{"id":157660,"date":"2018-10-31T06:45:32","date_gmt":"2018-10-30T22:45:32","guid":{"rendered":"\/\/m.iemloyee.com\/?p=157660"},"modified":"2018-10-30T15:22:02","modified_gmt":"2018-10-30T07:22:02","slug":"%e5%8d%8e%e5%8d%97%e7%90%86%e5%b7%a5science%e5%ad%90%e5%88%8a%ef%bc%9a%e7%94%b5%e9%a9%b1%e5%8a%a8%e5%88%b6%e5%a4%87%e5%88%9a%e6%80%a7mof%e8%86%9c%e5%ae%9e%e7%8e%b0%e4%b8%99%e7%83%af%e4%b8%99%e7%83%b7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=157660","title":{"rendered":"\u534e\u5357\u7406\u5de5Science\u5b50\u520a\uff1a\u7535\u9a71\u52a8\u5236\u5907\u521a\u6027MOF\u819c\u5b9e\u73b0\u4e19\u70ef\u4e19\u70f7\u9ad8\u6548\u5206\u79bb"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u4e19\u70ef\u662f\u751f\u4ea7\u4f17\u591a\u5316\u5de5\u4ea7\u54c1\u7684\u91cd\u8981\u539f\u6599\uff0c\u7136\u800c\u4e19\u70ef\u901a\u5e38\u4e0e\u4e19\u70f7\u7b49\u6742\u8d28\u5171\u5b58\uff0c\u76ee\u524d\u5de5\u4e1a\u4e0a\u57fa\u4e8e\u7cbe\u998f\u6cd5\u5236\u5907\u9ad8\u7eaf\u5ea6\u4e19\u70ef\u9700\u8981\u6d88\u8017\u5927\u91cf\u80fd\u91cf\u3002\u76f8\u6bd4\u800c\u8a00\uff0c\u819c\u5206\u79bb\u662f\u4e00\u79cd\u66f4\u9ad8\u6548\u8282\u80fd\u7684\u65b9\u6cd5\uff0c\u5176\u53ef\u8282\u7701\u8d85\u8fc780%\u7684\u80fd\u8017\u3002\u5176\u4e2d\uff0c\u591a\u5b54\u819c\u5206\u79bb\u53ef\u4ee5\u57fa\u4e8e\u5206\u5b50\u5c3a\u5bf8\u5dee\u5f02\u5bf9\u6df7\u5408\u7269\u8fdb\u884c\u6709\u6548\u7b5b\u5206\uff0c\u7136\u800c\u4e19\u70ef\u548c\u4e19\u70f7\u7684\u5c3a\u5bf8\u6781\u4e3a\u76f8\u8fd1\uff0c\u5176\u52a8\u529b\u5b66\u76f4\u5f84\u4ec5\u76f8\u5dee0.02\u7eb3\u7c73\uff0c\u5bf9\u5176\u5b9e\u73b0\u9ad8\u6548\u819c\u5206\u79bb\u662f\u4e00\u4e2a\u6781\u5927\u7684\u6311\u6218\u3002ZIF-8\u7684\u6709\u6548\u5b54\u5f84\u4ecb\u4e8e\u4e19\u70ef\u4e19\u70f7\u5206\u5b50\u5c3a\u5bf8\u4e4b\u95f4\uff0c\u7406\u8bba\u4e0a\u53ef\u4ee5\u5b9e\u73b0\u5176\u9ad8\u6548\u5206\u79bb\u3002\u4f46\u662f\u53d7MOF\u6750\u6599\u914d\u4f53\u8f6c\u52a8\u6027\u9650\u5236\uff0c\u4f7f\u5f97\u76ee\u524dZIF-8\u819c\u5bf9\u4e19\u70ef\u4e19\u70f7\u7684\u5206\u79bb\u9009\u62e9\u6027\u4ecd\u4e0d\u591f\u7406\u60f3\uff0c\u96be\u4ee5\u4e00\u6b65\u5f97\u5230\u9ad8\u7eaf\u5ea6\u4ea7\u7269\uff0c\u540c\u65f6ZIF-8\u819c\u7684\u5236\u5907\u65b9\u6cd5\u5927\u591a\u8f83\u4e3a\u7e41\u7410\uff0c\u9650\u5236\u4e86\u5176\u6f5c\u5728\u7684\u5de5\u4e1a\u5e94\u7528\u4ef7\u503c\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u738b\u6d77\u8f89\u6559\u6388\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u57fa\u4e8e\u7535\u5316\u5b66\u8d85\u5feb\u901f\u5408\u6210\u7684\u521a\u6027ZIF-8\u819c\u7684\u601d\u8def\uff0c\u5f97\u5230\u4e86\u6781\u9ad8\u7684\u4e19\u70ef\u4e19\u70f7\u5206\u79bb\u9009\u62e9\u6027\u3002\u8be5\u65b9\u6cd5\u901a\u8fc7\u7535\u6d41\u9a71\u52a8\uff0c\u53ef\u4ee5\u5728\u5341\u51e0\u5206\u949f\u4e4b\u5185\u8d85\u5feb\u901f\u5236\u5907\u51fa\u8fde\u7eed\u65e0\u7f3a\u9677\u7684ZIF-8\u819c\u3002\u7531\u4e8eZIF-8\u6750\u6599\u662f\u4e0d\u5bfc\u7535\u7684\uff0c\u56e0\u6b64\u751f\u6210\u7684ZIF-8\u8584\u819c\u53ef\u4ee5\u963b\u65ad\u57fa\u5e95\u7535\u6d41\u4e0e\u6eb6\u6db2\u7684\u63a5\u89e6\uff0c\u4ece\u800c\u6291\u5236\u819c\u5c42\u7684\u8fdb\u4e00\u6b65\u751f\u957f\uff0c\u6709\u5229\u4e8e\u5236\u5907\u51fa\u8d85\u8584\u7684\u819c\u5c42\uff1b\u800c\u5bf9\u4e8e\u819c\u5c42\u4e2d\u5b58\u5728\u7f3a\u9677\u7684\u5730\u65b9\uff0c\u57fa\u5e95\u7535\u6d41\u4e0e\u6eb6\u6db2\u7684\u63a5\u89e6\u5219\u4e0d\u4f1a\u88ab\u963b\u65ad\uff0c\u56e0\u6b64\u7f3a\u9677\u4f4d\u7f6e\u4f1a\u88ab\u9a71\u52a8\u7ee7\u7eed\u751f\u957f\uff0c\u76f4\u81f3\u4fee\u590d\u5b8c\u6210\uff0c\u6700\u7ec8\u5b9e\u73b0\u7f3a\u9677\u81ea\u4fee\u590d\u7684\u8fc7\u7a0b\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u9ad8ZIF-8\u819c\u7684\u5206\u79bb\u6027\u80fd\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u6291\u5236\u6750\u6599\u67d4\u6027\u7684\u601d\u8def\u3002\u4f20\u7edf\u7684ZIF-8\u914d\u4f53\u5177\u6709\u8f6c\u52a8\u6027\uff0c\u56e0\u6b64\u8f83\u5927\u7684\u5206\u5b50\u4ecd\u53ef\u4ee5\u4ece\u5176\u7a97\u53e3\u4e2d\u7f13\u6162\u901a\u8fc7\uff0c\u4ece\u800c\u96be\u4ee5\u5f97\u5230\u8f83\u9ad8\u7684\u5206\u79bb\u9009\u62e9\u6027\u3002\u5728\u6b64\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u5de7\u5999\u5730\u5229\u7528\u4e86\u7535\u5316\u5b66\u53cd\u5e94\u754c\u9762\u5904\u7684\u539f\u4f4d\u7535\u573a\uff0c\u4f7f\u5f97ZIF-8\u7684\u7ec4\u88c5\u8fc7\u7a0b\u5728\u7535\u573a\u4f5c\u7528\u4e0b\u53d1\u751f\uff0c\u4ece\u800c\u5f97\u5230\u4e00\u79cd\u626d\u66f2\u7684\u76f8\u7ed3\u6784\u3002\u4e0e\u666e\u901a\u76f8\u7ed3\u6784\u76f8\u6bd4\uff0c\u8be5\u626d\u66f2\u7684\u76f8\u7ed3\u6784\u5177\u6709\u66f4\u521a\u6027\u7684\u9aa8\u67b6\u7ed3\u6784\uff0c\u8868\u73b0\u51fa\u66f4\u597d\u7684\u5206\u5b50\u7b5b\u5206\u80fd\u529b\u3002\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u521a\u6027\u76f8ZIF-8\u5bf9\u4e19\u70ef\u4e19\u70f7\u7684\u5206\u79bb\u9009\u62e9\u6027\u662f\u666e\u901a\u67d4\u6027\u76f8\u768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Advances\u4e0a\uff0c\u9898\u4e3a\u201cParalyzed Membrane: Current-Driven Synthesis of a Metal-Organic Framework with Sharpened Propene\/Propane Separation\u201d\u3002\u534e\u5357\u7406\u5de5\u5927\u5b66\u738b\u6d77\u8f89\u6559\u6388\u4e3a\u8bba\u6587\u901a\u8baf\u4f5c\u8005\uff0c\u7814\u7a76\u751f\u5468\u80dc\u3001\u9b4f\u5ae3\u83b9\u7814\u7a76\u5458\u3001\u674e\u7406\u6ce2\u526f\u6559\u6388\u4e3a\u8bba\u6587\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\uff0c\u6c49\u8bfa\u5a01\u5927\u5b66\u7684Caro\u6559\u6388\u4e3a\u8bba\u6587\u7684\u5408\u4f5c\u8005\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p>\u56fe1\u00a0\u5b9e\u9a8c\u88c5\u7f6e\u56fe\u4ee5\u53ca\u5b9e\u9a8c\u8bbe\u8ba1\u601d\u8def\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-157661 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72471-15.png\" alt=\"\" width=\"550\" height=\"406\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72471-15.png 