{"id":158389,"date":"2018-11-13T06:30:02","date_gmt":"2018-11-12T22:30:02","guid":{"rendered":"\/\/m.iemloyee.com\/?p=158389"},"modified":"2018-11-12T19:36:32","modified_gmt":"2018-11-12T11:36:32","slug":"%e6%b5%99%e6%b1%9f%e5%a4%a7%e5%ad%a6-%e5%bc%a0%e5%85%b4%e5%ae%8f-macromolecules-%e5%8f%8c%e7%bb%84%e5%88%86%e6%9c%89%e6%9c%ba%e5%82%ac%e5%8c%96%e5%89%82%e7%94%a8%e4%ba%8e%e9%ab%98%e6%b4%bb%e6%80%a7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=158389","title":{"rendered":"\u6d59\u6c5f\u5927\u5b66 \u5f20\u5174\u5b8f Macromolecules: \u53cc\u7ec4\u5206\u6709\u673a\u50ac\u5316\u5242\u7528\u4e8e\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u5408\u6210\u5177\u6709\u9ad8\u5206\u5b50\u91cf\u7684\u7ebf\u6027\u805a\uff08\u03b3-\u4e01\u5185\u916f\uff09"},"content":{"rendered":"

\u3010\u7814\u7a76\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u00a0 \u00a0 \u00a0 \u00a0 \u7531\u4e8e\u4e0d\u53ef\u751f\u7269\u964d\u89e3\u6216\u4e0d\u53ef\u56de\u6536\u7684\u5546\u4e1a\u805a\u5408\u7269\u800c\u5bfc\u81f4\u7684\u767d\u8272\u6c61\u67d3\uff0c\u5bf9\u4eba\u7c7b\u548c\u81ea\u7136\u754c\u5176\u4ed6\u7269\u79cd\u7684\u751f\u5b58\u90fd\u9020\u6210\u4e86\u6781\u5927\u7684\u5371\u5bb3\uff0c\u6240\u4ee5\u5f00\u53d1\u4e00\u79cd\u5177\u6709\u7eff\u8272\u751f\u547d\u5468\u671f\u7684\u53ef\u5faa\u73af\u805a\u5408\u7269\u662f\u751f\u4ea7\u751f\u6d3b\u6240\u671f\u671b\u7684\uff0c\u4f46\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002\u76ee\u524d\u4e3b\u8981\u662f\u901a\u8fc7\u5bfb\u6c42\u53ef\u518d\u751f\u5355\u4f53\u548c\u5f00\u53d1\u9ad8\u6d3b\u6027\u50ac\u5316\u5242\u4e24\u4e2a\u65b9\u9762\u4ee5\u5236\u5907\u51fa\u53ef\u964d\u89e3\u7684\u805a\u5408\u7269\u3002
\n \u00a0 \u00a0 \u00a0 \u00a0 \u00a0\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u751f\u7269\u8d28\u884d\u751f\u7269\u03b3-\u4e01\u5185\u916f\uff08\u03b3-BL\uff09\u7684\u5f00\u73af\u805a\u5408\uff08ROP\uff09\u662f\u751f\u4ea7\u53ef\u5faa\u73af\u805a\u5408\u7269\u7684\u4e00\u79cd\u65b0\u5174\u7684\u65b9\u6cd5\u3002\u57282016\u5e74\uff0cHong\u548cChen\u7b49\u62a5\u9053\u7684\u4e00\u9879\u91cc\u7a0b\u7891\u5f0f\u7684\u7814\u7a76\uff0c\u7814\u7a76\u4e86\u03b3-BL\u7684\u5f00\u73af\u805a\u5408\uff08ROP\uff09\u8fc7\u7a0b\uff0c\u5728\u4f4e\u53cd\u5e94\u6e29\u5ea6\u4e0b\u4f7f\u7528\u91d1\u5c5e\uff08La\uff0cY\uff09\u914d\u5408\u7269\u4f5c\u4e3a\u50ac\u5316\u5242\uff08-40\u81f3-60 \u2103\uff09(Nat. Chem.