{"id":155951,"date":"2018-10-16T06:30:45","date_gmt":"2018-10-15T22:30:45","guid":{"rendered":"\/\/m.iemloyee.com\/?p=155951"},"modified":"2018-10-15T21:53:09","modified_gmt":"2018-10-15T13:53:09","slug":"%e3%80%90tutorial-review%e3%80%91%e3%80%90%e5%ae%a1%e7%a8%bf%e6%9c%aa%e5%9b%9e%e5%a4%8d%e3%80%91%e5%91%a8%e5%ae%8f%e6%89%8d%e8%af%be%e9%a2%98%e7%bb%84chem-soc-rev-%e6%89%8b%e6%8a%8a%e6%89%8b","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=155951","title":{"rendered":"\u5468\u5b8f\u624d\u8bfe\u9898\u7ec4Chem. Soc. Rev.\u624b\u628a\u624b\u6559\u4f60\u6784\u5efa\u7a33\u5b9a\u548c\u591a\u529f\u80fd\u5316\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6"},"content":{"rendered":"

\u3010\u524d\u8a00\u3011<\/strong><\/p>\n

\u5728\u4e0a\u4e16\u7eaa90\u5e74\u4ee3\u4e2d\u53f6\uff0c\u4e00\u79cd\u65b0\u578b\u7684\u591a\u5b54\u6750\u6599\u88ab\u5f00\u53d1\u51fa\u6765\uff0c\u5bf9\u5316\u5b66\u3001\u751f\u7269\u3001\u7269\u7406\u548c\u6750\u6599\u7b49\u9886\u57df\u4ea7\u751f\u4e86\u6df1\u523b\u7684\u5f71\u54cd\uff0c\u8fd9\u7c7b\u65b0\u578b\u7684\u591a\u5b54\u6750\u6599\u5c31\u662f\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\uff08MOFs\uff09\u3002<\/p>\n

\u7531\u4e8eMOFs\u5728\u7ed3\u6784\u548c\u529f\u80fd\u4e0a\u7684\u591a\u6837\u6027\uff0cMOFs\u5728\u6c14\u4f53\u50a8\u5b58\u548c\u5206\u79bb\u3001\u50ac\u5316\u3001\u836f\u7269\u4f20\u9012\u3001\u5316\u5b66\u4f20\u611f\u7b49\u5f88\u591a\u9886\u57df\u90fd\u6709\u91cd\u8981\u7684\u5e94\u7528\u3002\u591a\u79cd\u91d1\u5c5e\u7c07\u548c\u914d\u4f53\u5728\u51e0\u4f55\u4e0a\u7684\u4e0d\u540c\u6392\u5217\u7ed3\u5408\uff0c\u4f7f\u5f97MOFs\u5728\u7ed3\u6784\u4e0a\u5177\u6709\u9ad8\u5ea6\u7684\u591a\u6837\u6027\uff1b\u800c\u8fd9\u79cd\u7ed3\u6784\u4e0a\u7684\u591a\u6837\u6027\uff0c\u6269\u5c55\u4e86\u5176\u5728\u4e0d\u540c\u9886\u57df\u4e2d\u5e94\u7528\u7684\u53ef\u80fd\u6027\u3002\u56e0\u800c\u8bbe\u8ba1\u4e0e\u5408\u6210\u4e0d\u540c\u7ed3\u6784\u7684MOFs\uff0c\u662f\u5176\u5e94\u7528\u7684\u57fa\u7840\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u7f8e\u56fd\u5fb7\u5dde\u519c\u5de5\u5927\u5b66<\/b><\/strong>\u5468\u5b8f\u624d\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bfe\u9898\u7ec4<\/b><\/strong>\u5728Chem. Soc. Rev.<\/b><\/strong>\u4e0a\uff0c\u53d1\u8868\u4e86\u9898\u4e3a”From Fundamentals to Applications: A Toolbox for Robust and Multifunctional MOF Materials<\/b><\/strong>“\u7684\u7efc\u8ff0\u3002\u4ece\u7406\u8bba\u57fa\u7840\u5230\u5e94\u7528\u7684\u89d2\u5ea6\uff0c\u6559\u4f60\u6784\u5efa\u7a33\u5b9a\u548c\u591a\u529f\u80fd\u5316\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

1.<\/b><\/strong>MOFs\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210<\/b><\/strong><\/p>\n