550w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72471-15-300x221.png 300w\" sizes=\"(max-width: 550px) 100vw, 550px\" \/><\/p>\n<p>&nbsp;<\/p>\n<p>\u56fe2\u00a0\u4e0d\u540c\u751f\u957f\u65f6\u95f4\u4e0b\u819c\u5c42\u622a\u9762SEM\u56fe<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-157662 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72472-12.png\" alt=\"\" width=\"330\" height=\"422\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72472-12.png 330w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72472-12-235x300.png 235w\" sizes=\"(max-width: 330px) 100vw, 330px\" 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src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72474-11.png\" alt=\"\" width=\"440\" height=\"420\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72474-11.png 440w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/10\/\u56fe\u72474-11-300x286.png 300w\" sizes=\"(max-width: 440px) 100vw, 440px\" \/><\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u628aMOF\u819c\u5236\u5907\u5de5\u827a\u3001\u8d85\u8584\u539a\u5ea6\u7684\u63a7\u5236\u3001\u7f3a\u9677\u7684\u4fee\u590d\u4ee5\u53ca\u67d4\u6027\u63a7\u5236\u7b49\u591a\u4e2a\u590d\u6742\u6280\u672f\u96be\u9898\u7684\u89e3\u51b3\uff0c\u6574\u5408\u5230\u8017\u65f6\u4ec5\u6570\u5206\u949f\u7684\u4e00\u6b65\u7535\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u4e3a\u819c\u5206\u79bb\u6280\u672f\u7684\u53d1\u5c55\u5e26\u6765\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n<p>\u8bba\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/advances.sciencemag.org\/content\/4\/10\/eaau1393\"><u>http:\/\/advances.sciencemag.org\/content\/4\/10\/eaau1393<\/u><\/a><\/p>\n<p>\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\uff1a\u738b\u6d77\u8f89\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66\u5316\u5b66\u4e0e\u5316\u5de5\u5b66\u9662\u6559\u6388\u30022004\u5e74\u5165\u9009\u5fb7\u56fd\u6d2a\u5821\u5b66\u8005, 2007\u5e74\u5165\u9009\u6559\u80b2\u90e8\u65b0\u4e16\u7eaa\u4f18\u79c0\u4eba\u624d\u8ba1\u5212\uff0c2011\u5e74\u5165\u9009\u5e7f\u4e1c\u7701\u73e0\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\uff0c2012\u5e74\u83b7\u5f97\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\uff0c2015\u5e74\u5165\u9009\u79d1\u6280\u90e8\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\uff0c2016\u5e74\u5165\u9009\u82f1\u56fd\u7687\u5bb6\u5316\u5b66\u4f1aFellow\uff0c2017\u5e74\u5165\u9009\u7b2c\u4e09\u6279\u56fd\u5bb6\u201c\u4e07\u4eba\u8ba1\u5212\u201d\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\uff0c2018\u5e74\u83b7\u8058\u6559\u80b2\u90e8\u957f\u6c5f\u5b66\u8005\u7279\u8058\u6559\u6388\uff0c2018\u5e74\u5165\u9009\u5e7f\u4e1c\u7701\u7279\u652f\u8ba1\u5212\u201c\u6770\u51fa\u4eba\u624d\u201d\u3002\u5728<em><i>Nat. Commun., Sci. Advances, Joule, <\/i><\/em>Angew. Chem. Int. Ed., JACS, Adv. 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