{"id":161518,"date":"2018-12-18T06:11:57","date_gmt":"2018-12-17T22:11:57","guid":{"rendered":"\/\/m.iemloyee.com\/?p=161518"},"modified":"2018-12-16T22:21:06","modified_gmt":"2018-12-16T14:21:06","slug":"%e5%b9%b2%e8%b4%a7%ef%bc%9a%e4%b8%80%e6%96%87%e8%a7%a3%e8%af%bb%e9%93%9c%e5%9f%baco2%e8%bf%98%e5%8e%9f%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=161518","title":{"rendered":"\u5e72\u8d27\uff1a\u4e00\u6587\u89e3\u8bfb\u94dc\u57faCO2\u8fd8\u539f\u50ac\u5316\u5242"},"content":{"rendered":"

\u94dc\u57fa\u6750\u6599\u662fCO2<\/sub>\u8fd8\u539f\u53cd\u5e94\u4e2d\u975e\u5e38\u7279\u6b8a\u7684\u4e00\u7c7b\u50ac\u5316\u5242\uff0c\u65e0\u8bba\u662f\u5728CO2<\/sub>\u7535\u8fd8\u539f\u8fd8\u662f\u70ed\u8fd8\u539f\u52a0\u6c22\u53cd\u5e94\u3002Rossmeisl\u6559\u6388\u5728\u5176\u7efc\u8ff0[ChemPhysChem 2017, 18, 3266-3273]\u4e2d\u8ba4\u4e3aCu\u7684\u7279\u6b8a\u6027\u5728\u4e8eCu\u5bf9H\u7684\u5438\u9644\u5f31\uff0c\u800c\u5bf9CO\u7684\u5438\u9644\u9002\u4e2d\u3002\u5bf9H\u7684\u5438\u9644\u5f31\uff0c\u51b3\u5b9a\u4e86Cu\u5728\u7535\u5316\u5b66\u53cd\u5e94\u4e2d\u53ef\u4ee5\u6291\u5236\u4ea7\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u8fdb\u884c\uff0c\u63d0\u9ad8\u542b\u78b3\u4ea7\u7269\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\uff1b\u800c\u5728\u70ed\u50ac\u5316\u52a0\u6c22\u4e2d\uff0c\u53ef\u4ee5\u907f\u514dC\u5b8c\u5168\u52a0\u6c22\u751f\u6210\u7532\u70f7\uff0c\u56e0\u6b64Cu\u662fCO2<\/sub>\u52a0\u6c22\u5236\u7532\u9187\u7684\u9ad8\u6548\u50ac\u5316\u5242\uff0c\u526f\u4ea7\u7269\u4e3b\u8981\u662f\u9006\u6c34\u6c7d\u53d8\u6362\u53cd\u5e94\u4ea7\u751f\u7684CO\u3002\u5bf9CO\u7684\u5438\u9644\u9002\u4e2d\uff0c\u4fdd\u8bc1\u4e86Cu\u5728CO2<\/sub>\u8fd8\u539f\u4e2d\u4e00\u5b9a\u7684\u6d3b\u6027\uff0c\u540c\u65f6scaling relation\u51b3\u5b9a\u4e86C-C\u5076\u8054\u5f88\u96be\u5728Cu\u4e0a\u53d1\u751f\uff0c\u56e0\u6b64\uff0cCO2<\/sub>\u52a0\u6c22\u5236\u9ad8\u78b3\u4ea7\u7269\u7684\u50ac\u5316\u5242\u4e00\u822c\u662f\u94c1\u57fa\u50ac\u5316\u5242\uff08Fe3<\/sub>O4<\/sub>\u53ef\u4ee5\u9006\u6c34\u6c7d\u53d8\u6362\uff0cFe5<\/sub>C2<\/sub>\u53ef\u4ee5\u8d39\u6258\uff09\uff0cPS\uff1a\u8fd9\u4e00\u70b9\u4f3c\u4e4e\u53ef\u4ee5\u5229\u7528\u4f5c\u4e3a\u8f85\u52a9\u6d3b\u6027\u4f4d\u70b9\u5f97\u5230\u77ed\u94fe\u70ef\u70c3\u3002\u800c\u5728\u7535\u50ac\u5316\u4e2d\uff0c\u7531\u4e8e\u7535\u5b50\u8f6c\u79fb\u7684\u6548\u7387\u66f4\u4e3a\u9ad8\u6548\uff0c\u52a0\u4e0a\u9002\u5f53\u7684\u5316\u5b66\u4fee\u9970\uff0c\u5982\u5408\u91d1\u5316\uff0c\u63ba\u6742\u975e\u91d1\u5c5e\u7b49\u6765\u8c03\u63a7\u5bf9\u4e2d\u95f4\u7269\u79cd\u7684\u5438\u9644\u80fd\u529b\uff0c\u5c31\u53ef\u4ee5\u9ad8\u9009\u62e9\u6027\u7684\u5f97\u5230\u9ad8\u78b3\u4ea7\u7269\u3002<\/p>\n

