{"id":157136,"date":"2018-11-04T06:58:16","date_gmt":"2018-11-03T22:58:16","guid":{"rendered":"\/\/m.iemloyee.com\/?p=157136"},"modified":"2018-11-03T12:58:54","modified_gmt":"2018-11-03T04:58:54","slug":"%e5%9b%bd%e5%ae%b6%e7%ba%b3%e7%b1%b3%e4%b8%ad%e5%bf%83%e5%94%90%e6%99%ba%e5%8b%87adv-mater-%e7%bb%bc%e8%bf%b0%ef%bc%9a%e7%a3%81%e5%9c%86%e4%ba%8c%e8%89%b2%e8%b0%b1%e5%9c%a8%e7%ba%b3%e7%b1%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=157136","title":{"rendered":"\u56fd\u5bb6\u7eb3\u7c73\u4e2d\u5fc3\u5510\u667a\u52c7Adv. Mater. \u7efc\u8ff0\uff1a\u78c1\u5706\u4e8c\u8272\u8c31\u5728\u7eb3\u7c73\u6750\u6599\u9886\u57df\u7684\u5e94\u7528:\u6df1\u5165\u7406\u89e3\u548c\u8c03\u63a7\u6fc0\u5b50\u548c\u7b49\u79bb\u6fc0\u5143\u5171\u632f\u7684\u65b0\u673a\u9047"},"content":{"rendered":"

\u3010\u524d\u8a00\u3011<\/strong><\/p>\n

\u5706\u4e8c\u8272 (CD)\u662f\u5de6\u65cb\u5706\u504f\u632f(LCP)\u5149\u548c\u53f3\u65cb\u5706\u504f\u632f(RCP)\u5149\u7684\u5438\u6536\u4e4b\u5dee\uff0c\u7531\u4e8e\u6765\u6e90\u4e0d\u540c\uff0c\u53ef\u4ee5\u5206\u4e3a\u5929\u7136CD\u4fe1\u53f7\u548c\u78c1\u6027CD\u4fe1\u53f7\u3002\u5929\u7136CD\u6765\u6e90\u4e8e\u5177\u6709\u624b\u6027\u6216\u87ba\u65cb\u7a7a\u95f4\u5206\u5e03\u7684\u7535\u8377\u5bf9LCP\u548cRCP\u5149\u7684\u5438\u6536\u5dee\u5f02\u3002\u8fd9\u662f\u4e00\u79cd\u7f55\u89c1\u7684\u5149\u5b66\u73b0\u8c61\uff0c\u6765\u6e90\u4e8e\u6ca1\u6709\u955c\u9762\u6216\u5bf9\u79f0\u4e2d\u5fc3\u7684\u7269\u8d28\u3002\u7531\u4e8e\u5bf9\u7edd\u5bf9\u6784\u578b\u7684\u9ad8\u5ea6\u654f\u611f\u6027\uff0c\u5929\u7136CD\u88ab\u5e7f\u6cdb\u7528\u4e8e\u7814\u7a76\u624b\u6027\u5206\u5b50\u548c\u7eb3\u7c73\u6750\u6599\u7684\u6784\u8c61\u53d8\u5316\u3002\u76f8\u53cd\uff0cMCD\u4ea7\u751f\u4e8e\u78c1\u573a\u8bf1\u5bfc\u7684\u7535\u5b50\u7ed3\u6784Zeeman\u76f8\u4e92\u4f5c\u7528\u3002\u5b83\u662f\u7269\u8d28\u5728\u7eb5\u5411\u78c1\u573a\uff08\u4e0e\u5149\u4f20\u64ad\u65b9\u5411\u5e73\u884c\uff09\u4e0b\u7684\u666e\u904d\u7279\u6027\u3002<\/p>\n

MCD\u6280\u672f\u53ef\u4ee5\u8ffd\u6eaf\u52301845\u5e74\u6cd5\u62c9\u7b2c\u6548\u5e94(\u4e5f\u79f0\u4e3a\u78c1\u65cb\u5149\uff0cMOR)\u7684\u53d1\u73b0\u3002\u5728\u7eb5\u5411\u78c1\u573a\u4e0b\uff0cMOR\u6548\u5e94\u8868\u793a\u7269\u8d28\u5bf9LCP\u5149\u548cRCP\u5149\u7684\u6298\u5c04\u7387\u5dee\u5f02\u3002MCD\u54cd\u5e94\u662f\u6cd5\u62c9\u7b2c\u6548\u5e94\u5728\u7535\u5b50\u5438\u6536\u533a\u7684\u8868\u73b0\u3002\u4e0eMOR\u76f8\u6bd4\uff0cMCD\u5df2\u7ecf\u6210\u4e3a\u7814\u7a76\u7535\u5b50\u8dc3\u8fc1\u7684\u4e3b\u8981\u6280\u672f\uff0c\u56e0\u4e3a\u5b83\u6d88\u9664\u4e86\u5149\u8c31\u4eea\u5668\u5149\u5b66\u5143\u4ef6\u4e2d\u53cc\u6298\u5c04\u7f3a\u9677\u7684\u5e72\u6270\u3002\u4ee4\u4eba\u5370\u8c61\u6df1\u523b\u7684\u662f\uff0cMCD\u5c55\u793a\u4e86\u63ed\u793a\u7535\u5b50\u6001\u5bf9\u79f0\u6027\u548c\u7b80\u5e76\u6027\u4fe1\u606f\u7684\u4f18\u52bf\uff0c\u8fd9\u662f\u666e\u901a\u5438\u6536\u5149\u8c31\u65e0\u6cd5\u5b9e\u73b0\u7684\u3002\u81ea20\u4e16\u7eaa60\u5e74\u4ee3\u521d\u4ee5\u6765\uff0cMCD\u5df2\u7ecf\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5206\u5b50\u4f53\u7cfb\uff0c\u5c24\u5176\u5728\u5206\u6790\u91cd\u8981\u751f\u7269\u5206\u5b50\u5982\u91d1\u5c5e\u86cb\u767d\u548c\u535f\u5549\u884d\u751f\u7269\u65b9\u9762\u5177\u6709\u4e0d\u53ef\u66ff\u4ee3\u7684\u4f5c\u7528\u3002\u4e00\u65b9\u9762\uff0c\u901a\u8fc7\u68c0\u6d4b\u7535\u5b50\u6001\u7684\u7b80\u5e76\u72b6\u6001\u7684\u6270\u52a8\uff0cMCD\u53ef\u4ee5\u63a2\u6d4b\u8840\u7ea2\u7d20\u4e2d\u94c1\u539f\u5b50\u7684\u8f74\u5411\u914d\u4f4d\u3001\u81ea\u65cb\u548c\u6c27\u5316\u6001\u7b49\u7684\u7ed3\u6784\u53d8\u5316\u3002\u53e6\u4e00\u65b9\u9762\uff0cMCD\u4e3a\u76d1\u6d4b\u5408\u6210\u535f\u5549\u548c\u915e\u83c1\u7684\u529f\u80fd\u5316\u4fee\u9970\u63d0\u4f9b\u4e86\u6709\u6548\u5de5\u5177\uff0c\u56e0\u4e3a\u4fee\u9970\u9020\u6210\u7684\u7ed3\u6784\u6539\u53d8\u901a\u8fc7\u8c03\u63a7\u53ef\u4ee5\u7535\u5b50\u8dc3\u8fc1\u4ea7\u751fMCD\u6d3b\u6027\u7684\u53d8\u5316\u3002\u4f34\u968f\u7740\u5e7f\u6cdb\u7684\u5b9e\u9a8c\u89c2\u6d4b\uff0c\u6df1\u5165\u7684\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u4e3a\u7406\u89e3\u5206\u5b50\u6c34\u5e73\u7684MCD\u6548\u5e94\u5efa\u7acb\u4e86\u575a\u5b9e\u7684\u57fa\u7840\u3002<\/p>\n

