{"id":15855,"date":"2016-05-29T14:00:43","date_gmt":"2016-05-29T06:00:43","guid":{"rendered":"\/\/m.iemloyee.com\/?p=15855"},"modified":"2016-05-29T00:08:34","modified_gmt":"2016-05-28T16:08:34","slug":"nature-chemistry%e9%ab%98%e6%95%88%e5%82%ac%e5%8c%96%e5%89%82%e7%a0%b4%e8%a7%a3%e7%8e%af%e7%8a%b6%e9%ab%98%e5%88%86%e5%ad%90%e5%90%88%e6%88%90%e9%9a%be%e9%a2%98-%e7%82%94%e7%83%83%e5%90%88%e6%88%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=15855","title":{"rendered":"Nature Chemistry:\u9ad8\u6548\u50ac\u5316\u5242\u7834\u89e3\u73af\u72b6\u9ad8\u5206\u5b50\u5408\u6210\u96be\u9898-\u7094\u70c3\u5408\u6210\u73af\u72b6\u9ad8\u5206\u5b50"},"content":{"rendered":"<p><strong>\u6458\u8981:<\/strong><\/p>\n<p>\u4e0e\u7ebf\u6027\u9ad8\u5206\u5b50\u76f8\u6bd4\uff0c\u4e0e\u4e4b\u5bf9\u5e94\u7684\u73af\u72b6\u805a\u5408\u7269\u90fd\u6709\u7740\u975e\u5e38\u7279\u6b8a\u7684\u7269\u7406\u6027\u8d28\u3002\u4f46\u7531\u4e8e\u73af\u72b6\u805a\u5408\u7269\u5408\u6210\u53d7\u9650\uff0c\u5bf9\u73af\u72b6\u9ad8\u5206\u5b50\u7684\u7814\u7a76\u53d7\u5230\u963b\u788d\u3002\u5171\u8f6d\u7684\u7ebf\u6027\u805a\u4e59\u7094\u662f\u4e00\u79cd\u975e\u5e38\u91cd\u8981\u7684\u529f\u80fd\u6027\u6750\u6599\uff0c\u8bf8\u5982\u5bfc\u7535\u6750\u6599\u3001\u987a\u78c1\u6750\u6599\u3001\u975e\u7ebf\u6027\u5149\u5b66\u6750\u6599\u3001\u900f\u6c14\u6750\u6599\u3001\u6db2\u6676\u6750\u6599\u548c\u87ba\u65cb\u94fe\u6750\u6599\u7b49\u3002\u7136\u800c\uff0c\u4ed6\u4eec\u5bf9\u5e94\u7684\u73af\u72b6\u7c7b\u4f3c\u7269\u5374\u8fd8\u662f\u672a\u77e5\u7684\uff0c\u56e0\u6b64\u6ca1\u6709\u529e\u6cd5\u7814\u7a76\u73af\u72b6\u62d3\u6251\u7ed3\u6784\u5bf9\u5176\u6027\u80fd\u7684\u5f71\u54cd\u3002\u8fd1\u65e5\uff0c\u6211\u4eec\u89e3\u51b3\u4e86\u8fd9\u4e2a\u96be\u9898\uff1a\u6211\u80fd\u4f7f\u7528\u4e86\u4e00\u79cd\u8d1f\u8f7d\u6709\u56db\u9634\u79bb\u5b50\u87af\u5408\u914d\u4f53\u7684\u94a8\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5b83\u80fd\u591f\u5feb\u901f\u5730\u4f7f\u4e59\u7094\u805a\u5408\u6210\u5171\u8f6d\u7684\u5927\u73af\u9ad8\u5206\u5b50\uff0c\u4e14\u4ea7\u7387\u5f88\u9ad8\u3002\u50ac\u5316\u5242\u80fd\u591f\u5c06\u805a\u5408\u7269\u7684\u672b\u7aef\u4e0e\u4e2d\u5fc3\u91d1\u5c5e\u76f8\u94fe\u63a5\uff0c\u4ece\u800c\u514b\u670d\u73af\u5316\u65f6\u56fa\u6709\u7684\u71b5\u635f\u5931\u3002\u8fd0\u7528\u4e86\u51dd\u80f6\u6e17\u900f\u8272\u8c31\u3001\u52a8\u6001\u548c\u9759\u6001\u5149\u6563\u5c04\u3001\u7c98\u5ea6\u6cd5\u548c\u5316\u5b66\u6d4b\u8bd5\u7b49\u68c0\u6d4b\u65b9\u6cd5\u7684\u5b9e\u9a8c\u7ed3\u679c\u90fd\u548c\u7406\u8bba\u9884\u6d4b\u4fdd\u6301\u4e00\u81f4\uff0c\u5e76\u4e14\u63d0\u4f9b\u4e86\u5bf9\u73af\u72b6\u62d3\u8865\u7ed3\u6784\u6e05\u6670\u7684\u8868\u5f81\u3002\u73b0\u5728\uff0c\u9009\u62e9\u5408\u9002\u7684\u7094\u70c3\u5355\u4f53\uff0c\u5408\u6210\u5404\u79cd\u5404\u6837\u7684\u65b0\u578b\u73af\u72b6\u9ad8\u5206\u5b50\u4fbf\u6210\u4e3a\u53ef\u80fd\u3002<\/p>\n<p><strong>\u56fe1 \u6539\u826f\u50ac\u5316\u5242\u7684\u6539\u826f\u548c\u5236\u5907<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-15857 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f1.jpg\" alt=\"nchem.2516-f1\" width=\"700\" height=\"209\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f1.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f1-300x90.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><br \/>\n\u7528\u82ef\u4e59\u7094\u5904\u7406\u7edc\u5408\u7269-1\u5f97\u5230\u50ac\u5316\u5242-2\u548c\u50ac\u5316\u5242-3\uff08\u6bd4\u4f8b\u4e3a2:1\uff09\uff0c\u5e76\u8fdb\u884c\u7eaf\u5316\u548c\u5206\u79bb\u3002\u50ac\u5316\u5242-3\u7684\u6d3b\u6027\u5f88\u4f4e\u901a\u5e38\u4f5c\u4e3a\u5e9f\u6599\u5904\u7406\uff0c\u8fd9\u6837\u4f1a\u964d\u4f4e\u50ac\u5316\u5242\u7684\u6574\u4f53\u4ea7\u7387\u3002\u6539\u826f\u7684\u5408\u6210\u65b9\u6cd5\u662f\uff1a\u7528\u53d4\u4e01\u57fa\u4e59\u7094\u5904\u7406\u7edc\u5408\u7269-1\uff0c\u5f97\u5230\u552f\u4e00\u7684\u4ea7\u7269\u50ac\u5316\u5242-4\uff08100%\u7684\u4ea7\u7387\uff09\uff0c\u5e76\u4e14\u4ec5\u4ec5\u901a\u8fc7\u84b8\u53d1\u4fbf\u53ef\u9664\u53bb\u6eb6\u5242\u3002<\/p>\n<p><strong>\u56fe2 \u00a0\u7528\u692d\u5706\u4f53\u7ed8\u5236\u7edc\u5408\u7269-4\u53ef\u80fd\u7684\u5206\u5b50\u7ed3\u6784\uff0850%\u7684\u6982\u7387\uff09[\u4e3a\u4e86\u56fe\u793a\u6e05\u6670\uff0c\u6ca1\u6709\u753b\u51fa\u65e0\u5e8f\u7684\u56db\u6c22\u544b\u5583(THF)\u539f\u5b50\u4ee5\u53ca\u6676\u683c\u6eb6\u5242(\u620a\u70f7)\u5206\u5b50]<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-15858 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f2.jpg\" alt=\"nchem.2516-f2\" width=\"700\" height=\"682\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f2.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f2-300x292.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><br \/>\n\u5728\u56fa\u4f53\u72b6\u6001\u65f6\uff0c\u7edc\u5408\u7269-4\u662f\u4f2a\u4e2d\u5fc3\u5bf9\u79f0\u7684\uff0c\u5728\u975e\u6807\u51c6\u7684\u591a\u9762\u4f53\u51e0\u4f55\u7ed3\u6784\u4e2d\u5305\u542b\u6709\u4e94\u4ef7\u7684\u94a8\uff08W\uff09\u79bb\u5b50\u3002\u7edc\u5408\u7269-4\u5305\u542b\u56db\u9634\u79bb\u5b50\u87af\u5408\u914d\u4f53\uff0c\u8fd9\u79cd\u914d\u4f53\u7531\u4e24\u4efd\u915a\u76d0\u548c\u4e00\u4efd\u4e9a\u70f7\u57fa\u7ed3\u5408\u800c\u6210\u3002\u915a\u76d0\u4e2d\u7684\u6c27\u539f\u5b50\u8de8\u8d8a\u4e86\u53cd\u5f0f\u4f4d\u7f6e\u5f62\u6210O1-W-O2\u952e\uff08\u6c27-\u94a8-\u6c27\u952e\uff0c\u952e\u89d2\u4e3a152.37(6)\u00b0\uff09.