\uff081\uff09CO2<\/sub>\u7535\u8fd8\u539f<\/p>\n

Hori\u7b49\u5c06\u4f20\u7edf\u91d1\u5c5e\u7535\u6781\u6750\u6599\u6309\u7167\u8fd8\u539f\u4ea7\u7269\u5206\u7c7b\u5982\u4e0b:\uff081\uff09\u4e3b\u4ea7\u7269\u662fHCOOH\u7684\u6750\u6599\uff1aCd\u3001In\u3001Sn\u3001Hg\u3001Tl\u3001Pb\u7b49\uff1b\uff082\uff09\u4e3b\u4ea7\u7269\u662fCO\u7684\u6750\u6599\uff1aAg\u3001Au\u3001Zn\u7b49\uff1b\uff083\uff09\u4e3b\u4ea7\u7269\u662fH2\u7684\u6750\u6599\uff1aNi\u3001Fe\u3001Pd\u3001Pt\u3001Ti \u7b49\uff1b\uff084\uff09\u4e3b\u4ea7\u7269\u662f\u70c3\u7c7b\u7684\u6750\u6599\u53ea\u6709Cu\uff0c\u5982\u56fe1\u6240\u793a\u3002<\/p>\n

\u56fe1. \u4e0d\u540c\u50ac\u5316\u5242CO2<\/sub>\u7535\u8fd8\u539f\u4ea7\u7269\u3002\u8be5\u56fe\u9009\u81ea[ChemPhysChem 2017, 18, 3266-3273]\uff0c\u6539\u7f16\u81ea[J. Chem. Soc. Faraday Trans. 1989, 85, 2309-2326.]\u3002<\/p>\n

