{"id":161980,"date":"2018-12-16T06:26:56","date_gmt":"2018-12-15T22:26:56","guid":{"rendered":"\/\/m.iemloyee.com\/?p=161980"},"modified":"2018-12-15T21:37:47","modified_gmt":"2018-12-15T13:37:47","slug":"%e5%b7%b2%e6%a0%a1-%e5%8c%97%e5%a4%a7%e9%83%ad%e5%b0%91%e5%86%9badv-mater-mo%e6%8e%ba%e6%9d%82in2o3-znin2se4-%e8%b6%85%e8%96%84z%e5%9e%8b%e7%ba%b3%e7%b1%b3%e7%89%87%e7%9a%84%e5%88%b6%e5%a4%87","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=161980","title":{"rendered":"\u5317\u5927\u90ed\u5c11\u519bAdv. Mater. : Mo\u63ba\u6742In2O3-ZnIn2Se4 \u8d85\u8584Z\u578b\u7eb3\u7c73\u7247\u7684\u5236\u5907\u53ca\u5176\u5149\u50ac\u5316\u5236\u6c22"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\n \u53d7\u81ea\u7136\u5149\u5408\u4f5c\u7528\u7684\u542f\u53d1\uff0c\u7814\u7a76\u4eba\u5458\u8bbe\u8ba1\u4e86\u57fa\u4e8e\u4e24\u79cd\u534a\u5bfc\u4f53\u7684\u591a\u79cd\u5168\u56fa\u6001\u4eba\u5de5Z\u578b\u5149\u50ac\u5316\u4f53\u7cfb\uff0c\u5176\u5177\u6709\u826f\u597d\u5339\u914d\u7684\u80fd\u5e26\u7ed3\u6784\u3002\u7136\u800c\u8fc4\u4eca\u4e3a\u6b62\uff0c\u5927\u591a\u6570\u62a5\u9053\u7684Z\u578b\u5149\u50ac\u5316\u5242\u4f53\u7cfb\u4ece\u4f53\u76f8\u5230\u50ac\u5316\u5242\u8868\u9762\u7684\u7535\u8377\u8f6c\u79fb\u6548\u7387\u4ecd\u7136\u8f83\u4f4e\u3002\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u4e30\u5bcc\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u548c\u8f83\u77ed\u8f7d\u6d41\u5b50\u6269\u6563\u7a0b\u957f\u76842D\u7eb3\u7c73\u7247\u5728\u591a\u76f8\u5149\u50ac\u5316\u4e2d\u5177\u6709\u5e7f\u6cdb\u5e94\u7528\u30022D\u51e0\u4f55\u7ed3\u6784\u7684\u91d1\u5c5e\u786b\u5316\u7269 (\u5982In2<\/sub>Se3<\/sub>\u3001ZnIn2<\/sub>S4<\/sub>\u7b49)\u5177\u6709\u72ec\u7279\u4e14\u53ef\u8c03\u8282\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u4f5c\u4e3a\u53ef\u89c1\u5149\u54cd\u5e94\u5149\u50ac\u5316\u5242\u53ef\u7528\u4e8e\u5149\u50ac\u5316\u5206\u89e3\u6c34\u3002\u6b64\u5916\uff0c\u50ac\u5316\u5242\u8868\u9762\u548c\u7535\u89e3\u8d28\u754c\u9762\u5904\u7684\u6c34\u8fd8\u539f\u52a8\u529b\u5b66\u4e5f\u662f\u9650\u5236\u6790\u6c22\u7684\u5173\u952e\u56e0\u7d20\u3002\u53ef\u63a7\u8868\u9762\u5de5\u7a0b\u7684\u5143\u7d20\u63ba\u5165\u53ef\u4ee5\u5b9e\u73b0\u6d3b\u6027\u4f4d\u70b9\u7684\u534f\u540c\u8c03\u8282\u4ee5\u53ca\u5438\u9644\u6216\u89e3\u5438\uff0c\u4ee5\u5b9e\u73b0\u6709\u6548\u7684\u5236\u6c22\u6027\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\n \u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u90ed\u5c11\u519b\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5236\u5907\u4e86\u4e00\u7c7b\u8d85\u8584In2<\/sub>O3<\/sub>-ZnIn2<\/sub>Se4<\/sub>(\u7b80\u79f0In2<\/sub>O3<\/sub>-ZISe)\u81ea\u53d1Z\u578b\u7eb3\u7c73\u7247\u5149\u50ac\u5316\u5242\uff0c\u53ef\u663e\u8457\u589e\u5f3a\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd\u3002\u901a\u8fc7\u5f62\u6210Mo-Se\u952e\uff0c\u5c06Mo\u539f\u5b50\u5f15\u5165Z\u578bIn2<\/sub>O3<\/sub>-ZISe\u7eb3\u7c73\u7247\u5149\u50ac\u5316\u5242\u4e2d\uff0c\u5236\u5907\u7684In2<\/sub>O3<\/sub>-ZISe-Mo\u7684\u5149\u50ac\u5316\u5236\u6c22\u6d3b\u6027\uff0c\u76f8\u6bd4In2<\/sub>O3<\/sub>-ZnIn2<\/sub>Se4<\/sub>\u548cIn2<\/sub>O3<\/sub>\u7eb3\u7c73\u7247\u5206\u522b\u9ad8\u51fa21.7\u548c232.6\u500d\u3002In2<\/sub>O3<\/sub>-ZISe-Mo\u5177\u6709\u8f83\u597d\u7684\u5149\u50ac\u5316\u5236\u6c22\u7a33\u5b9a\u6027\uff0c16 h\u5b9e\u9a8c\u6d3b\u6027\u51e0\u4e4e\u6ca1\u6709\u8870\u51cf\u3002\u7d2b\u5916-\u53ef\u89c1\u6f2b\u53cd\u5c04\u5149\u8c31\u3001\u5149\u81f4\u53d1\u5149\u5149\u8c31\u3001\u77ac\u6001\u5149\u7535\u6d41\u8c31\u548c\u7535\u5316\u5b66\u963b\u6297\u8c31\u8868\u660e\uff0cIn2<\/sub>O3<\/sub>-ZISe-Mo\u7684\u5149\u50ac\u5316\u6027\u80fd\u589e\u5f3a\u4e3b\u8981\u5f52\u56e0\u4e8e\u5176\u7279\u6b8a\u7ed3\u6784\u5f15\u8d77\u7684\u5149\u54cd\u5e94\u8303\u56f4\u6269\u5927\u548c\u6709\u6548\u8f7d\u6d41\u5b50\u5206\u79bb\u3002\u7ed3\u679c\u4ee5\u201cUltrathin Visible-Light-Driven Mo Incorporating In2<\/sub>O3<\/sub>-ZnIn2<\/sub>Se4<\/sub> Z-Scheme Nanosheet Photocatalysts<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Materials<\/strong>.<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 In2<\/sub>O3<\/sub>-ZISe\u7684\u80fd\u5e26\u7ed3\u6784\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