\u00a0\u914d\u4f4d\u7684THF\u53d7\u5230\u4e86\u94a8-\u4e9a\u70f7\u57fa\u5f3a\u70c8\u7684\u53cd\u5f0f\u5f71\u54cd\uff0c\u4e00\u4e2a\u8f83\u957f\u7684W1-O3\u952e\uff08\u952e\u957f2.328(1)\u00c5\uff09\u4f50\u8bc1\u4e86\u8fd9\u4e00\u70b9\u3002\u4f5c\u4e3a\u5bf9\u6bd4\uff0c1\u4e2dTHF\u7684\u914d\u4f53\u540c\u6837\u4e5f\u6709\u957fW-O\u952e\uff082.472(2) \u00c5\u548c2.177(2) \u00c5\uff09\u3002 C32-C27\u8ddd\u79bb\uff081.312(4) \u00c5\uff09\u4e0e\u5178\u578b\u7684\u78b3\u78b3\u4e09\u952e\u952e\u957f\uff081.21 \u00c5\uff09\u76f8\u6bd4\u6709\u660e\u663e\u7684\u62c9\u957f\uff0c\u7531\u4e8e\u91d1\u5c5e\u73af\u4e19\u70ef\u7684\u5171\u632f\u4f5c\u7528\uff0c\u4fbf\u663e\u5f97\u66f4\u63a5\u8fd1\u4e8e\u53cc\u952e\u3002<\/p>\n<p><strong>\u56fe3 \u00a0\u4f7f\u7528\u50ac\u5316\u5242-4\u50ac\u5316\u7684\u5f00\u73af\u805a\u5408\uff0c\u5408\u6210\u5927\u73af\u805a\u70ef\u70c3.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-15859 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f3.jpg\" alt=\"nchem.2516-f3\" width=\"700\" height=\"880\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f3.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f3-239x300.jpg 239w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><br \/>\nTHF\u4ece\u4e2d\u5fc3\u91d1\u5c5e\u94a8\u539f\u5b50\u4e0a\u89e3\u79bb\uff0c\u4f7f\u50ac\u5316\u5242\u6d3b\u5316\uff0c\u7094\u70c3\u4f5c\u4e3a\u4e2d\u95f4\u7269\u8d77\u914d\u4f4d\u4f5c\u7528.<br \/>\na, \u914d\u4f4d\u7684\u7094\u70c3\u63d2\u5165\u5230\u03b72-\u914d\u4f4d\u7094\u70c3\u4e2d\uff0c\u5f62\u6210\u91d1\u5c5e\u73af\u4e19\u70ef.<br \/>\nb, \u53cd\u5e94\u901a\u8fc7\u5f00\u73af\u5e76\u63d2\u5165\u65b0\u7684\u7094\u70c3\u5355\u4f53\u5355\u5143\u800c\u5b9e\u73b0\u589e\u94fe.\u9ad8\u5206\u5b50\u94fe\u7684\u8fd8\u539f\u6d88\u9664\u53cd\u5e94\u9664\u53bb\u4e2d\u5fc3\u91d1\u5c5e\u539f\u5b50\uff0c\u5f97\u5230\u73af\u72b6\u805a\u70ef\u70c3. \u6e38\u79bb\u7094\u70c3\u7684\u914d\u4f4d\u4f5c\u7528\u4f7f\u5f97\u5f00\u73af\u673a\u7406\u80fd\u591f\u5faa\u73af\u91cd\u590d\u5f15\u53d1\u53cd\u5e94.<\/p>\n<p><strong>\u56fe4 \u7ebf\u6027\u805a\u82ef\u4e59\u7094\uff08\u84dd\u8272\uff09\u548c\u73af\u72b6\u805a\u82ef\u4e59\u7094\uff08\u6a59\u8272\uff09\u5747\u65b9\u6839\u56de\u8f6c\u534a\u5f84\u7684\u6bd4\u8f83.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-15866 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f4.jpg\" alt=\"nchem.2516-f4\" width=\"700\" height=\"367\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f4.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f4-300x157.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><br \/>\n\u5728\u8bd5\u6837\u5206\u5b50\u6eb6\u89e3\u5728\u6d53\u5ea6\u4e3a0.05M\u7684LiCl(\u6c2f\u5316\u9502)\u4e8c\u7532\u57fa\u4e59\u9170\u80fa\u6eb6\u6db2\u4e2d.