\u5c3d\u7ba1\u5728\u5206\u5b50\u6c34\u5e73\u4e0a\uff0cMCD\u7814\u7a76\u53d6\u5f97\u4e86\u5de8\u5927\u8fdb\u5c55\u548c\u4e30\u7855\u6210\u679c\uff0c\u4f46MCD\u5728\u7eb3\u7c73\u4f53\u7cfb\u4e2d\u7684\u5e94\u7528\u4ecd\u5904\u4e8e\u521d\u7ea7\u9636\u6bb5\u3002\u7eb3\u7c73\u5408\u6210\u6280\u672f\u548c\u7eb3\u7c73\u5236\u9020\u7b56\u7565\u7684\u84ec\u52c3\u53d1\u5c55\u4e3aMCD\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u65b0\u673a\u9047\u3002\u5f97\u76ca\u4e8e\u72ec\u7279\u7684\u5149\u5b66\u7279\u6027\uff0c\u534a\u5bfc\u4f53\u548c\u8d35\u91d1\u5c5e\u7eb3\u7c73\u6750\u6599\u5728\u81ea\u65cb\u7535\u5b50\u5b66\u3001\u592a\u9633\u80fd\u7535\u6c60\u5668\u4ef6\u3001\u53d1\u5149\u4e8c\u6781\u7ba1\u548c\u751f\u7269\u6210\u50cf\/\u4f20\u611f\u7b49\u9886\u57df\u6709\u7740\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\uff0c\u662f\u6781\u5177\u4ee3\u8868\u6027\u7684\u7eb3\u7c73\u5149\u5b66\u6750\u6599\u3002\u7279\u522b\u662f\uff0c\u534a\u5bfc\u4f53\u72ec\u7279\u7684\u91cf\u5b50\u9650\u57df\u6548\u5e94\u548c\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u7684\u5c40\u57df\u8868\u9762\u7b49\u79bb\u6fc0\u5143\u5171\u632f(SPR)\u4f7f\u5176\u663e\u793a\u51fa\u5f3a\u70c8\u7684\u5149\u5b66\u5438\u6536\u6548\u5e94\u3002\u901a\u8fc7\u6210\u5206\u8c03\u6574\u6216\u7ed3\u6784\u8bbe\u8ba1\uff0c\u53ef\u4ee5\u5b9e\u73b0\u8fd9\u79cd\u91cf\u5b50\u5316\u5438\u6536\u7279\u6027\u5728\u7d2b\u5916\u53ef\u89c1\uff08UV-vis\uff09\u8303\u56f4\u5185\u7684\u53ef\u63a7\u8c03\u8282\u3002\u81ea20\u4e16\u7eaa90\u5e74\u4ee3\u521d\u4ee5\u6765\uff0cMCD\u63d0\u4f9b\u4e86\u6df1\u5165\u7406\u89e3\u6fc0\u5b50\u8dc3\u8fc1\u548c\u7b49\u79bb\u6fc0\u5143\u5171\u632f\u7684\u7ed3\u6784\u548c\u7535\u5b50\u6001\u4fe1\u606f\u7684\u6709\u6548\u5de5\u5177\u3002\u5728\u63ba\u6742\u534a\u5bfc\u4f53\u7eb3\u7c73\u6676\u4f53\u4f53\u7cfb\uff0cMCD\u6280\u672f\u80fd\u591f\u76f4\u63a5\u6d4b\u91cfZeeman\u5206\u88c2\u7684\u589e\u5f3a\u6548\u5e94\uff1b\u5bf9\u4e8e\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\uff0cMCD\u6280\u672f\u63ed\u793a\u4e86\u5c40\u57dfSPR\u7684\u5bf9\u79f0\u6027\u8d77\u6e90\uff0c\u4ee5\u4e0a\u4e3a\u8c03\u63a7\u78c1\u5149\u6548\u5e94\u5960\u5b9a\u4e86\u57fa\u7840\u3002\u7136\u800c\uff0c\u9700\u8981\u6307\u51fa\u7684\u662f\uff0c\u5c3d\u7ba1MCD\u5177\u6709\u91cd\u8981\u7684\u5e94\u7528\u4ef7\u503c\uff0c\u7531\u4e8e\u7f3a\u4e4f\u53ca\u65f6\u7684\u603b\u7ed3\uff0c\u76ee\u524d\u7814\u7a76\u4eba\u5458\u5bf9\u4e8eMCD\u6280\u672f\u5728\u7eb3\u7c73\u4f53\u7cfb\u4e2d\u7684\u5e94\u7528\u4ecd\u7f3a\u4e4f\u5e7f\u6cdb\u7684\u8ba4\u77e5\u548c\u7406\u89e3\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u78c1\u6027\u5706\u4e8c\u8272\u8c31( MCD )\u5728\u63ed\u793a\u6750\u6599\u7535\u5b50\u6001\u4fe1\u606f\u65b9\u9762\u5177\u6709\u72ec\u7279\u4f18\u52bf\uff0c\u4e3a\u63a2\u7d22\u7eb3\u7c73\u5149\u5b66\u6750\u6599\u7684\u7ed3\u6784\u548c\u78c1\u5149\u7279\u6027\u4e4b\u95f4\u7684\u5173\u7cfb\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u4f1a\u3002\u8fd1\u65e5\uff0c\u56fd\u5bb6\u7eb3\u7c73\u4e2d\u5fc3\u7684\u5510\u667a\u52c7\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728Advanced Materials<\/strong>\u4e0a\u53d1\u8868\u6587\u7ae0\uff0c\u9898\u4e3a\u201cMagnetic Circular Dichroism in Nanomaterials: New Opportunity in Understanding and Modulation of Excitonic and Plasmonic Resonances<\/strong>\u201d\u3002\u672c\u6587\u7efc\u8ff0\u4e86MCD\u6280\u672f\u5728\u534a\u5bfc\u4f53\u548c\u8d35\u91d1\u5c5e\u7eb3\u7c73\u6750\u6599\u4e2d\u5e94\u7528\u7684\u4ee3\u8868\u6027\u7814\u7a76\u3002MCD\u5728\u9610\u660e\u534a\u5bfc\u4f53\u7eb3\u7c73\u6676\u4f53\u4e2d\u7684\u6fc0\u5b50\u8dc3\u8fc1\u3001\u8d35\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u4e2d\u7684\u7535\u5b50\u8dc3\u8fc1\u4ee5\u53ca\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7ed3\u6784\u4e2d\u7684\u7b49\u79bb\u6fc0\u5143\u5171\u632f\u7684\u7ed3\u6784\u4fe1\u606f\u65b9\u9762\u5177\u6709\u4e0d\u53ef\u53d6\u4ee3\u7684\u4f5c\u7528\u3002\u51ed\u501f\u8fd9\u4e9b\u4f18\u52bf\uff0cMCD\u6280\u672f\u5728\u8bc4\u4f30\u5177\u6709\u4e0d\u540c\u5316\u5b66\u6210\u5206\u3001\u51e0\u4f55\u5f62\u72b6\u3001\u7ec4\u88c5\u6784\u8c61\u548c\u8026\u5408\u6548\u5e94\u7684\u7eb3\u7c73\u6750\u6599\u7684\u6fc0\u5b50\u548c\u7b49\u79bb\u6fc0\u5143\u5149\u5b66\u6d3b\u6027\u7684\u78c1\u8c03\u5236\u65b9\u9762\u663e\u793a\u51fa\u65e0\u53ef\u5339\u654c\u7684\u80fd\u529b\u3002\u4e86\u89e3\u5229\u7528MCD\u6280\u672f\u8c03\u63a7\u7eb3\u7c73\u5c3a\u5ea6\u78c1\u5149\u6548\u5e94\u7684\u5173\u952e\u56e0\u7d20\u5c06\u6781\u5927\u5730\u4fc3\u8fdb\u534a\u5bfc\u4f53\u548c\u8d35\u91d1\u5c5e\u7eb3\u7c73\u6750\u6599\u5728\u4f20\u611f\u3001\u81ea\u65cb\u7535\u5b50\u5b66\u3001\u7eb3\u7c73\u5149\u5b50\u5b66\u7b49\u9886\u57df\u7684\u5e94\u7528\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/p>\n

