{"id":158758,"date":"2018-11-16T06:16:33","date_gmt":"2018-11-15T22:16:33","guid":{"rendered":"\/\/m.iemloyee.com\/?p=158758"},"modified":"2018-11-15T18:16:51","modified_gmt":"2018-11-15T10:16:51","slug":"%e5%8c%97%e7%90%86%e5%b7%a5%e6%9b%b2%e8%89%af%e4%bd%93%e5%9b%a2%e9%98%9facs-nano%ef%bc%9a%e9%87%8d%e6%9e%84%e6%b0%a7%e5%8c%96%e7%9f%b3%e5%a2%a8%e7%83%af%e6%b6%b2%e6%99%b6%e5%ae%9e%e7%8e%b0%e7%9f%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=158758","title":{"rendered":"\u5317\u7406\u5de5\u66f2\u826f\u4f53\u56e2\u961fACS Nano\uff1a\u91cd\u6784\u6c27\u5316\u77f3\u58a8\u70ef\u6db2\u6676\u5b9e\u73b0\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\u7684\u5927\u89c4\u6a21\u5236\u5907"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\u4f5c\u4e3a\u8fd1\u5e74\u6765\u6700\u5177\u5438\u5f15\u529b\u7684\u78b3\u6750\u6599\u4e4b\u4e00\uff0c\u5728\u50a8\u80fd\u8f6c\u6362\u3001\u73af\u5883\u4fee\u590d\u3001\u9ad8\u6027\u80fd\u4f20\u611f\u5668\u3001\u8d85\u8f7b\u578b\u963b\u71c3\u5242\u3001\u7535\u78c1\u5e72\u6270\u5c4f\u853d\u3001\u5438\u58f0\u3001\u9ad8\u6548\u592a\u9633\u70ed\u8f6c\u6362\u7b49\u9886\u57df\u663e\u793a\u51fa\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5236\u5907\u8d85\u8f7b\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\u7684\u65b9\u6cd5\u548c\u5de5\u827a\uff0c\u5305\u62ec\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u3001\u6eb6\u6db2\u51b7\u51bb\u5e72\u71e5\u3001\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u3001\u6a21\u677f\u4ecb\u5bfc\u7684\u6eb6\u6db2\u7ec4\u88c5\u548c3D\u6253\u5370\u7b49\u3002\u5728\u4ee5\u5f80\u7684\u7814\u7a76\u4e2d\uff0c\u6eb6\u80f6-\u51dd\u80f6\u6cd5\u548c\u7a7a\u6c14\u5e72\u71e5\u6cd5\u88ab\u8ba4\u4e3a\u662f\u5b9e\u73b0\u8d85\u5f39\u6027\uff08>90%\u5e94\u53d8\uff09\u548c\u8d85\u4f4e\u5bc6\u5ea6\uff08\u5c0f\u4e8e10 mg cm-3<\/sup>\uff09\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\u7684\u4f4e\u6210\u672c\u3001\u5927\u89c4\u6a21\u5546\u4e1a\u5316\u751f\u4ea7\u7684\u91cd\u8981\u65b9\u6cd5\u3002\u5316\u5b66\u8fd8\u539f\u6216\u4ea4\u8054\u9a71\u52a8\u7684\u6c27\u5316\u77f3\u58a8\u70ef\uff08GO\uff09\u7684\u51dd\u80f6\u5316\u8fc7\u7a0b\u662f\u5176\u4e2d\u7684\u5173\u952e\u6b65\u9aa4\u3002\u6db2\u6676\uff08LC\uff09\u76f8\u901a\u5e38\u5728GO\u6c34\u5206\u6563\u4f53\u4e2d\u81ea\u53d1\u5f62\u6210\uff0c\u5f53\u4e0d\u5b58\u5728\u7279\u6b8a\u63a7\u5236\u65f6\uff0c\u5176\u901a\u5e38\u663e\u793a\u5e38\u89c4\u7684\u5411\u5217\u76f8\u6216\u5c42\u72b6\u76f8\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u5411\u5217\u76f8\u6216\u5c42\u72b6\u76f8GO\u00a0LCs\u5728\u5fae\u89c2\u4e0a\u6709\u5e8f\uff0c\u4f46\u5b8f\u89c2\u4e0a\u662f\u4e25\u91cd\u65e0\u5e8f\uff0c\u5c24\u5176\u662f\u5927\u5c3a\u5bf8\uff08e.g. \u7c73\u7ea7\u5c3a\u5bf8\uff09\uff0c\u8fd9\u5c06\u4e25\u91cd\u7834\u574f\u5927\u5c3a\u5bf8\u6837\u54c1\u77f3\u58a8\u70ef\u6c34\u51dd\u80f6\u7684\u5747\u5300\u6027\u548c\u5b8c\u6574\u6027\uff0c\u8fdb\u4e00\u6b65\u963b\u788d\u4e86\u5e72\u71e5\u540e\u5927\u5757\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\u7684\u6210\u529f\u5236\u5907\u3002\u56e0\u6b64\uff0c\u5efa\u7acb\u9002\u5408\u5de5