\"\"<\/p>\n

\u8fc4\u4eca\u4e3a\u6b62\uff0c\u6240\u6709\u9ad8\u78b3\u4ea7\u7269\u7684\u50ac\u5316\u5242\u57fa\u672c\u90fd\u662fCu\u57fa\u50ac\u5316\u5242\u3002\u4e00\u79cd\u5178\u578b\u7684CO2<\/sub>\u7535\u8fd8\u539f\u5236C2+<\/sub>\u4ea7\u7269\u7684\u50ac\u5316\u5242\u5c31\u662fCu\u57fa\u5408\u91d1\u5982Cu-Ag\u3001Cu-Au\u3001Cu-Pd\u3001Cu-Zn\u7b49\uff0c\u89c1\u88681\u3002\u6700\u8fd1\uff0c\u4e54\u4e16\u748b\u8bfe\u9898\u7ec4\u5728\u5176\u7efc\u8ff0\u4e2d\u961f\u4e0eCu\u5f62\u6210\u5408\u91d1\u7684\u91d1\u5c5e\u8fdb\u884c\u4e86\u5206\u7c7b\uff0c\u4ed6\u4eec\u7684\u5206\u7c7b\u4f9d\u636e\u662f\u8be5\u91d1\u5c5e\u4e0eCu\u76f8\u6bd4\uff0c\u662f\u4eb2O\uff0c\u8fd8\u662f\u4eb2H\uff0c\u89c1\u56fe2[Chem 2018, 4, 1809-1831]\u3002\u5bf9\u4e8e\u6bd4Cu\u5bf9O\u7684\u5438\u9644\u66f4\u5f3a\u4f46\u5bf9H\u7684\u5438\u9644\u66f4\u5f31\u7684\u91d1\u5c5e\u5982In, Sn, Hg\u548cPb\u6765\u8bf4\uff0c*COOH\u662f\u7b2c\u4e00\u6b65\u4ea7\u7269\uff0c\u56e0\u6b64\u53cd\u5e94\u4e3b\u8981\u4ea7\u7269\u662fHCOOH\u3002\u5bf9\u4e8e\u6bd4Cu\u5bf9O\u548cH\u7684\u5438\u9644\u90fd\u5f31\u7684\u91d1\u5c5e\u5982Zn, Ag\u548cAu\u6765\u8bf4\uff0c\u5b83\u4eec\u5bf9*COOH\u7684\u5438\u9644\u6bd4*CO\u5f3a\uff0c\u56e0\u6b64CO\u66f4\u5bb9\u6613\u8131\u9644\uff0c\u5e76\u6210\u4e3a\u4e3b\u8981\u4ea7\u7269\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u6bd4Cu\u5bf9H\u7684\u5438\u9644\u66f4\u5f3a\u7684\u91d1\u5c5e\uff0c\u65e0\u8bba\u5b83\u4eec\u5bf9O\u7684\u5438\u9644\u662f\u5f31\uff08\u5982Pd\uff09\u8fd8\u662f\u5f3a\uff08\u5982Co, Ni, Fe, Ir\u548cPt\uff09\uff0cHER\u90fd\u662f\u4e3b\u8981\u53cd\u5e94\u3002\u7b14\u8005\u8ba4\u4e3a\u8fd9\u79cd\u5212\u5206\u5bf9C1<\/sub>\u4ea7\u7269\u5f88\u6709\u6548\uff0c\u800c\u5bf9\u4e8eC2+<\/sub>\u4ea7\u7269\uff0c\u5219\u4f1a\u6d89\u53ca\u5230C-C\u5076\u8054\uff0c\u5c31\u9700\u8981\u8003\u8651\u5230C,H,O\u4e09\u79cd\u5143\u7d20\u4e4b\u95f4\u7684\u7ade\u4e89\u5438\u9644\u4e86\u3002\u4e0d\u540c\u4e8e\u5148\u524d\u8bfe\u9898\u7ec4\u7684\u5408\u91d1\u4f53\u7cfb\uff0cSargent\u6559\u6388\u8bfe\u9898\u7ec4\u5229\u7528\u975e\u91d1\u5c5e\u63ba\u6742\u5b9e\u73b0\u4e86\u5f88\u9ad8\u7684C2+<\/sub>\u4ea7\u7269\u9009\u62e9\u6027\u3002<\/p>\n

\u88681. Cu\u57fa\u50ac\u5316\u5242CO2<\/sub>\u7535\u8fd8\u539f\u5236C2+<\/sub>\u4ea7\u7269\u603b\u7ed3\u3002<\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
\n

\u50ac\u5316\u5242<\/p>\n<\/td>\n

\n

\u7535\u89e3\u6db2<\/p>\n<\/td>\n

\n

\u7535\u52bf<\/p>\n<\/td>\n

\n

\u9009\u62e9\u6027<\/p>\n<\/td>\n

\n

\u53c2\u8003\u6587\u732e<\/p>\n<\/td>\n<\/tr>\n

\n

graphite\/carbon NPs\/Cu\/PTFE<\/p>\n<\/td>\n

\n

7 M KOH<\/p>\n<\/td>\n

\n

-0.55 V versus RHE<\/p>\n<\/td>\n

\n

C2<\/sub>H4<\/sub>\u00a0(70%)<\/p>\n<\/td>\n

\n

Science 2018, 360, 783\u2013787<\/p>\n<\/td>\n<\/tr>\n

\n

Cu(B)<\/p>\n<\/td>\n

\n

0.1\u2009M KCl<\/p>\n<\/td>\n

\n

-1.1\u2009V versus RHE<\/p>\n

 <\/p>\n<\/td>\n

\n

C2+<\/sub>\u00a0products (79%): C2<\/sub>H4<\/sub>\u00a0(52%), C2<\/sub>H5<\/sub>OH (27%)<\/p>\n<\/td>\n

\n

Nat. Chem. 2018, 10, 974-980<\/p>\n<\/td>\n<\/tr>\n

\n

Cu2<\/sub>S\u2013Cu-V<\/p>\n<\/td>\n

\n

0.1 M KHCO<\/p>\n<\/td>\n

\n

-0.95 V versus RHE<\/p>\n<\/td>\n

\n

C3<\/sub>H7<\/sub>OH (8%), C2<\/sub>H5<\/sub>OH (15%)<\/p>\n<\/td>\n

\n

Nat. Catal. 2018, 1, 421-428<\/p>\n<\/td>\n<\/tr>\n

\n

Cu-on-Cu3<\/sub>N<\/p>\n<\/td>\n

\n

0.1 M KHCO3<\/p>\n<\/td>\n

\n

-0.95 V versus\u00a0RHE<\/p>\n<\/td>\n

\n

C2+<\/sub>\u00a0products (64%): C2<\/sub>H4<\/sub>\u00a0(39%), C2<\/sub>H5<\/sub>OH (19%), C3<\/sub>H7<\/sub>OH (6%)<\/p>\n<\/td>\n

\n

Nat. Commun. 2018, 9, 3828<\/p>\n<\/td>\n<\/tr>\n

\n

Cu63.9<\/sub>Au36.1<\/sub>\/NCF<\/p>\n<\/td>\n

\n

0.5 M KHCO3<\/sub><\/p>\n<\/td>\n

\n

-1.1 V versus SCE<\/p>\n<\/td>\n

\n

CH3<\/sub>OH (15.9%), C2<\/sub>H5<\/sub>OH (12%)<\/p>\n<\/td>\n

\n

J. Power Sources 2014, 252, 85\u201389.<\/p>\n<\/td>\n<\/tr>\n

\n

Au@Cu<\/p>\n<\/td>\n

\n

PBS<\/p>\n<\/td>\n

\n

-0.6 V versus RHE<\/p>\n<\/td>\n

\n

C2<\/sub>H4<\/sub>\u00a0(distribution 20%)
\n CH4 <\/sub>(distribution 20%)<\/p>\n<\/td>\n

\n

J. Mater. Chem. A 2015, 3, 23690\u201323698.<\/p>\n<\/td>\n<\/tr>\n

\n

Ag@Cu<\/p>\n<\/td>\n

\n

0.1 M KHCO3<\/sub><\/p>\n<\/td>\n

\n

-1.06 V versus RHE<\/p>\n<\/td>\n

\n

CO (82%)
\n C2<\/sub>H4<\/sub>\u00a0(28.6%)<\/p>\n<\/td>\n

\n

J. Phys. Chem. C 2017, 121, 11368\u201311379.<\/p>\n<\/td>\n<\/tr>\n

\n

CuAg surface alloys<\/p>\n<\/td>\n

\n

0.05 M Cs2<\/sub>CO3<\/sub><\/p>\n<\/td>\n

\n

 <\/p>\n<\/td>\n

\n

CO dominant (low at % Cu)
\n H2<\/sub>\u00a0and C2<\/sub>H4<\/sub>\u00a0dominant (high at % Cu)<\/p>\n<\/td>\n

\n

J. Am. Chem. Soc. 2017, 139, 15848-15857.<\/p>\n<\/td>\n<\/tr>\n

\n

Nanocoral Cu-Ag<\/p>\n<\/td>\n

\n

0.2 M CsHCO3<\/sub><\/p>\n<\/td>\n

\n

-1.0 V versus RHE<\/p>\n<\/td>\n

\n

C2<\/sub>H4<\/sub>\u00a0(20%), H2<\/sub>\u00a0(30%\u201335%)<\/p>\n<\/td>\n

\n

Energy<\/p>\n

Environ. Sci. 2017, 10, 2222\u20132230<\/p>\n<\/td>\n<\/tr>\n

\n

Oxide-derived Cu4<\/sub>Zn<\/p>\n<\/td>\n

\n

0.1 M KHCO3<\/sub><\/p>\n<\/td>\n

\n

-1.05 V versus RHE<\/p>\n<\/td>\n

\n

C2<\/sub>H5<\/sub>OH (29.1%), C2<\/sub>H4<\/sub>\u00a0(10%)<\/p>\n<\/td>\n

\n

ACS Catal. 2016, 6, 8239\u20138247<\/p>\n<\/td>\n<\/tr>\n

\n

Pd-decorated Cu<\/p>\n<\/td>\n

\n

0.5 M KHCO3<\/sub><\/p>\n<\/td>\n

\n

-0.96 V versus RHE<\/p>\n<\/td>\n

\n

CH4<\/sub>\u00a0(46%\u201340%), C2<\/sub>H4<\/sub>\u00a0(7\u201311%)<\/p>\n<\/td>\n

