{"id":157106,"date":"2018-10-27T06:30:37","date_gmt":"2018-10-26T22:30:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=157106"},"modified":"2018-10-26T21:13:40","modified_gmt":"2018-10-26T13:13:40","slug":"acs-energy-lett-%e7%94%a8%e4%ba%8e%e6%9c%aa%e6%9d%a5%e4%bb%a5%e5%8f%91%e5%85%89%e4%ba%8c%e6%9e%81%e7%ae%a1%e4%b8%ba%e5%85%89%e6%ba%90%e7%9a%84%e9%ab%98%e8%be%90%e5%b0%84%e9%80%9a%e9%87%8f%e8%b6%85","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=157106","title":{"rendered":"ACS Energy Lett: \u7528\u4e8e\u672a\u6765\u4ee5\u53d1\u5149\u4e8c\u6781\u7ba1\u4e3a\u5149\u6e90\u7684\u9ad8\u8f90\u5c04\u901a\u91cf\u8d85\u5bbd\u8fd1\u7ea2\u5916\u8367\u5149\u7c89"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u7ea2\u5916\uff08NIR\uff09\u5149\u6e90\u662f\u6ce2\u957f\u8303\u56f4\u5728650-1400nm\u7684\u90e8\u5206\u5149\uff0c\u5904\u4e8e\u7535\u78c1\u5149\u8c31\u7684\u53ef\u89c1\u5149\u548c\u7ea2\u5916\u533a\u57df\u4e4b\u95f4\u3002\u8fd1\u7ea2\u5916\u5149\u8c31\u4f7f\u7528\u8fd1\u7ea2\u5916\u5149\u4f5c\u4e3a\u98df\u54c1\u52a0\u5de5\u4e1a\u7684\u5b9e\u65f6\u76d1\u6d4b\u5206\u6790\u548c\u65e0\u635f\u5de5\u5177\u3002\u8fd1\u7ea2\u5916\u5149\u53ef\u65e0\u635f\u5bb3\u5730\u6df1\u5165\u4eba\u4f53\u751f\u7269\u7ec4\u7ec7\uff0c\u5177\u6709\u9ad8\u8870\u51cf\u6027\u8d28\u3002\u5c31\u533a\u522b\u80bf\u7624\u7ec4\u7ec7\u548c\u63d0\u4f9b\u751f\u7269\u7ec4\u7ec7\u4fe1\u606f\u800c\u8a00\uff0c\u4eba\u4f53\u4e2d\u6709\u8272\u5316\u5408\u7269\u548c\u7ec4\u7ec7\u7684\u7279\u5f81\u5438\u6536\u6216\u6563\u5c04\u63d0\u4f9b\u4e86\u65e0\u521b\u65e0\u635f\u4f24\u6d4b\u8bd5\u7684\u53ef\u80fd\u3002\u9002\u7528\u4e8e\u7ea2\u5916\u5149\u6e90\u7684\u5546\u4e1a\u5149\u6e90\uff0c\u7279\u522b\u662f\uff0c\u5364\u94a8\u706f\u3001\u6fc0\u5149\u4e8c\u6781\u7ba1\u548c\u8d85\u8fde\u7eed\u6fc0\u5149\u5668\u90fd\u6709\u51e0\u4e2a\u7f3a\u70b9\uff0c\u5305\u62ec\u5149\u8c31\u7a33\u5b9a\u6027\u4e0d\u7a33\u5b9a\u3001\u53d1\u5c04\u5149\u8c31\u7a84\u3001\u8f83\u9ad8\u7684\u7535\u6d88\u8017\uff0c\u6bd4\u53d1\u5149\u4e8c\u6781\u7ba1\uff08LED\uff09\u77ed\u7684\u5bff\u547d\uff0c\u5927\u91cf\u7684\u70ed\u91cf\u751f\u6210\u7b49