a, b) In2<\/sub>O3<\/sub>\u548cZnIn2<\/sub>Se4<\/sub>\u7684\u4f18\u5316\u51e0\u4f55\u7ed3\u6784\uff1b
\n c-f) In2<\/sub>O3<\/sub>\u548cZnIn2<\/sub>Se4<\/sub>\u76f8\u5e94\u7684\u6001\u5bc6\u5ea6(DOS)\u56fe\uff0c\u5176\u4e2d\u865a\u7ebf\u8868\u793a\u8d39\u7c73\u80fd\u7ea7\u3002<\/p>\n

\u56fe2 In2<\/sub>O3<\/sub>-ZISe Z\u578b\u7eb3\u7c73\u7247\u7684\u5f62\u8c8c\u548c\u5143\u7d20\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

a) In2<\/sub>O3<\/sub>-ZISe Z\u578b\u7eb3\u7c73\u7247\u7684SEM\u56fe\u50cf\uff1b
\n b, c) In2<\/sub>O3<\/sub>-ZISe Z\u578b\u7eb3\u7c73\u7247\u7684TEM\u56fe\u50cf\uff1b
\n d) In2<\/sub>O3<\/sub>-ZISe Z\u578b\u7eb3\u7c73\u7247\u7684AFM\u56fe\u50cf\uff1b
\n e) In2<\/sub>O3<\/sub>-ZISe Z\u578b\u7eb3\u7c73\u7247\u7684\u9ad8\u5ea6\u5206\u5e03\uff1b
\n f) In2<\/sub>O3<\/sub>-ZISe Z\u578b\u7eb3\u7c73\u7247\u7684HRTEM\u56fe\u50cf\uff1b
\n g) In2<\/sub>O3<\/sub>-ZISe Z\u578b\u7eb3\u7c73\u7247\u7684\u5143\u7d20\u5206\u5e03\u56fe\u50cf\u3002<\/p>\n

\u56fe3 In2<\/sub>O3<\/sub>-ZISe-Mo Z\u578b\u7eb3\u7c73\u7247\u7684\u5f62\u8c8c\u548c\u5143\u7d20\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

a, b) In2<\/sub>O3<\/sub>-ZISe-Mo Z\u578b\u7eb3\u7c73\u7247\u7684STEM\u56fe\u50cf\uff1b
\n c) In2<\/sub>O3<\/sub>-ZISe-Mo Z\u578b\u7eb3\u7c73\u7247\u7684\u5143\u7d20\u5206\u5e03\u56fe\u50cf\u3002<\/p>\n

\u56fe4 In2<\/sub>O3<\/sub>-ZISe-Mo Z\u578b\u7eb3\u7c73\u7247\u7684\u5236\u6c22\u6027\u80fd\u6d4b\u8bd5\u4e0e\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

a) \u4e0d\u540cIn2<\/sub>O3<\/sub>-ZISe\u7eb3\u7c73\u7247\u5236\u6c22\u91cf\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff1b
\n b) \u4e0d\u540cMo\u63ba\u5165\u91cf\u7684\u8d85\u8584In2<\/sub>O3<\/sub>-ZISe-Mo Z\u578b\u7eb3\u7c73\u7247\u7684\u5236\u6c22\u901f\u7387\uff1b
\n c) In2<\/sub>O3<\/sub>-ZISe-Mo\u7eb3\u7c73\u7247\u7684\u5149\u50ac\u5316\u5236\u6c22\u5faa\u73af\u7a33\u5b9a\u6027\uff1b
\n d) In2<\/sub>O3<\/sub>\u548cIn2<\/sub>O3<\/sub>-ZISe\u6837\u54c1\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\u548c\u5e26\u9699\u80fd\uff1b
\n e) In2<\/sub>O3<\/sub>\u548cIn2<\/sub>O3<\/sub>-ZISe\u6837\u54c1\u7684XPS\u4ef7\u5e26\u8c31\uff1b
\n f) In2<\/sub>O3<\/sub>-ZISe Z\u578b\u4f53\u7cfb\u7684\u5149\u50ac\u5316\u5236\u6c22\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe5 In2<\/sub>O3<\/sub>-ZISe-Mo Z\u578b\u7eb3\u7c73\u7247\u7684\u8f7d\u6d41\u5b50\u5206\u79bb<\/strong><\/p>\n