\n

Angew. Chem. Int. Ed. 2017, 56, 13135\u201313139<\/p>\n<\/td>\n<\/tr>\n

\n

PhaseSep CuPd<\/p>\n<\/td>\n

\n

1 M KOH<\/p>\n<\/td>\n

\n

-0.74 V versus RHE<\/p>\n<\/td>\n

\n

C2<\/sub>\u00a0chemicals (65%)<\/p>\n<\/td>\n

\n

J. Am. Chem. Soc. 2017, 139, 47\u201350<\/p>\n<\/td>\n<\/tr>\n

\n

Cu2<\/sub>O-derived Cu with PdCl2<\/sub><\/p>\n<\/td>\n

\n

0.1 M KHCO3<\/sub><\/p>\n<\/td>\n

\n

-1.0 V versus RHE<\/p>\n<\/td>\n

\n

C2<\/sub>H6<\/sub>\u00a0(30.1%), C2<\/sub>H4<\/sub>\u00a0(3.4%)<\/p>\n<\/td>\n

\n

J. Phys. Chem. C 2015, 119, 26875\u201326882<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u00a0<\/p>\n

\u56fe2. \u57fa\u4e8eH\u548cO\u7684\u5438\u9644\u80fd\u529b\u5bf9\u91d1\u5c5e\u7684\u5206\u7c7b[Chem 2018, 4, 1809-1831]\u3002<\/p>\n

\"\"<\/p>\n

\uff082\uff09CO2<\/sub>\u52a0\u6c22<\/p>\n

Cu\/ZnO\/Al2<\/sub>O3<\/sub>\u662f20\u4e16\u7eaa70\u5e74\u4ee3ICI\u516c\u53f8\u53d1\u660e\u7684\u4e00\u79cd\u7528\u4e8e\u5236\u7532\u9187\u7684\u5546\u7528\u50ac\u5316\u5242\uff0c\u4e00\u76f4\u4ee5\u6765\u5c31\u5e7f\u53d7\u5173\u6ce8\uff0c\u5bf9\u5176\u6d3b\u6027\u4f4d\u70b9\u7684\u7814\u7a76\u7ecf\u4e45\u4e0d\u8870\u3002\u6709\u4eba\u8ba4\u4e3aCu \u57fa\u50ac\u5316\u5242\u6d3b\u6027\u6210\u5206\u4e3a Cu0<\/sup>\u548c Cu+<\/sup>\uff0c\u4e14 Cu+<\/sup>\/Cu \u7684\u6bd4\u503c\u4e3a 0.7 \u65f6\u50ac\u5316\u5242\u6027\u80fd\u6700\u4f73\uff0cDFT\u8ba1\u7b97\u4e5f\u8868\u660eCu+<\/sup>\u51fa\u73b0\u5728Cu\u4e0e\u6c27\u5316\u7269\u8f7d\u4f53\u754c\u9762\u4e0a\uff0c\u4e14Cu+<\/sup>\u4e3b\u8981\u50ac\u5316\u751f\u6210\u7532\u9187\u7684\u53cd\u5e94\uff0c\u9006\u6c34\u6c7d\u53cd\u5e94\u5728 Cu0<\/sup>\u4e0a\u8fdb\u884c[Science\uff0c2014\uff0c345\uff1a546-550]\u3002\u7136\u800c\uff0c\u4e5f\u6709\u4eba\u8ba4\u4e3aCu\u57fa\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4f4d\u70b9\u4ec5\u4e3aCu0<\/sup>\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0cCO2<\/sub>\u5728Cu(111)\u3001Cu(100)\u548cCu(110)\u7b49\u4f4e\u6307\u6570\u6676\u9762\u4e0a\u5438\u9644\u8f83\u5f31\uff0c\u8868\u73b0\u51fa\u8f83\u4f4e\u7684CO2<\/sub>\u52a0\u6c22\u6d3b\u6027\u53ca\u7532\u9187\u9009\u62e9\u6027\uff0c\u4ea7\u7269\u4e3b\u8981\u4e3aCO\u3002<\/p>\n

