{"id":158359,"date":"2018-11-12T06:15:28","date_gmt":"2018-11-11T22:15:28","guid":{"rendered":"\/\/m.iemloyee.com\/?p=158359"},"modified":"2018-11-11T19:15:50","modified_gmt":"2018-11-11T11:15:50","slug":"%e5%b1%b1%e5%a4%a7%e5%ad%99%e9%a0%94nature%e5%ad%90%e5%88%8a-%e7%be%a7%e9%85%b8%e5%88%ba%e6%bf%80%e8%af%b1%e5%af%bc%e7%9a%84%e7%ba%b3%e7%b1%b3%e9%93%b6%e7%b0%87%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=158359","title":{"rendered":"\u5c71\u5927\u5b59\u9814Nature\u5b50\u520a: \u7fa7\u9178\u523a\u6fc0\u8bf1\u5bfc\u7684\u7eb3\u7c73\u94f6\u7c07\u53cd\u5e94"},"content":{"rendered":"

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\u00a0<\/b><\/strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

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\u00a0<\/b><\/strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

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\"\"(a)\u00a0SD<\/b><\/strong>\/<\/b><\/strong>Ag<\/b><\/strong>44<\/b><\/sub><\/strong>\u7684\u5206\u5b50\u7ed3\u6784\uff1b(b)\u5185\u90e8Mo6<\/sub>O22<\/sub>8-<\/sup>\u7684\u591a\u9762\u4f53\u6a21\u5f0f\u56fe\uff1b(c)\u00a0SD\/Ag<\/b><\/strong>50<\/b><\/sub><\/strong>\u7684\u5206\u5b50\u7ed3\u6784\uff1b(d) \u5185\u90e8Mo8<\/sub>O2<\/sub>8<\/sub>8-<\/sup>\u7684\u591a\u9762\u4f53\u6a21\u5f0f\u56fe\u3002<\/p>\n

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(a) PhCOOH\u8bf1\u5bfcSD\/Ag44\u5411SD\/Ag50\u8f6c\u53d8\u7684\u8d28\u8c31\u8ddf\u8e2a\u56fe\u3002<\/p>\n

(b)\u8f6c\u5316\u8fc7\u7a0b\u4e2d\uff0c\u4e2d\u95f4\u4f53\u7269\u79cd\u7684\u6d53\u5ea6\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\u56fe\u3002<\/p>\n

\u56fe\u56db \u4eceSD\/Ag44\u5230SD\/Ag50\u7684\u8f6c\u5316\u7684<\/b><\/strong>\u673a\u7406\u9610\u91ca\u56fe\u793a<\/b><\/strong><\/p>\n

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\u672c\u6587\u8fd0\u7528\u4f4e\u6e29\u6eb6\u5242\u70ed\u7684\u65b9\u6cd5\u5f97\u5230\u4e86\u4e24\u4e2a\u9634\u79bb\u5b50\u6a21\u677f\u7684\u94f6\u7c07(SD\/Ag44<\/b><\/strong>\u548cSD\/A<\/b><\/strong>g50<\/b><\/strong>)\uff0c\u540e\u8005\u53ef\u4ee5\u7531\u524d\u8005\u5728\u7fa7\u9178\u523a\u6fc0\u8bf1\u5bfc\u4e0b\u83b7\u5f97\u3002\u8f6c\u5316\u8fc7\u7a0b\u7ecf\u5386\u4e86\u5185\u90e8\u9634\u79bb\u5b50\u6a21\u677f(Mo6<\/sub>O22<\/sub>8-<\/sup>\u2192Mo8<\/sub>O28<\/sub>8-<\/sup>)\u548c\u5916\u58f3\u5c42(Ag44<\/sub>\u2192Ag50<\/sub>)\u7684\u534f\u540c\u751f\u957f\uff0c\u5229\u7528\u9ad8\u5206\u8fa8\u8d28\u8c31\u5efa\u7acb\u4e86\u4eceAg44\u5230Ag50\u7684\u2018\u7834\u788e\u751f\u957f\u518d\u7ec4\u88c5\u2019\u7684\u8f6c\u5316\u673a\u5236\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u63ed\u793a\u4e86\u7fa7\u9178\u5728\u8bf1\u5bfc\u94f6\u7c07\u8f6c\u5316\u8fc7\u7a0b\u4e2d\u7684\u91cd\u8981\u6027\uff0c\u800c\u4e14\u4e3a\u5408\u6210\u96be\u4ee5\u83b7\u5f97\u7684\u5927\u5c3a\u5bf8\u94f6\u56e2\u7c07\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/b><\/strong>Deciphering synergetic core-shell transformation<\/b><\/u><\/strong>\u00a0<\/b><\/u><\/strong>from [Mo<\/b><\/u><\/strong>6<\/b><\/sub><\/u><\/strong>O<\/b><\/u><\/strong>22<\/b><\/sub><\/u><\/strong>@Ag<\/b><\/u><\/strong>44<\/b><\/sub><\/u><\/strong>]<\/b><\/u><\/strong>\u00a0<\/b><\/u><\/strong>to<\/b><\/u><\/strong>\u00a0<\/b><\/u><\/strong>[Mo<\/b><\/u><\/strong>8<\/b><\/sub><\/u><\/strong>O<\/b><\/u><\/strong>28<\/b><\/sub><\/u><\/strong>@Ag<\/b><\/u><\/strong>50<\/b><\/sub><\/u><\/strong>]<\/b><\/u><\/strong><\/a>\u201d(<\/b><\/strong>Nat. Commun. 2018.<\/b><\/strong>DOI: 10.1038\/s41467-018-06755-4<\/b><\/strong>)<\/p>\n

\u8fd1\u5e74\u6765\uff0c\u5b59\u9814\u8bfe\u9898\u7ec4\u8fd0\u7528\u591a\u79cd\u8c03\u63a7\u7b56\u7565\uff0c\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u94f6\u7eb3\u7c73\u7c07\u5982\u5305\u88f9\u8fd8\u539f\u6001\u94f6\u7c07\u7684\u4e03\u91cd\u7eb3\u7c73\u94f6\u8f6e(Nat. Commun. 2018<\/b><\/strong>, 9, <\/b><\/strong>2094<\/b><\/strong>)\uff1b\u5404\u5411\u5f02\u6027\u7684\u94f6\u7eb3\u7c73\u7c07\u00a0(J Am Chem Soc<\/b><\/strong>\u00a02018, 140, 1600<\/b><\/strong>)\uff1b\u54e5\u5fb7\u5821\u7eb3\u7c73\u94f6\u7b3c\u00a0(Proc. Natl. Acad. Sci. USA 2017, 114, 12132<\/b><\/strong>)\uff1b\u5171\u6676\u4e8e\u540c\u4e00\u9897\u5355\u6676\u7684\u4e24\u4e2a\u4e0d\u540c\u8fd8\u539f\u578b\u7eb3\u7c73\u94f6\u7c07\uff0cAg21<\/sub>0<\/sub>\u548cAg211<\/sub>\u00a0(Angew<\/b><\/strong>\u00a0<\/b><\/strong>Chem<\/b><\/strong>. Int, Ed, <\/b><\/strong>2019<\/b><\/strong>, DOI: 10.1002\/anie.201810772)\u7b49\u3002<\/p>\n

\u66f4\u591a\u5de5\u4f5c\u8be6\u89c1\uff1ahttp:\/\/www.researcherid.com\/rid\/G-3352-2010<\/a>.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\uff0c\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u5b59\u9814<\/b><\/strong>\u6559\u6388<\/b><\/strong>\u4fee\u6b63\u4f9b\u7a3f\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu \u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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