{"id":161403,"date":"2018-12-11T06:30:02","date_gmt":"2018-12-10T22:30:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=161403"},"modified":"2018-12-10T19:11:32","modified_gmt":"2018-12-10T11:11:32","slug":"%e5%8e%a6%e9%97%a8%e5%a4%a7%e5%ad%a6%e6%9d%8e%e5%89%91%e9%94%8b%e8%af%be%e9%a2%98%e7%bb%84nature-energy%ef%bc%9a%e5%8e%9f%e4%bd%8d%e6%8b%89%e6%9b%bc","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=161403","title":{"rendered":"\u53a6\u95e8\u5927\u5b66\u674e\u5251\u950b\u8bfe\u9898\u7ec4Nature Energy\uff1a\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u7814\u7a76\u94c2\u5355\u6676\u8868\u9762\u6c27\u8fd8\u539f\u53cd\u5e94\u673a\u7406\u53d6\u5f97\u65b0\u7a81\u7834"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u94c2\u57fa\u50ac\u5316\u5242\u8868\u9762\u7684\u6c27\u8fd8\u539f\u53cd\u5e94\uff08ORR\uff09\u662f\u71c3\u6599\u7535\u6c60\u6700\u91cd\u8981\u7684\u9634\u6781\u53cd\u5e94\u3002\u867d\u7136\u7ecf\u8fc7\u51e0\u5341\u5e74\u7684\u7814\u7a76\uff0cORR\u7684\u5177\u4f53\u53cd\u5e94\u8def\u5f84\u5e76\u6ca1\u6709\u771f\u6b63\u89e3\u6790\u6e05\u695a\u3002\u4eba\u4eec\u4e00\u822c\u8ba4\u4e3a\u94c2\u8868\u9762\u7684ORR\u8fc7\u7a0b\u53ef\u5206\u4e3a\u4e24\u7c7b\uff1a\u4e00\u7c7b\u662f\u6c27\u5206\u5b50\u7ecf\u8fc74\u7535\u5b50\u7684\u8fd8\u539f\u8fc7\u7a0b\u6700\u7ec8\u751f\u6210H2<\/sub>O\u6216OH\uff1b\u53e6\u4e00\u7c7b\u5219\u662f\u6c27\u5206\u5b50\u7ecf\u8fc72\u7535\u5b50\u7684\u8fd8\u539f\u8fc7\u7a0b\u751f\u6210\u8fc7\u6c27\u5316\u7269\u3002\u4f46\u5b9e\u9645\u94c2\u57fa\u50ac\u5316\u5242\u8868\u9762\u7684ORR\u8fc7\u7a0b\u7684\u5177\u4f53\u53cd\u5e94\u8def\u5f84\u5e76\u672a\u5f62\u6210\u5171\u8bc6\uff0c\u56e0\u4e3a\u8be5\u8fc7\u7a0b\u7275\u6d89\u5230\u4f17\u591a\u75d5\u91cf\u3001\u77ed\u5bff\u547d\u7684\u4e2d\u95f4\u7269\u79cd\uff0c\u96be\u4ee5\u88ab\u6709\u6548\u5730\u6355\u83b7\u3002\u540c\u65f6\u590d\u6742\u7684\u7535\u5316\u5b66\u73af\u5883\u4e5f\u7ed9ORR\u53cd\u5e94\u8def\u5f84\u548c\u673a\u7406\u7684\u7814\u7a76\u5e26\u6765\u6311\u6218\u3002\u867d\u7136\u539f\u5b50\u7ea7\u5e73\u6ed1\u7684\u5355\u6676\u8868\u9762\u5177\u6709\u786e\u5b9a\u7684\u8868\u9762\u539f\u5b50\u6392\u5e03\u7ed3\u6784\u4ee5\u53ca\u8868\u9762\u80fd\u7ea7\uff0c\u662f\u5173\u8054\u5b9e\u9a8c\u548c\u7406\u8bba\u7684\u7406\u60f3\u6a21\u578b\u4f53\u7cfb\u3002\u7136\u800c\u539f\u5b50\u7ea7\u5e73\u6ed1\u7684\u5355\u6676\u8868\u9762\u96be\u4ee5\u83b7\u5f97\u589e\u5f3a\u7684\u62c9\u66fc\u4fe1\u53f7\uff0c\u65e0\u6cd5\u83b7\u5f97ORR\u53cd\u5e94\u76f4\u63a5\u7684\u5149\u8c31\u8bc1\u636e\uff0c\u9650\u5236\u4e86\u4eba\u4eec\u5bf9ORR\u53cd\u5e94\u8fc7\u7a0b\u7684\u7406\u89e3\u548c