\u4e1a\u5e94\u7528\u7684\u65b9\u6cd5\u5236\u5907\u5927\u5c3a\u5bf8\u3001\u7ed3\u6784\u5b8c\u6574\u7684\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\u4ecd\u7136\u662f\u4e00\u4e2a\u91cd\u5927\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u66f2\u826f\u4f53\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u56e2\u961f\u7684\u5e26\u9886\u4e0b\uff0c\u5317\u4eac\u7406\u5de5\u5927\u5b66<\/b><\/strong>\u4e0e\u6e05\u534e\u5927\u5b66<\/b><\/strong>\u5408\u4f5c\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u8868\u9762\u6d3b\u6027\u5242\u53d1\u6ce1\u6eb6\u80f6-\u51dd\u80f6\u6cd5\uff0c\u901a\u8fc7\u5fae\u6ce1\u6a21\u677f\u6709\u6548\u5730\u7834\u574f\u548c\u91cd\u5efa\u5206\u6563\u4f53\u7cfb\u4e2d\u7684GO LCs\uff0c\u4ece\u800c\u83b7\u5f97\u5927\u5c3a\u5bf8\u3001\u7ed3\u6784\u5b8c\u6574\u7684\u77f3\u58a8\u70ef\u6c34\u51dd\u80f6\u5757(GHB)\u3002\u7ecf\u8fc7\u7b80\u5355\u51b7\u51bb\u548c\u98ce\u5e72\u540e\uff0c\u5f97\u5230\u7684\u77f3\u58a8\u70ef\u6c14\u51dd\u80f6\u5757\uff08GAB\uff09\u8868\u73b0\u51fa\u7ed3\u6784\u5b8c\u6574\u7684\u5c3a\u5bf8\u7ea6\u4e3a1 m2<\/sup>\uff0c\u8d85\u5f39\u6027\u9ad8\u8fbe99\uff05\u538b\u7f29\u5e94\u53d8\uff0c\u8d85\u4f4e\u5bc6\u5ea62.8 mg cm-3<\/sup>\uff0c\u5177\u6709\u5feb\u901f\u7684\u592a\u9633\u80fd\u70ed\u8f6c\u6362\u80fd\u529b\u3002\u6b64\u5916\uff0c\u7531\u516d\u6c2f\u73af\u4e09\u78f7\u8148\uff08HCTP\uff09\u6539\u6027\u7684GAB\uff0c\u5728\u7a7a\u6c14\u4e2d\u663e\u793a\u51fa735\u2103\u7684\u9ad8\u5206\u89e3\u6e29\u5ea6\uff08Tmax<\/sub>\uff09\uff0c\u6bd4\u6765\u81ea\u76f8\u540c\u7a7a\u6c14\u4e2d\u7684\u9ad8\u6e29\u91d1\u5c5e\uff08e.g. \u954d\u3001\u94dc\uff09\u6ce1\u6cab\u7684\u6e29\u5ea6\u964d\u4f4e\u901f\u7387\u5feb\u5f97\u591a\u3002\u8fd9\u4e9b\u4f18\u5f02\u7684\u6027\u80fd\u4f7fGABs\u5728\u8bb8\u591a\u5b9e\u9645\u5e94\u7528\u4e2d\u5177\u6709\u6f5c\u529b\uff0c\u4f8b\u5982\u53ef\u4ee5\u4f5c\u4e3a\u9ad8\u538b\u7f29\u529b\u5438\u6536\u5668\u3001\u9ad8\u5438\u6cb9\u6216\u5371\u9669\u6eb6\u5242\u7684\u5438\u6536\u6750\u6599\u3001\u5feb\u901f\u52a0\u70ed\u5668\u6216\u63a7\u5236\u906e\u853d\u7269\u7684\u4f18\u8d28\u592a\u9633\u80fd\u70ed\u7ba1\u7406\u6750\u6599\u4ee5\u53ca\u9ad8\u6548\u7684\u8010\u706b\u4fdd\u6e29\u6750\u6599\u3002\u6574\u4e2a\u5236\u5907\u8fc7\u7a0b\u6613\u4e8e\u6269\u5c55\uff0c\u5177\u6709\u6210\u672c\u6548\u76ca\uff0c\u9002\u7528\u4e8e\u5927\u89c4\u6a21\u751f\u4ea7\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cReconstruction of Inherent Graphene Oxide Liquid Crystals for Large-Scale Fabrication of Structure-Intact Graphene Aerogel Bulk toward Practical Applications<\/b><\/strong>\u201d\u53d1\u8868\u5728\u4e86ACS Nano<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u00a0<\/b><\/strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe1 <\/b><\/strong>\u5236\u9020\u5927\u5c3a\u5bf8\u548c\u7ed3\u6784\u5b8c\u6574\u7684GHB<\/b><\/strong>s<\/b><\/strong>\u7684\u8868\u9762\u6d3b\u6027\u5242\u53d1\u6ce1\u5de5\u827a\u7684<\/b><\/strong>\u793a\u610f\u56fe<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff094\u00a0mg mL-1<\/sup>\u00a0GO\u6c34\u5206\u6563\u4f53\u7684POM\u56fe\u50cf\u3002<\/p>\n

