{"id":159094,"date":"2018-11-14T06:30:05","date_gmt":"2018-11-13T22:30:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=159094"},"modified":"2018-11-14T12:35:37","modified_gmt":"2018-11-14T04:35:37","slug":"%e6%9e%97%e7%92%8b%e5%9b%a2%e9%98%9fangewandte-chemie%ef%bc%9ani-mofs%e5%8d%95%e5%b1%82%e7%ba%b3%e7%b1%b3%e7%89%87%e5%ae%9e%e7%8e%b0%e4%ba%86%e4%bd%8e%e6%b5%93%e5%ba%a6co2%e5%85%89%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=159094","title":{"rendered":"\u6797\u748b\u56e2\u961fAngewandte Chemie\uff1aNi MOFs\u5355\u5c42\u7eb3\u7c73\u7247\u5b9e\u73b0\u4e86\u4f4e\u6d53\u5ea6CO2\u5149\u50ac\u5316\u8fd8\u539f\uff0c\u4e3a\u5de5\u4e1a\u5e9f\u6c14\u4e2dCO2\u7684\u8d44\u6e90\u5316\u5229\u7528\u63d0\u4f9b\u65b0\u601d\u8def"},"content":{"rendered":"

\"\"\u3010\u7814\u7a76\u80cc\u666f\u3011<\/b><\/strong><\/p>\n

\u5feb\u901f\u53d1\u5c55\u7684\u73b0\u4ee3\u5de5\u4e1a\u5e26\u6765\u4e86\u5927\u91cf\u542b\u6709CO2<\/sub>\u7684\u5de5\u4e1a\u5e9f\u6c14\uff0c\u9020\u6210\u4e86\u5168\u7403\u6c14\u5019\u53d8\u5316\u7b49\u751f\u6001\u73af\u5883\u5371\u673a\u3002\u5229\u7528\u5149\u50ac\u5316\u6280\u672f\uff0c\u5728\u592a\u9633\u80fd\u7684\u9a71\u52a8\u4e0b\u76f4\u63a5\u5c06\u5de5\u4e1a\u5e9f\u6c14\u4e2d\u542b\u6709\u7684\u4f4e\u6d53\u5ea6CO2<\/sub>\u8fd8\u539f\u4e3a\u5316\u5de5\u539f\u6599\u6216\u78b3\u57fa\u71c3\u6599\u4e3a\u5de5\u4e1a\u5e9f\u6c14\u8d44\u6e90\u5229\u7528\u548c\u7f13\u89e3\u5168\u7403\u6c14\u5019\u53d8\u5316\u63d0\u4f9b\u4e86\u4e00\u4e2a\u6709\u975e\u5e38\u6709\u6f5c\u529b\u7684\u89e3\u51b3\u9014\u5f84\u3002\u7136\u800c\uff0c\u7531\u4e8eCO2<\/sub>\u5206\u5b50\u7684\u9ad8\u7a33\u5b9a\u6027\u548c\u590d\u6742\u7684\u591a\u7535\u5b50\u53cd\u5e94\u8fc7\u7a0b\uff0c\u9ad8\u6548\u9ad8\u9009\u62e9\u6027\u7684CO2<\/sub>\u5149\u50ac\u5316\u8fd8\u539f\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u6311\u6218\uff0c\u5c24\u5176\u662f\u5728\u4f4eCO2<\/sub>\u6d53\u5ea6\u7684\u53cd\u5e94\u6761\u4ef6\u4e0b\u3002\u56e0\u6b64\uff0c\u5b9e\u73b0\u4f4eCO2<\/sub>\u6d53\u5ea6\u6761\u4ef6\u4e0b\u7684\u9ad8\u6548\u9ad8\u9009\u62e9\u6027CO2<\/sub>\u5149\u50ac\u5316\u8fd8\u539f\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u3010\u7814\u7a76\u4eae\u70b9\u3011<\/b><\/strong><\/p>\n

1.\u5b9e\u73b0\u4e86\u4f4e\u6d53\u5ea6CO2<\/sub>\uff0810%\uff0c\u6a21\u62df\u5de5\u4e1a\u5e9f\u6c14\u4e2d\u7684CO2<\/sub>\u542b\u91cf\uff09\u6761\u4ef6\u4e0b\u9ad8\u6548\u9ad8\u9009\u62e9\u6027CO2<\/sub>\u5149\u50ac\u5316\u8fd8\u539f\u3002<\/p>\n