\u9ad8\u6d3b\u6027\u50ac\u5316\u5242\u7684\u5236\u5907\u3002\u674e\u5251\u950b\u6559\u6388\u8bfe\u9898\u7ec4\u9996\u6b21<\/strong>\u5229\u7528\u7535\u5316\u5b66\u58f3\u5c42\u9694\u7edd\u7eb3\u7c73\u7c92\u5b50\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\uff08SHINERS\uff09\u6280\u672f\uff0c\u539f\u4f4d\u7814\u7a76\u4e86Pt(hkl<\/em>)\u5355\u6676\u8868\u9762\u7684ORR\u53cd\u5e94\u8fc7\u7a0b\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u53a6\u95e8\u5927\u5b66<\/strong>\u7684\u674e\u5251\u950b\u6559\u6388<\/strong>\u548c\u897f\u73ed\u7259<\/strong>Alicante<\/strong>\u5927\u5b66<\/strong>\u7684Juan Miguel Feliu<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\uff0c\u91c7\u7528\u539f\u4f4d\u7535\u5316\u5b66\u58f3\u5c42\u9694\u7edd\u7eb3\u7c73\u7c92\u5b50\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\uff08SHINERS\uff09\u548c\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\uff08DFT\uff09\uff0c\u7814\u7a76\u4e86Pt(hkl<\/em>)\u5355\u6676\u8868\u9762\u7684ORR\u53cd\u5e94\u8fc7\u7a0b\u3002\u8be5\u7814\u7a76\u5728Pt(111)\u5355\u6676\u8868\u9762\u83b7\u5f97ORR\u4e2d\u95f4\u7269\u79cdHO2<\/sub>*\u7684\u5149\u8c31\u8bc1\u636e\uff0c\u5728Pt(110)\u548cPt(100)\u5355\u6676\u8868\u9762\uff0c\u5219\u83b7\u5f97ORR\u4e2d\u95f4\u7269\u79cdOH*\u7684\u5149\u8c31\u8bc1\u636e\u3002\u800c\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c\u4ed6\u4eec\u5728Pt(hkl<\/em>)\u4e09\u4e2a\u57fa\u7840\u5355\u6676\u8868\u9762\u83b7\u5f97ORR\u8fc7\u7a0b\u7684\u4e2d\u95f4\u7269\u79cdO2<\/sub>–<\/sup>\u7684\u5149\u8c31\u8bc1\u636e\u3002\u56e0\u6b64\uff0cSHINERS\u6280\u672f\u4e3a\u539f\u5b50\u7ea7\u5e73\u6ed1\u7684\u5355\u6676\u8868\u9762\u7684\u50ac\u5316\u8fc7\u7a0b\u7684\u7814\u7a76\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u800c\u53ef\u9760\u7684\u539f\u4f4d\u5149\u8c31\u9014\u5f84\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>In situ Raman spectroscopic evidence for oxygen reduction reaction intermediates at platinum single-crystal surfaces<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Energy<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 Pt(hkl<\/em>)<\/strong>\u5355\u6676\u8868\u9762\u4e0a<\/strong>ORR<\/strong>\u8fc7\u7a0b\u793a\u610f\u56fe\u548c<\/strong>SHINs<\/strong>\u7ed3\u6784\u8868\u5f81\u53ca\u5176<\/strong>3D-FDTD<\/strong>\u6a21\u62df\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Pt(111)\u5355\u6676\u8868\u9762\u7684\u58f3\u5c42\u9694\u7edd\u7eb3\u7c73\u7c92\u5b50\uff08Au@SiO2<\/sub> NPs\uff0cSHINs\uff09\u6a21\u578b\u548c\u539f\u4f4d\u7535\u5316\u5b66SHINERS\u7814\u7a76ORR\u8fc7\u7a0b\u6a21\u578b\u56fe;<\/p>\n

