6d4b\u76f8\u543b\u5408\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Controllable nitrogen-doping of nanoporous carbons enabled by coordination frameworks<\/strong>“\u53d1\u8868\u5728\u671f\u520aJournal of Materials Chemistry A<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 K\u5728\u5421\u54af-N\u3001\u5421\u5576-N\u3001\u77f3\u58a8-N\u548c\u77f3\u58a8\u70ef\u4e0a\u7684\u5438\u9644\u4e0e\u6269\u6563<\/strong><\/p>\n

\"\"<\/p>\n

(a) K\u5728\u5421\u54af-N\u3001\u5421\u5576-N\u3001\u77f3\u58a8-N\u548c\u77f3\u58a8\u70ef\u4e0a\u7684\u5438\u9644\u80fd\uff1b<\/p>\n

(b) K\u5728\u5421\u54af-N\u3001\u5421\u5576-N\u3001\u77f3\u58a8-N\u548c\u77f3\u58a8\u70ef\u4e0a\u7684\u6269\u6563\u8def\u5f84\uff1b<\/p>\n

(c) K\u5728\u5421\u54af-N\u3001\u5421\u5576-N\u3001\u77f3\u58a8-N\u548c\u77f3\u58a8\u70ef\u4e0a\u7684\u76f8\u5e94\u6269\u6563\u80fd\u5792\u3002<\/p>\n

\u56fe2 \u5421\u54af-N\u3001\u5421\u5576-N\u548c\u77f3\u58a8-N\u7684\u5f62\u6210\u80fd\u91cf\u548c\u603b\u4f53\u6982\u7387<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5421\u54af-N\u3001\u5421\u5576-N\u548c\u77f3\u58a8-N\u7684\u5f62\u6210\u80fd\u91cf\uff1b<\/p>\n

(b) \u968f\u7740\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u5421\u54af-N\u3001\u5421\u5576-N\u548c\u77f3\u58a8-N\u7684\u603b\u4f53\u6982\u7387\u3002<\/p>\n

\u56fe3 \u4e0d\u540c\u6e29\u5ea6\u4e0bZIF-8\u9897\u7c92\u9000\u706b\u6837\u54c1\u7684PXRD\u66f2\u7ebf\u548cN2<\/sub>\u5438\u9644-\u8131\u9644\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(a) ZIF-8\u9897\u7c92\u548c\u5c06ZIF-8\u9897\u7c92\u4ece300\u81f3600 \u00baC\u9000\u706b\u83b7\u5f97\u4ea7\u7269\u7684PXRD\u66f2\u7ebf\uff1b<\/p>\n

(b) \u5c06ZIF-8\u9897\u7c92\u4ece600\u81f31000 \u00baC\u9000\u706b\u83b7\u5f97\u7684\u4ea7\u7269\u7684PXRD\u66f2\u7ebf\uff1b<\/p>\n

(c) \u5728\u5404\u79cd\u6e29\u5ea6\u4e0bZIF-8\u9897\u7c92\u9000\u706b\u5f97\u5230\u7684\u6837\u54c1\u7684N2<\/sub>\u5438\u9644-\u8131\u9644\u66f2\u7ebf\uff1b<\/p>\n

(d) \u901a\u8fc7NLDFT\u65b9\u6cd5\u8ba1\u7b97\u7684\u6837\u54c1\u7684\u5b54\u5f84\u5206\u5e03\u3002<\/p>\n

\u56fe4 \u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u6837\u54c1\u7684N 1s\u8c31\u56fe\u548c\u5421\u5576-N\u3001\u5421\u54af-N\u548c\u77f3\u58a8-N\u7684\u542b\u91cf<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5728600 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u6837\u54c1\u7684N 1s\u8c31\u56fe\uff1b<\/p>\n

(b) \u5728700 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u6837\u54c1\u7684N 1s\u8c31\u56fe\uff1b<\/p>\n

(c) \u5728800 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u6837\u54c1\u7684N 1s\u8c31\u56fe\uff1b<\/p>\n

(d) \u5728900 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u6837\u54c1\u7684N 1s\u8c31\u56fe\uff1b<\/p>\n

(e) \u57281000 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u6837\u54c1\u7684N 1s\u8c31\u56fe\uff1b<\/p>\n

(f) \u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u6837\u54c1\u4e2d\u5421\u5576-N\u3001\u5421\u54af-N\u548c\u77f3\u58a8-N\u7684\u542b\u91cf\u3002<\/p>\n

\u56fe5 \u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u6837\u54c1\u7684CV\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5728600 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u7684\u6837\u54c1\u7684CV\u66f2\u7ebf\uff1a\u626b\u63cf\u901f\u7387\u4e3a0.1 mV s-1<\/sup>\uff0c\u626b\u63cf\u8303\u56f4 0-3 V\uff1b<\/p>\n

(b) \u5728700 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u7684\u6837\u54c1\u7684CV\u66f2\u7ebf\uff1a\u626b\u63cf\u901f\u7387\u4e3a0.1 mV s-1<\/sup>\uff0c\u626b\u63cf\u8303\u56f4 0-3 V\uff1b<\/p>\n

(c) \u5728800 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u7684\u6837\u54c1\u7684CV\u66f2\u7ebf\uff1a\u626b\u63cf\u901f\u7387\u4e3a0.1 mV s-1<\/sup>\uff0c\u626b\u63cf\u8303\u56f4 0-3 V\uff1b<\/p>\n