1.\u89e3\u8bfbMCD\u7406\u8bba\u57fa\u7840<\/p>\n

\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cMCD\u548cUV – vis\u5438\u6536\u5149\u8c31\u90fd\u6765\u81ea\u7535\u5b50\u8dc3\u8fc1\uff0c\u4f46\u662f\u8fd9\u4e24\u79cd\u5149\u8c31\u5177\u6709\u4e0d\u540c\u7684\u7279\u5f81: 1) MCD\u5149\u8c31\u5177\u6709\u9ad8\u5ea6\u53ef\u533a\u5206\u7684\u5bfc\u6570\u6216\u9ad8\u65af\u5f62\u4fe1\u53f7\uff0c\u8868\u660e\u7535\u5b50\u6001\u7684\u7b80\u5e76\u6027\u5dee\u5f02\uff0c\u800cUV – vis\u5438\u6536\u5bf9\u4e8e\u4e0d\u540c\u7684\u8dc3\u8fc1\u6ca1\u6709\u7ebf\u5f62\u5dee\u522b\u3002 2) MCD\u4fe1\u53f7\u662f\u7b26\u53f7\u91cf\uff0c\u5728\u8bc6\u522b\u591a\u4e2a\u91cd\u53e0\u5438\u6536\u5e26\u7684\u7535\u5b50\u6001\u6765\u6e90\u65f6\uff0c\u6bd4\u5438\u6536\u5149\u8c31\u5177\u6709\u66f4\u9ad8\u7684\u5206\u8fa8\u7387\u30023) \u9664\u4e86\u7535\u5076\u6781\u77e9\u4e4b\u5916\uff0cMCD\u5f3a\u5ea6\u8fd8\u5f3a\u8c03\u78c1\u5076\u6781\u77e9\u7684\u8d21\u732e\uff0c\u800c\u7535\u5076\u6781\u77e9\u4e3b\u5bfc\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u3002MCD\u4fe1\u53f7\u53ef\u4ee5\u7b80\u5316\u8868\u793a\u4e3a\u4e09\u7c7b\u4fe1\u53f7\u7684\u52a0\u548c\uff0c\u5982\u56fe1\u6240\u793a\u3002<\/p>\n