\uff08b\uff09Au@SiO2<\/sub>\u7eb3\u7c73\u7c92\u5b50\u7684TEM\u56fe;<\/p>\n

\uff08c\uff09SHINs\u4fee\u9970\u7684Pt(111)\u5355\u6676\u7535\u6781\u8868\u9762\u7684SEM\u56fe;<\/p>\n

\uff08d\uff09Pt\u57fa\u5e95\u4e0a\uff0c2\u00d72\u9635\u5217SHINs\u7684\u7535\u78c1\u573a\u5206\u5e033D-FDTD\u6a21\u62df\u56fe\u3002<\/p>\n

\u56fe<\/strong> 2 <\/strong>\u9178\u6027\u6761\u4ef6\u4e0b\uff0c<\/strong>Pt(hkl<\/em>)<\/strong>\u5355\u6676\u8868\u9762<\/strong>ORR<\/strong>\u8fc7\u7a0b\u5206\u6790\u548c<\/strong>Pt(111)<\/strong>\u5355\u6676\u8868\u9762<\/strong>ORR<\/strong>\u8fc7\u7a0b\u7684\u539f\u4f4d<\/strong>SHINERS<\/strong>\u7814\u7a76\u53ca<\/strong>HO2<\/sub>*<\/strong>\u7269\u79cd\u7684<\/strong>DFT<\/strong>\u7406\u8bba\u6a21\u62df<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09O2<\/sub>\u9971\u548c\u76840.1 M HClO4<\/sub>\u6eb6\u6db2\u4e2d\uff0c\u4e09\u4e2a\u57fa\u7840Pt(hkl<\/em>)\u5355\u6676\u7535\u6781\u8868\u9762ORR\u53cd\u5e94\u7684RDE\u6781\u5316\u66f2\u7ebf\uff0c\u8f6c\u901f\u4e3a1600 r\/min\uff0c\u626b\u901f50 mV s-1<\/sup>\uff1b<\/p>\n

\uff08b\uff09O2<\/sub>\u9971\u548c\u76840.1 M HClO4<\/sub>\u6eb6\u6db2\u4e2d\uff0cPt(111)\u5355\u6676\u7535\u6781\u8868\u9762ORR\u8fc7\u7a0b\u7684\u539f\u4f4dSHINERS\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08c\uff09O-OH\u4f38\u7f29\u632f\u52a8\u5cf0\uff08732 cm-1<\/sup>\u9644\u8fd1\uff09\uff0c\u5728\u4e0d\u540c\u7535\u4f4d\u4e0b\u7684\u5f52\u4e00\u5316\u5f3a\u5ea6\u56fe\uff1b<\/p>\n

\uff08d\uff09Pt(111)\u8868\u9762\u9876\u4f4d\u548c\u6865\u4f4d\u5438\u9644\u6784\u578b\u7684HO2<\/sub>*\u7269\u79cd\u7684DFT\u7406\u8bba\u6a21\u62df\u56fe\u3002<\/p>\n