\"\"<\/p>\n

a) In2<\/sub>O3<\/sub>\u3001In2<\/sub>O3<\/sub>-ZISe\u548cIn2<\/sub>O3<\/sub>-ZISe-Mo\u7684\u7a33\u6001PL\u5149\u8c31\uff1b
\n b) In2<\/sub>O3<\/sub>\u3001In2<\/sub>O3<\/sub>-ZISe\u548cIn2<\/sub>O3<\/sub>-ZISe-Mo\u7684\u65f6\u95f4\u5206\u8fa8\u77ac\u6001PL\u8870\u51cf\u66f2\u7ebf\uff1b
\n c) In2<\/sub>O3<\/sub>\u3001In2<\/sub>O3<\/sub>-ZISe\u548cIn2<\/sub>O3<\/sub>-ZISe-Mo\u7684\u77ac\u6001\u5149\u7535\u6d41\uff1b
\n d) In2<\/sub>O3<\/sub>\u3001In2<\/sub>O3<\/sub>-ZISe\u548cIn2<\/sub>O3<\/sub>-ZISe-Mo\u7684EIS\u8c31\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\n \u4f5c\u8005\u4ece\u7406\u8bba\u548c\u5b9e\u9a8c\u4e0a\u8bc1\u660e\u4e86\u4e00\u7c7b\u65b0\u578b\u81ea\u53d1Z\u578bIn2<\/sub>O3<\/sub>-ZISe\u5149\u50ac\u5316\u4f53\u7cfb\u3002\u5f53Mo\u539f\u5b50\u4ee5Mo\u2014Se\u952e\u7684\u5f62\u5f0f\u8fdb\u4e00\u6b65\u63ba\u5165In2<\/sub>O3<\/sub>-ZISe Z\u578b\u7eb3\u7c73\u7247\u65f6\uff0c\u6240\u5f97In2<\/sub>O3<\/sub>-ZISe-Mo\u7eb3\u7c73\u7247\u53ef\u6574\u5408Z\u578b\u50ac\u5316\u5242\u548c\u52a9\u50ac\u5316\u5242\u7684\u4f18\u52bf\uff0c\u76f8\u6bd4In2<\/sub>O3<\/sub>-ZISe\u548cIn2<\/sub>O3<\/sub>\u7eb3\u7c73\u7247(\u5206\u522b\u4e3a319.7\u548c29.9 \u03bcmol\u00b7h-1<\/sup>\u00b7g-1<\/sup>)\u5177\u6709\u66f4\u9ad8\u7684\u5236\u6c22\u901f\u7387(6.95 mmol\u00b7h-1<\/sup>\u00b7g-1<\/sup>)\u3002\u572816 h\u6d4b\u8bd5\u540e\u5236\u6c22\u6d3b\u6027\u51e0\u4e4e\u6ca1\u6709\u964d\u4f4e\uff0c\u5177\u6709\u8f83\u9ad8\u7684\u5149\u50ac\u5316\u7a33\u5b9a\u6027\u3002 In2<\/sub>O3<\/sub>-ZISe-Mo\u7eb3\u7c73\u7247\u7684\u7d2b\u5916-\u53ef\u89c1\u6f2b\u53cd\u5c04\u5149\u8c31\u663e\u793a\u5176\u5149\u5438\u6536\u589e\u5f3a\uff0c\u5176PL\u5149\u8c31\u3001\u77ac\u6001\u5149\u7535\u6d41\u548cEIS\u663e\u793a\u5176\u53ef\u4fc3\u8fdb\u5149\u751f\u8f7d\u6d41\u5b50\u7684\u5206\u79bb\u548c\u4f20\u8f93\uff0c\u8fd9\u4e24\u8005\u90fd\u662f\u63a8\u52a8\u5149\u50ac\u5316\u5236\u6c22\u7684\u5173\u952e\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aUltrathin Visible-Light-Driven Mo Incorporating In2<\/sub>O3<\/sub>\u2013ZnIn2<\/sub>Se4<\/sub> Z-Scheme Nanosheet Photocatalysts<\/a> <\/strong>(Adv. Mater.<\/strong>, 2018, DOI: 10.1002\/adma.201807226)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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