\u56fe1. \u673a\u7406\u7b80\u56fe\uff1a<\/p>\n

\"\"a) A, b) B, c) C \uff1b<\/p>\n

2. MCD\u5728\u534a\u5bfc\u4f53\u7eb3\u7c73\u6750\u6599\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

2.1 \u786e\u5b9a\u534a\u5bfc\u4f53\u7eb3\u7c73\u6676\u4f53\u4e2d\u6fc0\u5b50\u7684g<\/em>-\u56e0\u5b50<\/strong><\/p>\n

\u5c3d\u7ba1\u534a\u5bfc\u4f53\u7eb3\u7c73\u6676\u4f53\u5c3a\u5bf8\u7684\u4e0d\u5747\u5300\u5206\u5e03\u5bfc\u81f4\u5149\u8c31\u62d3\u5bbd\uff0c\u4f46MCD\u80fd\u591f\u5728\u975e\u5e38\u4f4e\u7684\u78c1\u573a(<1 T)\u4e0b\u5206\u8fa8\u51fa\u5c0f\u7684\u6fc0\u5b50Zeeman\u5206\u88c2\u3002\u59cb\u4e8e\u901a\u8fc7\u5bf9MCD \u5149\u8c31\u4e2dZeeman\u5206\u88c2\u7684\u5206\u6790\uff0c\u53ef\u4ee5\u76f4\u63a5\u8ba1\u7b97\u7a7a\u7a74\u548c\u6fc0\u5b50\u7684\u78c1\u6027g-\u56e0\u5b50\uff0c\u8fd9\u662fMCD\u6280\u672f\u5728\u534a\u5bfc\u4f53\u7eb3\u7c73\u6750\u6599\u4e2d\u5e94\u7528\u7684\u57fa\u7840\u3002<\/p>\n

\u56fe2. MCD\u5e94\u7528\u5b9e\u4f8b<\/p>\n

\"\"a) Inx<\/sub>Ga1<\/sub>\u2212<\/sub>x<\/sub>As\u91cf\u5b50\u9631\u7684MCD\u5149\u8c31\uff1b<\/p>\n

b)\u8d1f\u5de6\u5bfc\u6570\u578bMCD\u4fe1\u53f7\u6765\u6e90\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

c)\u4e0d\u540c\u78c1\u573a\u4e0b\u76f8\u5173\u8dc3\u8fc1\u7684Zeeman\u5206\u88c2\uff1b<\/p>\n

d)\u6b63\u5de6\u5bfc\u6570\u578bMCD\u4fe1\u53f7\u6765\u6e90\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

2.2. \u7a00\u78c1\u534a\u5bfc\u4f53(DMSs)\u4e2dsp-d\u4ea4\u6362\u4f5c\u7528\u7684\u8868\u5f81<\/strong><\/p>\n

DMSs\u662f\u63ba\u6742\u6709\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u7684\u534a\u5bfc\u4f53\u7eb3\u7c73\u6676\u4f53\uff0c\u4e3b\u8981\u662f\u78c1\u6027\u539f\u5b50\u63ba\u6742\u3002\u8fd9\u7c7b\u6750\u6599\u7531\u4e8e\u5176\u72ec\u7279\u7684\u78c1\u5149\u7279\u6027\uff0c\u901a\u8fc7\u5c06\u78c1\u6027\u5f15\u5165\u534a\u5bfc\u4f53\u7eb3\u7c73\u6676\u4f53\uff0c\u5728\u81ea\u65cb\u7535\u5b50\u5b66\u9886\u57df\u5177\u6709\u5de8\u5927\u7684\u6f5c\u529b\u3002\u5177\u6709\u5f00\u58f3\u5c42\u7684\u78c1\u6027\u63ba\u6742\u539f\u5b50\u4e0e\u975e\u78c1\u6027\u534a\u5bfc\u4f53\u7684\u7ed3\u5408\u5bfc\u81f4\u5c40\u57df\u4e0d\u6210\u5bf9\u7535\u5b50\u81ea\u65cb\u4e0e\u5f1b\u8c6b\u5149\u751f\u7535\u5b50-\u7a7a\u7a74\u5bf9(\u6fc0\u5b50)\u8026\u5408\uff0c\u8fd9\u88ab\u79f0\u4e3asp – d\u4ea4\u6362\u76f8\u4e92\u4f5c\u7528( s-d\u548cp-d\u76f8\u4e92\u4f5c\u7528\u5206\u522b\u8868\u793a\u63ba\u6742\u79bb\u5b50\u4e0e\u7535\u5b50\u548c\u7a7a\u7a74\u7684\u8026\u5408)\u3002<\/p>\n

\u56fe3. \u7a00\u78c1\u534a\u5bfc\u4f53Zeeman\u5206\u88c2\u7684\u4ea7\u751f\u673a\u7406<\/p>\n

\"\"a) \u901a\u5e38\uff0c\u975e\u78c1\u6027\u534a\u5bfc\u4f53\u7684\u7535\u5b50\u80fd\u91cf\u4e0e\u81ea\u65cb\u65b9\u5411\u65e0\u5173\u3002\u4e5f\u5c31\u662f\u8bf4\uff0c\u5177\u6709\u81ea\u65cb\u5411\u4e0a\u6216\u81ea\u65cb\u5411\u4e0b\u72b6\u6001\u7684\u7535\u5b50\u662f\u65e0\u6cd5\u533a\u5206\u7684\uff1b<\/p>\n

b) \u76f8\u53cd\uff0c\u78c1\u6027\u534a\u5bfc\u4f53\u7684s\u548cp\u7535\u5b50\u53d7\u5230\u78c1\u6027\u79bb\u5b50d\u7535\u5b50\u7684\u5f71\u54cd\uff0c\u5bfc\u81f4\u5bfc\u5e26\u548c\u4ef7\u5e26\u4e4b\u95f4\u7684Zeeman\u5206\u88c2\uff1b<\/p>\n