 <\/p>\n

\u56fe<\/strong> 3 <\/strong>\u9178\u6027\u6761\u4ef6\u4e0b\uff0c<\/strong>Pt(100)<\/strong>\u548c<\/strong>Pt(110)<\/strong>\u5355\u6676\u8868\u9762<\/strong>ORR<\/strong>\u8fc7\u7a0b\u7684\u539f\u4f4d\u7535\u5316\u5b66<\/strong>SHINERS<\/strong>\u7ed3\u679c\u548c<\/strong>Pt(110)<\/strong>\u8868\u9762<\/strong>OH*<\/strong>\u7269\u79cd\u7684<\/strong>DFT<\/strong>\u7406\u8bba\u6a21\u62df\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff090.1 M HClO4<\/sub>\u6eb6\u6db2\u4e2d\uff0cPt(100)\uff08a\uff09\u548cPt(110)\uff08b\uff09\u5355\u6676\u7535\u6781\u8868\u9762ORR\u8fc7\u7a0b\u7684\u539f\u4f4dSHINERS\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08c\uff09Pt(110)\u8868\u9762\uff0c\u9876\u4f4d\u5438\u9644\u7684OH*\u7269\u79cd\u7684DFT\u7406\u8bba\u6a21\u62df\u7ed3\u679c\u3002<\/p>\n

 <\/p>\n

\u56fe<\/strong> 4 <\/strong>\u78b1\u6027\u6761\u4ef6\u4e0b\uff0c<\/strong>Pt(<\/strong>hkl<\/em><\/strong>)<\/strong>\u5355\u6676\u8868\u9762<\/strong>ORR<\/strong>\u8fc7\u7a0b\u7684\u539f\u4f4d\u7535\u5316\u5b66<\/strong>SHINERS<\/strong>\u5149\u8c31\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

O2<\/sub>\u9971\u548c\u76840.1 M NaClO4<\/sub>\u6eb6\u6db2\u4e2d\uff08pH~10.3\uff09\uff0cPt(110)\uff08a\uff09\u3001Pt(111)\uff08b\uff09\u548cPt(100)\uff08c\uff09\u5355\u6676\u7535\u6781\u8868\u9762ORR\u8fc7\u7a0b\u7684\u539f\u4f4d\u7535\u5316\u5b66SHINERS\u5149\u8c31\u56fe\u3002<\/p>\n

 <\/p>\n

\u56fe<\/strong> 5 <\/strong>\u9178\u6027\u6761\u4ef6\u4e0b\uff0c<\/strong>Pt(<\/strong>hkl<\/em><\/strong>)<\/strong>\u5355\u6676\u8868\u9762<\/strong>ORR<\/strong>\u8fc7\u7a0b\u673a\u7406\u793a\u610f\u56fe\u53ca\u4e0d\u540c\u4e2d\u95f4\u7269\u79cd\u7684<\/strong>Gibbs<\/strong>\u81ea\u7531\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