\u4e0d\u540c\u5206\u5b50\u8d28\u91cf\u7684\u9ad8\u5206\u5b50\u5728\u6240\u6709\u70b9\u7684\u56de\u8f6c\u534a\u5f84\u4e4b\u6bd4\u4e0e\u9884\u671f\u503c\uff08&lt;Rg2&gt;cyclic\/&lt;Rg2&gt;linear = 0.5)\uff0c\u5373\u73af\u72b6\u4e0e\u7ebf\u6027\u805a\u82ef\u4e59\u7094\u7684\u5747\u65b9\u56de\u8f6c\u534a\u5f84\u4e4b\u6bd4\u4e3a0.5\uff09\u76f8\u7b26\u5408\uff0c\u8fd9\u8bf4\u660e\u8be5\u79cd\u9ad8\u5206\u5b50\u5177\u6709\u73af\u72b6\u62d3\u8865\u7ed3\u6784. \u4e0a\u8ff0\u6bd4\u4f8b\u5728\u5927\u7684\u5206\u5b50\u91cf\u53d8\u5316\u8303\u56f4\u5185\u4fdd\u6301\u6052\u5b9a\uff0c\u8fd9\u786e\u4fdd\u4e86\u5e76\u975e\u4ec5\u5728\u67d0\u4e9b\u7279\u5b9a\u5206\u5b50\u91cf\u65f6\u73af\u72b6\u8bd5\u6837\u548c\u7ebf\u6027\u8bd5\u6837\u624d\u6709\u4e0a\u8ff0\u6bd4\u4f8b.<\/p>\n<p><strong>\u56fe5 Mark-Houwink \u65b9\u7a0b\u66f2\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-15867 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f5.jpg\" alt=\"nchem.2516-f5\" width=\"700\" height=\"404\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f5.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f5-300x173.jpg 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><br \/>\n\u6bd4\u8f83\u4e86\u4e0d\u540c\u5206\u5b50\u91cf\u7684\u73af\u72b6\u805a\u82ef\u4e59\u7094\uff08\u84dd\u8272\uff09\u548c\u7ebf\u6027\u805a\u82ef\u4e59\u7094\uff08\u6a59\u8272\uff09\u7684\u7279\u6027\u7c98\u5ea6([\u03b7])\u7684\u53d8\u5316\uff0835\u2103,THF\u4e3a\u6eb6\u5242\uff09. \u5728\u5927\u7684\u5206\u5b50\u91cf\u53d8\u5316\u8303\u56f4\u4e2d\uff0c\u4e24\u8005\u4e4b\u95f4\u7684\u7c98\u5ea6\u6bd4\u5f88\u597d\u5730\u7b26\u5408\u73af\u72b6\u548c\u7ebf\u6027\u9ad8\u5206\u5b50\u95f4\u7684\u5173\u7cfb.<\/p>\n<p><strong>\u56fe6 \u51dd\u80f6\u6e17\u900f\u8272\u8c31\uff08GPC\uff09<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-15868 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f6.jpg\" alt=\"nchem.2516-f6\" width=\"700\" height=\"865\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f6.jpg 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f6-243x300.jpg 243w\" sizes=\"(max-width: 700px) 100vw, 700px\" \/><br \/>\n\u90e8\u5206\u52a0\u6c22\u7684\u73af\u72b6\u805a\u82ef\u4e59\u7094\u548c\u7ebf\u6027\u805a\u82ef\u4e59\u7094\u8bd5\u6837\uff0c\u672a\u7ecf\u81ed\u6c27\u5206\u89e3\uff08\u84dd\u8272\uff09\u548c\u7ecf\u81ed\u6c27\u5206\u89e330\u79d2\uff08\u6a59\u8272\uff09\u548c\u7ecf\u81ed\u6c27\u5206\u89e316\u5206\u949f\uff08\u7070\u8272\uff09\u7684GPC\u66f2\u7ebf.<br \/>\na, \u73af\u72b6\u805a\u82ef\u4e59\u7094\u8bd5\u6837\uff0c\u7ecf\u81ed\u6c27\u5206\u89e3\u540e\uff0c\u6709\u66f4\u4f4e\u7684\u6d41\u51fa\u65f6\u95f4\u548c\u8f83\u5927\u7684\u6d41\u4f53\u529b\u5b66\u4f53\u79ef\u6bd4\u7387\uff0c\u8fd9\u4e00\u7ed3\u679c\u4e0e\u73af\u5f62\u62d3\u6251\u7ed3\u6784\u76f8\u4e00\u81f4.