2.3. \u63ed\u793a\u534a\u5bfc\u4f53\u56e2\u7c07\u7684\u7cbe\u7ec6\u7535\u5b50\u7ed3\u6784<\/strong><\/p>\n

\u63ba\u6742\u7684\u5177\u6709magic-size\u7684\u7eb3\u7c73\u56e2\u7c07(\u5c3a\u5bf8\u4ecb\u4e8e\u91cf\u5b50\u70b9\u548c\u5206\u5b50\u4e4b\u95f4\u7684\u5177\u6709\u4e00\u5b9a\u6570\u91cf\u7684\u539f\u5b50\u7ec4\u6210\u7684\u534a\u5bfc\u4f53\u56e2\u7c07)\u7684\u5236\u5907\u5df2\u7ecf\u6210\u4e3a\u4e00\u4e2a\u65b0\u5174\u7684\u8bfe\u9898\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u72ec\u7279\u7684\u78c1\u5149\u529f\u80fd\uff0c\u6709\u53ef\u80fd\u5b9e\u73b0solotronic\u5668\u4ef6\u5728\u9ad8\u7d2b\u5916\u533a\u57df\u7684\u5e94\u7528\u3002\u7ed3\u5408MCD\u5149\u8c31\u548cUV-vis\u5149\u8c31\u53ef\u4ee5\u5bf9\u534a\u5bfc\u4f53\u7eb3\u7c73\u56e2\u7c07\u7684\u7cbe\u7ec6\u7ed3\u6784\u8fdb\u884c\u533a\u5206\u3002<\/p>\n

\u56fe4. Mn2+<\/sup>\u63ba\u6742(CdSe)13<\/sub>\u7c07\u8868\u5f81<\/p>\n

\"\"a) \u57282k\u7684\u4e0d\u540c\u78c1\u573a\u4e0b\uff0c4% Mn2+<\/sup>\u63ba\u6742(CdSe)13<\/sub>\u7c07\u7684\u5438\u6536(\u9876\u90e8)\u548cMCD (\u5e95\u90e8)\u5149\u8c31\u3002\u5438\u6536\u5149\u8c31\u4e2d\u7684\u7eff\u8272\u3001\u7d2b\u8272\u548c\u9ed1\u8272\u865a\u7ebf\u5206\u522b\u4ee3\u8868\u5b9e\u9a8c\u7ed3\u679c\u3001\u78c1\u5149\u6d3b\u6027\u548c\u975e\u6d3b\u6027\u54cd\u5e94\u3002\u7ea2\u8272\u66f2\u7ebf\u5c5e\u4e8e\u78c1\u5149\u6d3b\u6027\u8dc3\u8fc1\u7684\u8d21\u732e\uff1b<\/p>\n

b) \u6839\u636e4% (\u7ea2\u8272) \u548c10% (\u7eff\u8272) Mn2+<\/sup>-\u63ba\u6742(CdSe)13<\/sub>\u7c07\u7684MCD\u5149\u8c31\u8ba1\u7b97\u7684\u5de8\u5927Zeeman\u5206\u88c2\uff1b<\/p>\n

c) 4% Mn2+<\/sup>\u63ba\u6742(CdSe)13<\/sub>\u7c07\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684MCD\u5149\u8c31\uff1b<\/p>\n

d) 4% Mn2+<\/sup>\u63ba\u6742\u7c07\u7684MCD\u54cd\u5e94\u7684\u6700\u5927\u503c\u57286T\u78c1\u573a\u4e0b\u968f\u7740\u6e29\u5ea6\u7684\u53d8\u5316\u8d8b\u52bf\uff0c\u56fe\u4e2d\u9ed1\u8272\u66f2\u7ebf\u4ee3\u8868\u7406\u8bba\u5e03\u91cc\u6e0a\u62df\u5408\uff1b<\/p>\n

3. MCD\u5728\u8d35\u91d1\u5c5e\u7eb3\u7c73\u56e2\u7c07\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

\u91d1\u7eb3\u7c73\u56e2\u7c07\u662f\u4e00\u79cd\u7279\u5b9a\u7c7b\u578b\u7684\u91d1\u7eb3\u7c73\u7c92\u5b50\uff0c\u5176\u5c3a\u5bf8(<2 nm)\u63a5\u8fd1\u8d39\u7c73\u6ce2\u957f\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u4e2d\uff0c\u91d1\u7eb3\u7c73\u56e2\u7c07\u5728\u50ac\u5316\u3001\u7eb3\u7c73\u7535\u5b50\u3001\u836f\u7269\u8f93\u9001\u3001\u751f\u7269\u4f20\u611f\u7b49\u9886\u57df\u7684\u5e94\u7528\u6f5c\u529b\u5de8\u5927\u3002\u5728\u53ef\u89c1\u533a\u57df\u4e2d\uff0c\u91d1\u7eb3\u7c73\u9897\u7c92\u8868\u73b0\u51fa\u57fa\u4e8eSPR\u6548\u5e94\u7684\u5c16\u9510\u4e14\u5206\u79bb\u826f\u597d\u7684\u5438\u6536\u5cf0\u3002\u4e0d\u540c\u7684\u662f\uff0c\u7531\u4e8e\u79bb\u6563\u7684\u7535\u5b50\u8dc3\u8fc1\uff0c\u91d1\u7eb3\u7c73\u56e2\u7c07\u5438\u6536\u5e26\u76f8\u4e92\u91cd\u53e0\uff0c\u96be\u4ee5\u5206\u8fa8\u3002\u4e3a\u4e86\u4fc3\u8fdb\u91d1\u7eb3\u7c73\u56e2\u7c07\u7684\u5e94\u7528\uff0c\u79d1\u5b66\u5bb6\u8bd5\u56fe\u901a\u8fc7\u5206\u6790\u6280\u672f\u548c\u8ba1\u7b97\u65b9\u6cd5\u6765\u52a0\u6df1\u5bf9\u51e0\u4f55\u548c\u7535\u5b50\u7ed3\u6784\u7684\u7406\u89e3\u3002\u800cMCD\u5149\u8c31\u5b66\u63d0\u4f9b\u4e86\u4e86\u89e3\u7535\u5b50\u8dc3\u8fc1\u7684\u8be6\u7ec6\u4fe1\u606f\u7684\u673a\u4f1a\u3002<\/p>\n

