{"id":157631,"date":"2018-11-02T06:30:10","date_gmt":"2018-11-01T22:30:10","guid":{"rendered":"\/\/m.iemloyee.com\/?p=157631"},"modified":"2018-11-01T18:55:32","modified_gmt":"2018-11-01T10:55:32","slug":"%e5%8d%97%e5%bc%80%e5%8d%9c%e6%98%be%e5%92%8c%e5%b8%b8%e6%b3%bdadv-mater-%e5%9f%ba%e4%ba%8e%e6%99%b6%e4%bd%93%e4%b8%bb-%e5%ae%a2%e4%bd%93%e5%b9%b3%e5%8f%b0%e7%90%86%e6%80%a7%e6%9e%84%e7%ad%91","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=157631","title":{"rendered":"\u5357\u5f00\u535c\u663e\u548c&\u5e38\u6cfdAdv. Mater. : \u57fa\u4e8e\u6676\u4f53\u4e3b-\u5ba2\u4f53\u5e73\u53f0\u7406\u6027\u6784\u7b51\u9ad8\u5ea6\u53ef\u8c03\u7ed9\u4f53-\u53d7\u4f53\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\n \u7531\u4e8e\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u5177\u6709\u4f18\u5f02\u7684\u7406\u5316\u6027\u8d28\uff0c\u5176\u5728\u591a\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u53ef\u901a\u8fc7\u6539\u53d8\u6709\u673a\u7ec4\u5206\u76f4\u63a5\u8c03\u8282MOF\u7684\u6676\u4f53\u7ed3\u6784\u3002\u6b64\u5916\uff0c\u5229\u7528\u7ed3\u6784\u660e\u786e\u7684\u591a\u5b54\u6846\u67b6\uff0c\u53ef\u4ee5\u5728\u4f5c\u4e3a\u4e3b\u4f53\u7684MOF\u4e2d\u5b9e\u73b0\u5ba2\u4f53\u7684\u6709\u5e8f\u6392\u5e03\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u7531\u4e8eMOF\u7684\u7ec4\u88c5\u662f\u57fa\u4e8e\u91d1\u5c5e\u79bb\u5b50\u548c\u6709\u673a\u8fde\u63a5\u4f53\u4e4b\u95f4\u7684\u914d\u4f4d\u952e\uff0c\u4e0e\u7eaf\u6709\u673a\u5206\u5b50\u901a\u8fc7\u76f8\u5bf9\u5f31\u7684\u8d85\u5206\u5b50\u76f8\u4e92\u4f5c\u7528\u7684\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u76f8\u6bd4\uff0c\u5176\u7ed3\u6784\u66f4\u52a0\u7a33\u5b9a\uff0c\u66f4\u6613\u5b9e\u73b0\u5b9a\u5411\u6784\u7b51\u3002\u4e0a\u8ff0\u4f18\u70b9\u4f7f\u5f97MOF\u6210\u4e3a\u5236\u5907\u548c\u7cfb\u7edf\u7814\u7a76\u4e3b-\u5ba2\u4f53\u4f53\u7cfb\u7684\u7406\u60f3\u4e3b\u4f53\u5e73\u53f0\u3002
\n \u57fa\u4e8e\u6709\u673a\u7535\u5b50\u7ed9\u4f53(Donor)\u548c\u53d7\u4f53(Acceptor)\u6784\u7b51\u7684\u7ed9-\u53d7\u4f53(Donor-Acceptor\uff0cD-A)\u4f53\u7cfb\u56e0\u5176\u5728\u5149\u7535\u6750\u6599\u7b49\u9886\u57df\u7684\u5e7f\u9614\u5e94\u7528\u524d\u666f\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002D\u3001A\u7ec4\u5206\u95f4\u7684\u7535\u8377\u8f6c\u79fb\u4f5c\u7528\u53ef\u901a\u8fc7\u5bf9\u7ec4\u5206\u7684\u5408\u7406\u9009\u62e9\u548c\u6709\u5e8f\u6392\u5217\u5b9e\u73b0\u3002\u7136\u800c\uff0c\u76ee\u524d\u7edd\u5927\u591a\u6570\u7684\u6676\u6001\u6709\u673aD-A\u6750\u6599\u662f\u901a\u8fc7D\u3001A\u7ec4\u5206\u95f4\u81ea\u7ec4\u88c5\u7ed3\u6676\u6784\u7b51\u7684\u3002\u5728\u81ea\u7ec4\u88c5\u8fc7\u7a0b\u4e2d\uff0c\u7ec4\u5206\u6d53\u5ea6\u3001\u6bd4\u4f8b\u3001\u53cd\u5e94\u6eb6\u5242\u3001\u6e29\u5ea6\u7b49\u8bf8\u591a\u6761\u4ef6\u90fd\u4f1a\u5bf9\u6700\u7ec8\u4ea7\u7269\u7684\u7ec4\u6210\u548c\u7ed3\u6784\u9020\u6210\u5f71\u54cd\uff0c\u589e\u52a0\u5176\u4e0d\u53ef\u9884\u6d4b\u6027\u3002\u56e0\u6b64\uff0c\u5b9e\u73b0\u6709\u673aD-A\u6750\u6599\u7684\u53ef\u63a7\u7ec4\u88c5(\u7ec4\u5206\u53ca\u6392\u5217\u65b9\u5f0f)\u662f\u4e00\u9879\u5177\u6709\u610f\u4e49\u548c\u6311\u6218\u6027\u7684\u5de5\u4f5c\u3002