<\/strong> <\/em>2016, 8, 42\u221249); \u540c\u65f6\uff0c\u4e5f\u62a5\u5bfc\u4e86\u03b3-BL\u7684\u65e0\u91d1\u5c5eROP\u5de5\u827a\uff0c\u4f7f\u75281-\u53d4\u4e01\u57fa-4,4,4-\u4e09\uff08\u4e8c\u7532\u57fa\u6c28\u57fa\uff09-2,2-\u53cc[\u4e09\uff08\u4e8c\u7532\u57fa\u6c28\u57fa\uff09\u4e9a\u78f7\u9170\u57fa\u6c28\u57fa] – 2\u03bb5<\/sub>,4\u03bb5<\/sub>\u78f7\u8148 (Angew. Chem., Int. Ed.<\/strong><\/em> 2016, 55, 4188\u22124193.), \u8d85\u5f3a\u78b1\uff08pKa\uff1a42.6 \u5728CH3<\/sub>CN\u4e2d; 30.2 \u5728DMSO\u4e2d\uff09\u4f5c\u4e3a\u50ac\u5316\u5242\u3002\u5176\u4e2d\uff0c\u4e24\u79cd\u50ac\u5316\u65b9\u6cd5\u5bf9\u4e8e\u03b3-BL\u7684ROP\u90fd\u63d0\u4f9b\u4e86\u5177\u670926.7-30.0 kg\/mol\u7684\u6570\u5747\u5206\u5b50\u91cf\uff08Mns\uff0cGPC\uff09\u7684\u7ebf\u6027\u548c\u73af\u72b6\u805a\uff08\u03b3-\u4e01\u5185\u916f\uff09\uff08P\u03b3BLs\uff09\u7684\u6df7\u5408\u7269\u3002Li\u548cLiu\u7b49\u4eba\u4e5f\u62a5\u9053\u4e86\u4f7f\u7528\u65b0\u516c\u5f00\u7684\u73af\u72b6\u4e09\u805a\u78f7\u8148\u78b1\uff08CH3<\/sub>CN\u4e2d pKa = 33.3\uff09\u9009\u62e9\u6027\u5408\u6210Mns\u9ad8\u8fbe22.9 kg\/mol\u7684P\u03b3BLs\uff0c\u53ef\u4ee5\u663e\u8457\u51cf\u5c11\u5927\u73afP\u03b3BL\u7684\u4ea7\u751f\u3002(Angew. Chem., Int. Ed.<\/strong> <\/em>2017, 56, 12987\u221212990.; Polym. Chem.<\/strong> <\/em>2018, 9, 2936\u22122941.)\u3002\u805a\u5408\u7269\u7684\u673a\u68b0\u6027\u80fd\u4e0e\u5176\u5206\u5b50\u91cf\uff08MW\uff09\u548c\u62d3\u6251\u7ed3\u6784\u5bc6\u5207\u76f8\u5173\u3002\u5bf9\u4e8eP\u03b3BLs\u800c\u8a00\uff0c\u9ad8MW\u548c\u7ebf\u6027\u7ed3\u6784\u5bf9\u4e8e\u6539\u5584\u673a\u68b0\u6027\u80fd\u662f\u6709\u5229\u7684\uff0c\u800c\u5927\u73af\u805a\u5408\u7269\u5f15\u8d77\u8f83\u5c11\u7684\u94fe\u7f20\u7ed3\u5e76\u56e0\u6b64\u524a\u5f31\u673a\u68b0\u6027\u80fd\u3002\u4e4b\u524d\u7684\u7814\u7a76\u53d1\u73b0\uff0c\u6d3b\u6027\u94fe\u7684\u9634\u79bb\u5b50\u4e0e\u94fe\u4e2d\u7684\u7fb0\u57fa\u4f4d\u70b9\u7684\u53d1\u751f\u94fe\u56de\u54ac\u53cd\u5e94\uff0c\u4ea7\u751f\u7684\u5927\u73afP\u03b3BL\u964d\u4f4e\u4e86\u5176MW\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u51fa\u80fd\u591f\u6291\u5236\u94fe\u56de\u54ac\u53cd\u5e94\u7684\u9ad8\u6d3b\u6027\u50ac\u5316\u5242\u63d0\u9ad8\u5176\u5206\u5b50\u91cf\u5f88\u5177\u6709\u6311\u6218\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6d59\u6c5f\u5927\u5b66\u7684\u5f20\u5174\u5b8f\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5f00\u53d1\u4e86\u7528\u4e8e\u03b3-BL\u7684ROP\u7684\u53cc\u7ec4\u5206\u6709\u673a\u50ac\u5316\u5242\uff0c\u4f7f\u7528\u5177\u6709\u7ed9\u7535\u5b50\u57fa\u56e2\u7684\u5bf9\u79f0\uff08\u786b\uff09\u8132\u6765\u8c03\u63a7\u7531\u8d85\u5f3a\u78b1\u78f7\u8148\uff08P4\uff09\u4ea7\u751f\u7684\u9634\u79bb\u5b50\u7684\u4eb2\u6838\u6027\u3002\u9009\u62e9\u6027\u5730\u5408\u6210\u4e86\u7ebf\u6027P\u03b3BLs\uff0c\u5177\u6709\u9ad8\u53cd\u5e94\u6d3b\u6027\uff0c\u5e76\u4e14\u6570\u5747\u5206\u5b50\u91cf\u9ad8\u8fbe64.3 