{"id":16222,"date":"2016-05-30T08:00:49","date_gmt":"2016-05-30T00:00:49","guid":{"rendered":"\/\/m.iemloyee.com\/?p=16222"},"modified":"2016-05-30T10:17:06","modified_gmt":"2016-05-30T02:17:06","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81-%e8%bf%91%e6%9c%9fmof%e6%9d%90%e6%96%99%e7%a0%94%e7%a9%b6%e8%bf%9b%e5%b1%95%e6%b1%87%e6%80%bb%e3%80%90mof%e6%9d%90%e6%96%9920160530%e3%80%91","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=16222","title":{"rendered":"\u9876\u520a\u52a8\u6001 | JACS\/Angew \u8fd1\u671fMOF\u6750\u6599\u7814\u7a76\u8fdb\u5c55\u6c47\u603b\u3010MOF\u6750\u659920160530\u3011"},"content":{"rendered":"
1\u3001JACS<\/strong>\uff1a\u5229\u7528<\/strong>MOFs<\/strong>\u7eb3\u7c73\u7247\u4f5c\u4e3a\u524d\u9a71\u4f53\u5408\u6210\u4e8c\u7ef4<\/strong>CoS1.097\/<\/strong>\u6c2e\u5305\u8986\u7684<\/strong>C<\/strong>\u7eb3\u7c73\u590d\u5408\u6750\u6599\u53ca\u5176\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n \u4e3b\u8981\u7684\u7814\u7a76\u5185\u5bb9\u53ca\u521b\u65b0\u70b9<\/strong>:<\/strong><\/p>\n \u4e8c\u7ef4\u6750\u6599\u662f\u8fd1\u5e74\u4e86\u975e\u5e38\u706b\u7684\u4e00\u7c7b\u6750\u6599\uff0c\u7531\u4e8e\u5176\u7279\u6b8a\u7684\u7269\u7406\u548c\u5316\u5b66\u6027\u8d28\uff0c\u5f15\u8d77\u4e86\u5f88\u591a\u6750\u6599\u79d1\u5b66\u5bb6\u7684\u7814\u7a76\u5174\u8da3\uff0c\u5728\u50ac\u5316\u3001\u6c14\u4f53\u50a8\u5b58\u548c\u80fd\u529b\u50a8\u5b58\u7b49\u9886\u57df\u6709\u7740\u6f5c\u5728\u7684\u5e94\u7528\u524d\u666f\u3002\u5176\u4e2d\uff0c\u4e8c\u7ef4\u7684MOFs\u7eb3\u7c73\u7247\u662f\u4e8c\u7ef4\u6750\u6599\u5bb6\u65cf\u4e2d\u7684\u65b0\u6210\u5458\uff0c\u76f8\u5bf9\u4e8e\u4e09\u7ef4\u7684MOFs\u6750\u6599\uff0c\u4e8c\u7ef4MOFs\u7eb3\u7c73\u7247\u6709\u8bb8\u591a\u4f18\u70b9\uff0c\u4f8b\u5982\u66f4\u5927\u7684\u6bd4\u8868\u9762\u79ef\u3001\u66f4\u6613\u591a\u7684\u6d3b\u6027\u4f4d\u70b9\u7b49\u3002<\/p>\n 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Metal\u2212Organic Framework Nanosheets as Precursors for Supercapacitor Application<\/a><\/strong><\/p>\n 2\u3001JACS<\/strong>\uff1a<\/strong>COF-MOF<\/strong>\u590d\u5408\u819c\u7684\u5236\u5907\u53ca\u5176\u5728\u9ad8\u6548\u6c14\u4f53\u9009\u62e9\u6027\u5206\u79bb\u6027\u80fd<\/strong><\/p>\n \u4e3b\u8981\u7684\u7814\u7a76\u5185\u5bb9\u53ca\u521b\u65b0\u70b9<\/strong>:<\/strong><\/p>\n \u5bfb\u627e\u65b0\u578b\u819c\u6750\u6599\u5bf9\u4e8e\u5b66\u672f\u754c\u548c\u5de5\u4e1a\u9886\u57df\u6709\u7740\u91cd\u8981\u7684\u610f\u4e49\uff0c\u56e0\u4e3a\u65b0\u578b\u819c\u6750\u6599\u5728\u9009\u62e9\u6027\u5206\u79bb\u6280\u672f\u65b9\u9762\u53d1\u6325\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n \u5409\u6797\u5927\u5b66\u7b49\u4eba\u7684\u7814\u7a76\u56e2\u961f\uff0c\u9996\u6b21\u5c06MOF\u751f\u957f\u5728COF\u4e0a\uff0c\u5236\u5907\u51fa\u4e86COF-MOF\u590d\u5408\u819c\uff0c\u76f8\u5bf9\u4e8e\u5355\u4e2a\u7684MOF\u548cCOF\u6750\u6599\uff0c\u8fd9\u79cdCOF-MOF\u590d\u5408\u819c\u5c55\u73b0\u51fa\u9ad8\u6548\u7684\u6c14\u4f53\u5206\u79bb\u6027\u80fd(\u5728H2\/CO2\u6df7\u5408\u6c14\u4f53\u4e2d)\uff0c\u8fd9\u4e24\u8005\u6750\u6599\u7684\u534f\u8c03\u6c14\u4f53\u5206\u79bb\u6027\u80fd\u7684\u4e5f\u88ab\u8bc1\u5b9e\u4e86\uff0c\u5728COF-MOF\u590d\u5408\u819c\u8d85\u8d8a\u4e86\u7f57\u4f2f\u900a\u805a\u5408\u7269\u819c\u5bf9H2\/CO2\u6c14\u4f53\u5bf9\u6df7\u5408\u5206\u79bb\u7684\u4e0a\u9650\u3002<\/p>\n \u56fe MOF-COF\u590d\u5408\u819c\u7684\u5236\u5907\u6d41\u7a0b<\/p>\n \u6587\u732e\u94fe\u63a5\uff1aFabrication of COF-MOF Composite Membranes and Their Highly Selective Separation of H2\/CO<\/a><\/strong><\/p>\n 3\u3001JACS<\/strong>\uff1a\u94b4\uff08<\/strong>II<\/strong>\uff09\u4e09\u5511<\/strong>\/<\/strong>\u5421\u5511\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u53ca\u5176\u53ef\u9009\u62e9\u7684\u3001\u53ef\u8c03\u7684\u7ed3\u5408\u6c27\u6c14<\/strong><\/p>\n \u4e3b\u8981\u7684\u7814\u7a76\u5185\u5bb9\u53ca\u521b\u65b0\u70b9<\/strong>:<\/strong><\/p>\n \u6700\u8fd1\uff0c\u7531\u4e8e\u5de5\u4e1a\u5316\u7684\u8fdb\u7a0b\u548c\u4eba\u7c7b\u7684\u6d3b\u52a8\uff0c\u5927\u6c14\u4e2d\u4e0d\u65ad\u589e\u52a0\u4e8c\u6c27\u5316\u78b3\uff0c\u8fd9\u5c31\u4f7f\u5f97\u5f88\u591a\u6750\u6599\u5b66\u5bb6\u90fd\u5728\u81f4\u529b\u4e8e\u5f00\u53d1\u65b0\u578b\u6750\u6599\u6765\u964d\u4f4e\u7a7a\u6c14\u4e2d\u7684CO2\u542b\u91cf\uff0c\u4f46\u662f\u5728\u63d0\u51fa\u7684\u5f88\u591a\u78b3\u6355\u6349\u7684\u6280\u672f\u4e2d\uff0c\u90fd\u662f\u9700\u8981\u9ad8\u7eaf\u5ea6\u7684O2\u3002\u5176\u6b21\uff0c\u5728\u8bb8\u591a\u5de5\u4e1a\u751f\u4ea7\u90fd\u662f\u9700\u8981\u5927\u91cf\u7eaf\u51c0\u7684\u6c27\u6c14\uff0c\u8fd9\u5c31\u4fc3\u4f7f\u4eba\u4eec\u7814\u53d1\u4e00\u79cd\u4ef7\u683c\u4f4e\u5ec9\u3001\u9ad8\u6548\u7684\u6c14\u4f53\u5206\u79bb\u6280\u672f\u3002<\/p>\n \u5728\u672c\u6587\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u5728\u65e0\u6c27\u7684\u6761\u4ef6\u4e0b\uff0c\u5728CoCl2\u548c1,3,5-tri(1H-1,2,3-triazol-5-yl)benzene (H3BTTri)\u5728DMF\u548c\u7532\u9187\u4f53\u7cfb\u4e2d\u5408\u6210\u4e86\u4e00\u79cdMOFs\uff08Co-BTTri (Co3[(Co4Cl)3(BTTri)8]2\u00b7DMF)\uff09\uff0c\u5728\u8be5\u79cdMOF\u53bb\u6eb6\u5242\u5316\u4ee5\u540e\uff0c\u4f1a\u4ea7\u751f\u4e0d\u9971\u548c\u7684\u4f4e\u81ea\u65cb\u94b4\uff08II\uff09\u7684\u4e2d\u5fc3\uff0c\u8fd9\u4e2a\u4e0d\u9971\u548c\u7684\u91d1\u5c5e\u4e2d\u5fc3\u4e0eO2\u7684\u7ed3\u5408\u80fd\u529b\u5927\u4e8e\u4e0eN2\u7684\u7ed3\u5408\u80fd\u529b\uff0c\u9aa8\u67b6\u4e2d\u4e0d\u9971\u548c\u4f4e\u81ea\u65cb\u91d1\u5c5e\u4e2d\u5fc3\u7531\u5176\u7ed3\u6784\u3001\u78c1\u5316\u7387\u548c\u7406\u8bba\u8ba1\u7b97\u7ed3\u679c\u8bc1\u660e\u3002\u5355\u6676\u884d\u5c04\u7ed3\u6784\u8868\u5f81\u4e86\u6750\u6599\u7684\u7ed3\u6784\u548c\u4e0eO2\u7ed3\u5408\u7684\u60c5\u51b5\u3002\u8fd9\u79cd\u6750\u6599\u7684\u4f18\u826f\u9009\u62e9\u6027\u6c14\u4f53\u5206\u79bb\u6027\u80fd\u4e3a\u8be5\u6750\u6599\u7684\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n \u56fe Co-BTTri\u7684\u7ed3\u6784\u56fe<\/p>\n<\/p>\n
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