{"id":160568,"date":"2018-12-02T06:30:13","date_gmt":"2018-12-01T22:30:13","guid":{"rendered":"\/\/m.iemloyee.com\/?p=160568"},"modified":"2018-12-01T18:52:02","modified_gmt":"2018-12-01T10:52:02","slug":"%e9%ba%a6%e7%ab%8b%e5%bc%ba-%e5%91%a8%e4%ba%aechem-soc-rev-%e7%a1%85%e6%b0%a7%e5%8c%96%e7%89%a9%ef%bc%9a%e5%af%8c%e6%9c%89%e5%89%8d%e6%99%af%e7%9a%84%e9%94%82%e7%a6%bb%e5%ad%90%e7%94%b5","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=160568","title":{"rendered":"\u9ea6\u7acb\u5f3a &#038;\u5468\u4eaeChem. Soc. Rev.: \u7845\u6c27\u5316\u7269\uff1a\u5bcc\u6709\u524d\u666f\u7684\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599"},"content":{"rendered":"<p><strong>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n<p>\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u957f\u5bff\u547d\u548c\u73af\u4fdd\u6027\u7684\u7279\u70b9\uff0c\u662f\u76ee\u524d\u6700\u5177\u5438\u5f15\u529b\u7684\u50a8\u80fd\u88c5\u7f6e\u4e4b\u4e00\uff0c\u88ab\u5e7f\u6cdb\u7684\u5e94\u7528\u4e8e\u624b\u673a\u3001\u7b14\u8bb0\u672c\u7535\u8111\u548c\u6570\u7801\u76f8\u673a\u7b49\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\u7684\u5e02\u573a\u3002\u540c\u65f6\uff0c\u5b83\u4eec\u4e5f\u88ab\u8ba4\u4e3a\u662f\u7535\u52a8\u6c7d\u8f66\u548c\u56fa\u5b9a\u5f0f\u80fd\u6e90\u50a8\u5b58\u7cfb\u7edf\u7684\u9996\u9009\u7535\u6e90\u3002\u7136\u800c\uff0c\u76ee\u524d\u6700\u5148\u8fdb\u7684LIB\u4ecd\u65e0\u6cd5\u6ee1\u8db3\u9ad8\u529f\u7387\u7535\u52a8\u6c7d\u8f66\u548c\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u4e0d\u65ad\u589e\u957f\u7684\u9700\u6c42\u3002\u56e0\u4e3a\u73b0\u5728\u5927\u591a\u6570\u5546\u4e1a\u5316\u7684LIBs\u91c7\u7528\u4e86\u57fa\u4e8e\u5d4c\u5165\u53cd\u5e94\u7684\u8d1f\u6781\u6750\u6599\uff0c\u4f8b\u5982\u77f3\u58a8\u548cLi<sub>4<\/sub>Ti<sub>5<\/sub>O<sub>12<\/sub>\u3002\u8fd9\u79cd\u8d1f\u6781\u6750\u6599\u5177\u6709\u7a81\u51fa\u7684\u5faa\u73af\u5bff\u547d\u4f46\u5bb9\u91cf\u6709\u9650\u7684\u7279\u5f81\uff0c\u800c\u76f8\u5bf9\u4f4e\u7684\u5bb9\u91cf\u4e25\u91cd\u9650\u5236\u4e86\u9502\u79bb\u5b50\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002<\/p>\n<p>\u5728\u4e3aLIBs\u63a2\u5bfb\u65b0\u5174\u8d1f\u6781\u6750\u6599\u4e2d\uff0c\u7845(Si)\u88ab\u8ba4\u4e3a\u662f\u6700\u6709\u5e0c\u671b\u66ff\u4ee3\u77f3\u58a8\u7684\u5019\u9009\u6750\u6599\u3002\u56e0\u4e3a\u5b83\u662f\u5730\u58f3\u4e2d\u7b2c\u4e8c\u4e30\u5bcc\u7684\u5143\u7d20\uff0c\u5e76\u5177\u6709\u8d85\u9ad8\u7684\u7406\u8bba\u5bb9\u91cf\uff084200 mA h g<sup>-1<\/sup>\uff09\u3002\u7136\u800c\uff0c\u5728\u9502\u5316\/\u8131\u9502\u7684\u8fc7\u7a0b\u4e2dSi\uff08~ 400\uff05\uff09\u4e25\u91cd\u7684\u4f53\u79ef\u81a8\u80c0\u548c\u7eb3\u7c73\u7ed3\u6784Si\u9ad8\u6602\u7684\u751f\u4ea7\u6210\u672c\u4e25\u91cd\u963b\u788d\u4e86\u5176\u8fdb\u4e00\u6b65\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u6700\u8fd1\u7684\u7814\u7a76\u53d1\u73b0\u7845\u6c27\u5316\u7269\u662f\u6709\u5e0c\u671b\u7684\u66ff\u4ee3\u5355\u8d28\u7845\uff0c\u56e0\u4e3a\u5b83\u5177\u6709\u6781\u5176\u4e30\u5bcc\u7684\u50a8\u5907\u3001\u8f83\u4f4e\u6210\u672c\u4e14\u6613\u4e8e\u5408\u6210\u3002\u540c\u65f6\uff0c\u4e0e\u5355\u8d28Si\u76f8\u6bd4\uff0c\u7845\u6c27\u5316\u7269\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u663e\u793a\u51fa\u5c0f\u7684\u4f53\u79ef\u53d8\u5316\u3002\u5e76\u4e14\u5728\u7b2c\u4e00\u6b21\u9502\u5316\u8fc7\u7a0b\u4e2d\u539f\u4f4d\u4ea7\u751f\u7684\u6c27\u5316\u9502\u548c\u7845\u9178\u9502\u7b49\u526f\u4ea7\u7269\u53ef\u4ee5\u7f13\u51b2\u5927\u7684\u4f53\u79ef\u53d8\u5316\u5e76\u6539\u5584\u5faa\u73af\u7684\u7a33\u5b9a\u6027\u3002\u4f46\u662f\uff0c\u7845\u6c27\u5316\u7269\u4e5f\u5b58\u5728\u4ee5\u4e0b\u51e0\u4e2a\u7f3a\u70b9\uff1a(I).\u7845\u6c27\u5316\u7269\u56fa\u6709\u7684\u4f4e\u7535\u5bfc\u7387\u4e25\u91cd\u964d\u4f4e\u4e86\u5176\u7535\u5316\u5b66\u6d3b\u6027\uff1b (II).\u4ecd\u6709\u4e0d\u53ef\u5ffd\u89c6\u7684\u4f53\u79ef\u81a8\u80c0\u95ee\u9898\uff1b(III). \u5728\u7b2c\u4e00\u6b21\u5faa\u73af\u4e2dLi<sub>2<\/sub>O\u548c\u7845\u9178\u9502\u7684\u5f62\u6210\u662f\u4e0d\u53ef\u9006\u7684\uff0c\u5bfc\u81f4\u7845\u6c27\u5316\u7269\u7684\u521d\u59cb\u5e93\u4ed1\u6548\u7387\uff08\u9996\u6b21\u5e93\u4f26\u6548\u7387\uff09\u76f8\u5bf9\u8f83\u4f4e\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u00a0 \u8fd1\u65e5\uff0c<strong>\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u7684\u9ea6\u7acb\u5f3a\u6559\u6388\u548c\u5468\u4eae\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728<strong>Chem. Soc. Rev. <\/strong>\u4e0a\u53d1\u8868\u4e86\u5bf9\u4ee5\u7845\u6c27\u5316\u7269\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u7684\u7efc\u8ff0\uff0c\u9898\u4e3a <strong>\u201cSilicon oxides: a promising family of anode materials for lithium-ion batteries\u201d<\/strong><strong>\u3002<\/strong>\u9488\u5bf9\u7845\u6c27\u5316\u7269\u5b58\u5728\u7684\u4e00\u4e9b\u95ee\u9898\uff0c\u76ee\u524d\u5df2\u7ecf\u5728\u81f4\u529b\u4e8e\u89e3\u51b3\u5e76\u5c06\u57fa\u4e8e\u7845\u6c27\u5316\u7269\u7684\u8d1f\u6781\u6750\u6599\u63a8\u5411LIBs\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5b9e\u9645\u4e0a\uff0c\u7845\u6c27\u5316\u7269\u5df2\u7ecf\u4e0e\u77f3\u58a8\u6df7\u5408\uff08\u901a\u5e38\u542b\u91cf\u4f4e\u4e8e10\uff05\uff09\u5e76\u7528\u4e8e\u5546\u4e1a\u5316\u7684LIBs\u4e2d\u3002\u7136\u800c\uff0c\u76ee\u524d\u5e76\u6ca1\u6709\u4e13\u95e8\u9488\u5bf9\u7845\u6c27\u5316\u7269\u57fa\u8d1f\u6781\u6750\u6599\u7684\u7efc\u5408\u8bc4\u8ff0\u3002\u56e0\u6b64\uff0c\u672c\u7efc\u8ff0\u603b\u7ed3\u4e86\u7845\u6c27\u5316\u7269\u8d1f\u6781\u6750\u6599\u7684\u5fae\u89c2\u7ed3\u6784\u3001\u9502\u5b58\u50a8\u673a\u5236\u3001\u5408\u6210\u65b9\u6cd5\u548c\u7535\u5316\u5b66\u6027\u80fd\u7684\u6700\u65b0\u8fdb\u5c55\u3002\u4e3a\u4e86\u7cfb\u7edf\u5730\u5448\u73b0\u8be5\u9886\u57df\u7684\u6210\u679c\u8fdb\u5c55\uff0c\u8be5\u7efc\u8ff0\u8fdb\u884c\u4e86\u4ee5\u4e0b\u56db\u4e2a\u90e8\u5206\uff1a(i). SiO\u8d1f\u6781\u6750\u6599\uff1b(ii). SiO<sub>2<\/sub>\u8d1f\u6781\u6750\u6599\uff1b(iii). \u975e\u5316\u5b66\u8ba1\u91cf\u7684SiO<em><sub>x<\/sub><\/em>\u8d1f\u6781\u6750\u6599\uff1b(iv). Si -O-C\u8d1f\u6781\u6750\u6599\u3002\u5728\u672c\u7efc\u8ff0\u6700\u540e\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u5bf9\u57fa\u4e8e\u7845\u6c27\u5316\u7269\u7684\u8d1f\u6781\u6750\u6599\u8fdb\u884c\u4e86\u603b\u7ed3\u548c\u5c55\u671b\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u89e3\u6790\u3011<\/strong><\/p>\n<p><strong>1\u3001SiO\u57fa\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u00a0\u5728\u5404\u79cd\u7845\u6c27\u5316\u7269\uff08SiO\u3001SiO<sub>2<\/sub>\u3001SiO<em><sub>x<\/sub><\/em>\u548cSi-O-C\uff09\u4e2d\uff0c\u57fa\u4e8eSiO\u7684\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u5f15\u8d77\u4e86\u6700\u591a\u7684\u5173\u6ce8\u3002\u5b83\u662f\u7531\u67e5\u5c14\u65af\u00b7\u9a6c\u5e03\u91cc\u4e8e1887\u5e74\u9996\u6b21\u62a5\u9053\u7684\u3002\u901a\u8fc7\u5728\u5347\u9ad8\u7684\u6e29\u5ea6\u4e0b\u52a0\u70edSiO<sub>2<\/sub>\u548cSi\u6df7\u5408\u7269\u4ee5\u4ea7\u751f\u6c14\u6001SiO\uff08SiO<sub>2<\/sub> + Si = 2SiO\uff09, \u7136\u540e\u51b7\u51ddSiO\u84b8\u6c14\u6765\u5236\u5907\u5546\u54c1\u5316\u7684SiO\u3002<\/p>\n<p><strong>1.1\u3001\u65e0\u5b9a\u5f62SiO\u7684\u539f\u5b50\u7ed3\u6784<\/strong><\/p>\n<p>\u00a0\u81ea\u53d1\u73b0\u4ee5\u6765\uff0cSiO\u7684\u539f\u5b50\u7ed3\u6784\u4e00\u76f4\u662f\u4e89\u8bae\u7684\u4e3b\u9898\u3002Philipp\u63d0\u51fa\u4e86\u4e00\u79cd\u968f\u673a\u952e\u5408\u7684\u6a21\u578b\uff0c\u8be5\u6a21\u578b\u5c06SiO\u63cf\u8ff0\u4e3a\u5747\u5300\u7684\u5355\u76f8\u6750\u6599\uff0c\u5177\u6709\u7531\u968f\u673a\u5206\u5e03\u7684Si-Si\u548cSi-O\u952e\u7ec4\u6210\u7684\u8fde\u7eedSi-(O<sub>x<\/sub>Si<sub>4-x<\/sub>)\u7684\u7f51\u7edc\u3002Brady\u548cTemkin\u5efa\u7acb\u4e86\u968f\u673a-\u6df7\u5408\u7269\u6a21\u578b\uff0c\u5176\u4e2dSiO\u88ab\u63cf\u8ff0\u4e3a\u7eb3\u7c73\u5c3a\u5bf8\u7684\u975e\u6676Si\u548cSiO<sub>2<\/sub>\u7684\u6df7\u5408\u7269\u3002\u7136\u800c\uff0c\u66f4\u5b9e\u9645\u7684\u6a21\u578b\u8868\u660e\uff0c\u4f4e\u6c27\u542b\u91cf\u7684\u7845\u6c27\u5316\u7269\u53ef\u80fd\u5b58\u5728\u4e8eSi\u548cSiO<sub>2<\/sub>\u57df\u4e4b\u95f4\u7684\u754c\u9762\u533a\u57df\u4e2d\u3002\u754c\u9762\u8fb9\u754c\u5c42\u5360SiO\u4e2d\u539f\u5b50\u603b\u6570\u768420-25\uff05\u3002\u7531\u4e8e\u4f20\u7edf\u8868\u5f81\u6280\u672f\u7684\u7a7a\u95f4\u5206\u8fa8\u7387\u7684\u9650\u5236\uff0c\u5bf9SiO\u7684\u5c40\u90e8\u539f\u5b50\u7ed3\u6784\u7684\u76f4\u63a5\u5b9e\u9a8c\u89c2\u5bdf\u662f\u975e\u5e38\u5177\u6709\u6311\u6218\u6027\u7684\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160570\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/1-1.gif\" alt=\"\" width=\"600\" height=\"395\" \/>Figure 1. \uff08a\uff09\u975e\u6676Si\u7684\u539f\u5b50\u6a21\u578b\uff1b\uff08b\uff09\u4f4e\u7684\u7845\u6c27\u5316\u7269\u7684\u539f\u5b50\u6a21\u578b\uff1b\uff08c\uff09\u65e0\u5b9a\u5f62SiO<sub>2<\/sub>\u7684\u539f\u5b50\u6a21\u578b\uff1b\uff08d\uff09\u975e\u6676SiO\u7684\u539f\u5b50\u6a21\u578b\uff1b\uff08e\uff09\u5b58\u5728\u4e8e\u65e0\u5b9a\u5f62SiO\u4e2d\u7684\u4e94\u4e2a\u539f\u5b50\u5750\u6807\u7684\u5206\u6570\u3002\u5176\u4e2dSi-Si<sub>4<\/sub>\u6765\u81eaSi\u7c07\uff1bSi-O<sub>4<\/sub>\u6765\u81eaSiO<sub>2<\/sub>\u57fa\u8d28\uff1bSi-\uff08Si<sub>3<\/sub>O\uff09\uff0cSi-\uff08Si<sub>2<\/sub>O<sub>2<\/sub>\uff09\u548cSi-\uff08SiO<sub>3<\/sub>\uff09\u6765\u81eaSi \/ SiO<sub>2<\/sub>\u754c\u9762\u3002<\/p>\n<p><strong>1.2\u3001SiO\u7684\u9502\u5316\u884c\u4e3a<\/strong><\/p>\n<p>\u4e86\u89e3\u9502\u5316\/\u8131\u9502\u7684\u673a\u7406\u5bf9\u4e8e\u8fdb\u4e00\u6b65\u6539\u5584SiO\u7684\u7535\u5316\u5b66\u6027\u80fd\u662f\u81f3\u5173\u91cd\u8981\u3002\u901a\u5e38\u8ba4\u4e3aLi<em><sub>x<\/sub><\/em>Si\u662f\u7845\u9178\u9502\uff08Li<sub>4<\/sub>SiO<sub>4<\/sub>\u3001Li<sub>2<\/sub>Si<sub>2<\/sub>O<sub>5<\/sub>\u3001Li<sub>6<\/sub>Si<sub>2<\/sub>O<sub>7<\/sub>\u3001Li<sub>2<\/sub>SiO<sub>3<\/sub>\uff09\u548cLi<sub>2<\/sub>O\u5728SiO\u7684\u7b2c\u4e00\u6b21\u9502\u5316\u8fc7\u7a0b\u4e2d\u5f62\u6210\u7684\u3002Li<em><sub>x<\/sub><\/em>Si\u5408\u91d1\u4e2dLi<sup>+<\/sup>\u7684\u8131\u5d4c\/\u5d4c\u5165\u662f\u53ef\u9006\u7684\u3002\u5047\u8bbeSiO\u4e2d\u7684\u6240\u6709Si\u90fd\u53ef\u4ee5\u5728\u9502\u5316\u8fc7\u7a0b\u4e2d\u8f6c\u5316\u4e3aLi<sub>4.4<\/sub>Si\uff0c\u5219SiO\u7684\u7406\u8bba\u53ef\u9006\u5bb9\u91cf\u8fbe\u52302680 mA h g<sup>-1<\/sup>\u3002\u7845\u9178\u9502\u548cLi<sub>2<\/sub>O\u901a\u5e38\u662f\u4e0d\u53ef\u9006\u76f8\u3002\u4e00\u65b9\u9762\uff0c\u5b83\u4eec\u7528\u4f5c\u5728\u9502\u5316\/\u53bb\u9502\u5316\u8fc7\u7a0b\u4e2d\u62b5\u6297\u4f53\u79ef\u53d8\u5316\u7684\u7f13\u51b2\u57fa\u8d28\uff0c\u4ece\u800c\u589e\u5f3aSiO\u7684\u5faa\u73af\u6027\u80fd\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u4e0d\u53ef\u9006\u7684\u7845\u9178\u9502\u548cLi<sub>2<\/sub>O\u7684\u5f62\u6210\u964d\u4f4e\u4e86SiO\u7684\u9996\u6b21\u5e93\u4f26\u6548\u7387\u3002SiO\u7684\u9502\u5316\u4ea7\u7269\u7684\u7ec4\u6210\u76f8\u5bf9\u590d\u6742\u3002\u5df2\u7ecf\u5728\u9502\u5316\u7684SiO\u4e2d\u89c2\u5bdf\u5230\u5404\u79cd\u7845\u9178\u9502\uff0c\u5e76\u4e14\u5b83\u4eec\u7684\u8868\u73b0\u53d6\u51b3\u4e8e\u7ec4\u6210\u800c\u5b8c\u5168\u4e0d\u540c\u3002\u731c\u6d4b\u53ef\u80fd\u7684\u4f5c\u7528\u8fc7\u7a0b\u5982\u4e0b\uff1a<a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/\u672a\u6807\u9898-1.tif\"><img decoding=\"async\" class=\"aligncenter size-full wp-image-160572\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/\u672a\u6807\u9898-1.tif\" alt=\"\" \/><\/a><img decoding=\"async\" class=\"aligncenter size-full wp-image-160572\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/\u672a\u6807\u9898-1.tif\" alt=\"\" \/> <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160575\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/\u672a\u6807\u9898-2-1.jpg\" alt=\"\" width=\"600\" height=\"333\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/\u672a\u6807\u9898-2-1.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/\u672a\u6807\u9898-2-1-300x167.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n <strong>1.3\u3001SiO\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p>\u7531\u4e8e\u5b58\u5728\u7845\u9178\u9502\u548cLi<sub>2<\/sub>O\uff0c\u9502\u5316\/\u8131\u9502\u8fc7\u7a0b\u4e2dSiO\u7684\u4f53\u79ef\u53d8\u5316\u663e\u7740\u964d\u4f4e\u5e76\u4e14\u5faa\u73af\u7a33\u5b9a\u6027\u589e\u5f3a\u3002\u4f46\u662f\uff0c\u5b8c\u5168\u6d88\u9664\u4f53\u79ef\u6548\u5e94\u95ee\u9898\u4f9d\u7136\u5f88\u56f0\u96be\u3002\u6839\u636e\u5df2\u6709\u62a5\u9053\uff0c\u5728\u9502\u5316\u65f6SiO\u7684\u4f53\u79ef\u81a8\u80c0\u7ea6\u4e3a200\uff05\u3002\u8fd9\u79cd\u5267\u70c8\u7684\u4f53\u79ef\u81a8\u80c0\u53ef\u80fd\u5728\u6d3b\u6027\u6750\u6599\u4e2d\u5f15\u8d77\u5e94\u529b\u5bfc\u81f4\u6d3b\u6027\u6750\u6599\u7c89\u788e\u548c\u5206\u79bb\u3001\u7535\u6781\u5d29\u89e3\u3001\u9ad8\u8868\u9762\u526f\u53cd\u5e94\u4ee5\u53ca\u91cd\u590d\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u819c\u5f62\u6210\u548c\u7834\u88c2\u3002\u56e0\u6b64\uff0cSiO\u7684\u8f83\u5927\u4f53\u79ef\u53d8\u5316\u662f\u5176\u5728\u5faa\u73af\u65f6\u5bb9\u91cf\u8870\u51cf\u7684\u4e3b\u8981\u539f\u56e0\u3002\u6b64\u5916\uff0cSiO\u8fd8\u5177\u6709\u4f4e\u9996\u6b21\u5e93\u4f26\u6548\u7387\u548c\u4f4e\u500d\u7387\u6027\u80fd\u3002\u5bf9\u4e8e\u5b9e\u9645\u5e94\u7528\uff0c\u4ecd\u7136\u5b58\u5728\u76f8\u5