kg\/mol\u3002\u8fd9\u4e9bP4\/\uff08\u786b\u4ee3\uff09\u8132\u5bf9\u50ac\u5316\u8fc7\u7a0b\u7684\u8f6c\u6362\u9891\u7387\u9ad8\u8fbe125 h-1<\/sup>\u3002\u9ad8\u5206\u5b50\u91cfP\u03b3BLs\u663e\u793a\u51fa\u663e\u7740\u6539\u5584\u7684\u673a\u68b0\u6027\u80fd\u3002\u7814\u7a76\u6210\u679c\u4ee5\u9898\u4e3a\u201cDual Organocatalysts for Highly Active and Selective Synthesis of Linear Poly(\u03b3-butyrolactone)s with High Molecular Weights\u201d<\/strong>\u53d1\u5e03\u5728\u56fd\u9645\u8457\u540d\u671f\u520aMacromolecules<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u89e3\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001\u7814\u7a76\u4e86\u4e0d\u540c\u786b\u8132\u7ed3\u6784\u5bf9\u4e8e\u03b3-BL\u7684ROP\u7684\u5f71\u54cd\uff0c\u9009\u51fa\u6700\u4f18\u5316\u5408\u7269\u3002<\/strong>
\n \"\"
\n Scheme 1.<\/strong>\u00a0 P4\u8054\u5408\uff08\u786b\u4ee3\uff09\u8132\u5bf9\u03b3-BL\u7684\u4f5c\u7528\u3002\uff08a\uff09\uff08\u786b\u4ee3\uff09\u8132\u7684\u8c03\u63a7\u4f5c\u7528\uff0c\u7528\u4e8e\u6291\u5236\u9187\u76d0\u4e2d\u7684\u9634\u79bb\u5b50\u7684\u53cd\u5e94\u3002\uff08b\uff09\u5404\u79cd\uff08\u786b\uff09\u8132\u3002\u5177\u6709\u7ed9\u7535\u5b50\u57fa\u56e2\u7684TU-3-TU-7\uff0cU-1\u548cU-2\u5bf9\u4e8e\u03b3-BL\u7684ROP\u66f4\u597d\u3002<\/p>\n

\u56fe\u4e8c\u3001\u901a\u8fc7\u52a8\u529b\u5b66\u7814\u7a76\u63ed\u793a\u4e86TU-3\u5bf9P4\u50ac\u5316\u7684\u03b3-BL\u7684ROP\u7684\u6d3b\u6027\u7684\u5f71\u54cd\uff08Figure 1a\uff09\u3002\u68c0\u6d4b\u4e86\u4f7f\u7528P4 \/ TU-3\u5bf9\u7684\u03b3-BL\u7684ROP\u7684\u52a8\u529b\u5b66\uff0c\u5e76\u4e14\u4f7f\u7528\u5355\u72ecP4\u548cP4\/TU-1\u5bf9\u4f5c\u4e3a\u5bf9\u7167\u3002 \u5355\u72ecP4\u7684BnOH\u7684\u5e73\u8861\u5e38\u6570\u4e3a84.6 \u00b1 9.2\uff0cP4\/TU-3\u5bf9\u4e3a30.1 \u00b1 2.3\uff0c\u800c\u572825 \u2103\u65f6C6<\/sub>D6<\/sub>\u4e2d\u7684P4\/TU-1\u5bf9\u7684\u5e73\u8861\u5e38\u6570\u4e3a16.7 \u00b1 2.7 \uff08Figure 1b\uff09\uff0c\u8868\u660e\u751f\u6210\u7684BnO–<\/sup> \u7684\u78b1\u6027\u987a\u5e8f\u4e3aP4 > P4\/TU-3 > P4\/TU-1\u3002<\/strong>