\n \u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u8bc1\u5b9e\uff0c\u57fa\u4e8e\u7535\u8377\u8f6c\u79fb\u7684\u53d1\u5c04\u53ef\u4ee5\u901a\u8fc7MOF\u5b9e\u73b0\u548c\u8c03\u63a7\u5e76\u7528\u4e8e\u4f20\u611f\u548c\u53d1\u5149\u4f53\u4e2d\u3002\u4e0a\u8ff0\u7ed3\u679c\u8868\u660e\uff0c\u7ed9\u4f53-\u53d7\u4f53\u4f53\u7cfb\u7684\u6784\u7b51\u548c\u8c03\u63a7\u53ef\u4ee5\u5728\u5177\u6709\u9002\u5f53\u7ec4\u5206\u548c\u7ed3\u6784\u7684MOF\u4e2d\u5b9e\u73b0\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong>
\n \u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u535c\u663e\u548c\u6559\u6388\u3001\u5e38\u6cfd\u526f\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u57fa\u4e8e\u6676\u4f53\u4e3b-\u5ba2\u4f53\u5e73\u53f0\u5b9e\u73b0\u4e86\u9ad8\u5ea6\u53ef\u8c03\u7684\u7ed9\u4f53-\u53d7\u4f53\u6750\u6599\u7684\u5408\u7406\u6784\u5efa\uff0c\u5e76\u5728Adv. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cRational Construction of Highly Tunable Donor-Acceptor Materials Based on a Crystalline Host-Guest Platform<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u6587\u4e2d\u62a5\u9053\u7684MOF(NKU-111)\u53ef\u4f5c\u4e3a\u7ed3\u6676\u4e3b\u4f53\u548c\u53d7\u4f53\uff0c\u901a\u8fc7\u76f8\u5bf9\u7a33\u5b9a\u7684\u914d\u4f4d\u5bfc\u5411\u7ec4\u88c5\uff0c\u5728\u6676\u4f53\u4e2d\u5f15\u5165\u5e76\u6392\u5e03\u5ba2\u4f53\u5206\u5b50\u4f5c\u4e3a\u7ed9\u4f53\uff0c\u8fdb\u800c\u5408\u7406\u6784\u7b51\u4e86\u57fa\u4e8eNKU-111\u2283\u5ba2\u4f53\u7684\u7ed9\u4f53-\u53d7\u4f53\u7cfb\u7edf\u3002\u4f53\u7cfb\u4e2d\u7684\u7ed9\u4f53-\u53d7\u4f53\u76f8\u4e92\u4f5c\u7528\u53ef\u901a\u8fc7\u5f15\u5165\u4e0d\u540c\u7684\u5ba2\u4f53\u5206\u5b50\u8c03\u8282\uff0c\u8fd9\u4e00\u70b9\u53ef\u7531\u5ba2\u4f53\u4f9d\u8d56\u7684\u7535\u8377\u8f6c\u79fb\u6027\u8d28\u7279\u5f81\u8bc1\u660e\u3002\u56e0\u6b64\uff0cNKU-111\u2283\u5ba2\u4f53\u663e\u793a\u51fa\u9ad8\u5ea6\u53ef\u8c03\u7684\u7ed9\u4f53-\u53d7\u4f53\u7279\u6027\uff0c\u4f8b\u5982\u57fa\u4e8e\u7535\u8377\u8f6c\u79fb\u7684\u53d1\u5c04\u548c\u7535\u5bfc\u7387\u3002\u8fd9\u9879\u5de5\u4f5c\u663e\u793a\u51fa\u6676\u6001\u4e3b-\u5ba2\u4f53\u4f53\u7cfb\u4f5c\u4e3a\u7cfb\u7edf\u6784\u7b51\u7ed9\u4f53-\u53d7\u4f53\u6750\u6599\u53ca\u7814\u7a76\u76f8\u5e94\u6027\u8d28\u7684\u7406\u60f3\u5e73\u53f0\u7684\u6f5c\u529b\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u5229\u7528\u4e3b-\u5ba2\u4f53MOF\u6676\u4f53\u6784\u7b51\u7ed9\u4f53-\u53d7\u4f53\u7cfb\u7edf\u7b56\u7565<\/strong><\/p>\n