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u7ea2\u5916\u5149\u6e90\u6709\u671b\u7528\u4e8e\u98df\u7269\u5206\u6790\u3001\u5065\u5eb7\u76d1\u6d4b\u3001\u8679\u819c\u8bc6\u522b\u548c\u7ea2\u5916\u7ebf\u62cd\u6444\u7b49\u5b9e\u65f6\u65e0\u635f\u68c0\u6d4b\u5e94\u7528\u3002\u7531\u4e8e\u98df\u54c1\u548c\u4eba\u4f53\u4e2d\u7684\u6709\u673a\u5143\u7d20\u5728\u84dd\u5149\u548c\u8fd1\u7ea2\u5916\u533a\u57df\u6709\u5bbd\u7684\u5438\u6536\u548c\u53cd\u5c04\uff0c\u56e0\u6b64\uff0c\u7ea2\u5916\u5149\u6e90\u7684\u53d1\u5c04\u8c31\u5e94\u5c3d\u53ef\u80fd\u7684\u5bbd\u3002\u8fd1\u65e5\uff0c\u53f0\u6e7e\u5927\u5b66<\/strong>\u7684\u5218\u5982\u71b9\u6559\u6388\u3001<\/strong>\u53f0\u5317\u79d1\u6280\u5927\u5b66<\/strong>\u7684\u5f20\u5408\u6559\u6388\u4e0e<\/strong>\u53f0\u6e7e\u5e08\u8303\u5927\u5b66<\/strong>\u7684\u80e1\u6dd1\u82ac\u6559\u6388<\/strong>\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09\u5408\u4f5c\u5728ACS Energy Letters<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cSuper Broadband Near-Infrared Phosphors with High Radiant Flux as Future Light Sources for Spectroscopy Applications<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u5de5\u4f5c\u7528\u84dd\u8272LED\u6fc0\u53d1\u8d85\u5bbd\u5e26\u7684NIR\u8367\u5149\u7c89\u00a0\u00a0\u00a0 (La3<\/sub>Ga5(1-x<\/em>)<\/sub>GeO14<\/sub>:5x<\/em>Cr3+<\/sup>)\u6765\u83b7\u5f97NIR\u5149\u6e90\uff0c\u9996\u6b21\u83b7\u5f97\u4e86\u5bbd\u8fbe330nm\u7684\u534a\u5cf0\u5bbd\u548c\u9ad8\u8fbe18.2mW\u7684\u8f90\u5c04\u901a\u91cf\u3002\u901a\u8fc7\u7535\u5b50\u987a\u78c1\u5171\u632f\u3001X\u5c04\u7ebf\u5438\u6536\u8fd1\u8fb9\u7ed3\u6784\u3001\u7a33\u6001\u5149\u8c31\u4ee5\u53ca\u5e38\u538b\u548c\u9ad8\u538b\u73af\u5883\u4e0b\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u8868\u5f81\uff0c\u7ed3\u679c\u8868\u660e\u8d85\u5bbd\u53d1\u5149\u6765\u6e90\u4e8e\u4e24\u4e2a\u4e0d\u540c\u7684\u53d1\u5149\u4e2d\u5fc3\u3002\u6700\u540e\uff0c\u901a\u8fc7\u5f62\u4f4d\u5750\u6807\u56fe\u63a2\u8ba8\u4e86\u53d1\u5149\u673a\u7406\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\uff1a\u6837\u54c1\u7cbe\u7ec6\u7ed3\u6784\u8868\u5f81\u3002<\/p>\n