(d) \u5728900 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u7684\u6837\u54c1\u7684CV\u66f2\u7ebf\uff1a\u626b\u63cf\u901f\u7387\u4e3a0.1 mV s-1<\/sup>\uff0c\u626b\u63cf\u8303\u56f4 0-3 V\uff1b<\/p>\n

(e) \u57281000 \u00baC\u6e29\u5ea6\u4e0b\u9000\u706bZIF-8\u9897\u7c92\u83b7\u5f97\u7684\u6837\u54c1\u7684CV\u66f2\u7ebf\uff1a\u626b\u63cf\u901f\u7387\u4e3a0.1 mV s-1<\/sup>\uff0c\u626b\u63cf\u8303\u56f4 0-3 V\u3002<\/p>\n

\u56fe6 ZIF-8800\u548c\u786c\u78b3\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a) ZIF-8800\u548c\u786c\u78b3\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

(b) \u5728\u521d\u59cb\u5faa\u73af\u4e2d\u4ee520 mA g-1<\/sup>\u5faa\u73af\u6d3b\u5316\u540e\uff0c\u5f53\u7535\u6d41\u5bc6\u5ea6\u4e3a100 mA g-1<\/sup>\u6761\u4ef6\u4e0bZIF-8800\u548c\u786c\u78b3\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u4e2d\uff0c\u5728\u7b2c\u4e00\u539f\u7406\u8ba1\u7b97\u7684\u57fa\u7840\u4e0a\uff0c\u4f5c\u8005\u5229\u7528\u4e00\u79cd\u6e29\u5ea6\u63a7\u5236\u7b56\u7565\u5b9e\u73b0\u4e86\u57fa\u4e8eN\u63ba\u6742\u5242\u7684\u4e0d\u540c\u70ed\u7a33\u5b9a\u6027\u7684\u7eb3\u7c73\u591a\u5b54\u78b3\u4e2dN\u6784\u578b\u7684\u5b9a\u5236\u3002\u901a\u8fc7\u5728\u4e00\u5b9a\u6e29\u5ea6\u8303\u56f4\u5185\u4f7f\u914d\u4f4d\u76842-\u7532\u57fa\u54aa\u5511\u5206\u5b50\u9000\u706b\uff0c\u7eb3\u7c73\u591a\u5b54\u78b3\u4e2dN\u63ba\u6742\u5242\u7684\u542b\u91cf\u53ef\u4ee5\u53ef\u63a7\u8c03\u8282\uff0c\u6700\u7ec8\u5f97\u5230\u5421\u5576-N\u7684\u6700\u5927\u767e\u5206\u6bd4\u3002\u78b3\/K\u534a\u7535\u6c60\u6d4b\u8bd5\u7ed3\u679c\u8868\u660e\uff0cN\u63ba\u6742\u7eb3\u7c73\u591a\u5b54\u78b3\u7684K\u79bb\u5b50\u5b58\u50a8\u5bb9\u91cf\u4e0eN\u6784\u578b\u5177\u6709\u5f3a\u76f8\u5173\u6027\u3002\u5177\u6709\u6700\u5927\u5421\u5576-N\u542b\u91cf\u7684\u7eb3\u7c73\u591a\u5b54\u78b3\u5c55\u73b0\u51fa\u4f18\u826f\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u4e0e\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u7684\u9884\u6d4b\u76f8\u543b\u5408\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aControllable nitrogen-doping of nanoporous carbons enabled by coordination frameworks\u00a0<\/a>\u00a0(J. Mater. Chem. A 2019, DOI: 10.1039\/C8TA09817D)<\/strong><\/p>\n

\u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8881\u6e05\u7ea2\uff0c\u534e\u4e1c\u5e08\u8303\u5927\u5b66\u7cbe\u5bc6\u5149\u8c31\u79d1\u5b66\u4e0e\u6280\u672f\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u5458\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u534e\u4e1c\u5e08\u8303\u5927\u5b66\u7d2b\u6c5f\u9752\u5e74\u5b66\u8005\u3002\u4e3b\u8981\u4ece\u4e8b\u4f4e\u7ef4\u78b3\u57fa\u7eb3\u7c73\u6750\u6599\u751f\u957f\u673a\u5236\u548c\u6027\u8d28\u7684\u7406\u8bba\u7814\u7a76\uff0c\u63d0\u51fa\u7684\u7406\u8bba\u9884\u6d4b\u88ab\u56fd\u5185\u5916\u591a\u4e2a\u8bfe\u9898\u7ec4\u7684\u540e\u7eed\u5b9e\u9a8c\u7ed3\u679c\u8bc1\u5b9e\u3002\u8fd1\u5e74\u6765\u53d1\u8868\u5b66\u672f\u8bba\u6587\u517140\u4f59\u7bc7\uff0c\u5176\u4e2d\u4ee5\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u5728Nat. Mater.<\/em>\uff0cJ. Am. Chem.<\/em> Soc.<\/em>\uff0cAngew. Chem. Int. Ed.<\/em>\uff0cPhys. Rev. Lett.<\/em>\uff0cNano Letters<\/em>\uff0cAdv. Funct. Mater.<\/em>\uff0cAdv. Sci.<\/em>\u7b49\u56fd\u9645\u9876\u7ea7\u671f\u520a\u4e0a\u53d1\u8868\u591a\u7bc7\u8bba\u6587\uff0c\u603b\u88ab\u5f15950\u4f59\u6b21\u3002<\/p>\n

\u76f8\u5173\u7814\u7a76\u8bba\u6587\uff1a<\/p>\n