\"\"<\/p>\n

\u5229\u7528\u4e3b-\u5ba2\u4f53MOF\u6676\u4f53\u6784\u7b51\u7ed9\u4f53-\u53d7\u4f53\u7cfb\u7edf\u7b56\u7565\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 NKU-111\u548cNKU-111\u2283\u84bd\u7684\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5355\u4e00\u6846\u67b6\u7ed3\u6784\uff1b
\n b) \u4e09\u91cd\u4e92\u7a7f\u6846\u67b6\u7ed3\u6784\uff1b
\n c) \u72ec\u7acb\u7f51\u7edc\u4e2d\u7684\u4e09\u68f1\u67f1\u5f62\u7b3c\uff1b
\n d) \u4e24\u91cd\u4e92\u7a7f\u7f51\u7edc\u7684\u516d\u68f1\u67f1\u5f62\u7b3c\uff1b
\n e) NKU-111\u6846\u67b6\u5185\u516d\u68f1\u67f1\u5f62\u7b3c\u4e2d\u53ef\u5bb9\u7eb3\u5ba2\u4f53\u7684\u7a7a\u95f4\uff1b
\n f) \u6846\u67b6\u4e2d\u84bd\u5ba2\u4f53\u5206\u5b50\u7684\u72b6\u6001\uff0c\u4e3a\u6e05\u695a\u8d77\u89c1\u7701\u7565\u4e86\u90e8\u5206tpt\u548cPTA\u914d\u4f53\uff0c\u7b3c\u7684\u8303\u5fb7\u534e\u8868\u9762\u5448\u7eff\u8272\u3002<\/p>\n

\u56fe3 NKU-111\u2283\u5ba2\u4f53\u6676\u4f53\u968f\u5ba2\u4f53\u53d8\u5316\u7684\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

NKU-111\u2283\u5ba2\u4f53\u6676\u4f53\u968f\u5ba2\u4f53\u53d8\u5316\u7684\u5149\u5b66(\u4e2d\u95f4)\u548c\u53d1\u5149(\u5e95\u90e8)\u56fe\u50cf\u3002<\/p>\n

\u56fe4 NKU-111\u2283\u5ba2\u4f53\u7684\u5149\u7269\u7406\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

a) NKU-111\u548cNKU-111\u2283\u5ba2\u4f53\u7684\u7d2b\u5916-\u53ef\u89c1\u5149\u8c31\uff1b
\n b) 420 nm\u6fc0\u53d1\u4e0b\u7684NKU-111 \u548cNKU-111\u2283\u5ba2\u4f53\u7684\u5f52\u4e00\u5316\u53d1\u5c04\u5149\u8c31\uff1b
\n c) NKU-111 \u548cNKU-111\u2283\u5ba2\u4f53\u53d1\u5c04\u5149\u8c31\u7684CIE\u8272\u5ea6\u5750\u6807\u3002<\/p>\n

\u56fe5 \u7ed9\u4f53-\u53d7\u4f53\u76f8\u4e92\u4f5c\u7528\u7684\u8c03\u63a7<\/strong><\/p>\n