Pt(111)\uff08a\uff09\u548cPt(100)\uff08b\uff09\u8868\u9762ORR\u53cd\u5e94\u8def\u5f84\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u91c7\u7528\u539f\u4f4d\u7535\u5316\u5b66SHINERS\u65b9\u6cd5\uff0c\u7cfb\u7edf\u5730\u7814\u7a76Pt(hkl<\/em>)\u5355\u6676\u8868\u9762\u7684ORR\u8fc7\u7a0b\uff0c\u76f4\u63a5\u83b7\u5f97OH*\uff0cHO2<\/sub>*\u548cO2<\/sub>–<\/sup>\u7b49ORR\u91cd\u8981\u4e2d\u95f4\u7269\u79cd\u7684\u539f\u4f4d\u5149\u8c31\u6570\u636e\u3002\u8be5\u7814\u7a76\u53d1\u73b0\uff0c\u5728ORR\u8fc7\u7a0b\u4e2d\uff0cHO2<\/sub>*\u7269\u79cd\u80fd\u591f\u8f83\u7a33\u5b9a\u5730\u5438\u9644\u5728Pt(111)\u8868\u9762\uff0c\u800c\u5728Pt(110)\u548cPt(100)\u8868\u9762\uff0cHO2<\/sub>*\u7269\u79cd\u5219\u5f88\u5bb9\u6613\u88c2\u89e3\u4e3a\u4e00\u5bf9\u5438\u9644\u6001\u7684OH*\u548cO*\u3002\u5728\u78b1\u6027\u6761\u4ef6\u4e0b\uff0cPt(hkl<\/em>)\u5355\u6676\u8868\u9762\u7684ORR\u8fc7\u7a0b\u5219\u7ecf\u8fc7\u5f62\u6210O2<\/sub>–<\/sup>\u7684\u6b65\u9aa4\u3002\u603b\u7684\u6765\u8bf4\uff0c\u57fa\u4e8e\u539f\u4f4d\u62c9\u66fc\u5149\u8c31\u5b9e\u9a8c\u548cDFT\u7406\u8bba\u6a21\u62df\uff0c\u8be5\u7814\u7a76\u8ba4\u4e3a\u5728\u9178\u6027\u6761\u4ef6\u4e0b\uff0c\u5f53\u6eb6\u6db2\u4e2d\u7684O2<\/sub>\u5206\u5b50\u5438\u9644\u5728Pt(hkl<\/em>)\u5355\u6676\u7535\u6781\u4e0a\u5f62\u6210\u5438\u9644\u6001\u7684O2<\/sub>*\u540e\uff0c\u7ecf\u8fc7\u8d28\u5b50\u7535\u5b50\u8f6c\u79fb\u6b65\u9aa4\u5f62\u6210HO2<\/sub>*\u7269\u79cd\uff0cHO2<\/sub>*\u518d\u8fdb\u4e00\u6b65\u901a\u8fc7O-O\u952e\u7684\u65ad\u88c2\u5728\u90bb\u8fd1Pt\u539f\u5b50\u4e0a\u5f62\u6210\u4e00\u5bf9\u5438\u9644\u6001\u7684O*\u548cOH*\uff0c\u6700\u540eOH*\u901a\u8fc7\u8d28\u5b50\u7535\u5b50\u8f6c\u79fb\u5f62\u6210H2<\/sub>O\u3002\u7531\u4e8e\u540c\u79cd\u7269\u79cd\u5728\u4e0d\u540c\u6676\u9762\u4e0a\u7684Gibbs\u81ea\u7531\u80fd\u548c\u6d3b\u5316\u80fd\u7684\u4e0d\u540c\uff0c\u4f7f\u5f97\u8fd9\u4e9b\u7269\u79cd\u7684\u5b58\u5728\u72b6\u6001\u548c\u8fdb\u884c\u4e0b\u4e00\u6b65ORR\u53cd\u5e94\u7684\u96be\u6613\u7a0b\u5ea6\u4e0d\u540c\uff0c\u5bfc\u81f4\u5728\u4e0d\u540cPt(hkl<\/em>)\u7535\u6781\u8868\u9762\u4e0a\u7684ORR\u6d3b\u6027\u6709\u660e\u663e\u7684\u5dee\u5f02\u3002<\/p>\n

\u672c\u7814\u7a76\u4e0d\u4ec5\u83b7\u5f97\u4e86Pt(hkl<\/em>)\u8868\u9762ORR\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u95f4\u7269\u79cd\u7684\u539f\u4f4d\u5149\u8c31\u4fe1\u606f\uff0c\u63d0\u51fa\u5408\u7406\u7684ORR\u673a\u7406\uff0c\u4e5f\u4e3a\u5176\u4ed6\u754c\u9762\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u7684\u539f\u4f4d\u5149\u8c31\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u4e2a\u5f88\u597d\u7684\u8303\u4f8b\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>In situ Raman spectroscopic evidence for oxygen reduction reaction intermediates at platinum single-crystal surfaces<\/strong><\/a>\uff08Nature Energy, 2018, DOI: 10.1038\/s41560-018-0292-z\uff09\u3002<\/p>\n