2012\u5e74\uff0cBehrens\u548cSchl\u00f6gl\u8bfe\u9898\u7ec4\u7814\u7a76\u8ba4\u4e3a\uff081\uff09\u5e73\u9762\u7684\u7eafCu\u5bf9\u7532\u9187\u5408\u6210\u7684\u6d3b\u6027\u4f4e\uff1b\uff082\uff09Cu\u7684\u53f0\u9636\u9762\u80fd\u589e\u5f3a\u5bf9\u4e2d\u95f4\u4ea7\u7269\u7684\u5438\u9644\uff0c\u964d\u4f4e\u53cd\u5e94\u80fd\u5792\uff0c\u662f\u7532\u9187\u5408\u6210\u7684\u6d3b\u6027\u4f4d\u70b9\uff1b\uff083\uff09\u5728Cu\u7684\u7f3a\u9677\u4f4d\u63ba\u5165Zn\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u7532\u9187\u5408\u6210\u7684\u6d3b\u6027\uff0c\u542b\u6c27\u4e2d\u95f4\u7269\u79cd\uff08HCOO*, H2<\/sub>CO*\uff0cH3<\/sub>CO*\u7b49\uff09\u901a\u8fc7O\u539f\u5b50\u4e0e\u50ac\u5316\u5242\u8868\u9762\u8fde\u63a5\uff0c\u63ba\u6742Zn\u540e\uff0c\u53ef\u4ee5\u589e\u5f3a\u6d3b\u6027\u4f4d\u70b9\u5bf9\u542b\u6c27\u4e2d\u95f4\u7269\u79cd\u7684\u5438\u9644\u3002ZnO\u4e0eCu\u4e4b\u95f4\u91d1\u5c5e\u8f7d\u4f53\u5f3a\u76f8\u4e92\u4f5c\u7528\u4f7fCu\u9897\u7c92\u88ab\u90e8\u5206ZnOx<\/sub>\u8986\u76d6 [Science, 2012: 1219831]\u3002\u8be5\u7814\u7a76\u56e2\u961f\u8ba4\u4e3aCO2\u52a0\u6c22\u5728Cu-Zn\u8868\u9762\u8d70\u7684\u662f\u7532\u9178\u76d0\u8def\u5f84\uff0c\u800c\u4e0d\u662f\u9006\u6c34\u6c7d\u53d8\u6362\u8def\u5f84\uff0c\u89c1\u56fe3a\u30022016\u5e74\uff0cSehested\u7ec4\u5b9a\u91cf\u5206\u6790\u4e86ZnO\u5bf9Cu\u7684\u4fc3\u8fdb\u4f5c\u7528\u3002\u4ed6\u4eec\u53d1\u73b0\u65e0\u8bba\u662fZn\u8986\u76d6\u5728Cu\u7684\u4f4e\u6307\u6570\u6676\u9762\uff0c\u8fd8\u662f\u53f0\u9636\u9762\uff0c\u90fd\u80fd\u5f62\u6210\u6d3b\u6027\u4f4d\u70b9\u3002\u89c1\u56fe3b\uff0cZn\u7684\u8986\u76d6\u5ea6\u8d8a\u9ad8\uff0c\u50ac\u5316\u5242\u6d3b\u6027\u8d8a\u9ad8\u3002\u6b64\u5916\uff0c\u5728Cu\/ZnO\u50ac\u5316\u5242\u4e2d\uff0cZnO\u548cCu\u7684\u9897\u7c92\u5c3a\u5bf8\u5927\u5c0f\u4e5f\u4e0eZn\u7684\u8986\u76d6\u5ea6\u76f8\u5173\uff0c\u4e00\u822c\u800c\u8a00\uff0cZnO\u7684\u9897\u7c92\u8d8a\u5927\uff0cZn\u7684\u8986\u76d6\u5ea6\u8d8a\u4f4e\uff1bCu\u7684\u9897\u7c92\u8d8a\u5c0f\uff0cZn\u7684\u8986\u76d6\u5ea6\u8d8a\u4f4e\u30022017\u5e74\uff0cRodriguez\u8bfe\u9898\u7ec4\u7528ZnCu \u548cZnO\/Cu\u4e3a\u6a21\u578b\uff0c\u8fdb\u4e00\u6b65\u7814\u7a76\u4e86Cu\/ZnO\u50ac\u5316\u5242\u3002\u4ed6\u4eec\u53d1\u73b0ZnCu\u5408\u91d1\u5728CO2<\/sub>\u52a0\u6c22\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0cZn\u4f1a\u8f6c\u5316\u4e3aZnO\uff0c\u8fd9\u6837\u5177\u6709\u76f8\u540cZn\u8986\u76d6\u5ea6\u7684ZnCu \u548cZnO\/Cu\u7684\u6d3b\u6027\u4e5f\u63a5\u8fd1\u3002\u4ed6\u4eec\u8ba4\u4e3a\u8be5\u50ac\u5316\u5242\u8d70\u7532\u9178\u76d0\u8def\u5f84\uff0c\u4e14\u6d3b\u6027\u4f4d\u70b9\u5728Cu\u548cZnO\u7684\u754c\u9762\u51fa\uff0c\u89c1\u56fe3c\u548c3d\u3002<\/p>\n

