{"id":158176,"date":"2018-11-07T08:00:20","date_gmt":"2018-11-07T00:00:20","guid":{"rendered":"\/\/m.iemloyee.com\/?p=158176"},"modified":"2018-11-06T18:49:38","modified_gmt":"2018-11-06T10:49:38","slug":"angew-chem-int-ed-%e6%96%b0%e5%9e%8bmof%e6%9d%90%e6%96%99%e5%8a%a9%e5%8a%9b%e9%ab%98%e6%95%88%e4%b9%99%e7%83%af%e7%ba%af%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=158176","title":{"rendered":"Angew. Chem. Int. Ed. :\u65b0\u578bMOF\u6750\u6599\u52a9\u529b\u9ad8\u6548\u4e59\u70ef\u7eaf\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8f7b\u8d28\u70c3\uff0c\u5982\u4e59\u70f7\u3001\u4e59\u70ef\u548c\u4e59\u7094\uff0c\u662f\u77f3\u6cb9\u5316\u5de5\u4e2d\u4f7f\u7528\u6700\u4e3a\u5e7f\u6cdb\u7684\u539f\u6599\u5206\u5b50\u3002\u7531\u4e8eC2<\/sub>H4<\/sub>\u548cC2<\/sub>H6<\/sub>\u7684\u5206\u5b50\u5927\u5c0f\u548c\u6325\u53d1\u6027\u76f8\u4f3c\uff0cC2<\/sub>H4<\/sub>\/C2<\/sub>H6<\/sub>\u6df7\u5408\u7269\u7684\u5206\u79bb\u88ab\u8ba4\u4e3a\u662f\u6700\u5177\u6311\u6218\u6027\u4f46\u6700\u91cd\u8981\u7684\u5de5\u4e1a\u8fc7\u7a0b\u4e4b\u4e00\u3002\u76ee\u524d\uff0cC2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>\u6216C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>\u5206\u79bb\u7684\u65b0\u65b9\u6cd5\u4e3b\u8981\u96c6\u4e2d\u5728\u819c\u5206\u79bb\u3001\u6709\u673a\u6eb6\u5242\u5438\u9644\u5242\u5206\u79bb\u548cMOF\u57fa\u5438\u9644\u5242\u5206\u79bb\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0cMOF\u5df2\u6210\u4e3a\u7528\u4e8e\u5206\u79bbC2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>\u6216C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>\u6df7\u5408\u7269\u7684\u65b0\u578b\u529f\u80fd\u6027\u591a\u5b54\u6750\u6599\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u8bb8\u591aMOF\u5728C2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>\u7684\u5206\u79bb\u8fc7\u7a0b\u4e2d\u5177\u6709\u51fa\u8272\u7684\u8868\u73b0\u3002\u7136\u800c\u4eceC2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>\/C2<\/sub>H6<\/sub>\u7684\u4e09\u5143\u6df7\u5408\u7269\u4e2d\u540c\u65f6\u5e76\u9009\u62e9\u6027\u5730\u5438\u6536C2<\/sub>H4<\/sub>\u548cC2<\/sub>H2<\/sub>\u7684MOF\u6750\u6599\u5c1a\u672a\u89c1\u6587\u732e\u62a5\u9053\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5929\u6d25\u7406\u5de5\u5927\u5b66\u9c81\u7edf\u90e8\u6559\u6388\u3001\u5f20\u5fd7\u660e\u6559\u6388\u3001\u7f8e\u56fd\u5fb7\u514b\u8428\u65af<\/strong>A&M<\/strong>\u5927\u5b66\u5468\u5b8f\u624d\u6559\u6388<\/strong>(<\/strong>\u5171\u540c\u901a\u8baf\u4f5c\u8005<\/strong>)<\/strong>\u7b49<\/strong>\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u7a33\u5b9a\u7684\u91d1\u5c5e-\u6709\u673a\u6846\u67b6TJT-100\uff0c\u5176\u53ef\u4ece\u4e09\u5143\u6df7\u5408\u6c14\u4e2d\u663e\u8457\u9009\u62e9\u6027\u5438\u9644C2<\/sub>H2<\/sub>\u548cC2<\/sub>H6<\/sub>\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cSimultaneously Trapping C2<\/sub>H2<\/sub> and C2<\/sub>H6<\/sub>into a Robust Metal-Organic Framework from a Ternary Mixture of C2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>\/C2<\/sub>H6<\/sub> forPurification of C2<\/sub>H4<\/sub><\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u7a81\u7834\u6027\u5b9e\u9a8c\u8868\u660e\uff0cTJT-100\u53ef\u4f5c\u4e3a\u4eceC2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>\/C2<\/sub>H6<\/sub>(0.5\/99\/0.5)\u4e09\u5143\u6df7\u5408\u7269\u4e2d\u9ad8\u6548\u7eaf\u5316C2<\/sub>H4<\/sub>\u7684\u5438\u9644\u5242\uff0c\u6240\u5f97C2<\/sub>H4<\/sub>\u7eaf\u5ea6\u5927\u4e8e99.997%\uff0c\u5df2\u8d85\u8fc7\u4e59\u70ef\u805a\u5408\u6240\u9700\u7eaf\u5ea6\u3002\u8ba1\u7b97\u7814\u7a76\u8868\u660e\uff0c\u672a\u914d\u4f4d\u7684\u7fa7\u9178\u6c27\u539f\u5b50\u548c\u914d\u4f4d\u6c34\u5206\u5b50\u901a\u8fc7\u5f62\u6210\u591a\u91cdC-H\u2022\u2022\u2022O\u6c22\u952e\u548c\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u53ef\u4ee5\u6355\u83b7C2<\/sub>H2<\/sub>\u548cC2<\/sub>H6<\/sub>\uff0c\u800c\u76f8\u5e94\u7684’C2<\/sub>H4<\/sub>-\u6846\u67b6’\u76f8\u4e92\u4f5c\u7528\u8f83\u5f31\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 TJT-100<\/strong>\u7684\u7ed3\u6784<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