\"\"<\/p>\n

(a) La3<\/sub>Ga5(1-x)<\/sub>GeO14<\/sub>: 5xCr3+<\/sup>\u7684XRD\u5149\u8c31\uff1b<\/p>\n

(b) La3<\/sub>Ga4.95<\/sub>GeO14<\/sub>:0.05Cr3+<\/sup>\u7684Rietveld\u7cbe\u7ec6\u5316\u56fe\u50cf\uff1b<\/p>\n

(c) La3<\/sub>Ga4.95<\/sub>GeO14<\/sub>:0.05Cr3+<\/sup>\u5e26\u6709\u9009\u533a\u884d\u5c04\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

(d) La3<\/sub>Ga4.95<\/sub>GeO14<\/sub>:0.05Cr3+<\/sup>\u7684XANES\u5149\u8c31\uff1b<\/p>\n

(e) La3<\/sub>Ga4.95<\/sub>GeO14<\/sub>:0.05Cr3+<\/sup>\u4e2d\u516b\u9762\u4f53(1)\u548c\u56db\u9762\u4f53(2)Cr\u4e2d\u5fc3\u7684EPR\u5b9e\u9a8c\u548c\u6a21\u62df\u5149\u8c31\u3002<\/p>\n

 <\/p>\n

\u56fe2\uff1a\u6837\u54c1\u5149\u81f4\u53d1\u5149\u5149\u8c31\u3002<\/p>\n

\"\"<\/p>\n

(a)La3<\/sub>Ga4.95<\/sub>GeO14<\/sub>: 0.05Cr3+<\/sup>\u7684\u5149\u81f4\u53d1\u5149\u5149\u8c31\uff1b<\/p>\n

(b)La3<\/sub>Ga4.95<\/sub>GeO14<\/sub>: 0.05Cr3+<\/sup>\u7684\u6e29\u5ea6\u76f8\u5173\u7684\u5149\u81f4\u53d1\u5149\u5149\u8c31\u3002<\/p>\n

 <\/p>\n

\u56fe3\uff1a\u6837\u54c1\u7684\u65f6\u95f4\u5206\u8fa8\u53d1\u5149\u5149\u8c31\u3002<\/p>\n

\"\"<\/p>\n

(a)\u6e29\u5ea6\u4e3a10K\u65f6\uff0c\u65f6\u95f4\u8303\u56f4\u57280-10ms\u7684\u65f6\u95f4\u5206\u8fa8\u53d1\u5149\u5149\u8c31\uff1b<\/p>\n

(b)\u6e29\u5ea6\u4e3a300K\u65f6\uff0c\u65f6\u95f4\u8303\u56f4\u57280-10ms\u7684\u65f6\u95f4\u5206\u8fa8\u53d1\u5149\u5149\u8c31\uff1b<\/p>\n

(c)La3<\/sub>Ga95<\/sub>GeO14<\/sub>:0.05Cr3+<\/sup>\u4e2dCr1\u7684\u65f6\u95f4\u8870\u51cf\u66f2\u7ebf\uff1b<\/p>\n

(d)La3<\/sub>Ga95<\/sub>GeO14<\/sub>:0.05Cr3+<\/sup>\u4e2dCr2\u7684\u65f6\u95f4\u8870\u51cf\u66f2\u7ebf\u3002<\/p>\n

 <\/p>\n

\u56fe4\uff1aLa3<\/sub>Ga4.95<\/sub>GeO14<\/sub>:0.05Cr3+<\/sup>\u7684\u53d1\u5149\u4e8c\u6781\u7ba1\u5c01\u88c5\u7ed3\u679c\u3002<\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4e0a\u8ff0\u5de5\u4f5c\u4e3a\u8bbe\u8ba1\u5177\u6709\u6e05\u6670\u80cc\u666f\u7684\u5bbd\u5e26\u8fd1\u7ea2\u5916\u8367\u5149\u6750\u6599\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002\u6709\u5e0c\u671b\u6fc0\u52b1\u66f4\u591a\u7814\u7a76\u4eba\u5458\u53d1\u5c55\u53ef\u7528\u4e8e\u8d85\u5bbd\u8fd1\u7ea2\u5916\u8367\u5149\u5149\u6e90\u7684\u5176\u4ed6\u8367\u5149\u7c89\u7cfb\u7edf\uff0c\u7279\u522b\u662f\u901a\u8fc7\u57fa\u8d28\u7684\u5316\u5b66\u8c03\u63a7\u5b9e\u73b0\u66f4\u9ad8\u6548\u7684\u53d1\u5149\uff0c\u83b7\u5f97\u66f4\u9ad8\u7684\u8f90\u5c04\u901a\u91cf\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aSuper Broadband Near-Infrared Phosphors with High Radiant Flux as Future Light Sources for Spectroscopy Applications<\/a> (ACS Energy Lett, 2018, DOI\uff1a10.1021\/acsenergylett.8b01643)<\/p>\n