\n \"\"Figure 1.<\/strong> \uff08a\uff09{-[BL]0-<\/sub>[BL]eq<\/sub>\/\uff08[BL]t –<\/sub> [BL]eq<\/sub>\uff09}\u5bf9-40 \u2103 \u03b3-BL\u7684ROP\u65f6\u95f4\u7684\u4e00\u9636\u56fe-BL\/P4\/BnOH = 300\/1\/1; \u03b3-BL\/P4\/TU-3 \/BnOH = 300\/1\/1\/1; \u03b3-BL\/P4\/TU-1\/BnOH = 300\/1\/1\/1\u3002\uff08b\uff09\u7ed3\u5408\u4f53\u7cfb\u7684\u5316\u5b66\u4f4d\u79fb\u4e0eC6<\/sub>D6<\/sub>\u4e2d25 \u2103\u7684BnOH\u548cP4\uff08-TU\uff09\uff0c[BnOH] = [P4\uff08-TU\uff09]\u6d53\u5ea6\u7684\u5316\u5b66\u4f4d\u79fb\u56fe\u3002<\/p>\n

\u56fe\u4e09\u3001\u901a\u8fc7NMR\u6280\u672f\u68c0\u6d4bTU-3\uff0cP4\u548cBnOH\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u8fdb\u4e00\u6b65\u63a2\u8ba8\u4e86TU-3\u5728P4\u50ac\u5316\u7684\u03b3-BL ROP\u4e2d\u7684\u4f5c\u7528\u300231<\/sup>P NMR\uff08Figure 2a\uff09\u548c1<\/sup>H NMR\u5149\u8c31\uff08Figure S3\uff09\u663e\u793aP4\u4ee5\u5316\u5b66\u8ba1\u91cf\u65b9\u5f0f\u5b8c\u5168\u53bb\u8d28\u5b50\u5316TU-3\u3002 \u56e0\u6b64\uff0cP4\/TU-3\u79bb\u5b50\u5bf9\u53ef\u4ee5\u5f62\u6210\u4e3a\u65b9\u68482\u4e2d\u7684\u79cd\u7c7b\u3002\u5f53\u5f15\u5165\u5177\u6709\u6bd4TU-3\u548cP4\u5c0f\u5f97\u591a\u7684pKa\u7684BnOH\u65f6\uff08\u7ea2\u7ebf\uff0cFigure 2b\uff09\uff0c\u53ef\u4ee5\u53bb\u8d28\u5b50\u5316\u3002<\/strong>
\n \"\"Figure 2.<\/strong> \uff08a\uff09P4\uff0cP4\/TU-3\uff081\/0.5\uff09\uff0cP4\/TU-3\uff081\/1\uff09\u768431<\/sup>P NMR\u5149\u8c31; \uff08b\uff09 C6<\/sub>D6<\/sub>\u4e2dBnOH\uff0cBnOH\/P4\uff081\/1\uff09\uff0cBnOH\/P4\/TU-3\uff081\/1\/1\uff09\uff0cBnOH\/P4\/TU-1\uff081\/1\/1\uff09\u76841<\/sup>H NMR\u5149\u8c31\u3002<\/p>\n

\u56fe\u56db\u3001P4\/TU-3\u79bb\u5b50\u5bf9\u53ef\u4ee5\u5f62\u6210\u4e3aScheme 2\u4e2d\u7684\u79cd\u7c7b\uff081\uff09\u3002\u5f53\u5f15\u5165\u5177\u6709\u6bd4TU-3\u548cP4\u5c0f\u5f97\u591a\u7684pKa\u7684BnOH\u65f6\uff08\u7ea2\u7ebf\uff0cFigure 2b\uff09\uff0c\u5b83\u53ef\u4ee5\u53bb\u8d28\u5b50\u5316\u3002\u901a\u8fc7\u6c22\u952e\u76f8\u4e92\u4f5c\u7528\u63d0\u4f9b\u4e0eTU3\u7ed3\u5408\u7684BnO-\uff0c\u5728Scheme 2\u4e2d\u4ea7\u751f\u7269\u8d28\uff082\uff09\u3002<\/strong>
\n \"\"Scheme 2.<\/strong> \u7528P4\/TU-3\u5bf9\u63d0\u51fa\u03b3-BL\u7684ROP\u673a\u7406\u3002<\/p>\n

\u56fe\u4e94\u3001\u57281.0\u5f53\u91cfTU-3\u5b58\u5728\u4e0b\uff0c\u03b1-OBn\uff0c\u03c9-OH- \u7ec8\u6b62\u805a\u5408\u7269\uff08BnO- [C\uff08= O\uff09CH2<\/sub>CH2<\/sub>CH2<\/sub>O]n<\/sub> + H + K+<\/sup>\uff09\u7684\u4e00\u4e2a\u4e3b\u8981\u5206\u5e03\uff08Figure 3a\uff09\uff0c\u901a\u8fc7\u5bf9\u6bd4\u5728\u4e0d\u5b58\u5728TU-3\u7684\u60c5\u51b5\u4e0b\uff0c\u5728\u4f4eMW\u533a\u57df\u4e2d\u89c2\u5bdf\u5230\u76f8\u5f53\u5927\u91cf\u7684\u5927\u73af\u805a\u5408\u7269\uff08[C\uff08= O\uff09CH2<\/sub>CH2<\/sub>CH2<\/sub>O]n<\/sub> + K+<\/sup>\uff09\uff08Figure 3b\uff09\u3002<\/strong>