\u56fe5. Au25<\/sub>\u56e2\u7c07\u5149\u8c31\u4e0e\u7535\u5b50\u7ed3\u6784<\/p>\n

\"\"<\/p>\n

 <\/p>\n

Au25<\/sub>\u56e2\u7c07\u7684a) \u5438\u6536\u548cb) MCD\u5149\u8c31\u7684\u9ad8\u65af\u62df\u5408\uff1b<\/p>\n

c) Au25<\/sub>(SR)18<\/sub>\u7c07\u7684\u7535\u5b50\u7ed3\u6784\u793a\u610f\u56fe\u3002\u63d2\u56fe\u663e\u793a\u4e86\u7c07\u7684\u6838\u5fc3\u548c\u5916\u58f3( S – Au – S – Au – S )\u72b6\u6001\uff1b<\/p>\n

4. MCD\u5728\u7b49\u79bb\u6fc0\u5143\u7eb3\u7c73\u7ed3\u6784\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

4.1. \u7ed3\u6784-\u78c1\u7b49\u79bb\u6fc0\u5143\u5149\u5b66\u6d3b\u6027\u5173\u7cfb\u7684\u9610\u660e<\/strong><\/p>\n

\u5728\u5206\u5b50\u5c3a\u5ea6\u4e0a\uff0cMCD\u4fe1\u53f7\u7684\u7ebf\u5f62\u5bf9\u76f4\u63a5\u5f71\u54cd\u7535\u5b50\u80fd\u7ea7\u7b80\u5e76\u6027\u7684\u51e0\u4f55\u53d8\u5316\u975e\u5e38\u654f\u611f\u3002\u6700\u8fd1\uff0c\u5bf9\u5177\u6709\u72ec\u7279SPR\u7279\u6027\u7684\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u7684MCD\u7814\u7a76\u8868\u660e\uff0c\u7eb3\u7c73\u5c3a\u5ea6\u7684MCD\u6d3b\u6027\u6e90\u81ea\u76f8\u540c\u7684\u5bf9\u79f0\u539f\u7406\u3002<\/p>\n

\u56fe6. \u91d1\u7eb3\u7c73\u68d2\u7684MCD\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u5206\u6563\u7684\u91d1\u7eb3\u7c73\u68d2\u7684a) MCD\u5149\u8c31\u548cb) \u5438\u6536\u5149\u8c31\uff1b<\/p>\n

c) \u91d1\u7eb3\u7c73\u68d2\u7684\u77ed\u8f74SPR\u548c\u957f\u8f74SPR\u6a21\u5f0f\u7684\u5bf9\u79f0\u6027\u793a\u610f\u56fe\uff1b<\/p>\n

d) \u957f\u5f84\u6bd4\u548c\u7ec4\u88c5\u6784\u8c61\u8c03\u63a7\u5bfc\u81f4\u7684\u91d1\u7eb3\u7c73\u68d2\u4f53\u7cfb\u7ed3\u6784\u56e0\u5b50\u5bf9\u78c1\u7b49\u79bb\u6fc0\u5143CD\u4fe1\u53f7\u7684\u4f5c\u7528\uff1b<\/p>\n

4.2. \u8868\u5f81\u5206\u5b50-\u8d35\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u6742\u5316\u4f53\u7cfb\u4e2d\u7684\u6fc0\u5b50-\u7b49\u79bb\u6fc0\u5143\u8026\u5408\u4f5c\u7528<\/strong><\/p>\n

\u56fe7. Au@Ag\u6838-\u58f3\u7eb3\u7c73\u68d2MCD\u5149\u8c31<\/strong><\/p>\n

\"\"a) \u82b1\u9752\u67d3\u6599JC1\u7684\u5438\u6536\u5149\u8c31(\u63d2\u56fe\u663e\u793a\u4e86JC1\u67d3\u6599\u7684\u5206\u5b50\u7ed3\u6784\u4ee5\u53caJ\u805a\u96c6\u4f53\u7684\u6fc0\u5b50\u793a\u610f\u56fe)\uff1b<\/p>\n

b)\u4e0d\u540c\u957f\u5f84\u6bd4\u7684\u6838-\u58f3\u7ed3\u6784Au@Ag\u7eb3\u7c73\u68d2\u7684\u5b9e\u9a8c(\u5b9e\u7ebf)\u548c\u7406\u8bba(\u865a\u7ebf)\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

c) Au@Ag\u6838-\u58f3\u7eb3\u7c73\u68d2\/J-\u805a\u96c6\u4f53\u6742\u5316\u7ed3\u6784\u7684MCD\u5149\u8c31\uff1b<\/p>\n

d)\u7531\u4e8eJ\u805a\u96c6\u4f53\u6fc0\u5b50\u548c\u7eb3\u7c73\u68d2\u7b49\u79bb\u6fc0\u5143\u4e4b\u95f4\u7684\u8026\u5408\u4f5c\u7528\u800c\u4ea7\u751f\u7684\u4e0a\/\u4e0b\u6fc0\u53d1\u6001\u7684\u793a\u610f\u56fe(\u63d2\u56fe\u663e\u793a\u4e86J\u805a\u96c6\u4f53\u7684\u5206\u5b50\u7ed3\u6784)\uff1b<\/p>\n

e)\u6742\u5316\u7ed3\u6784\u4e0e\u6838-\u58f3\u7ed3\u6784Au@Ag\u7eb3\u7c73\u68d2\u5728\u4e0a(\u7ea2\u65b9\u5f62)\/\u4e0b(\u84dd\u65b9\u5f62)\u6fc0\u53d1\u6001\u4f4d\u7f6e\u7684MCD\u5f3a\u5ea6\u6bd4\u968f\u6fc0\u5b50\u548c\u7b49\u79bb\u6fc0\u5143\u4e4b\u95f4\u80fd\u91cf\u5dee\u7684\u53d8\u5316\u8d8b\u52bf\u3002<\/p>\n