2.\u786e\u8ba4\u4e86\u50ac\u5316\u6750\u6599\u7684CO2<\/sub>\u5438\u9644\u662f\u6574\u4e2a\u53cd\u5e94\u8fc7\u7a0b\u7684\u5173\u952e\u6b65\u9aa4\u3002<\/p>\n

3.\u9a8c\u8bc1\u4e86\u954d\u57faMOFs\u5bf9\u4e8e\u4f4e\u6d53\u5ea6CO2<\/sub>\u5149\u50ac\u5316\u7684\u9ad8\u9009\u62e9\u6027\u5177\u6709\u666e\u904d\u7684\u4f18\u8d8a\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u6709\u9274\u4e8e\u6b64\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u6797\u748b\u6559\u6388\u8bfe\u9898\u7ec4\u4e0e\u798f\u5dde\u5927\u5b66\u5f90\u827a\u519b\u6559\u6388\u8bfe\u9898\u7ec4\u5408\u4f5c<\/strong>\uff0c\u53d1\u5c55\u4e86\u4e00\u79cd\u5b9e\u73b0\u4f4e\u6d53\u5ea6\u6761\u4ef6\u4e0b\u9ad8\u9009\u62e9\u6027\u5149\u50ac\u5316CO2<\/sub>\u5236CO\u7684\u5355\u5c42Ni MOFs\u50ac\u5316\u6750\u6599\uff0c\u8be5\u6210\u679c\u53d1\u8868\u5728Angewandte Chemie<\/i><\/em>\uff0c\u5e76\u5165\u9009Very Important Paper (VIP)\u3002\u672c\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u97e9\u5f6c\uff0c\u6b27\u65b0\u6587<\/strong>\uff0c\u901a\u8baf\u4f5c\u8005\u662f\u6797\u748b\u6559\u6388<\/strong>\uff0c\u901a\u8baf\u5355\u4f4d\u4e3a\u534e\u5357\u7406\u5de5\u5927\u5b66(South China University of Technology)\u3002<\/p>\n

\u56fe1. Ni MOF \u5355\u5c42\u7eb3\u7c73\u7247\u7684\u5236\u5907\u65b9\u6cd5\u53ca\u7ed3\u6784\u4fe1\u606f<\/p>\n

\"\"<\/p>\n

\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u8d85\u58f0\u6cd5\u7ed3\u5408\u6c34\u8f85\u52a9\u51b7\u51bb\u5e72\u71e5\uff0c\u6210\u529f\u5236\u5907\u4e86Ni MOFs\u5355\u5c42\u7eb3\u7c73\u7247\u3002\u4f5c\u4e3a\u5bf9\u7167\uff0c\u5408\u6210\u4e86\u5806\u53e0\u7684Ni MOFs\u7eb3\u7c73\u6750\u6599\uff0c\u4e24\u8005\u5177\u6709\u76f8\u540c\u7684\u6676\u4f53\u7ed3\u6784\u3002<\/p>\n

\u56fe2. Ni MOF \u5355\u5c42\u7eb3\u7c73\u7247\u7684\u5f62\u8c8c\u8868\u5f81<\/p>\n

\"\"<\/p>\n

SEM\u548cTEM\u8868\u660e\u6240\u5236\u5907\u6750\u6599\u5448\u73b0\u660e\u663e\u7684\u4e8c\u7ef4\u7eb3\u7c73\u7247\u5f62\u8c8c\u3002\u901a\u8fc7AFM\u5bf9\u6750\u6599\u7684\u539a\u5ea6\u8fdb\u884c\u5b9a\u91cf\u8868\u5f81\uff0c\u786e\u8ba4\u6240\u5236\u5907Ni MOFs\u7684\u539a\u5ea6\u4e3a1.0\u7eb3\u7c73\u5de6\u53f3\uff0c\u4e0e\u5355\u5c42Ni MOFs \u7684\u7406\u8bba\u539a\u5ea6\u76f8\u543b\u5408\u3002<\/p>\n

\u56fe3. Ni MOF \u5355\u5c42\u7eb3\u7c73\u7247\u7684\u50ac\u5316\u6027\u80fd\u53ca\u673a\u7406\u7814\u7a76<\/p>\n