\n \"\"Figure 3.<\/strong> \uff08a\uff09\u03b3-BL\/ P4\/ TU-3\/ BnOH = 300\/ 1\/ 1\/ 1\uff08Mn\uff1a3.5 kg\/ mol\uff0cGPC\uff09\uff0c\uff08b\uff09\u03b3-BL\/ P4\u5408\u6210\u7684P\u03b3BLs\u7684MALDI-TOF MS\u8c31\/ BnOH = 300\/ 1\/ 1\uff08Mn\uff1a3.8 kg\/ mol\uff0cGPC\uff09\u3002<\/p>\n

\u56fe\u516d\u3001\u4e3a\u4e86\u8bc1\u660eP\u03b3BLs\u7684MWs\u5bf9\u529b\u5b66\u6027\u80fd\u7684\u5f71\u54cd\uff0c\u6bd4\u8f83\u7814\u7a76\u4e86\u4e0d\u540cMWs\u7684P\u03b3BLs\u7684\u5e94\u529b-\u5e94\u53d8\u884c\u4e3a\u3002Figure 4\u6240\u793a\uff0cMn\u4e3a42.5 kg\/mol\u7684P\u03b3BL\u7684\u6781\u9650\u62c9\u4f38\u5f3a\u5ea6\u5728\u5ba4\u6e29\u4e0b\u7684\u65ad\u88c2\u4f38\u957f\u7387\u4e3a183.5\uff05\uff0c\u62c9\u4f38\u5f3a\u5ea6\u4e3a16.3 MPa\uff0c\u800cMn\u4e3a18.5 kg \/ mol\u7684P\u03b3BL\u8868\u73b0\u51fa\u6765\u3002\u5931\u6548\u5e94\u53d8\u4ec5\u4e3a8.5\uff05\uff0c\u6297\u62c9\u5f3a\u5ea6\u4e3a8.6 MPa\u3002<\/strong>
\n \"\"Figure 4.<\/strong> \u5728\u5ba4\u6e29\u4e0b\uff0c50 mm\/min\uff0cMn\u4e3a18.5 kg\/mol\uff08\u84dd\u7ebf\uff09\u548c42.5 kg\/mol\uff08\u7ea2\u7ebf\uff09\u7684P\u03b3BLs\u7684\u5e94\u529b-\u5e94\u53d8\u66f2\u7ebf\u3002\u5408\u6210\u6761\u4ef6\u4e0eentries 2\u548cTable 2\u4e2d\u7684\u6761\u4ef6\u76f8\u540c\u3002\u91cd\u590d\u70ed\u5904\u7406\u964d\u4f4e\u4e86\u7eafP\u03b3BLs\u7684Mn\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u901a\u8fc7\u7814\u7a76\u5df2\u7ecf\u8bc1\u660e\u4e86\u4f7f\u7528\u5546\u4e1a\u4e0a\u53ef\u83b7\u5f97\u7684P4\u548c\u5404\u79cd\u7ed9\u7535\u5b50\u57fa\u56e2\u53d6\u4ee3\u7684\uff08\u786b\uff09\u8132\uff0c\u53ef\u4ee5\u5b9e\u73b0\u03b3-BL\u7684\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027ROP\u7528\u4e8e\u5408\u6210\u9ad8MW\u7ebf\u6027P\u03b3BLs\u3002\u8fd9\u662f\u4e00\u79cd\u4e0d\u542b\u91d1\u5c5e\u7684\u805a\u5408\u65b9\u6cd5\uff0c\u5373\u4f7f\u5728P4\u7684\u4f4e\u8d1f\u8f7d\u4e0b\u4e5f\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u9ad8MW\u7684P\u03b3BLs\u8868\u73b0\u51fa\u6781\u5927\u6539\u8fdb\u7684\u673a\u68b0\u6027\u80fd\u3002\u901a\u8fc7\uff08\u786b\uff09\u8132\u4e0eP4\u7684\u76f8\u4e92\u4f5c\u7528\u4ea7\u751f\u6709\u673a\u9178\u78b1\u8c03\u63a7\u4f53\u7cfb\uff0c\u53ef\u4ee5\u8c03\u63a7\u751f\u957f\u7684\u9634\u79bb\u5b50\u5e76\u5728\u6c22\u952e\u4f5c\u7528\u4e0b\u6d3b\u5316\u03b3BL\u3002\u53cc\u7ec4\u5206\u6709\u673a\u50ac\u5316\u5242\u5b8c\u7f8e\u5730\u53cd\u6620\u4e86\u9634\u9633\u54f2\u5b66\u539f\u7406\uff08\u9650\u5236\u548c\u4fc3\u8fdb\u5f7c\u6b64\u5e73\u8861\u7684\u4e24\u4e2a\u56e0\u7d20\uff09\u3002\u