f53\u5927\u7684\u7a7a\u95f4\u6765\u6539\u5584SiO\u7684\u5faa\u73af\u6027\u3001\u9996\u6b21\u5e93\u4f26\u6548\u7387\u548c\u500d\u7387\u6027\u80fd\u3002<\/p>\n<p><strong>1.3.1\u3001\u7eafSiO\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u00a0\u5229\u7528\u7f29\u5c0f\u5c3a\u5bf8\u3001\u6784\u5efa\u591a\u5b54\u7ed3\u6784\u3001\u7eb3\u7c73\u590d\u5408\u548c\u4f7f\u7528\u65b0\u7684\u7c98\u7ed3\u5242\u7b49\u7b56\u7565\u7528\u4e8e\u89e3\u51b3SiO\u57fa\u8d1f\u6781\u7684\u4f53\u79ef\u53d8\u5316\u95ee\u9898\u3002\u4f8b\u5982\uff0c\u901a\u8fc7\u8bbe\u8ba1\u9002\u5f53\u7684\u5fae\u89c2\u7ed3\u6784\u548c\u5c3a\u5bf8\uff0c\u7eafSiO\u8d1f\u6781\u6750\u6599\u4ecd\u663e\u793a\u51fa\u826f\u597d\u7684\u9502\u50a8\u5b58\u6027\u80fd\uff1b\u6784\u5efa\u7684\u591a\u5b54\u7ed3\u6784\u4e0d\u4ec5\u63d0\u4f9b\u7528\u4e8e\u4f53\u79ef\u81a8\u80c0\u8c03\u8282\u7684\u81ea\u7531\u7a7a\u95f4\uff0c\u800c\u4e14\u63d0\u4f9b\u7528\u4e8eLi<sup>+<\/sup> \u6269\u6563\u7684\u6709\u6548\u901a\u9053\uff0c\u7528\u4e8e\u63d0\u9ad8SiO\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160576\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/2-1.gif\" alt=\"\" width=\"600\" height=\"646\" \/>Figure 2. \uff08a\uff09\u5236\u5907d-SiO\u7684\u793a\u610f\u56fe\u3002\uff08b\uff09SiO\u3001HEMM\u5904\u7406\u7684d-SiO\uff083h\uff09\u548cHEMM\u5904\u7406\u7684d-SiO\uff0810h\uff09\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160577\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/3-1.gif\" alt=\"\" width=\"600\" height=\"594\" \/>Figure 3. \uff08a\uff09\u5236\u5907\u591a\u5b54SiOx\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09\u591a\u5b54SiO<sub>x<\/sub>\u7684TEM\u56fe\u50cf\uff1b\uff08c\uff09\u591a\u5b54SiO<sub>x<\/sub>\u7684HR-TEM\u56fe\u50cf\uff1b\uff08d\uff09SiO\u3001d-SiO\u3001HEMM\u5904\u7406\u7684d-SiO\u548c\u591a\u5b54SiO<sub>x<\/sub>\u7684\u5faa\u73af\u6027\u80fd\uff1b\uff08e\uff09 HEMM\u5904\u7406\u7684d-SiO\u548c\u591a\u5b54SiO<sub>x<\/sub>\u7684\u901f\u7387\u6027\u80fd\uff0c1C = 1500 mA h g<sup>-1<\/sup>\u3002<\/p>\n<p><strong>1.3.2\u3001SiO \/ C\u6742\u5316\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u5728\u5404\u79cd\u7535\u5316\u5b66\u6027\u80fd\u4f18\u5316\u7b56\u7565\u4e2d\uff0c\u6700\u5927\u9650\u5ea6\u5730\u7814\u7a76\u4e86\u7528\u5bfc\u7535\u78b3\u590d\u5408SiO\u3002\u5df2\u7ecf\u6784\u5efa\u5e76\u6d4b\u8bd5\u4e86\u5404\u79cdSiO \/ C\u590d\u5408\u6750\u6599\u3002\u78b3\u4e0d\u4ec5\u51cf\u8f7b\u4e86\u6574\u4f53\u7684\u4f53\u79ef\u53d8\u5316\uff0c\u800c\u4e14\u63d0\u9ad8\u4e86SiO\u7684\u5bfc\u7535\u6027\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u3002\u4e0e\u78b3\u6d82\u8986\u7684d-SiO\u548c\u88f8d-SiO\u5bf9\u5e94\u7269\u76f8\u6bd4\uff0c\u5fae\u7c73\u5316\u7684NC-d-SiO\u8868\u73b0\u51fa\u589e\u5f3a\u7684\u5bb9\u91cf\u548c\u500d\u7387\u6027\u80fd\u3002 <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160578\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/4-1.gif\" alt=\"\" width=\"600\" height=\"204\" \/>Figure 4. \uff08a\uff09d-SiO \/ C\u7684SEM\u56fe\u50cf\uff1b\uff08b\uff09d-SiO \/ C\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160579\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/5-1.gif\" alt=\"\" width=\"600\" height=\"547\" \/>Figure 5. \uff08a\uff09\u5145\u7535\/\u653e\u7535\u671f\u95f4d-SiO @ vG\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09d-SiO \/ vG\u7684\u793a\u610f\u6027\u7ed3\u6784\uff1b\uff08c\uff09d-SiO \/ vG\u7684TEM\u56fe\uff1b\uff08d\uff09d-SiO\u548cd-SiO @ vG\u5728320 mA g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b\uff08e\uff09\u7ec4\u88c5\u7684d-SiO @ vG \/\u77f3\u58a8\/\/ NCA 18 650\u5168\u7535\u6c60\u7684\u6570\u7801\u7167\u7247\uff1b\uff08f\uff09\u5b8c\u6574\u7ec6\u80de\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160580\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/6-1.gif\" alt=\"\" width=\"600\" height=\"601\" \/>Figure 6. \uff08a\uff09\u901a\u8fc7\u91d1\u5c5e\u8f85\u52a9\u8680\u523b\u5408\u6210\u591a\u5b54SiO\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09\u591a\u5b54SiO \/ C\u7684SEM\u56fe\uff1b\uff08c\uff09\u591a\u5b54SiO \/ C\u7684\u653e\u7535-\u5145\u7535\u66f2\u7ebf\uff1b\uff08d\uff09\u591a\u5b54d-SiO\u7684HR-TEM\u56fe\u50cf\u663e\u793a\u7eb3\u7c73\u6676Si \/\u975e\u6676SiO<sub>x<\/sub>\u590d\u5408\u7ed3\u6784\uff1b\uff08e\uff09\u591a\u5b54SiO \/ C\u548cd-SiO \/ C\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><strong>1.3.3\u3001SiO \/\u91d1\u5c5e\u548cSiO \/\u91d1\u5c5e\u6c27\u5316\u7269\u6742\u5316\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u9664\u78b3\u4e4b\u5916\uff0c\u91d1\u5c5e\u548c\u91d1\u5c5e\u6c27\u5316\u7269\u4e5f\u5df2\u7528\u4e8e\u4e0eSiO\u590d\u5408\u4ee5\u6539\u5584\u5176\u9502\u50a8\u5b58\u6027\u80fd\u3002\u4f8b\u5982\uff0c\u57282001\u5e74\uff0cTatsumisago\u62a5\u9053\u4e86\u5728\u60f0\u6027\u6c14\u6c1b\u4e2d\u673a\u68b0\u7814\u78e8SiO\u548cSnO\u5408\u6210SiO \/ SnO\u590d\u5408\u6750\u6599\uff1bJeong\u7b49\u4eba\u62a5\u9053\u4e86\u91c7\u7528\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u5236\u5907\u4e86\u5177\u6709TiO<sub>2<\/sub>\u6d82\u5c42\u7684SiO\u590d\u5408\u8d1f\u6781\u3002\u5177\u6709TiO<sub>2<\/sub>\u6d82\u5c42\u7684SiO\u5177\u6709\u66f4\u9ad8\u7684\u6bd4\u5bb9\u91cf\u3001\u9996\u6b21\u5e93\u4f26\u6548\u7387\u3001\u66f4\u597d\u7684\u500d\u7387\u6027\u80fd\u4ee5\u53ca\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>1.3.4\u3001\u4f18\u5316SiO\u57fa\u8d1f\u6781\u6750\u6599\u7684\u7c98\u5408\u5242<\/strong><\/p>\n<p>\u805a\u5408\u7269\u7c98\u7ed3\u5242\u4e5f\u5bf9SiO\u57fa\u8d1f\u6781\u7684\u53ef\u5faa\u73af\u6027\u6709\u5f88\u5927\u5f71\u54cd\u3002SiO\u7684\u9ad8\u5bb9\u91cf\u4f34\u968f\u7740200\uff05\u7684\u5927\u4f53\u79ef\u81a8\u80c0\uff0c\u5bfc\u81f4\u7535\u6781\u6750\u6599\u7c89\u5316\u7834\u88c2\u7b49\u95ee\u9898\u3002\u5408\u9002\u7684\u7c98\u7ed3\u5242\u53ef\u5728\u6d3b\u6027\u6750\u6599\uff0c\u5bfc\u7535\u78b3\u548c\u96c6\u7535\u5668\u4e4b\u95f4\u63d0\u4f9b\u6301\u4e45\u7684\u63a5\u89e6\uff0c\u6709\u6548\u5730\u6539\u5584\u7535\u6781\u5b8c\u6574\u6027\u3002\u4e3a\u4e86\u9ad8\u5bb9\u91cf\u8d1f\u6781\u6750\u6599\u7684\u5faa\u73af\u6027\u80fd\uff0c\u9700\u8981\u6bd4\u4f20\u7edf\u7535\u6781\u4e2d\u4f7f\u7528\u7684\u66f4\u5927\u91cf\u7684\u7c98\u7ed3\u5242\u548c\u5bfc\u7535\u78b3\uff0c\u4f46\u662f\u8fd9\u4e9b\u975e\u6d3b\u6027\u6dfb\u52a0\u5242\u4e0d\u53ef\u907f\u514d\u5730\u727a\u7272\u4e86\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002 \u800c\u901a\u8fc7\u5728\u7535\u6781\u4e2d\u5f15\u5165\u727a\u7272\u5242\u6216NaCl\uff0c\u53ef\u4ee5\u5f88\u597d\u5730\u63a7\u5236\u7535\u6781\u7684\u5b54\u9699\u7387\u5e76\u4e14\u589e\u52a0\u7535\u6781\u7684\u9762\u79ef\u5bb9\u91cf\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160587\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/7-1.gif\" alt=\"\" width=\"600\" height=\"556\" \/>\u00a0Figure 