\"\"<\/p>\n

\u5728\u7eafCO2<\/sub>\u6c1b\u56f4\u4e0b\uff0cNi MOFs\u5355\u5c42\u7eb3\u7c73\u7247\u8868\u73b0\u51fa97.8%\u7684CO\u9009\u62e9\u6027\u548c2.2%\u7684\u8868\u89c2\u91cf\u5b50\u6548\u7387(420 nm)\u3002\u5728\u4f4e\u6d53\u5ea6CO2<\/sub>(10%\uff0c\u6a21\u62df\u70df\u6c14\u4e2d\u7684CO2<\/sub>\u542b\u91cf)\u6761\u4ef6\u4e0b\uff0cNi MOFs\u8868\u73b0\u51fa96.8%\u7684CO\u9009\u62e9\u6027\u548c1.98%\u7684\u8868\u89c2\u91cf\u5b50\u6548\u7387(420 nm)\u3002\u8be5\u6548\u7387\u4e0d\u4ec5\u9ad8\u4e8e\u76ee\u524d\u6587\u732e\u62a5\u9053\u7684\u4f4e\u6d53\u5ea6CO2<\/sub>\u8fd8\u539f\u4f53\u7cfb\u7684\u6548\u7387\uff0c\u8fd8\u8d85\u8fc7\u4e86\u5927\u90e8\u5206\u5728\u7eafCO2<\/sub>\u6c1b\u56f4\u4e0b\u7684\u50ac\u5316\u4f53\u7cfb\u7684\u6548\u7387\uff0c\u5373Ni MOFs\u5355\u5c42\u7eb3\u7c73\u7247\u6210\u529f\u5b9e\u73b0\u4e86\u4f4e\u6d53\u5ea6\u4e0b\u7684\u9ad8\u6548\u9ad8\u9009\u62e9\u6027\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u3002\u540c\u6784\u7684Co MOFs\u5728\u4f4e\u6d53\u5ea6\u4e0b\u51e0\u4e4e\u6ca1\u6709\u6d3b\u6027\uff0c\u8bf4\u660e\u5728MOFs\u7684\u91d1\u5c5e\u6838\u5fc3\u5bf9\u4e8e\u8be5\u50ac\u5316\u4f53\u7cfb\u5177\u6709\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

\u5b9e\u9a8c\u6570\u636e\u548cDFT\u8ba1\u7b97\u53d1\u73b0\uff0cCo MOFs\u8f83Ni MOFs\u5177\u6709\u66f4\u597d\u7684\u5149\u751f\u7535\u5b50\u4f20\u8f93\u80fd\u529b\uff0c\u66f4\u4f4e\u7684COOH*\u6d3b\u5316\u80fd\u5792\uff0c\u4f46Ni MOFs\u8f83Co MOFs\u6709\u660e\u663e\u66f4\u5f3a\u7684CO2<\/sub>\u4eb2\u548c\u80fd\u548c\u66f4\u5f31\u7684H2<\/sub>O\u4eb2\u548c\u80fd\u3002\u8bf4\u660e\uff0cCO2<\/sub>\u7684\u5438\u9644\u662f\u6574\u4e2a\u8fc7\u7a0b\u7684\u5173\u952e\u6b65\u9aa4\u3002<\/p>\n

\u901a\u8fc7\u5408\u6210\u5176\u5b83\u7684Ni\/Co MOFs, \u8bc1\u660e\u4e86Ni MOFs\u5728\u63d0\u9ad8CO2<\/sub>\u8fd8\u539f\u7684\u9009\u62e9\u6027\u65b9\u9762\u6709\u666e\u904d\u7684\u4f18\u8d8a\u6027\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u603b\u4e4b\uff0c\u8fd9\u9879\u7814\u7a76\u4e3a\u63d0\u9ad8\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\uff0c\u4e3a\u5b9e\u73b0\u4f4e\u6d53\u5ea6CO2<\/sub>\u8fd8\u539f\u548c\u5e9f\u6c14\u8d44\u6e90\u5316\u5229\u7528\u6307\u5f15\u4e86\u65b0\u65b9\u5411\u3002<\/p>\n

\u53c2\u8003\u6587\u732e<\/b><\/strong><\/p>\n

Bin Han+<\/sup>, Xinwen Ou+<\/sup>, Ziqi Deng, Yao Song, Chen Tian, Hong Deng, Yi-Jun Xu, Zhang Lin,*\u00a0Ni Metal-Organic Frameworks Monolayers for Photoreduction of Diluted CO2<\/sub>: Metal Nodes-Dependent Activity and Selectivity,\u00a0<\/b><\/strong>Angewandte Chemie 2018, 10.1002\/ange.201811545 (<\/i><\/em>VIP<\/i><\/b><\/em><\/strong>)<\/i><\/em><\/p>\n