a) \u6cbfb\u8f74\u89c2\u5bdf\u7684TJT-100\u7684\u7ed3\u6784(\u4e3a\u6e05\u695a\u8d77\u89c1\uff0c\u7701\u7565\u4e86Me2<\/sub>NH2<\/sub>+<\/sup>\u548c\u5ba2\u4f53\u6c34\u5206\u5b50)\uff1b<\/p>\n

b) TJT-100\u4e2d\u7684\u4e09\u6838{Co3<\/sub>}\u4e9a\u7ed3\u6784\u5355\u5143\uff1b<\/p>\n

c) C2<\/sub>H6<\/sub>\u5728TJT-100\u4e2d\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9\u8ba1\u7b97\u6a21\u62df\uff1b<\/p>\n

d) C2<\/sub>H4<\/sub>\u5728TJT-100\u4e2d\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9\u8ba1\u7b97\u6a21\u62df\uff1b<\/p>\n

e) C2<\/sub>H2<\/sub>\u5728TJT-100\u4e2d\u7684\u4f18\u5148\u5438\u9644\u4f4d\u70b9\u8ba1\u7b97\u6a21\u62df\u3002<\/p>\n

\u56fe<\/strong>2\u00a0 TJT-100<\/strong>\u7684\u5438\u9644\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) \u6d3b\u5316TJT-100\u572877K\u4e0b\u7684N2<\/sub>\u5438-\u8131\u9644\u7b49\u6e29\u7ebf\uff0c\u5185\u63d2\u4e3a\u5b54\u5f84\u5206\u5e03\uff1b<\/p>\n

b) \u6d3b\u5316TJT-100\u5728273 K\u4e0b\u7684C2<\/sub>H2<\/sub>\u5438-\u8131\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

c) \u6d3b\u5316TJT-100\u5728298 K\u4e0b\u7684C2<\/sub>H4<\/sub>\u5438-\u8131\u9644\u7b49\u6e29\u7ebf\uff1b<\/p>\n

d) \u6d3b\u5316TJT-100\u5728318K\u4e0b\u7684C2<\/sub>H6<\/sub>\u5438-\u8131\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

\u56fe<\/strong>3<\/strong>\u00a0 TJT-100<\/strong>\u7684\u7a81\u7834\u5b9e\u9a8c<\/strong>\"\"<\/strong><\/p>\n

a) \u6d3b\u5316TJT-100\u5728298K\u4e0bC2<\/sub>H6<\/sub>,C2<\/sub>H4<\/sub>\u548cC2<\/sub>H2<\/sub>\u7684\u8ba1\u7b97Q<\/em>st<\/sub>\u503c\uff1b<\/p>\n

b) 298K\u30011 bar\u4e0b\uff0c\u6d3b\u5316TJT-100\u5bf9C2<\/sub>H6<\/sub>\/C2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>(0.5\/0.5\/99)\u7684\u7a81\u7834\u66f2\u7ebf\uff1b<\/p>\n

c) 298 K\u30011 bar\u4e0b\uff0c\u6d3b\u5316TJT-100\u5bf9C2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>(1\/99)\u7684\u7a81\u7834\u66f2\u7ebf\uff1b<\/p>\n

d) 298 K\u30011 bar\u4e0b\uff0c\u6d3b\u5316TJT-100\u5bf9C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>(1\/99)\u7684\u7a81\u7834\u66f2\u7ebf\u3002<\/p>\n