7. \uff08a\uff09 PVDF\u3001PVA\u3001CMCNa\u548cPAA\u7c98\u5408\u5242\u7684\u5316\u5b66\u7ed3\u6784\uff1b\uff08b\uff09\u5177\u6709\u4e0d\u540c\u7c98\u5408\u5242\u7684SiO\u57fa\u7535\u6781\u7684\u5faa\u73af\u6027\u80fd\uff1b\uff08c\uff09\u5728\u5145\u7535\/\u653e\u7535\u671f\u95f4\u5177\u6709PVDF\u7c98\u5408\u5242\u7684SiO\u57fa\u7535\u6781\u7684\u793a\u610f\u56fe\uff1b\uff08d\uff09\u5728\u5145\u7535\/\u653e\u7535\u671f\u95f4\u5177\u6709PAA\u7c98\u5408\u5242\u7684SiO\u57fa\u7535\u6781\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160588\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/8-1.gif\" alt=\"\" width=\"600\" height=\"590\" \/>\u00a0Figure 8. \uff08a\uff09\u5177\u6709\u4f4e\u6d53\u5ea6\u529f\u80fd\u5bfc\u7535\u805a\u5408\u7269\u7c98\u5408\u5242\u548c\u9ad8\u6d53\u5ea6SiO \/ C\u7684SiO\u57fa\u7535\u6781\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09PFM\u529f\u80fd\u6027\u5bfc\u7535\u805a\u5408\u7269\u7c98\u5408\u5242\u7684\u5316\u5b66\u7ed3\u6784\uff0c\u5177\u6709\u5f3a\u7c98\u9644\u6027\u548c\u5bfc\u7535\u529f\u80fd\uff1b\uff08c\uff09PFM\u7c98\u5408\u5242\u7684\u916f\u5b98\u80fd\u56e2\u4e0e\u8868\u9762Si-OH\u57fa\u56e2\u4e4b\u95f4\u7684\u916f\u4ea4\u6362\u53cd\u5e94\uff0c\u63d0\u4f9b\u5f3a\u7c98\u5408\u529b\uff1b\uff08d\u3001e\uff09\u5177\u67092, 5\u548c10 wt\uff05PFM\u7c98\u5408\u5242\u7684SiO\u8d1f\u6781\u5728200 mA g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><strong> 1.3.5\u3001\u57fa\u4e8eSiO\u7684\u8d1f\u6781\u6750\u6599\u7684ICE\u6539\u8fdb<\/strong><\/p>\n<p>\u521d\u59cb\u5faa\u73af\u8fc7\u7a0b\u4e2d\u5927\u7684\u4e0d\u53ef\u9006\u5bb9\u91cf\u663e\u7740\u963b\u788d\u4e86SiO\u5728LIBs\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u3002\u5b83\u4ec5\u9700\u8981\u8fc7\u91cf\u7684\u9634\u6781\u6750\u6599\u7528\u4e8e\u521d\u59cb\u5faa\u73af\uff0c\u727a\u7272\u4e86\u6574\u4e2a\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u3002\u56e0\u6b64\uff0c\u8bb8\u591a\u7814\u7a76\u81f4\u529b\u4e8e\u6539\u8fdb\u5176\u9996\u6b21\u5e93\u4f26\u6548\u7387\u3002\u4f8b\u5982\uff0cLi\u548cWen\u7b49\u4eba\u5236\u5907\u4e86\u7531\u7eb3\u7c73\u6676\u7845\u3001Li<sub>4<\/sub>SiO<sub>4<\/sub>\u548c\u5176\u4ed6\u5bcc\u9502\u7ec4\u5206\uff08Li<sub>2<\/sub>O\uff09\u7ec4\u6210\u7684\u590d\u5408\u8d1f\u6781\u6750\u6599\u3002\u5f97\u5230\u7684Li\/SiO\u884d\u751f\u590d\u5408\u6750\u6599\u7684\u7b2c\u4e00\u6b21\u653e\u7535\u5bb9\u91cf\u4e3a951 mA h g<sup>-1<\/sup>\uff0c\u9996\u6b21\u5e93\u4f26\u6548\u7387\u4e3a81\uff05\u3002Yoon\u7b49\u4eba\u5408\u6210\u4e86\u9884\u9502\u5316\u7684SiO \/ C\u8d1f\u6781\uff0c\u4e0e\u539f\u59cbSiO \/ C\u76f8\u6bd4\uff0c\u5b83\u8868\u73b0\u51fa\u8f83\u4f4e\u7684\u521d\u59cb\u5bb9\u91cf\u635f\u5931\u548c\u8f83\u9ad8\u7684\u9996\u6b21\u5e93\u4f26\u6548\u7387\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160589\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/9-1.gif\" alt=\"\" width=\"600\" height=\"276\" \/>\u00a0Figure 9. \uff08a\uff09\u9884\u5236\u5907\u9502\u5316\u5de5\u827a\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09\u53ef\u6269\u5c55\u7684\u5377\u5bf9\u5377\u9884\u9502\u5316\u5de5\u827a\u7684\u793a\u610f\u56fe\uff1b\uff08c\uff09\u539f\u59cb\u548c\u9884\u9502\u5316SiO\u5728\u534a\u7535\u6c60\u4e2d\u7684\u5faa\u73af\u6027\u80fd, 1C = 1500 mA g<sup>-1<\/sup>\uff1b\uff08d\uff09\u539f\u59cb\u548c\u9884\u9502\u5316SiO\u5728SiO \/ NCA\u5168\u7535\u6c60\u4e2d\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><strong> 2\u3001SiO<sub>2<\/sub>\u57fa\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u00a0\u4e8c\u6c27\u5316\u7845\uff08SiO<sub>2<\/sub>\uff09\u662f\u5730\u7403\u4e0a\u6700\u4e30\u5bcc\u7684\u6750\u6599\u4e4b\u4e00\u3002SiO<sub>2<\/sub>\u7684\u65e0\u5b9a\u5f62\u548c\u5404\u79cd\u7ed3\u6676\u591a\u6676\u578b\u7269\u5728\u81ea\u7136\u754c\u4e2d\u666e\u904d\u5b58\u5728\u3002\u4f8b\u5982\uff0c\u77f3\u82f1\uff08SiO<sub>2<\/sub>\u7684\u7ed3\u6676\u591a\u6676\u578b\u7269\uff09\u662f\u6c99\u5b50\u7684\u4e3b\u8981\u6210\u5206\uff0c\u800c\u65e0\u5b9a\u5f62SiO<sub>2<\/sub>\u5df2\u5e7f\u6cdb\u5b58\u5728\u4e8e\u5404\u79cd\u751f\u7269\u4f53\u4e2d\uff0c\u4f8b\u5982\u7845\u85fb\uff0c\u7a3b\u58f3\u548c\u82a6\u82c7\u53f6\u3002<\/p>\n<p><strong> 2.1\u3001SiO<sub>2<\/sub>\u7684\u9502\u5316\u884c\u4e3a<\/strong><\/p>\n<p>\u00a0\u5728\u65e9\u671f\u7814\u7a76\u4e2d\uff0c\u8ba4\u4e3aSiO<sub>2<\/sub>\u5bf9Li\u662f\u7535\u5316\u5b66\u60f0\u6027\u7684\u3002\u5b9e\u9645\u4e0a\uff0c\u5b83\u88ab\u8ba4\u4e3a\u662f\u60f0\u6027\u57fa\u8d28\uff0c\u7f13\u51b2\u9502\u5316\u65f6\u6d3b\u6027\u7ec4\u5206\u7684\u4f53\u79ef\u81a8\u80c0\u3002 \u57282001\u5e74\uff0c\u5468\u7b49\u4eba\u53d1\u73b0\u5e02\u552e\u7684SiO<sub>2<\/sub>\u7eb3\u7c73\u9897\u7c92\uff08~7nm\uff09\u53ef\u4e0eLi\u53cd\u5e94\uff0c\u63d0\u4f9b~400 mA h g<sup>-1<\/sup>\u7684\u6bd4\u5bb9\u91cf\u3002\u4f46\u662fLi\u548cSiO<sub>2<\/sub>\u4e4b\u95f4\u7684\u53cd\u5e94\u673a\u7406\u5c1a\u4e0d\u6e05\u695a\uff1b\u5173\u4e8e\u53cd\u5e94\u9014\u5f84\u548c\u6700\u7ec8\u4ea7\u7269\u4ecd\u5b58\u5728\u4e89\u8bae\u3002\u73b0\u5728\u5e38\u7528\u7406\u8bba\u8ba1\u7b97\u548c\u539f\u4f4dTEM\u7528\u4e8e\u63ed\u793aSiO<sub>2<\/sub>\u7684\u9502\u5316\u3002\u800c\u901a\u8fc7\u7406\u8bba\u7814\u7a76\u8868\u660e\uff0c\u5728\u9502\u5316\/\u53bb\u9502\u5316\u8fc7\u7a0b\u4e2d\uff0cSiO<sub>2<\/sub>\u7684\u7535\u5bfc\u7387\u663e\u7740\u589e\u5f3a\uff0cLi<sup>+<\/sup>\u7684\u6269\u6563\u7cfb\u6570\u964d\u4f4e\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160590\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/10-1.gif\" alt=\"\" width=\"600\" height=\"618\" \/>\u00a0Figure 10. \uff08a\uff09\u7531SiC @ SiO<sub>2<\/sub>\u5355\u7eb3\u7c73\u7ebf\u5de5\u4f5c\u7535\u6781\u548cLi \/ Li<sub>2<\/sub>O\u5bf9\u7535\u6781\/\u7535\u89e3\u8d28\u7ec4\u6210\u7684\u7eb3\u7c73\u7535\u6c60\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09\u539f\u59cb\u72b6\u6001\u5230\u7b2c\u4e00\u6b21\u9502\u5316\u7ed3\u675f\u7684SiC @ SiO<sub>2<\/sub>\u7eb3\u7c73\u7ebf\u7684TEM\u56fe\uff1b \uff08c\uff09 \u7ed9\u5b9a\u9502\u5316\u72b6\u6001\u4e0b\u7684\u76f8\u5e94SAED\u56fe\u6848\u3002<\/p>\n<p><strong> 2.2\u3001SiO<sub>2<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p><strong> 2.2.1\u3001\u7eaf\u7684SiO<sub>2<\/sub>\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u5c3d\u7ba1\u5176\u7406\u8bba\u5bb9\u91cf\u9ad8\uff081965 mA h