\u8bba\u6587\u94fe\u63a5\uff1a<\/b><\/strong>https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.201811545?af=R<\/b><\/u><\/strong><\/a>\u00a0<\/b><\/strong><\/p>\n

\u4f5c\u8005\u7b80\u4ecb<\/b><\/strong><\/p>\n

\u6797\u748b\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\u3001\u957f\u6c5f\u5b66\u8005\u3001\u56fd\u5bb6\u6770\u9752\u3001\u56fd\u5bb6\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\u3001\u79d1\u6280\u90e8\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\u3001\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u56fd\u5bb6\u7ea7\u4eba\u9009\u3001\u5e7f\u4e1c\u7701\u73af\u5883\u7eb3\u7c73\u6750\u6599\u5de5\u7a0b\u6280\u672f\u7814\u7a76\u4e2d\u5fc3\u4e3b\u4efb\u3001\u73af\u5883\u4e0e\u80fd\u6e90\u5b66\u9662\u526f\u9662\u957f\u3002Elsevier \u671f\u520aSurfaces and Interface \u4e3b\u7f16\uff0cRSC\u671f\u520aEnviron. Sci.<\/i><\/em>: Nano\u526f\u4e3b\u7f16\u3002\u4e94\u5e74\u6765\u627f\u62c5\u56fd\u5bb6\u6770\u9752\u3001\u79d1\u6280\u90e8973\u3001\u57fa\u91d1\u59d4\u91cd\u70b9\u3001\u4e2d\u79d1\u9662\u5148\u5bfcA\u3001\u5e7f\u4e1c\u7701\u201c\u73e0\u6c5f\u4eba\u624d\u8ba1\u5212\u201d\u56e2\u961f\u9879\u76ee\u7b49\u91cd\u8981\u79d1\u7814\u4efb\u52a1\u5341\u591a\u9879\u3002\u5df2\u5728J. Am. Chem. Soc.\u3001Angew. Chem.\u3001ES&T\u7b49\u671f\u520a\u5171\u53d1\u8868SCI\u8bba\u6587170\u591a\u7bc7\uff0c\u5176\u4e2d4\u7bc7\u5165\u9009ESI\u9ad8\u88ab\u5f15\u8bba\u6587\u3002\u8fd1\u4e94\u5e74\u83b7\u6388\u6743\u53d1\u660e\u4e13\u522923\u4ef6\uff0c\u5176\u4e2dPCT\u4e13\u52297\u4ef6\uff1b\u83b7\u591a\u9879\u7701\u90e8\u7ea7\u79d1\u6280\u5956\u52b1\uff0c\u4e3a\u591a\u4e2a\u4e13\u4e1a\u59d4\u5458\u4f1a\u59d4\u5458\u3001\u671f\u520a\u7f16\u59d4\u3002<\/p>\n

\u8bfe\u9898\u7ec4\u7f51\u9875:\u00a0http:\/\/linzhang-group.com\/<\/u><\/a><\/p>\n

\u672c\u6587\u7531\u534e\u5357\u7406\u5de5\u5927\u5b66\u6797\u748b\u6559\u6388\u8bfe\u9898\u7ec4<\/strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7f16\u8f91\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenvip\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u7814\u7a76\u80cc\u666f\u3011 \u5feb\u901f\u53d1\u5c55\u7684\u73b0\u4ee3\u5de5\u4e1a\u5e26\u6765\u4e86\u5927\u91cf\u542b\u6709CO2\u7684\u5de5\u4e1a\u5e9f\u6c14\uff0c\u9020\u6210\u4e86\u5168\u7403\u6c14\u5019\u53d8\u5316\u7b49\u751f\u6001\u73af\u5883\u5371\u673a\u3002\u5229\u7528\u5149\u50ac\u5316\u6280\u672f\uff0c\u5728\u592a\u9633\u80fd\u7684\u9a71\u52a8\u4e0b\u76f4\u63a5\u5c06\u5de5\u4e1a\u5e9f\u6c14\u4e2d\u542b\u6709\u7684\u4f4e\u6d53\u5ea6C…<\/p>\n","protected":false},"author":10213,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-159094","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/159094"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=159094"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/159094\/revisions"}],"predecessor-version":[{"id":159106,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/159094\/revisions\/159106"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=159094"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=159094"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=159094"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}