\uff08b\uff09GO\u6c34\u5206\u6563\u4f53\u5728\u76f4\u5f84\u4e3a40cm\u7684\u5927\u76d8\u4e2d\u7684\u7167\u7247\u3002<\/p>\n

\uff08c\uff09\u6297\u574f\u8840\u9178\u9884\u8fd8\u539f\u540e\u4eceGO\u6c34\u5206\u6563\u4f53\u5f97\u5230\u7684PRGH\u7684\u7167\u7247\u3002<\/p>\n

\uff08d\uff094\u00a0mg mL-1<\/sup>\u00a0<\/sup>FGO\u6c34\u5206\u6563\u4f53\u7684 POM\u56fe\u50cf\u3002<\/p>\n

\uff08e\uff09\u5c06\u53d1\u6ce1\u70f7\u57fa\u591a\u7cd6\u82f7\u540e\u7531GO\u6c34\u5206\u6563\u4f53\u5236\u5907\u7684FGO\u6c34\u5206\u6563\u4f53\u88c5\u5165\u76f4\u5f84\u4e3a40cm\u7684\u5927\u76d8\u4e2d\u7684\u7167\u7247\u3002<\/p>\n

\uff08f\uff09\u6297\u574f\u8840\u9178\u8fd8\u539f\u540e\u7531FGO\u6c34\u5206\u6563\u4f53\u5f97\u5230\u7684GHB\u7684\u7167\u7247\u3002<\/p>\n

\uff08g,h\uff09\u8be5\u793a\u610f\u56fe\u8bf4\u660e\u4e86\u901a\u8fc7\u5316\u5b66\u8fd8\u539f\uff08\u6db2\u4f53\u8868\u9762\u76f4\u5f84> 30cm\uff09\u9a71\u52a8\u7684\u5927\u5c3a\u5bf8GO\u6c34\u5206\u6563\u4f53\uff08g\uff09\u548cFGO\u6c34\u5206\u6563\u4f53\uff08h\uff09\u7684\u51dd\u80f6\u5316\u8fc7\u7a0b\u3002<\/p>\n