g<sup>-1<\/sup>\uff09\uff0c\u4f46\u662f\u7531\u4e8eLi<sup>+<\/sup>\u6269\u6563\u6027\u7f13\u6162\u548c\u56fa\u6709\u5bfc\u7535\u6027\u5dee\uff0cSiO<sub>2<\/sub>\u5bf9Li\u7684\u7535\u5316\u5b66\u6d3b\u6027\u5f88\u5c0f\u3002\u7814\u7a76\u5df2\u7ecf\u8bc1\u660e\uff0c\u51cf\u5c0f\u7c92\u5f84\u662f\u7f29\u77edLi<sup>+<\/sup>\u6269\u6563\u957f\u5ea6\u548c\u589e\u5f3a\u67d0\u4e9b\u7535\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6d3b\u6027\u7684\u6709\u6548\u7b56\u7565\u3002 \u56e0\u6b64\uff0c\u76ee\u524d\u7814\u7a76\u4e3b\u8981\u81f4\u529b\u4e8e\u5236\u5907\u7cbe\u7ec6\u5c3a\u5bf8\u7684SiO<sub>2<\/sub>\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160591\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/11-1.gif\" alt=\"\" width=\"600\" height=\"400\" \/>\u00a0Figure 11. \uff08a\u3001b\uff09 SiO<sub>2<\/sub>\u4e2d\u7a7a\u7eb3\u7c73\u5fae\u7403\u7684\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\uff1b\uff08c\u3001d\uff09\u4e2d\u7a7a\u591a\u5b54SiO<sub>2<\/sub>\u7eb3\u7c73\u7acb\u65b9\u4f53\u7684\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\uff1b\uff08e\u3001f\uff09SiO<sub>2<\/sub>\u7eb3\u7c73\u7ba1\u7684\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\u3002<\/p>\n<p><strong> 2.2.2\u3001SiO<sub>2<\/sub> \/ C\u6742\u5316\u8d1f\u6781\u6750<\/strong><\/p>\n<p>\u5728\u7845\u6c27\u5316\u7269\u6750\u6599\u4e2d\uff0cSiO<sub>2<\/sub>\u5177\u6709\u6700\u4f4e\u7684\u5bfc\u7535\u6027\uff0c\u800c\u78b3\u5177\u6709\u826f\u597d\u7684\u5bfc\u7535\u6027\u3002\u56e0\u6b64\uff0c\u8bb8\u591a\u7814\u7a76\u90fd\u81f4\u529b\u4e8e\u901a\u8fc7\u4e0e\u78b3\u7684\u590d\u5408\u6765\u63d0\u9ad8SiO<sub>2<\/sub>\u7684\u5bfc\u7535\u6027\u5e76\u4e14\u4e0e\u78b3\u7684\u8026\u5408\u8fd8\u53ef\u4ee5\u7f13\u51b2SiO<sub>2<\/sub>\u7684\u4f53\u79ef\u6ce2\u52a8\u3002\u56e0\u6b64\uff0cSiO<sub>2<\/sub> \/ C\u590d\u5408\u6750\u6599\u901a\u5e38\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u6027\u3002\u5728\u5404\u79cdSiO<sub>2<\/sub> \/ C\u590d\u5408\u6750\u6599\u4e2d\uff0c\u591a\u5b54\u7684\u7279\u522b\u662f\u4ecb\u5b54\u7684SiO<sub>2<\/sub> \/ C\u6df7\u5408\u7269\u5f15\u8d77\u4e86\u5f88\u591a\u5173\u6ce8\u3002\u56e0\u4e3a\u591a\u5b54\u7ed3\u6784\u4e0d\u4ec5\u4e3a\u9502\u5316\u65f6\u9502\u7684\u4f53\u79ef\u81a8\u80c0\u63d0\u4f9b\u4e86\u81ea\u7531\u7a7a\u95f4\uff0c\u800c\u4e14\u8fd8\u80fd\u591f\u5feb\u901fLi<sup>+<\/sup>\u6269\u6563\uff0c\u53ef\u4ee5\u589e\u5f3a\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160592\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/12-1.gif\" alt=\"\" width=\"600\" height=\"323\" \/>\u00a0Figure 12. \uff08a\u3001b\uff09\u4ecb\u5b54SiO<sub>2<\/sub> \/ C\u590d\u5408\u6750\u6599\u7684\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\uff1b\uff08c\u3001d\uff09\u4ecb\u5b54SiO<sub>2<\/sub>\u7eb3\u7c73\u5fae\u7403\/\u9cde\u7247\u72b6\u77f3\u58a8\u7684\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\uff1b\uff08e\u3001f\uff09\u78b3\u82af\/\u4ecb\u5b54SiO<sub>2<\/sub> \/ \u78b3\u58f3\u7684\u4e09\u5c42\u7ed3\u6784\u6885\u82b1\u5e03\u4e01\u7684\u793a\u610f\u56fe\u548cTEM\u56fe\u50cf\u3002<\/p>\n<p><strong> 2.2.3\u3001SiO<sub>2<\/sub> \/\u91d1\u5c5e\u6742\u5316\u8d1f\u6781\u6750<\/strong><\/p>\n<p>\u5c06SiO<sub>2<\/sub>\u4e0e\u5bfc\u7535\u91d1\u5c5e\u5076\u8054\u4e5f\u5df2\u88ab\u8bc1\u660e\u5728\u63d0\u9ad8\u7535\u5bfc\u7387\u548c\u589e\u5f3a\u7535\u5316\u5b66\u6d3b\u6027\u65b9\u9762\u662f\u6709\u6548\u7684\u3002\u4f8b\u5982\uff0cZhou\u548cMai\u7b49\u4eba\u901a\u8fc7\u8fd8\u539f\u6784\u5efa\u4e86\u5177\u6709\u5206\u7ea7\u7a7a\u5fc3\u7ed3\u6784\u7684\u65b0\u578bSiO<sub>2<\/sub> \/ Ni\u7eb3\u7c73\u590d\u5408\u6750\u6599\u3002\u6240\u5f97\u7684SiO<sub>2<\/sub> \/ Ni\u7eb3\u7c73\u590d\u5408\u6750\u6599\u5177\u6709\u4ee5\u4e0b\u9502\u50a8\u5b58\u7ed3\u6784\u4f18\u70b9\uff1a\uff08I\uff09\u7528\u4e8e\u4f53\u79ef\u6ce2\u52a8\u8c03\u8282\u548c\u5e94\u53d8\u677e\u5f1b\u7684\u4e2d\u7a7a\u7403\u5f62\u7ed3\u6784\uff1b\uff08II\uff09 \u7528\u4e8e\u6709\u6548Li<sup>+<\/sup>\u6269\u6563\u7684\u8d85\u8584\u7eb3\u7c73\u7247\u6784\u4ef6\uff1b \uff08III\uff09\u7528\u4e8e\u7535\u5b50\u8f6c\u79fb\u589e\u5f3a\u7684\u8d85\u7ec6Ni\u7eb3\u7c73\u9897\u7c92\u88c5\u9970\u3002SiO<sub>2<\/sub> \/ Ni\u5206\u7ea7\u7a7a\u5fc3\u7403\u5728100 mA g<sup>-1<\/sup>\u65f6\u7ecf\u8fc750\u6b21\u5faa\u73af\u540e\u5177\u6709672 mA h g<sup>-1<\/sup>\u7684\u9ad8\u6bd4\u5bb9\u91cf\uff0c\u5e76\u4e14\u572810 A g<sup>-1<\/sup>\u4e0b1000\u6b21\u5faa\u73af\u540e\u663e\u793a\u51fa337 mA h g<sup>-1<\/sup>\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160593\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/13-1.gif\" alt=\"\" width=\"600\" height=\"323\" \/>\u00a0Figure 13. \uff08a\uff09\u7531\u8d85\u7ec6Ni\u7eb3\u7c73\u9897\u7c92\u4fee\u9970\u7684SiO<sub>2<\/sub>\u7eb3\u7c73\u7247\u6784\u6210\u7684SiO<sub>2<\/sub> \/ Ni\u5206\u7ea7\u7a7a\u5fc3\u5fae\u7403\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09SiO<sub>2<\/sub> \/ Ni\u5206\u7ea7\u7a7a\u5fc3\u5fae\u7403\u7684SEM\u56fe\u50cf\uff1b \uff08c\uff09SiO<sub>2<\/sub> \/ Ni\u5206\u7ea7\u7a7a\u5fc3\u5fae\u7403\u7684TEM\u56fe\u50cf\uff1b\uff08d\uff09SiO<sub>2<\/sub> \/ Ni\u5206\u7ea7\u7a7a\u5fc3\u7403\u5728100 mA g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\uff1b\uff08e\uff09SiO<sub>2<\/sub> \/ Ni\u5206\u7ea7\u7a7a\u5fc3\u7403\u572810 A g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><strong>3\u3001\u57fa\u4e8eSiO<sub>x<\/sub>\u7684\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u4e0eSiO\u548cSiO<sub>2<\/sub>\u4e00\u6837\uff0c\u975e\u5316\u5b66\u8ba1\u91cf\u7684\u4f4e\u6c27\u542b\u91cf\u7684\u7845\u6c27\u5316\u7269\uff08SiO<em><sub>x<\/sub><\/em>\uff09\u4e5f\u88ab\u8ba4\u4e3a\u662f\u53ef\u4ee5\u7528\u4e8e\u4e0b\u4e00\u4ee3LIBs\u7684\u9ad8\u5bb9\u91cf\u8d1f\u6781\u6750\u6599\uff0c\u7279\u522b\u662fO\u542b\u91cf\u4f4e\u4e8e1.0\u7684 SiO<em><sub>x<\/sub><\/em>\u8d1f\u6781\u6750\u6599\uff08\u5bcc\u542bSi\u7684SiO<em><sub>x<\/sub><\/em>\uff09\u3002<\/p>\n<p><strong>3.1\u3001SiO<sub>x<\/sub>\u7684\u9502\u5316\u884c\u4e3a<\/strong><\/p>\n<p>\u00a0Chou\u548cHwang\u7b49\u4eba\u901a\u8fc7DFT\u8ba1\u7b97\u7814\u7a76\u4e86SiO<sub>1\/3<\/sub>\u7684\u9502\u5316\u884c\u4e3a\u3002\u53d1\u73b0SiO<sub>1\/3<\/sub>\u4e3b\u4f53\u57fa\u4f53\u9010\u6e10\u5206\u89e3\u4e3a\u9502\u5316\u7684\u8f83\u5c0f\u788e\u7247\u3002\u540c\u65f6\uff0cSi-O-Si\u5355\u5143\u7834\u88c2\uff0cO\u539f\u5b50\u503e\u5411\u4e8e\u88abLi\u539f\u5b50\u5305\u56f4\u3002\u968f\u7740Li\u542b\u91cf\u7684\u589e\u52a0\uff0cSi-Li\u914d\u4f4d\u6570\u5728\u975e\u6676Li<sub>4<\/sub>SiO<sub>1\/3<\/sub>\u4e2d\u5355\u8c03\u589e\u52a0\u523010\u5de6\u53f3\uff0c\u800cO-Li\u914d\u4f4d\u6570\u5728\u5b8c\u5168\u9502\u5316\u4e4b\u524d\u5927\u7ea6\u57286\u5de6\u53f3\u9971\u548c\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160594\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/14-1.gif\" alt=\"\" width=\"600\" height=\"352\" \/>\u00a0Figure 