6269\u5c55\u5404\u79cd\uff08\u786b\u4ee3\uff09\u8132\u548c\u5f00\u53d1\u5546\u4e1a\u4e0a\u53ef\u83b7\u5f97\u7684\u548c\u4f4e\u6210\u672c\u7684\uff08\u786b\u4ee3\uff09\u8132\uff08\u5c24\u5176\u662f\u8132\uff09\u76f8\u5bf9\u4e8e\u91d1\u5c5e\u50ac\u5316\u5242\u662f\u5f88\u6709\u7ade\u4e89\u529b\uff0c\u5e76\u4e14\u662f\u975e\u5e38\u503c\u5f97\u7279\u522b\u5173\u6ce8\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aDual Organocatalysts for Highly Active and Selective Synthesis of Linear Poly(\u03b3-butyrolactone)s with High Molecular Weights<\/a><\/strong>\uff08Macromolecules, 2018<\/strong>, DOI: 10.1021\/acs.macromol.8b01757\uff09<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb:<\/strong><\/p>\n

\u5f20\u5174\u5b8f\uff0c\u6559\u6388\uff0c\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u9ad8\u5206\u5b50\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u7cfb\u526f\u7cfb\u4e3b\u4efb\u3002<\/strong>
\n \u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee5\u9879\uff0c\u4e2d\u56fd\u535a\u58eb\u540e\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u4e00\u7b49\u8d44\u52a9\u9879\u76ee1\u9879\uff0c\u6d59\u6c5f\u7701\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u9879\u76ee1\u9879\uff1b\u6d59\u6c5f\u7701\u79d1\u6280\u5385\u793e\u4f1a\u516c\u76ca\u6280\u672f\u9879\u76ee1\u9879\uff1b\u83b72016\u5e74\u6d59\u6c5f\u7701\u6770\u51fa\u9752\u5e74\u57fa\u91d1\u9879\u76ee\uff1b\u627f\u62c5\u9999\u6e2f\u5efa\u6ed4\u5316\u5de5\u96c6\u56e2\u3001\u5fb7\u56fd\u5df4\u65af\u592b\u59d4\u6258\u7684\u56fd\u5185\u5916\u7814\u7a76\u8bfe\u9898\u591a\u9879\u3002\u5728Nature communications, Angew Chem., Accounts of Chemical Research, Chemical Science, Macromolecules, J. Polym. Sci. Part A: Polym. Chem.\u548cPolymer\u7b49\u56fd\u5185\u5916\u671f\u520a\u53d1\u886870\u7bc7\u8bba\u6587\uff1b\u53d7\u9080\u64b0\u5199\u82f1\u6587\u4e13\u84573\u7ae0(Wiley\u548cElsevier\u51fa\u7248\u793e)\uff1b\u6388\u6743\u53d1\u660e\u4e13\u522920\u4f59\u9879(\u542b\u7f8e\u56fd\u4e13\u52292\u9879)\u3002<\/p>\n

\u4e2a\u4eba\u4e3b\u9875\uff1ahttps:\/\/person.zju.edu.cn\/xinghongzhang<\/a><\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u751f\u7ec4\u3001\u7eb3\u7c73\u7ec4\u7684\u5c0f\u80d6\u7eb8\u7f16\u8bd1\uff0c\u6750\u6599\u4eba\u6574\u7406\u7f16\u8f91\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1: tougao@cailiaoren.com<\/strong>.<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/strong><\/p>\n

 <\/p>\n","protected":false},"excerpt":{"rendered":"

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