\u3010\u56e2\u961f\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u53f0\u6e7e\u5927\u5b66\u5316\u5b66\u7cfb\u5218\u5982\u71b9\u6559\u6388\u6240\u9886\u5bfc\u4e4b\u7814\u7a76\u5c0f\u7ec4\uff0c\u5176\u4e3b\u8981\u4ee5\u6750\u6599\u5316\u5b66\u6838\u5fc3\u6280\u672f\u4e3a\u57fa\u7840\uff0c\u53d1\u5c55\u5177\u53ef\u5e94\u7528\u5728\u5149\u8f6c\u6362\u4e3a\u5149\u3001\u7535\u4e0e\u70ed\u4e4b\u65b0\u6750\u6599\uff0c\u5176\u5c06\u5206\u522b\u5e94\u7528\u5728\u5149\u7535\u3001\u80fd\u6e90\u4e0e\u751f\u533b(\u5982\u56fe5\u6240\u793a)\u3002\u5176\u56e2\u961f\u4e4b\u7814\u7a76\u517c\u987e\u57fa\u7840\u4e0e\u5b9e\u9645\u5e94\u7528\uff0c\u9664\u56fd\u9645\u4e0a\u91cd\u8981\u671f\u520a\u5982Nature Commu<\/em>\u3001<\/em>ACS Energy Lett<\/em>, Angew. Chem. It. Edit.<\/em>\u3001<\/em>J. Am. Chem. Soc.<\/em>\u3001<\/em>Chem. Mater.<\/em>\u7b49\u53d1\u8868\u591a\u7bc7\u91cd\u8981\u8457\u4f5c\u5916\uff0c\u5e76\u5df2\u83b7100\u4ef6\u4ee5\u4e0a\u4e4b\u4e13\u5229\u3002<\/p>\n

\u56fe5\uff1a\u53f0\u6e7e\u5927\u5b66\u5316\u5b66\u7cfb\u5218\u5982\u71b9\u6559\u6388\u6240\u9886\u5bfc\u4e4b\u7814\u7a76\u5c0f\u7ec4\u4e8e\u5149\u8f6c\u6362\u6750\u6599\u7814\u7a76\u4e4b\u6982\u5ff5\u56fe\u3002<\/p>\n

\"\"<\/p>\n

 <\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7eb3\u7c73\u6750\u6599\u7ec4Isobel\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fd1\u7ea2\u5916\uff08NIR\uff09\u5149\u6e90\u662f\u6ce2\u957f\u8303\u56f4\u5728650-1400nm\u7684\u90e8\u5206\u5149\uff0c\u5904\u4e8e\u7535\u78c1\u5149\u8c31\u7684\u53ef\u89c1\u5149\u548c\u7ea2\u5916\u533a\u57df\u4e4b\u95f4\u3002\u8fd1\u7ea2\u5916\u5149\u8c31\u4f7f\u7528\u8fd1\u7ea2\u5916\u5149\u4f5c\u4e3a\u98df\u54c1\u52a0\u5de5\u4e1a\u7684\u5b9e\u65f6\u76d1\u6d4b\u5206\u6790\u548c…<\/p>\n","protected":false},"author":4765,"featured_media":157108,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3650,2960,3651],"class_list":["post-157106","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-3650","tag-2960","tag-3651"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/157106"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4765"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=157106"}],"version-history":[{"count":6,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/157106\/revisions"}],"predecessor-version":[{"id":157460,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/157106\/revisions\/157460"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/157108"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=157106"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=157106"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=157106"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}