\u3010\u603b\u7ed3\u3011<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aMagnetic Circular Dichroism in Nanomaterials: New Opportunity in Understanding and Modulation of Excitonic and Plasmonic Resonances<\/a>, (Advanced Materials, 2018, DOI: 10.1002\/adma.201801491)<\/p>\n

\u3010\u4eba\u7269\u7b80\u4ecb\u3011<\/p>\n

\u5510\u667a\u52c7\uff0c2000\u5e74\u5728\u4e2d\u56fd\u79d1\u5b66\u9662\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240\u83b7\u7406\u5b66\u535a\u58eb\u5b66\u4f4d\uff0c\u6307\u5bfc\u8001\u5e08\u4e3a\u6c6a\u5c14\u5eb7\u9662\u58eb\u30022000-2001\u5e74\uff0c2001-2006\u5e74\u5206\u522b\u5728\u745e\u58eb\u82cf\u9ece\u4e16\u8054\u90a6\u9ad8\u7b49\u5de5\u4e1a\u5b66\u9662Prins\u6559\u6388\u7814\u7a76\u5c0f\u7ec4\u548c\u7f8e\u56fd\u5bc6\u6b47\u6839\u5927\u5b66Kotov\u6559\u6388\u7814\u7a76\u5c0f\u7ec4\u4ece\u4e8b\u7eb3\u7c73\u6750\u6599\u7684\u7814\u7a76\u5de5\u4f5c\u30022006\u5e7411\u6708\u5165\u9009\u4e2d\u56fd\u79d1\u5b66\u9662\u201c\u767e\u4eba\u8ba1\u5212\u201d\uff0c\u52a0\u5165\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u3002\u73b0\u4efb\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u7814\u7a76\u5458\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u56fd\u5bb6\u7eb3\u7c73\u79d1\u5b66\u4e2d\u5fc3\u526f\u4e3b\u4efb\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7eb3\u7c73\u7cfb\u7edf\u4e0e\u591a\u7ea7\u6b21\u5236\u9020\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e3b\u4efb\u3002\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u8005\uff0c\u79d1\u6280\u90e8\u7eb3\u7c73\u91cd\u5927\u7814\u7a76\u8ba1\u5212\u9879\u76ee\u9996\u5e2d\u79d1\u5b66\u5bb6\uff0c\u79d1\u6280\u90e8\u4e2d\u9752\u5e74\u79d1\u6280\u521b\u65b0\u9886\u519b\u4eba\u624d\u5165\u9009\u8005\u3002\u62c5\u4efbMaterials Today Energy \u526f\u4e3b\u7f16\uff0cNanoscale Horizons\u548cAdvanced Sustainable Systems\u7f16\u59d4\uff0cChem, Nano Research, Small, ChemPhysChem, Chemistry-An Asian Journal, Nanoscale, NPG Asia Materials\u987e\u95ee\u7f16\u59d4\u3002\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u4e3a\u529f\u80fd\u7eb3\u7c73\u6750\u6599\u7684\u8bbe\u8ba1\u548c\u7ec4\u88c5\u53ca\u5176\u5728\u624b\u6027\u5149\u5b66\u548c\u80fd\u6e90\u50ac\u5316\u9886\u57df\u7684\u5e94\u7528\u3002\u5171\u53d1\u8868\u5b66\u672f\u8bba\u6587200\u4f59\u7bc7\uff0c\u5176\u4e2d\u5728\u5f71\u54cd\u56e0\u5b50\u5927\u4e8e10\u7684\u5b66\u672f\u671f\u520a\u4e0a\u5982Nature\u3001Nature Nanotechnology\u7b49\u53d1\u8868\u8bba\u658760\u4f59\u7bc7\uff0c\u622a\u81f32017\u5e749\u6708\uff0c\u53d1\u8868\u7684\u7814\u7a76\u8bba\u6587\u5171\u88ab\u5f15\u752815680\u6b21\uff0cH-index\u4e3a66\u3002\u5148\u540e\u627f\u62c5\u4e2d\u56fd\u79d1\u5b66\u9662\u201c\u767e\u4eba\u8ba1\u5212\u201d\u3001\u79d1\u6280\u90e8863\u8ba1\u5212\u4e13\u9898\u3001\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u3001973\u8ba1\u5212\u7b49\u9879\u76ee\uff0c\u5e76\u5165\u9009\u201c\u65b0\u4e16\u7eaa\u767e\u5343\u4e07\u4eba\u624d\u5de5\u7a0b\u56fd\u5bb6\u7ea7\u4eba\u9009\u201d\uff0c\u83b7\u7b2c\u5341\u4e00\u5c4a\u201c\u4e2d\u56fd\u79d1\u5b66\u9662\u6770\u51fa\u9752\u5e74\u201d\u8363\u8a89\u79f0\u53f7\uff0c\u83b7\u56fd\u52a1\u9662\u201c\u653f\u5e9c\u7279\u6b8a\u6d25\u8d34\u201d\uff0c2015\u5e74\u83b7\u5317\u4eac\u5e02\u79d1\u5b66\u6280\u672f\u8fdb\u6b65\u4e8c\u7b49\u5956\uff08\u7b2c\u4e00\u5b8c\u6210\u4eba\uff09\u3002<\/p>\n

\u3010\u76f8\u5173\u4f18\u8d28\u6587\u732e\u63a8\u8350\u3011<\/p>\n

1\u00a0\u00a0\u00a0\u00a0 Han, B.; Gao, X. Q.; Shi, L.; Zheng, Y. L.; Hou, K.; Lv, J. W.; Guo, J.; Zhang, W.; Tang, Z. Y.<\/strong> Geometry-modulated magnetoplasmonic optical activity of au nanorod-based nanostructures. Nano Lett<\/em> 2017<\/strong>, 17<\/em>, 6083-6089, 10.1021\/acs.nanolett.7b02583.<\/p>\n