\u56fe<\/strong>4 TJT-100<\/strong>\u7684\u4f18\u5316\u5438\u9644\u4f4d\u70b9<\/strong>\"\"<\/strong><\/p>\n

a,b) C2<\/sub>H2<\/sub>\u5728\u6d3b\u5316\u7684TJT-100\u4e2d\u7684GCMC\u6a21\u62df\u4f18\u5148\u5438\u9644\u4f4d\u70b9\uff1b<\/p>\n

c) C2<\/sub>H4<\/sub>\u5728\u6d3b\u5316\u7684TJT-100\u4e2d\u7684GCMC\u6a21\u62df\u4f18\u5148\u5438\u9644\u4f4d\u70b9\uff1b<\/p>\n

d) C2<\/sub>H6<\/sub>\u5728\u6d3b\u5316\u7684TJT-100\u4e2d\u7684GCMC\u6a21\u62df\u4f18\u5148\u5438\u9644\u4f4d\u70b9\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u5408\u6210\u4e86\u4e00\u79cd\u65b0\u578b\u591a\u5b54MOF(TJT-100)\uff0c\u5176\u5177\u6709\u8f83\u9ad8\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u9178\/\u78b1\u7a33\u5b9a\u6027\u3002\u8be5\u6846\u67b6\u5177\u6709\u76f8\u5bf9\u8f83\u9ad8\u7684C2<\/sub>H6<\/sub>\u3001C2<\/sub>H4<\/sub>\u548cC2<\/sub>H2<\/sub>\u5438\u9644\u80fd\u529b\uff0c\u5728C2<\/sub>H2<\/sub>\/C2<\/sub>H6<\/sub>\/C2<\/sub>H4<\/sub>(0.5:0.5:99,v\/v)\u4e09\u5143\u6df7\u5408\u7269\u4e2d\u663e\u793a\u51fa\u5bf9C2<\/sub>H6<\/sub>\u548cC2<\/sub>H2<\/sub>\u72ec\u7279\u7684\u9009\u62e9\u6027\u5438\u9644\uff0c\u4ece\u800c\u5b9e\u73b0\u6240\u5f97C2<\/sub>H4<\/sub>\u7eaf\u5ea6\u5927\u4e8e99.997%\u3002\u8fd9\u4e3b\u8981\u5f52\u56e0\u4e8e\u5728\u5b54\u8868\u9762\u4e0a\u5b58\u5728\u9ad8\u5bc6\u5ea6\u7684\u672a\u914d\u4f4d\u7fa7\u9178\u76d0\u6c27\u539f\u5b50\u548c\u914d\u4f4d\u6c34\u5206\u5b50\uff0c\u53ef\u901a\u8fc7\u591a\u91cd\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u6355\u83b7C2<\/sub>H6<\/sub>\u548cC2<\/sub>H2<\/sub>\u5206\u5b50\u3002Me2<\/sub>NH2<\/sub>+<\/sup>\u5728\u6781\u5316C2<\/sub>H6<\/sub>\u8fdb\u800c\u63d0\u9ad8TJT-100\u5bf9C2<\/sub>H6<\/sub>\u7684\u4eb2\u548c\u529b\u4e2d\u8d77\u5230\u4e86\u91cd\u8981\u4f5c\u7528\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u63d0\u4f9b\u4e86\u4e00\u79cd\u53ef\u4ee5\u4eceC2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>\/C2<\/sub>H6<\/sub>\u7684\u4e09\u5143\u6df7\u5408\u7269\u4e2d\u83b7\u53d6\u9ad8\u7eaf\u5ea6\u7684C2<\/sub>H4<\/sub>\u7684\u65b0\u578b\u6750\u6599\uff0c\u800c\u4e14\u4e3a\u63a2\u7d22\u529f\u80fd\u6c27\u539f\u5b50\u5bf9MOFs\u4e2dC2<\/sub>\u7269\u79cd\u5206\u79bb\u7684\u5f71\u54cd\u63d0\u4f9b\u4e86\u65b0\u7684\u89c1\u89e3\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Simultaneously Trapping C2<\/sub>H2<\/sub> and C2<\/sub>H6<\/sub> into a Robust Metal-Organic Framework from a Ternary Mixture of C2<\/sub>H2<\/sub>\/C2<\/sub>H4<\/sub>\/C2<\/sub>H6<\/sub> forPurification of C2<\/sub>H4<\/sub><\/strong><\/a>(Angew. Chem. Int. Ed.,2018, DOI: 10.1002\/anie.201809884)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u3010\u8096\u6770\u3011<\/strong>\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>cailiaokefu<\/strong>\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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