14. \u968f\u7740Li\u542b\u91cf\u7684\u589e\u52a0\uff0c\u975e\u6676\u6001LixSiO<sub>1\/3<\/sub>\u7684\u7ed3\u6784\u6f14\u53d8\u3002<\/p>\n<p><strong> 3.2\u3001SiO<sub>x<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p><strong> 3.2.1\u3001\u7eaf\u7684SiO<sub>x<\/sub>\u8d1f\u6781\u6750<\/strong><\/p>\n<p>\u5bf9\u88f8SiO<sub>x<\/sub>\u57fa\u8d1f\u6781\u7684\u7814\u7a76\u4e3b\u8981\u96c6\u4e2d\u5728\u7814\u7a76SiO<em><sub>x<\/sub><\/em>\u4e2dO\u542b\u91cf\u5bf9\u5176\u7535\u5316\u5b66\u6027\u80fd\u7684\u5f71\u54cd\u3002\u57282002\u5e74\uff0c\u6768\u7b49\u4eba\u5bf9SiO<sub>0.8<\/sub><sub>\u3001<\/sub>SiO\u548cSiO<sub>1.1<\/sub>\u8fdb\u884c\u4e86\u5bf9\u6bd4\u7814\u7a76\u53d1\u73b0\uff0cSiO<em><sub>x<\/sub><\/em>\u4e2dO\u542b\u91cf\u7684\u964d\u4f4e\u63d0\u9ad8\u4e86\u53ef\u9006\u5bb9\u91cf\u548c\u9996\u6b21\u5e93\u4f26\u6548\u7387\uff0c\u4f46\u727a\u7272\u4e86\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u4eba\u4eec\u8ba4\u4e3a\u5bcc\u542bSi\u7684SiO<em><sub>x<\/sub><\/em>\u5177\u6709\u9ad8\u5bb9\u91cf\u4f46\u662f\u5177\u6709\u8f83\u5dee\u7684\u5faa\u73af\u6027\u80fd\uff0c\u800c\u5bcc\u542bO\u7684SiO<em><sub>x<\/sub><\/em>\u6709\u5229\u4e8e\u4f53\u79ef\u53d8\u5316\u8c03\u8282\u3002\u4e3a\u4e86\u6574\u5408\u8fd9\u4e24\u79cd\u7845\u6c27\u5316\u7269\u7684\u4f18\u70b9\uff0cYan\u548c\u540c\u4e8b\u8bbe\u8ba1\u4e86\u4e00\u79cdSiO<em><sub>x<\/sub><\/em> \/ SiO<em><sub>y<\/sub><\/em>\u53cc\u5c42\u7eb3\u7c73\u819c\u8d1f\u6781\u3002\u5185\u90e8\u5bcc\u542bSi\u7684SiO<em><sub>y<\/sub><\/em>\u5c42\uff08y = 0.5\uff09\u4e3a\u590d\u5408\u6750\u6599\u63d0\u4f9b\u4e86\u9ad8Li\u50a8\u5b58\u80fd\u529b\uff1b\u540c\u65f6\uff0c\u5916\u90e8\u5bccO\u7684SiO<em><sub>x<\/sub><\/em>\u5c42\uff08x = 1.85\uff09\u5145\u5f53\u7528\u4e8e\u4f53\u79ef\u53d8\u5316\u8c03\u8282\u7684\u7f13\u51b2\u5c42\u3002\u7531\u4e8e\u667a\u80fd\u8bbe\u8ba1\uff0cSiO<em><sub>x<\/sub> <\/em>\/ SiO<em><sub>y<\/sub><\/em>\u53cc\u5c42\u7eb3\u7c73\u819c\u5728100\u6b21\u5faa\u73af\u540e\u63d0\u4f9b\u4e86\u6bd4\u5bb9\u91cf\u4e3a~1300 mA h g<sup>-1<\/sup>\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160595\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/15-1.gif\" alt=\"\" width=\"600\" height=\"657\" \/>\u00a0Figure 15. \uff08a\uff09\u5377\u8d77\u7684SiO<sub>x<\/sub> \/ SiO<sub>y<\/sub>\u53cc\u5c42\u7eb3\u7c73\u819c\u7684\u793a\u610f\u7ed3\u6784\u793a\u610f\u56fe\uff1b\uff08b\uff09SiO<sub>x<\/sub> \/ SiO<sub>y<\/sub>\u53cc\u5c42\u7eb3\u7c73\u819c\u5728100 mA g<sup>-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p><strong> 3.2.2\u3001SiO<sub>x<\/sub> \/ C\u6742\u5316\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u4e0e\u672a\u6539\u6027\u7684SiO<em><sub>x<\/sub><\/em>\u76f8\u6bd4\uff0cSiO<em><sub>x<\/sub><\/em> \/ C\u590d\u5408\u6750\u6599\u7531\u4e8e\u5177\u6709\u4f18\u5f02\u7684\u5bfc\u7535\u6027\u548c\u78b3\u7684\u4f53\u79ef\u53d8\u5316\u9002\u5e94\u80fd\u529b\u800c\u8868\u73b0\u51fa\u66f4\u597d\u7684\u5faa\u73af\u6027\u548c\u500d\u7387\u6027\u80fd\u3002\u7845\u70f7\u7684\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u5df2\u88ab\u8bc1\u660e\u662f\u6784\u5efaSiO<em><sub>x<\/sub><\/em> \/ C\u590d\u5408\u8d1f\u6781\u6750\u6599\u7684\u6709\u6548\u65b9\u6cd5\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160596\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/16-1.gif\" alt=\"\" width=\"600\" height=\"402\" \/>\u00a0Figure 16. \uff08a\uff09SiO<sub>x<\/sub> \/ C\u590d\u5408\u5fae\u7403\u7684SEM\u56fe\u50cf\uff1b\uff08b\uff09SiO<sub>x<\/sub> \/ C\u590d\u5408\u5fae\u7403\u7684TEM\u56fe\u50cf\uff1b\uff08c\uff09 SiO<sub>x<\/sub> \/ C\u590d\u5408\u5fae\u7403\u7684EDS\u5143\u7d20\u6620\u5c04\u56fe\u50cf\uff1b \uff08d\uff09\u5747\u76f8SiO<sub>x<\/sub> \/ C\u590d\u5408\u5fae\u7403\u7684\u793a\u610f\u56fe\uff1b\uff08e\uff09 SiO<sub>x<\/sub> \/ C\u590d\u5408\u5fae\u7403\u5728500 mA g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160597\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/17-1.gif\" alt=\"\" width=\"600\" height=\"350\" \/>\u00a0Figure 17. \uff08a\uff09\u5375\u9ec4@\u58f3SiO<sub>x<\/sub> \/ C\u5fae\u7403\u7684\u5236\u5907\u793a\u610f\u56fe\uff0c\u5728\u5916\u8868\u9762\u548c\u5185\u8868\u9762\u4e0a\u5177\u6709\u534a\u77f3\u58a8\u78b3\u6d82\u5c42\uff08SiO<sub>x<\/sub> \/ C-CVD\uff09\uff1b\uff08b\uff09\u5375\u9ec4@\u58f3SiO<sub>x<\/sub> \/ C\u5fae\u7403\u7684TEM\u56fe\u50cf\uff1b\uff08c\uff09SiO<sub>x<\/sub> \/ C-CVD\u7684\u653e\u7535\u7535\u8377\u66f2\u7ebf\uff1b\uff08d\uff09SiO<sub>x<\/sub> \/ C\u548cSiO<sub>x<\/sub> \/ C-CVD\u5728500 mA g<sup>-1<\/sup>\u4e0b\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160598\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/18.gif\" alt=\"\" width=\"600\" height=\"501\" \/>\u00a0Figure 18\u3001\uff08a\uff09\u663e\u793aSiO<sub>x<\/sub> \/ C\u6c34\u51dd\u80f6\u7684\u5408\u6210\u65b9\u6cd5\u7684\u793a\u610f\u56fe\uff1b\uff08b\uff09 SiO<sub>x<\/sub> \/ C\u8d1f\u6781\u5728\u8d28\u91cf\u8f7d\u8377\u4e3a3.5 mg. cm<sup>-2<\/sup>\u65f6\u7684\u901f\u7387\u80fd\u529b\uff1b\uff08c\uff09 SiO<sub>x<\/sub> \/ G\u548cSiO<sub>x<\/sub> \/ C\u8d1f\u6781\u7684\u5faa\u73af\u6027\u80fd\uff0c\u538b\u5236\u5bc6\u5ea6\u4e3a1.3 g cm<sup>-3<\/sup>\u3002<\/p>\n<p><strong> 3.2.3\u3001SiO<sub>x<\/sub> \/\u91d1\u5c5e\u6742\u5316\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u00a0\u9664\u4e86SiO<sub>x<\/sub> \/ C\u590d\u5408\u6750\u6599\u5916\uff0cSiO<em><sub>x<\/sub><\/em> \/\u91d1\u5c5e\u6df7\u5408\u6750\u6599\u5bf9\u9502\u50a8\u5b58\u4e5f\u5f88\u6709\u5438\u5f15\u529b\u3002\u4f8b\u5982\uff0c\u901a\u8fc7CVD\u5236\u5907\u7684NiSi<em><sub>x<\/sub><\/em>@SiO<em><sub>x<\/sub><\/em>\u5f02\u8d28\u7ed3\u6784\u7684\u7eb3\u7c73\u7ebf\u8868\u73b0\u51fa1737 mA h g<sup>-1<\/sup>\u7684\u53ef\u9006\u5bb9\u91cf\uff08\u57fa\u4e8eSiO<em><sub>x<\/sub><\/em>\u7684\u8d28\u91cf\uff09\u3002\u5faa\u73af\u540e\u5bb9\u91cf\u7f13\u6162\u4e0b\u964d\uff0c100\u6b21\u5faa\u73af\u540e\u4fdd\u6301\u5728800 mA h g<sup>-1<\/sup>\u3002<\/p>\n<p>\n <img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160599\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/20.gif\" alt=\"\" width=\"600\" height=\"410\" \/>\u00a0Figure 20. \uff08a\uff09NiSi<sub>x<\/sub> @ SiO<sub>x<\/sub>\u5f02\u8d28\u7ed3\u6784\u7eb3\u7c73\u7ebf\u7684TEM\u548cSEM\uff08\u63d2\u56fe\uff09\u56fe\u50cf\uff1b\uff08b\uff09 STEM HAADF\u56fe\u50cf\u548c\u5355\u4e2aNiSi<sub>x<\/sub> @ SiO<sub>x<\/sub>\u5f02\u8d28\u7ed3\u6784\u7eb3\u7c73\u7ebf\u7684EDX\u5143\u7d20\u6620\u5c04\uff1b\uff08c\uff09\u6838@\u58f3\u7ed3\u6784FeSi\u5408\u91d1@Si \/ SiO<sub>x<\/sub>\u7684SEM\u56fe\u50cf\uff1b\uff08d\uff09\u6838\u5fc3@\u58f3\u7ed3\u6784FeSi<sub>x<\/sub> @ Si\/ SiO<sub>x<\/sub>\u7684\u5faa\u73af\u6027\u80fd\uff0c\u7535\u6d41\u5bc6\u5ea6\u4e3a50-1000 mA g<sup>-1<\/sup>\u3002<\/p>\n<p><strong> 4\u3001SiOC\u57fa\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u78b3\u6c27\u5316\u7845\uff08SiOC\uff09\u662f\u6307\u4e00\u79cd\u542b\u78b3\u7845\u9178\u76d0\u9676\u74f7\uff0c\u5176\u4e2dO\u548cC\u539f\u5b50\u4e0e\u975e\u6676\u683c\u4e2d\u7684Si\u539f\u5b50\u5177\u6709\u5171\u4ef7\u952e\u3002 Dahn\u7b49\u4eba\u9996\u5148\u8bc1\u660e\u4e86SiOC\u9676\u74f7\u7684\u9502\u50a8\u5b58\u80fd\u529b\u3002\u4ece\u90a3\u65f6\u8d77\uff0c\u7814\u7a76\u4eba\u5458\u5c31\u5df2\u7ecf\u81f4\u529b\u4e8e\u5236\u5907\u57fa\u4e8eSiOC\u7684\u8d1f\u6781\u6750\u6599\u3002<\/p>\n<p><strong> 4.1\u3001SiOC\u7684\u5fae\u89c2\u7ed3\u6784\u548c\u9502\u50a8\u5b58\u673a\u5236<\/strong><\/p>\n<p><strong> 4.1.1\u3001SiOC\u7684\u5fae\u89c2\u7ed3\u6784<\/strong><\/p>\n<p>SiOC\u662f\u4e00\u79cd\u9ad8\u6e29\u9676\u74f7\uff0c\u5177\u6709\u5f00\u653e\u7684\u805a\u5408\u7269\u72b6\u7f51\u7edc\u7ed3\u6784\uff0c\u7531\u975e\u6676SiOC\u73bb\u7483\u76f8\u548c\u6e38\u79bb\u78b3\u76f8\u7ec4\u6210\u7684\u3002\u5176\u8be6\u7ec6\u7684\u5fae\u89c2\u7ed3\u6784\u53ef\u4ee5\u7528\u7eb3\u7c73\u57df\u6a21\u578b\u6765\u8868\u793a\u3002\u5728\u8fd9\u6837\u7684\u6a21\u578b\u4e2d\uff0c\u6e38\u79bb\u78b3\u5f62\u6210\u8fde\u7eed\u7684\u57fa\u8d28\uff0c\u5305\u5c01SiOC\u7eb3\u7c73\u57df\u3002 SiO<sub>4<\/sub>\u56db\u9762\u4f53\u4f4d\u4e8eSiOC\u7eb3\u7c73\u57df\u7684\u4e2d\u5fc3\uff0cSiOnC<sub>4<\/sub>\uff08n=0~4\uff09\u56db\u9762\u4f53\u4f4d\u4e8eSiOC\u73bb\u7483\u548c\u6e38\u79bb\u78b3\u76f8\u7684\u754c\u9762\u3002<\/p>\n<p><strong> 4.1.2\u3001SiOC\u7684\u9502\u50a8\u5b58\u673a\u5236<\/strong><\/p>\n<p>\u00a0SiOC\u7684\u9502\u5b58\u50a8\u673a\u5236\u662f\u4e00\u4e2a\u91cd\u8981\u7684\u8bdd\u9898\u3002\u4f46\u662f\uff0cSiOC\u7684\u9502\u50a8\u5b58\u6d3b\u6027\u7684\u8d77\u6e90\u4ecd\u7136\u662f\u4e00\u4e2a\u6709\u4e89\u8bae\u7684\u95ee\u9898\u3002Kanamura\u7b49\u4eba\u901a\u8fc7\u4f7f\u75287Li NMR\u89c2\u5bdf\u5230\u4e09\u79cd\u7c7b\u578b\u7684\u7535\u5316\u5b66\u6d3b\u6027\u4f4d\u70b9\uff1a\u77f3\u58a8\u70ef\u5c42\u7684\u95f4\u9699\u7a7a\u95f4\u6216\u8fb9\u7f18\u3001\u975e\u6676SiOC\u73bb\u7483\u76f8\u548c\u5fae\u5b54\u3002\u5728\u8fd9\u4e09\u79cd\u7c7b\u578b\u7684\u6d3b\u6027\u4f4d\u70b9\u4e2d\uff0c\u77f3\u58a8\u70ef\u5c42\u7684\u95f4\u9699\u7a7a\u95f4\u6216\u8fb9\u7f18\u88ab\u8ba4\u4e3a\u662f\u9502\u50a8\u5b58\u7684\u4e3b\u8981\u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n<p><strong> 4.2\u3001SiOC\u7684\u7535\u5316\u5b66\u6027\u80fd\u4f18\u5316<\/strong><\/p>\n<p><strong> 4.2.1\u3001\u7eafSiOC\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u00a0\u5c3d\u7ba1\u805a\u5408\u7269\u884d\u751f\u7684\u9676\u74f7SiOC\u542b\u6709\u6e38\u79bb\u78b3\u76f8\uff0c\u4f46\u662f\u9664\u975e\u53e6\u6709\u8bf4\u660e\uff0c\u5426\u5219\u6211\u4eec\u4e00\u822c\u8ba4\u4e3a\u5b83\u662f\u539f\u59cb\u7684SiOC\u3002 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C\u6df7\u5408\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u5c3d\u7ba1SiOC\u5177\u6709\u9ad8\u6bd4\u5bb9\u91cf\uff0c\u4f46\u662f\u539f\u59cbSiOC\u7684\u9502\u50a8\u5b58\u6027\u80fd\u4ecd\u8fdc\u672a\u8fbe\u5230\u5b9e\u9645\u5e94\u7528\u7684\u8981\u6c42\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u8005\u4eec\u5df2\u7ecf\u81f4\u529b\u4e8e\u6784\u5efaSiOC\/C\u6742\u5316\u7269\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u7535\u5316\u5b66\u6027\u80fd\u3002\u5341\u591a\u5e74\u524d\uff0c\u4f7f\u7528\u81a8\u80c0\u77f3\u58a8\u4e0eSiOC\u5076\u8054\u4ee5\u63d0\u9ad8\u7535\u5bfc\u7387\u3002\u6700\u8fd1\uff0cCNT\u3001\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u3001\u77f3\u58a8\u70ef\u548c\u78b3\u7eb8\u4e5f\u7528\u4e8e\u7535\u5316\u5b66\u6027\u80fd\u589e\u5f3a\u3002\u6b64\u5916\uff0c\u5f53\u5f15\u5165\u8fd9\u4e9b\u4e00\u7ef4\/\u4e8c\u7ef4\u78b3\u6750\u6599\u65f6\uff0c\u53ef\u4ee5\u83b7\u5f97\u72ec\u7acb\u7684\u67d4\u6027SiOC\u57fa\u7535\u6781\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-160600\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/21.gif\" alt=\"\" width=\"600\" height=\"499\" \/>Figure 21. \uff08a\uff09\u6570\u7801\u7167\u7247\u3001\u72ec\u7acb\u5f0fSiOC\/ rGO\u590d\u5408\u6750\u6599\u7684\u793a\u610f\u56fe\uff0c\u4ee5\u53caSiOC\u7684\u539f\u5b50\u7ed3\u6784\uff1b\uff08b\uff09\u5177\u6709\u4e0d\u540cSiOC\u542b\u91cf\u7684SiOC\/ rGO\u590d\u5408\u6750\u6599\u7684\u901f\u7387\u6027\u80fd\uff1b\uff08c\uff09SiOC \/ rGO\u590d\u5408\u6750\u6599\u7684\u9502\u5316\/\u8131\u9502\u673a\u7406\u7684\u793a\u610f\u56fe\u3002<\/p>\n<p><strong> 4.2.3\u3001SiOC \/\u91d1\u5c5e\u6742\u5316\u8d1f\u6781\u6750\u6599<\/strong><\/p>\n<p>\u5c06\u91d1\u5c5e\u5f15\u5165SiOC\u4ee5\u5236\u5907SiOC 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/11\/22.gif\" alt=\"\" width=\"600\" height=\"197\" \/>Figure 22. \uff08a\uff09SiOC \/ Sn\u7684TEM\u56fe\u50cf\uff1b\uff08b\uff09\u5177\u6709EDS\u56fe\u6848\u7684\u975e\u6676SiOC\u57fa\u8d28\u7684\u9ad8\u5206\u8fa8\u7387\u56fe\u50cf\uff1b\uff08c\uff09 SiOC \/ Sn\u7684\u901f\u7387\u6027\u80fd\u548c\u5e93\u4ed1\u6548\u7387\uff08Z\uff09\u3002<\/p>\n<p><strong> 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\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<strong><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2018\/cs\/c8cs00441b#!divRelatedContent&amp;articles\" target=\"_blank\" rel=\"noopener\">Silicon oxides: a promising family of anode materials for lithium-ion batteries<\/a><\/strong>\uff08Chem. Soc. Rev., <strong>2018<\/strong>, DOI: 10.1039\/c8cs00441b\uff09<\/p>\n<p style=\"text-align: center;\"><strong>\u901a\u8baf\u4f5c\u8005\u53ca\u5176\u56e2\u961f\u7b80\u4ecb\uff1a<\/strong><\/p>\n<p><strong>\u5468\u4eae\u535a\u58eb\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u7279\u8058\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u6606\u58eb\u5170\u5927\u5b66\u6fb3\u5927\u5229\u4e9a\u751f\u7269\u5de5\u7a0b\u4e0e\u7eb3\u7c73\u6280\u672f\u7814\u7a76\u6240\u8363\u8a89\u526f\u6559\u6388\u3002<\/strong>2006\u5e74\u83b7\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\u7406\u5b66\u5b66\u58eb\u5b66\u4f4d\uff0c2011\u5e74\u83b7\u5f97\u590d\u65e6\u5927\u5b66\u5316\u5b66\u7cfb\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u5e08\u4ece\u8d75\u4e1c\u5143\u9662\u58eb\u548c\u4f59\u627f\u5fe0\u6559\u6388\u30022011\u5e74\u52a0\u5165\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u697c\u96c4\u6587\u6559\u6388\u8bfe\u9898\u7ec4\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff0c2012\u5e74\u52a0\u5165\u6606\u58eb\u5170\u5927\u5b66\u4f59\u627f\u5fe0\u6559\u6388\u8bfe\u9898\u7ec4\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff0c2015\u5e743\u6708\u52a0\u5165\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u6750\u6599\u590d\u5408\u65b0\u6280\u672f\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u3002<strong>\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u529f\u80fd\u7eb3\u7c73\u6750\u6599\u7684\u7535\u5316\u5b66\u50a8\u80fd\u5e94\u7528\uff0c\u5728<em>Nat. Commun., Angew.Chem.Int.Ed., Adv.Mater., ACS