\u56fe3.<\/p>\n

\"\"<\/p>\n

(a) Cu(111), Cu(211)\u548cCuZn(211)\u8868\u9762CO2<\/sub>\u52a0\u6c22\u5236\u7532\u9187\u8def\u5f84[Science, 2012: 1219831]\u3002 (b) Cu\/ZnO\/Al2<\/sub>O3<\/sub>\u50ac\u5316\u5242\u4e2dZn\u8986\u76d6\u5ea6\u5bf9\u7532\u9187\u6d3b\u6027\u7684\u5f71\u54cd[Science, 2016, 352,\u00a0969-974]\u3002(c) ZnCu(211)\u548c(d) ZnO\/Cu(111)\u8868\u9762CO2<\/sub>\u52a0\u6c22\u5236\u7532\u9187\u8def\u5f84[Science 2017, 355,\u00a01296-1299]\u3002<\/p>\n

\u901a\u8fc7\u8fd1\u5e74\u6765\u7684\u6587\u732e\u53ef\u4ee5\u770b\u51fa\uff0cCu\u57fa\u50ac\u5316\u5242\u65e0\u8bba\u5728CO2<\/sub>\u7535\u8fd8\u539f\u8fd8\u662fCO2<\/sub>\u52a0\u6c22\u53cd\u5e94\u4e2d\u90fd\u5177\u6709\u4e0d\u53ef\u53d6\u4ee3\u7684\u4f5c\u7528\uff0c\u65e0\u8bba\u662f\u4ece\u6027\u80fd\u4e0a\uff0c\u8fd8\u662f\u5728\u673a\u7406\u4e2d\uff0c\u5b83\u4eec\u4ecd\u6709\u5f88\u5927\u7684\u6f5c\u529b\u53ef\u6316\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u79d1\u6280\u987e\u95ee\u674e\u535a\u58eb<\/strong>\u4f9b\u7a3f\uff0c\u7f16\u8f91\u90e8\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenVIP<\/b><\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u94dc\u57fa\u6750\u6599\u662fCO2\u8fd8\u539f\u53cd\u5e94\u4e2d\u975e\u5e38\u7279\u6b8a\u7684\u4e00\u7c7b\u50ac\u5316\u5242\uff0c\u65e0\u8bba\u662f\u5728CO2\u7535\u8fd8\u539f\u8fd8\u662f\u70ed\u8fd8\u539f\u52a0\u6c22\u53cd\u5e94\u3002Rossmeisl\u6559\u6388\u5728\u5176\u7efc\u8ff0[ChemPhysChem 2017, 1…<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-161518","post","type-post","status-publish","format-standard","hentry","category-ganhuo"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/161518"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=161518"}],"version-history":[{"count":10,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/161518\/revisions"}],"predecessor-version":[{"id":162068,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/161518\/revisions\/162068"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=161518"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=161518"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=161518"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}