\u56fe2 <\/b><\/strong>GAB<\/b><\/strong>s\u7684\u5fae\u89c2\u5f62\u8c8c\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09\u5728\u73af\u5883\u5927\u6c14\u4e2d\u8fdb\u884c\u7b80\u5355\u51b7\u51bb\uff0c\u98ce\u5e72\u548c\u9000\u706b\u5904\u7406\u540e\uff0cGHBs\u5236\u5907\u7684GABs\u7167\u7247\u3002<\/p>\n

\uff08b\uff09\u5927\u5c3a\u5bf8\u548c\u7ed3\u6784\u5b8c\u6574GABs\u7167\u7247\uff0c\u9762\u79ef\u7ea6\u4e3a1\u00a0m2<\/sup>\u3002<\/p>\n

\uff08c\uff09GO\uff0cU-GAB\u548cGAB\u7684XRD\u56fe\u8c31\u3002<\/p>\n

\uff08d\uff09FGO\u6eb6\u6db2\u7684\u9ad8\u500d\u7387POM\u56fe\u50cf\u3002<\/p>\n

\uff08e\uff09\u4e0d\u540c\u53d1\u6ce1\u81a8\u80c0\u65f6\u95f4\u7684FGO\u5206\u6563\u4f53\u7684POM\u56fe\u50cf\u3002<\/p>\n

\uff08f\uff09\u76f8\u540c\u53d1\u6ce1\u81a8\u80c0\u7387\u76848\u00a0mg mL-1<\/sup>\u548c16\u00a0mg mL-1<\/sup>\u00a0GO\u5206\u6563\u4f53\u5236\u5907\u7684FGO\u5206\u6563\u4f53\u7684POM\u56fe\u50cf\u3002<\/p>\n

\uff08g\uff09\u75318\u00a0mg mL-1<\/sup>\u548c16\u00a0mg mL-1<\/sup>\u00a0GO\u5206\u6563\u4f53\u5236\u5907\u7684GABs\u5fae\u7ed3\u6784\u7684SEM\u56fe\u3002<\/p>\n

\uff08h\uff09\u4e0d\u540c\u653e\u5927\u500d\u6570\u7684GABs\uff08\u5bc6\u5ea6\uff1a3.2\u00a0mg cm-3<\/sup>\uff09\u5fae\u7ed3\u6784\u7684SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe3<\/b><\/strong>\u00a0<\/b><\/strong>GAB<\/b><\/strong>s<\/b><\/strong>\u7684\u673a\u68b0\u6027\u80fd<\/b><\/strong>\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

\uff08a\uff09\u76f4\u5f84\u4e3a34\u00a0cm\u7684GAB\u6837\u54c1\uff084.6\u00a0mg cm-3<\/sup>\uff09\u572840\uff05\u7684\u5e94\u53d8\u4e0b\u53ef\u652f\u6491\u4f53\u91cd51\u00a0kg\u7684\u4eba\uff0c\u5e76\u80fd\u8fc5\u901f\u6062\u590d\u5230\u5176\u539f\u59cb\u9ad8\u5ea6\u3002<\/p>\n

\uff08b\uff09U-GAB\u572850\uff05\u5e94\u53d8\u4e0b\u4e09\u4e2a\u5faa\u73af\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u3002<\/p>\n

\uff08c\uff09GAB\uff082.8\u00a0mg cm-3<\/sup>\uff09\u572899\uff05\u5e94\u53d8\u4e0b\u4e09\u4e2a\u5faa\u73af\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u3002\u63d2\u56fe\uff1aGAB\u5728\u4f4e\u5e94\u53d8\u4e0b\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u653e\u5927\u56fe\u3002<\/p>\n