Nano., Adv.Energy Mater., Adv. Funct.Mater., Adv. Sci., Nano Energy<\/em>\u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868SCI\u8bba\u658790\u4f59\u7bc7\uff0c\u6587\u7ae0\u88ab\u5f15\u75283800\u4f59\u6b21\uff0cH\u56e0\u5b50\u4e3a35\u3002<\/strong><\/p>\n<p><strong>\u9ea6\u7acb\u5f3a\u535a\u58eb\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u6750\u6599\u5b66\u79d1\u9996\u5e2d\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u56fd\u9645\u5316\u793a\u8303\u5b66\u9662\u56fd\u9645\u4e8b\u52a1\u9662\u957f\uff0c\u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\uff082016\u5e74\u5ea6\uff09\uff0c\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u201c\u7eb3\u7c73\u79d1\u6280\u201d\u91cd\u70b9\u4e13\u9879\u603b\u4f53\u4e13\u5bb6\u7ec4\u6210\u5458\u3002<\/strong>2004\u5e74\u5728\u6b66\u6c49\u7406\u5de5\u5927\u5b66\u83b7\u5de5\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u968f\u540e\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u5916\u7c4d\u9662\u58eb\u7f8e\u56fd\u4f50\u6cbb\u4e9a\u7406\u5de5\u5b66\u9662\u738b\u4e2d\u6797\u6559\u6388\u8bfe\u9898\u7ec4\u3001\u7f8e\u56fd\u79d1\u5b66\u9662\u9662\u58eb\u54c8\u4f5b\u5927\u5b66CM Lieber\u6559\u6388\u8bfe\u9898\u7ec4\u3001\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u6768\u57f9\u4e1c\u6559\u6388\u8bfe\u9898\u7ec4\u4ece\u4e8b\u535a\u58eb\u540e\u3001\u9ad8\u7ea7\u7814\u7a76\u5b66\u8005\u7814\u7a76\u3002<strong>\u957f\u671f\u4ece\u4e8b\u7eb3\u7c73\u80fd\u6e90\u6750\u6599\u4e0e\u5668\u4ef6\u7814\u7a76\uff0c\u5df2\u53d1\u8868SCI\u8bba\u6587290\u4f59\u7bc7\uff0c\u5305\u62ec<em>Nature<\/em>\u53ca\u5176\u5b50\u520a11\u7bc7\uff0c<em>Chem. Rev.<\/em> 1 \u7bc7\uff0c<em>Adv. Mater.<\/em> 14\u7bc7\uff0c<em>J. Am. Chem. Soc.<\/em> 2\u7bc7\uff0c<em>Angew. Chem. Int. Ed.<\/em>2\u7bc7\uff0c<em>PNAS<\/em> 2\u7bc7\uff0c<em>Nano Lett.<\/em> 25\u7bc7\uff0c<em>Joule<\/em>2\u7bc7\uff0c<em>Chem<\/em>.1\u7bc7\uff0c<em>Acc. Chem. Res. <\/em>1\u7bc7\uff0c<em>Energy Environ. Sci.<\/em> 1\u7bc7\uff0c\u4ee5\u7b2c\u4e00\u6216\u901a\u8baf\u4f5c\u8005\u5728\u5f71\u54cd\u56e0\u5b5010.0\u4ee5\u4e0a\u7684\u671f\u520a\u53d1\u8868\u8bba\u658790\u4f59\u7bc7\uff0c2017\u5e74\u88ab\u8bc4\u4e3a\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1a\u4e2d\u56fd\u201c\u9ad8\u88ab\u5f15\u5b66\u8005\u201d\u3002\u4e3b\u6301\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u3001\u56fd\u5bb6\u91cd\u5927\u79d1\u5b66\u7814\u7a76\u8ba1\u5212\u8bfe\u9898\uff0c\u56fd\u5bb6\u56fd\u9645\u79d1\u6280\u5408\u4f5c\u4e13\u9879\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\u7b4930\u4f59\u9879\u79d1\u7814\u9879\u76ee\u3002\u83b7\u4e2d\u56fd\u9752\u5e74\u79d1\u6280\u5956\u3001\u5149\u534e\u5de5\u7a0b\u79d1\u6280\u5956\uff08\u9752\u5e74\u5956\uff09\u3001\u6e56\u5317\u7701\u81ea\u7136\u79d1\u5b66\u4e00\u7b49\u5956\u3001\u4faf\u5fb7\u699c\u5316\u5de5\u79d1\u5b66\u6280\u672f\u5956\uff08\u9752\u5e74\u5956\uff09\u3001EEST2018 Research Excellence Awards\u3001Nanoscience Research Leader\u5956\u3001\u5165\u9009\u56fd\u5bb6\u201c\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u8ba1\u5212\u201d\u3001\u79d1\u6280\u90e8\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\u8ba1\u5212\uff0c\u6559\u80b2\u90e8\u65b0\u4e16\u7eaa\u4f18\u79c0\u4eba\u624d\u8ba1\u5212\uff0c\u5e76\u88ab\u6388\u4e88\u201c\u6709\u7a81\u51fa\u8d21\u732e\u4e2d\u9752\u5e74\u4e13\u5bb6\u201d\u8363\u8a89\u79f0\u53f7\uff0c\u4eab\u53d7\u56fd\u52a1\u9662\u653f\u5e9c\u7279\u6b8a\u6d25\u8d34\u3002\u73b0\u4efb<em>Adv. 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Mai, Yolk@shell SiO<em><sub>x<\/sub><\/em>\/C microspheres with semi-graphitic carbon coating on the exterior and interior surfaces for durable lithium storage, <strong>Energy Storage Mater<\/strong>., 2018, DOI: 10.1016\/j.ensm.2018.10.011.<\/p>\n<p>3\u3001Tang, Y. Liu, C. Xu, J. Zhu, X. Wei, L. Zhou, L. He, W. Yang and L. Mai, Ultrafine nickel-Nanoparticle-enabled SiO<sub>2<\/sub> hierarchical hollow spheres for high-performance lithium Storage, <strong>Adv. Funct. Mater.<\/strong>, 2017, 28, 1704561.<\/p>\n<p>4\u3001Yu, P. P. Ge, Z. H. Liu, M. Xu, W. Yang, L. Zhou, D. Y. Zhao, L. Q. Mai, Ultrafine SiO<em><sub>x<\/sub><\/em>\/C nanospheres and their pomegranate-Like assemblies for high-performance lithium storage, <strong>Journal of Materials Chemistry A<\/strong>, 2018, 6,14903.<\/p>\n<p>5\u3001J. Tang, J. X. Zhu, X. J. Wei, L. He, K. N. Zhao, C. Xu, L. Zhou, B. Wang, J. Z. Sheng, L. Q. Mai, Copper silicate nanotubes anchored on reduced graphene oxide for long-life lithium-ion battery, <strong>Energy Storage Materials<\/strong>, 2017, 7, 152\u2013156.<\/p>\n<p><strong> \u672c\u6587\u7531\u6750\u6599\u4eba\u7535\u5b50\u7ec4\u5c0f\u80d6\u7eb8\u7f16\u8bd1\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/strong><\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1a<strong>tougao@cailiaoren.com<\/strong><\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<strong>cailiaokefu<\/strong>.<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 \u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u957f\u5bff\u547d\u548c\u73af\u4fdd\u6027\u7684\u7279\u70b9\uff0c\u662f\u76ee\u524d\u6700\u5177\u5438\u5f15\u529b\u7684\u50a8\u80fd\u88c5\u7f6e\u4e4b\u4e00\uff0c\u88ab\u5e7f\u6cdb\u7684\u5e94\u7528\u4e8e\u624b\u673a\u3001\u7b14\u8bb0\u672c\u7535\u8111\u548c\u6570\u7801\u76f8\u673a\u7b49\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7&#8230;<\/p>\n","protected":false},"author":7770,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[533],"tags":[],"class_list":["post-160568","post","type-post","status-publish","format-standard","hentry","category-zongshu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/160568"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7770"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=160568"}],"version-history":[{"count":8,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/160568\/revisions"}],"predecessor-version":[{"id":160892,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/160568\/revisions\/160892"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=160568"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=160568"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=160568"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}