<br \/>\nb, \u76f8\u53cd\u7684\u662f\uff0c\u7ebf\u6027\u805a\u82ef\u4e59\u7094\u8bd5\u6837\uff0c\u7ecf\u81ed\u6c27\u5206\u89e3\u540e\uff0c\u6709\u66f4\u9ad8\u7684\u6d41\u51fa\u65f6\u95f4\u548c\u8f83\u4f4e\u7684\u6d41\u4f53\u529b\u5b66\u4f53\u79ef\uff0c\u8fd9\u8bf4\u660e\u7ebf\u6027\u9ad8\u5206\u5b50\u88ab\u5207\u65ad\u6210\u4e86\u8f83\u5c0f\u7684\u7247\u6bb5\uff08\u5373\u53d1\u751f\u4e86\u65ad\u94fe\u548c\u5206\u89e3\uff09<\/p>\n<p><strong>\u56fe7 \u00a0\u5168\u90e8\u52a0\u6c22\u7684\u73af\u72b6\u805a\u82ef\u4e59\u70ef\uff08\u73af\u72b6PS\uff09\u548c\u5df2\u77e5\u7684\u7ebf\u6027PS\u6807\u51c6\u8bd5\u6837\u7684GPC\u66f2\u7ebf\u5bf9\u6bd4.<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-15870 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f7.jpg\" alt=\"nchem.2516-f7\" width=\"700\" height=\"869\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2016\/05\/nchem.2516-f7.jpg 700w, 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\/>\n\u672c\u6587\u62a5\u9053\u4e86\u4eba\u7c7b\u9996\u6b21\u5408\u6210\u7684\u73af\u72b6\u805a\u82ef\u4e59\u7094\uff0c\u5c1a\u5c5e\u4e00\u79cd\u7a7a\u524d\u7684\u73af\u72b6\u9ad8\u5206\u5b50\u3002\u4f5c\u8005\u4f7f\u7528\u7684\u5355\u4f53\u82ef\u4e59\u7094\u5e76\u4e0d\u6602\u8d35\uff0c\u5e76\u4e14\u6240\u91c7\u7528\u7684\u5f00\u73af\u805a\u5408\u53cd\u5e94\u6240\u5f97\u4ea7\u7269\u7684\u4ea7\u7387\u5f88\u9ad8\u3002\u8fd9\u4e0e\u4f5c\u8005\u6539\u826f\u800c\u6765\u7684\u65b0\u578b\u50ac\u5316\u5242\u5bc6\u4e0d\u53ef\u5206\u3002\u4e3a\u4e86\u68c0\u6d4b\u548c\u6bd4\u8f83\u73af\u72b6\u548c\u7ebf\u6027\u805a\u5408\u7269\u7684\u5dee\u522b\uff0c\u4f5c\u8005\u8fdb\u884c\u4e86\u4e86\u5927\u91cf\u7684\u5b9e\u9a8c\uff0c\u5206\u522b\u4f7f\u7528\u4e86GPC\u3001\u52a8\u6001\u548c\u9759\u6001\u5149\u6563\u5c04\u3001\u7c98\u5ea6\u6cd5\u7b49\u8fdb\u884c\u68c0\u6d4b\u3002\u4f5c\u8005\u7684\u5229\u7528\u7094\u70c3\u5408\u6210\u73af\u72b6\u805a\u5408\u7269\u7684\u65b9\u6cd5\u4f7f\u5f97\u539f\u672c\u56f0\u6270\u4eba\u4eec\u8bb8\u4e45\u7684\u73af\u72b6\u9ad8\u5206\u5b50\u7684\u5408\u6210\u95ee\u9898\u7684\u5230\u4e86\u4e00\u5b9a\u7a0b\u5ea6\u7684\u89e3\u51b3\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\u5730\u5740\uff1a<a href=\"http:\/\/www.nature.com\/nchem\/journal\/vaop\/ncurrent\/full\/nchem.2516.html\"> Cyclic polymers from alkynes<\/a><\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7cef\u7c73\u63d0\u4f9b\u7d20\u6750\uff0c\u674e\u5353\u6574\u7406\u7f16\u8bd1\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6458\u8981: 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