\uff08d,e\uff09GAB\uff084.3\u00a0mg cm-3<\/sup>\uff09\u572870\uff05\u5e94\u53d8\u4e0b1000\u4e2a\u5faa\u73af\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\uff08d\uff09\u548c\u5e94\u529b-\u5e94\u53d8\u6062\u590d\u7387\uff08e\uff09\u3002<\/p>\n

\uff08f\uff09GAB\u7684\u538b\u7f29\u529b\u66f2\u7ebf\uff084.3 mg cm-3<\/sup>\uff09\u4e0e\u6837\u54c1\u76f4\u5f84\u7684\u51fd\u6570\u5173\u7cfb\u3002<\/p>\n

\uff08g\uff09\u5f53\u53cd\u590d\u538b\u7f29\u81f360\uff05\u5e94\u53d820\u4e2a\u5faa\u73af\u65f6\uff0cGAB\u7684\u7535\u963b\u53d8\u5316\u3002<\/p>\n

\uff08h\uff09\u5236\u5907\u597d\u7684GAB\u5feb\u901f\u53bb\u9664\u6c34\u4e2d\u7684\u73af\u5df1\u70f7(\u6cb9\u7ea2O\u67d3\u8272)\u7684\u56fe\u50cf\u3002<\/p>\n

\uff08i\uff09GAB\u5728\u589e\u91cd\u65b9\u9762\u7684\u5438\u9644\u80fd\u529b\u3002\u63d2\u56fe\u663e\u793a\u4e86\u5438\u6536\u53ef\u71c3\u6cb9\u540eGAB\u7684\u71c3\u70e7\u5faa\u73af\u8fc7\u7a0b\u3002<\/p>\n

\u56fe<\/b><\/strong>4 <\/b><\/strong>GAB<\/b><\/strong>s<\/b><\/strong>\u592a\u9633\u70ed\u7ba1\u7406\u6027\u80fd<\/b><\/strong>\u8868\u5f81<\/b><\/strong>\"\"<\/p>\n

\uff08a,b\uff09GAB\uff08\u5176\u5bc6\u5ea6\u4e3a\u7ea66 mg cm-3<\/sup>\uff09\uff08a\uff09\u548cCu\u6ce1\u6cab\uff08b\uff09\u57281\u592a\u9633\u65e5\u7167\u4e0b\u6e29\u5ea6\u53d8\u5316\u7684\u7ea2\u5916\u56fe\u50cf\u300260s 1\u592a\u9633\u7167\u5c04\u540e\uff0cGAB\u7684\u8868\u9762\u6e29\u5ea6\u9ad8\u8fbe89\u00b0C\uff0cCu\u6ce1\u6cab\u4ec5\u4e3a40\u00b0C\u3002<\/p>\n

\uff08c\uff09\u57281\u592a\u9633\u65e5\u7167\u5c04\u4e0bGAB\u8868\u9762\u4e0a\u65f6Cu\u6ce1\u6cab\u7684\u6e29\u5ea6\u53d8\u5316\u7684\u7ea2\u5916\u56fe\u50cf\u3002\u7531\u4e8eGAB\u52a0\u70ed\u6548\u5e94\uff0cCu\u6ce1\u6cab\u7684\u6e29\u5ea6\u4ece40\u2103\u5347\u81f350\u2103\u3002<\/p>\n

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\u56fe<\/b><\/strong>5<\/b><\/strong>\u00a0<\/b><\/strong>GAB<\/b><\/strong>s<\/b><\/strong>\u9ad8\u6548\u963b\u71c3\u6027<\/b><\/strong>\u6d4b\u8bd5<\/b><\/strong>\"\"<\/p>\n

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\u6587\u732e\u94fe\u63a5<\/b><\/strong>\uff1a<\/b><\/strong>Reconstruction of Inherent Graphene Oxide Liquid Crystals for Large-Scale Fabrication of Structure-Intact Graphene Aerogel Bulk toward Practical Applications<\/u><\/a>\uff08ACS Nano\uff0c2018\uff0cDOI\uff1a10.1021\/acsnano.8b06380\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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