2\u00a0\u00a0\u00a0\u00a0 Gao, X. Q.; Zhang, X. W.; Deng, K.; Han, B.; Zhao, L. Y.; Wu, M. H.; Shi, L.; Lv, J. W.; Tang, Z. Y.<\/strong> Excitonic circular dichroism of chiral quantum rods. J. Am. Chem. Soc.<\/em> 2017<\/strong>, 139<\/em>, 8734-8739, 10.1021\/jacs.7b04224.<\/p>\n

3\u00a0\u00a0\u00a0\u00a0 Zhu, Y. F.; Wang, H.; Wan, K. W.; Guo, J.; He, C. T.; Yu, Y.; Zhao, L. Y.; Zhang, Y.; Lv, J. W.; Shi, L.; Jin, R. X.; Zhang, X. X.; Shi, X. H.; Tang, Z. Y.<\/strong> Enantioseparation of Au20<\/sub>(PP3<\/sub>)4<\/sub>Cl4<\/sub> clusters with intrinsically chiral cores. Angew. Chem. Int. Ed.<\/em> 2018<\/strong>, 57<\/em>, 9059-9063, 10.1002\/anie.201805695.<\/p>\n

4\u00a0\u00a0\u00a0\u00a0 Shi, L.; Zhu, L. Y.; Guo, J.; Zhang, L. J.; Shi, Y. N.; Zhang, Y.; Hou, K.; Zheng, Y. L.; Zhu, Y. F.; Lv, J. W.; Liu, S. Q.; Tang, Z. Y.<\/strong> Self-assembly of chiral gold clusters into crystalline nanocubes of exceptional optical activity. Angew. Chem. Int. Ed.<\/em> 2017<\/strong>, 56<\/em>, 15397-15401, 10.1002\/anie.201709827.<\/p>\n

5\u00a0\u00a0\u00a0\u00a0 Lv, J. W.; Hou, K.; Ding, D. F.; Wang, D. W.; Han, B.; Gao, X. Q.; Zhao, M.; Shi, L.; Guo, J.; Zheng, Y. L.; Zhang, X.; Lu, C. G.; Huang, L.; Huang, W.; Tang, Z. Y.<\/strong> Gold nanowire chiral ultrathin films with ultrastrong and broadband optical activity. Angew. Chem. Int. Ed.<\/em> 2017<\/strong>, 56<\/em>, 5055-5060, 10.1002\/anie.201701512.<\/p>\n

6\u00a0\u00a0\u00a0\u00a0 Han, B.; Zhu, Z. N.; Li, Z. T.; Zhang, W.; Tang, Z. Y.<\/strong> Conformation modulated optical activity enhancement in chiral cysteine and au nanorod assemblies. J. Am. Chem. Soc.<\/em> 2014<\/strong>, 136<\/em>, 16104-16107, 10.1021\/ja506790w.<\/p>\n

7\u00a0\u00a0\u00a0\u00a0 Zhu, Z. N.; Guo, J.; Liu, W. J.; Li, Z. T.; Han, B.; Zhang, W.; Tang, Z. Y.<\/strong> Controllable optical activity of gold nanorod and chiral quantum dot assemblies. Angew. Chem. Int. Ed.<\/em> 2013<\/strong>, 52<\/em>, 13571-13575, 10.1002\/anie.201305389.<\/p>\n

8\u00a0\u00a0\u00a0\u00a0 Liu, W. J.; Zhu, Z. N.; Deng, K.; Li, Z. T.; Zhou, Y. L.; Qu, H. B.; Gao, Y.; Che, S. N.; Tang, Z. Y.<\/strong> Gold nanorod@chiral mesoporous silica core-shell nanoparticles with unique optical properties. J. Am. Chem. Soc. <\/em>2013<\/strong>, 135<\/em>, 9659-9664, 10.1021\/ja312327m.<\/p>\n

9\u00a0\u00a0\u00a0\u00a0 Zhu, Z. N.; Liu, W. J.; Li, Z. T.; Han, B.; Zhou, Y. L.; Gao, Y.; Tang, Z. Y.<\/strong> Manipulation of collective optical activity in one-dimensional plasmonic assembly. ACS Nano<\/em> 2012<\/strong>, 6<\/em>, 2326-2332, 10.1021\/nn2044802.<\/p>\n

10\u00a0\u00a0 Li, Z. T.; Zhu, Z. N.; Liu, W. J.; Zhou, Y. L.; Han, B.; Gao, Y.; Tang, Z. Y.<\/strong> Reversible plasmonic circular dichroism of Au nanorod and DNA assemblies. J. Am. Chem. Soc.<\/em> 2012<\/strong>, 134<\/em>, 3322-3325, 10.1021\/ja209981n.<\/p>\n

11\u00a0\u00a0 Zhou, Y.; Zhu, Z.; Huang, W.; Liu, W.; Wu, S.; Liu, X.; Gao, Y.; Zhang, W.; Tang, Z. Y.<\/strong> Optical coupling between chiral biomolecules and semiconductor nanoparticles: Size-dependent circular dichroism absorption. Angew. Chem. Int. Ed.<\/em> 2011<\/strong>, 50<\/em>, 11456-11459, 10.1002\/anie.201103762.<\/p>\n

12\u00a0\u00a0 Zhou, Y. L.; Yang, M.; Sun, K.; Tang, Z. Y.<\/strong>; Kotov, N. A. Similar topological origin of chiral centers in organic and nanoscale inorganic structures: Effect of stabilizer chirality on optical isomerism and growth of cdte nanocrystals. J. Am. Chem. Soc.<\/em> 2010<\/strong>, 132<\/em>, 6006-6013, 10.1021\/ja906894r.<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u8ba1\u7b97\u7ec4Z,Chen<\/b><\/strong>\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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