\u56e2\u961f\u4ecb\u7ecd\uff1a<\/strong><\/p>\n

\u674e\u5251\u950b\uff0c\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u7cfb\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u30022003\u5e74\u83b7\u5f97\u6d59\u6c5f\u5927\u5b66\u5b66\u58eb\u5b66\u4f4d\u540e\u8fdb\u5165\u53a6\u95e8\u5927\u5b66\u7530\u4e2d\u7fa4\u9662\u58eb\u8bfe\u9898\u7ec4\u653b\u8bfb\u535a\u58eb\u5b66\u4f4d\uff0c\u5e76\u4e8e2010\u5e74\u83b7\u53a6\u95e8\u5927\u5b66\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\u30022010\u5e74~2014\u5e74\u5148\u540e\u5728\u745e\u58eb\u5c14\u5c3c\u5927\u5b66\u548c\u82cf\u9ece\u4e16\u8054\u90a6\u7406\u5de5\u5b66\u9662\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u30022014\u5e74\u5165\u9009\u56fd\u5bb6\u7b2c\u4e94\u6279\u201c\u9752\u5e74\u5343\u4eba\u201d\u8ba1\u5212\uff0c\u5e76\u56de\u5230\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\uff0c\u7ec4\u5efa\u72ec\u7acb\u79d1\u7814\u56e2\u961f\u30022015\u5e74\u83b7\u201c\u4f18\u79c0\u9752\u5e74\u57fa\u91d1\u201d\u8d44\u52a9\u3002\u674e\u5251\u950b\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u7814\u7a76\u65b9\u5411\u4e3b\u8981\u6d89\u53ca\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\u3001\u58f3\u5c42\u9694\u7edd\u7eb3\u7c73\u7c92\u5b50\u589e\u5f3a\u5149\u8c31\u3001\u6838\u58f3\u6750\u6599\u3001\u8868\u9762\u589e\u5f3a\u8367\u5149\u3001\u5355\u6676\u7535\u5316\u5b66\u3001\u5f02\u8d28\u91d1\u5c5e\u50ac\u5316\u3001\u65b0\u80fd\u6e90\u6750\u6599\u7b49\u9886\u57df\u3002\u674e\u5251\u950b\u6559\u6388\u662f\u58f3\u5c42\u9694\u7edd\u7eb3\u7c73\u7c92\u5b50\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\uff08SHINERS\uff09\u6280\u672f\u7684\u4e3b\u8981\u53d1\u660e\u8005\uff08Nature<\/em><\/strong> 2010<\/strong>, 464<\/em>, 392-395\uff1bNature Protoc<\/em><\/strong>. 2013<\/strong>, 8<\/em>, 52-65\uff09\u3002\u57282010\u5e74\u53d1\u660e\u7684SHINERS\u6280\u672f\uff0c\u89e3\u51b3\u4e86\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\uff08SERS\uff09\u9886\u57df40\u5e74\u6765\u957f\u671f\u5b58\u5728\u7684\u666e\u9002\u6027\u5dee\u7684\u95ee\u9898\uff0c\u88ab\u8a89\u4e3a\u65b0\u4e00\u4ee3\u7684\u5148\u8fdb\u5149\u8c31\u6280\u672f\uff0c\u5e76\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5404\u4e2a\u9886\u57df\u3002\u76ee\u524d\u8be5\u8bba\u6587\u5df2\u88ab\u5f15\u75282000\u4f59\u6b21\u3002\u674e\u5251\u950b\u6559\u6388\u4ee5\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005\u8eab\u4efd\u5df2\u5728Nature<\/em><\/strong>\u3001<\/em><\/strong>Nature Energy<\/em><\/strong>\u3001<\/em><\/strong>Nature Protoc.<\/em><\/strong>\u3001<\/em><\/strong>Nat. Commun.<\/em><\/strong>\u3001<\/em><\/strong>Sci. Adv.<\/em><\/strong>\u3001<\/em><\/strong>Chem. Rev.<\/em><\/strong>\u3001<\/em><\/strong>Chem. Soc. Rev.<\/em><\/strong>\u3001<\/em><\/strong>J. Am. Chem. Soc.<\/em><\/strong>\u3001<\/em><\/strong>Angew. Chem. Int. Ed.<\/em><\/strong>\u3001<\/em><\/strong>Nano Lett.<\/em><\/strong>\u7b49\u56fd\u9645\u9876\u7ea7\u6742\u5fd7\u4e0a\u53d1\u8868\u591a\u7bc7\u8bba\u6587\uff0c\u603b\u88ab\u5f155600\u4f59\u6b21\u3002\u6388\u6743\u53d1\u660e\u4e13\u52293\u9879\uff0c\u64b0\u5199\u82f1\u6587\u4e13\u84574\u7ae0\u3002\u5e94\u9080\u5728\u7f8e\u56fd\u5316\u5b66\u4f1a\u3001\u52a0\u62ff\u5927\u5316\u5b66\u4f1a\u7b49\u5927\u578b\u56fd\u9645\u4f1a\u8bae\u4f5c\u4e3b\u9898\u62a5\u544a\u548c\u9080\u8bf7\u62a5\u544a\u3002\u4f5c\u4e3a\u5927\u4f1a\u4e3b\u5e2d\uff0c\u7ec4\u7ec7\u627f\u529e2017\u5e74International Conference on SERS\uff08\u8868\u9762\u589e\u5f3a\u62c9\u66fc\u5149\u8c31\u56fd\u9645\u4f1a\u8bae\uff09\uff0c\u5e76\u62c5\u4efbAdv. Opt. Mater.<\/em><\/strong> (JCR\u4e00\u533a\uff0cIF = 7.430)\u3001ChemElectroChem<\/em><\/strong> (JCR\u4e8c\u533a\uff0cIF = 4.446)\u7b49\u56fd\u9645SCI\u671f\u520a\u7f16\u59d4\u3002<\/p>\n