\"\"<\/p>\n

a) NKU-111\u7684\u53d1\u5c04\u6700\u5927\u503c\u4e0e\u5ba2\u4f53\u7535\u79bb\u7535\u4f4d\u4e4b\u95f4\u7684\u76f8\u5173\u6027\uff0c\u5ba2\u4f53\u9aa8\u67b6\u76f8\u5173\u7684\u7ebf\u6027\u76f8\u5173\u6027\u4ee5\u4e0d\u540c\u989c\u8272\u7684\u7ebf\u5448\u73b0\uff1b
\n b) \u7f3a\u7535\u5b50tpt\u7ed3\u6784\u5355\u5143\u4e0e\u5ba2\u4f53\u84bd(\u5de6)\u548c\u8298(\u53f3)\u4e4b\u95f4\u91cd\u53e0\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u8bc1\u660e\u4e86\u6676\u4f53\u4e3b-\u5ba2\u4f53\u7cfb\u7edf\u662f\u5408\u7406\u6784\u5efa\u7ed9\u4f53-\u53d7\u4f53\u6750\u6599\u7684\u7406\u60f3\u5e73\u53f0\uff0c\u5e76\u57fa\u4e8e\u4e3b-\u5ba2\u4f53MOF\u83b7\u5f97\u4e86\u4e00\u7cfb\u5217\u7ed9\u4f53-\u53d7\u4f53\u6750\u6599\u3002\u5728\u8be5\u4f53\u7cfb\u4e2d\u4e5f\u5b9e\u73b0\u4e86\u5bcc\u7535\u5b50\u548c\u7f3a\u7535\u5b50\u57fa\u56e2\u4e4b\u95f4\u7684\u7ed9\u4f53-\u53d7\u4f53\u76f8\u4e92\u4f5c\u7528\u8c03\u63a7\uff0c\u5e76\u4e14\u5b9e\u73b0\u4e86\u57fa\u4e8e\u7535\u8377\u8f6c\u79fb\u76f8\u5173\u6027\u8d28\u7684\u8c03\u63a7\u3002\u6b64\u5916\uff0c\u8be5\u7cfb\u7edf\u4e2d\u7ed9\u4f53-\u53d7\u4f53\u76f8\u4e92\u4f5c\u7528\u7684\u7cfb\u7edf\u7814\u7a76\u8868\u660e\uff0c\u72ec\u7279\u7684\u5ba2\u4f53\u9aa8\u67b6\u4f9d\u8d56\u6027\u76f8\u4e92\u4f5c\u7528\u8d77\u6e90\u4e8eNKU-111\u7684\u521a\u6027\u6846\u67b6\uff0c\u6709\u5229\u4e8e\u7535\u8377\u8f6c\u79fb\u76f8\u4e92\u4f5c\u7528\u7684\u5408\u7406\u8c03\u63a7\u3002 \u4f5c\u8005\u5728\u6b64\u63d0\u51fa\u7684\u7b56\u7565\u548c\u65b9\u6cd5\u4e3a\u7ed9\u4f53-\u53d7\u4f53\u6750\u6599\u7684\u6027\u80fd\u5bfc\u5411\u6784\u5efa\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aRational Construction of Highly Tunable Donor-Acceptor Materials Based on a Crystalline Host-Guest Platform<\/a> <\/strong>(Adv. Mater.<\/strong>, 2018, DOI: 10.1002\/adma.201804715)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7531\u4e8e\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOFs)\u5177\u6709\u4f18\u5f02\u7684\u7406\u5316\u6027\u8d28\uff0c\u5176\u5728\u591a\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u53ef\u901a\u8fc7\u6539\u53d8\u6709\u673a\u7ec4\u5206\u76f4\u63a5\u8c03\u8282MOF\u7684\u6676\u4f53\u7ed3\u6784\u3002\u6b64\u5916\uff0c\u5229\u7528\u7ed3\u6784\u660e\u786e\u7684\u591a\u5b54\u6846\u67b6\uff0c\u53ef…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3674,2789,3675,3676,3677],"class_list":["post-157631","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-d-a","tag-mofs","tag-3675","tag-3676","tag-3677"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/157631"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=157631"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/157631\/revisions"}],"predecessor-version":[{"id":157963,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/157631\/revisions\/157963"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=157631"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=157631"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=157631"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}