\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b\uff1a<\/strong><\/p>\n

\u674e\u5251\u950b\u6559\u6388\u56e2\u961f\u501f\u52a9\u4e8eSHINERS\u6280\u672f\u5728\u5355\u6676\u754c\u9762\u7814\u7a76\u7684\u5de8\u5927\u4f18\u52bf\uff0c\u5b9e\u73b0\u4e86\u4e0d\u540c\u5355\u6676\u8868\u9762\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u7684\u539f\u4f4d\u52a8\u6001\u8ddf\u8e2a\uff0c\u5e76\u83b7\u5f97\u91cd\u8981\u4e2d\u95f4\u7269\u79cd\u7684\u76f4\u63a5\u5149\u8c31\u8bc1\u636e\uff0c\u8bc1\u5b9e\u4e86\u50ac\u5316\u9886\u57df\u4e2d\u957f\u671f\u4ee5\u6765\u7684\u63a8\u6d4b\u3002\u57282015\u5e74\uff0c\u674e\u5251\u950b\u6559\u6388\u8bfe\u9898\u7ec4\u5229\u7528\u539f\u4f4dSHINERS\u6280\u672f\u7cfb\u7edf\u7684\u7814\u7a76\u4e86\u5421\u5576\u5206\u5b50\u5728Au(hkl<\/em>)\u5355\u6676\u8868\u9762\u7684\u5438\u9644\u8fc7\u7a0b\uff08J. Am. Chem. Soc.<\/em><\/strong> 2015<\/strong>, 137<\/em>, 2400\u22122408\uff09\uff0c\u5b9e\u73b0\u4e86\u7535\u5316\u5b66\u4fe1\u606f\u548c\u539f\u4f4d\u8c31\u5b66\u4fe1\u606f\u7684\u5b8c\u7f8e\u5173\u8054\u3002\u4e4b\u540e\u4ed6\u4eec\u5728Au(hkl<\/em>)\u5355\u6676\u8868\u9762\u7684\u7535\u6c27\u5316\u8fc7\u7a0b\u7684\u7814\u7a76\u4e2d\uff0c\u9996\u6b21\u83b7\u5f97Au(hkl<\/em>)\u5355\u6676\u7535\u6781\u7535\u6c27\u5316\u91cd\u8981\u4e2d\u95f4\u7269\u79cdOH\u7684\u539f\u4f4d\u5149\u8c31\u4fe1\u606f\uff08J. Am. Chem. Soc<\/em><\/strong>.<\/em> 2015<\/strong>, 137,<\/em> 7648-7651\uff09\u3002\u8fd1\u671f\uff0c\u4ed6\u4eec\u5148\u540e\u628aSHINERS\u6280\u672f\u62d3\u5c55\u5230\u5f02\u8d28\u91d1\u5c5e\u5355\u6676\u754c\u9762\u7535\u5b50\u7ed3\u6784\u7684\u7814\u7a76\uff08Angew. Chem. Int. Ed. <\/em><\/strong>2018,<\/em><\/strong> 130<\/em>(35), 11427-11431\uff09\u548c\u8fc7\u6e21\u91d1\u5c5e\u754c\u9762\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u7814\u7a76\uff08Nature Energy<\/em><\/strong> 2018<\/strong>\uff0c<\/strong>doi:10.1038\/s41560-018-0292-z\uff09\uff0c\u8868\u5f81\u4e0d\u540c\u5355\u6676\u754c\u9762\u7535\u5b50\u7ed3\u6784\u53d8\u5316\u548c\u754c\u9762\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\uff0c\u4e3a\u63ed\u793a\u5355\u6676\u754c\u9762\u53cd\u5e94\u673a\u7406\u63d0\u4f9b\u76f4\u63a5\u7684\u539f\u4f4d\u5149\u8c31\u8bc1\u636e\uff0c\u4e5f\u4e3a\u540e\u7eed\u50ac\u5316\u5242\u7684\u7406\u6027\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u57fa\u7840\u3002\u8bfe\u9898\u7ec4\u94fe\u63a5<\/strong>\uff1ahttp:\/\/jfli.xmu.edu.cn\/<\/a><\/u><\/p>\n

\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\uff1a<\/strong><\/p>\n

[1]\u00a0\u00a0 Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy. Nature<\/em> 2010<\/strong>, 464, 392-395<\/p>\n

[2]\u00a0\u00a0 Surface Analysis Using Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy. Nature Protoc.<\/em> 2013<\/strong>, 8, 52-65.<\/p>\n

[3]\u00a0\u00a0 In Situ<\/em> Raman Spectroscopic Evidence for Oxygen Reduction Reaction Intermediates at Platinum Single Crystal Surfaces. Nature Energy<\/em><\/strong> 2018, doi: 10.1038\/s41560-018-0292-z.<\/p>\n

[4]\u00a0\u00a0 Probing Interfacial Electronic and Catalytic Properties on Well-Defined Surfaces Using in Situ Raman Spectroscopy, Angew. Chem. Int. Ed.<\/em> 2018<\/strong>, 130<\/em>(35), 11427-11431.<\/p>\n

[5]\u00a0\u00a0 In Situ Monitoring of Electrooxidation Processes at Gold Single Crystal Surfaces Using Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy. J. Am. Chem. Soc.<\/em> 2015<\/strong>, 137, 7648-7651.<\/p>\n

[6]\u00a0\u00a0 Electrochemical Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy: Correlating Structural Information and Adsorption Processes of Pyridine at the Au(hkl) Single Crystal\/Solution Interface. J. Am. Chem. Soc.<\/em> 2015<\/strong>, 137, 2400-2408.<\/p>\n

[7]\u00a0\u00a0 Core\u2013Shell Nanoparticle-Enhanced Raman Spectroscopy. Chem. Rev. <\/em>2017<\/strong>, 117, 5002-5069.<\/p>\n

[8]\u00a0\u00a0 Dielectric Shell Isolated and Graphene Shell Isolated Nanoparticle Enhanced Raman Spectroscopies and Their Applications. Chem. Soc. Rev.<\/em> 2015<\/strong>, 44, 8399-8409.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5f20\u91d1\u6d0b\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

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