\u5728\u6784\u5efaMOFs\u4e4b\u524d\uff0c\u9700\u8981\u4e86\u89e3\u7684\u662f\uff1aMOFs\u4f5c\u4e3a\u4e00\u79cd\u91d1\u5c5e\u7c07\u4e0e\u6709\u673a\u914d\u4f53\u7684\u7ed3\u5408\u7269\uff0c\u5f88\u591a\u7ec4\u4ef6\u90fd\u4f1a\u5bf9\u6700\u7ec8\u7684\u6846\u67b6\u7ed3\u6784\u4ea7\u751f\u5f71\u54cd\uff0c\u6bd4\u5982\u8fde\u63a5\u7269\u8bbe\u8ba1\u3001\u8fde\u63a5\u7269\u9ccc\u5408\u3001\u7ed3\u5408\u4eb2\u548c\u529b\u3001\u6709\u673a-\u91d1\u5c5e\u952e\u80fd\u548c\u5bf9\u79f0\u6027\u7b49\u3002\u8fd9\u4e9b\u6240\u6709\u590d\u6742\u56e0\u7d20\u5728MOFs\u7684\u7ed3\u6784\u8bbe\u8ba1\u3001\u529f\u80fd\u5316\u548c\u5e94\u7528\u65b9\u9762\u4e0a\u6709\u5341\u5206\u91cd\u8981\u7684\u4f5c\u7528\u3002<\/p>\n

MOFs\u901a\u8fc7\u91d1\u5c5e\u548c\u8fde\u63a5\u7269\u914d\u4f4d\uff0c\u4e0e\u53e6\u4e00\u4e2a\u91d1\u5c5e\u76f8\u8fde\u7684\u65b9\u5f0f\uff08M-L-M\uff09\u6269\u5c55\u6210\u4e00\u7ef4\u3001\u4e8c\u7ef4\u548c\u4e09\u7ef4\u6846\u67b6\u3002\u6846\u67b6\u672c\u8eab\u53ef\u4ee5\u901a\u8fc7\u6700\u521d\u91d1\u5c5e\u7c07\u5f62\u6210\u7684\u65b9\u5f0f\uff0c\u5728\u4efb\u4f55\u65b9\u5411\u65e0\u9650\u5ef6\u4f38\u6269\u5c55\u3002\u8fd9\u79cd\u539f\u59cb\u7684\u6846\u67b6\u53ef\u4ee5\u6269\u5c55\u5f62\u6210\u7c7b\u4f3c\u805a\u5408\u7269\u7684\u7ed3\u6784\uff0c\u5177\u6709\u7a7a\u95f4\u3001\u901a\u9053\u548c\u591a\u5b54\u7684\u6d77\u7ef5\u6750\u6599\u3002MOFs\u7684\u591a\u5b54\u6027\u7684\u5b9a\u4e49\u662f\u5728\u6ca1\u6709\u5ba2\u4f53\u5206\u5b50\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\uff0c\u4e5f\u53ef\u4ee5\u7ef4\u6301\u591a\u5b54\u7ed3\u6784\uff1b\u8fd9\u610f\u5473\u7740\u5f53\u5ba2\u4f53\u5206\u5b50\u5728\u771f\u7a7a\u4e2d\u88ab\u79fb\u9664\u65f6\uff0c\u6750\u6599\u7684\u5b54\u9699\u4e0d\u4f1a\u574d\u584c\uff0c\u662f\u4e00\u79cd\u6c38\u6052\u7684\u5b58\u5728\u3002<\/p>\n

MOFs\u4e3b\u8981\u901a\u8fc7\u6c34\u70ed\u548c\u6eb6\u5242\u70ed\u751f\u957f\u6280\u672f\u5236\u5907\uff0c\u6676\u4f53\u53ef\u4ece\u9ad8\u6e29\u6eb6\u5242\u4e2d\u7f13\u6162\u6790\u51fa\u3002\u6709\u673a\u914d\u4f53\u5728\u5236\u5907\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u5b8c\u6574\uff0c\u56e0\u800c\u5176\u72ec\u7279\u7684\u529f\u80fd\u6027\u53ef\u4ee5\u5728\u6846\u67b6\u4e2d\u5f97\u5230\u4fdd\u7559\u3002MOFs\u7684\u6784\u5efa\u4e3b\u8981\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u4e5d\u79cd\u65b9\u6cd5\u5b8c\u6210\u3002<\/p>\n

Figure<\/b><\/strong>\u00a01<\/b><\/strong>.<\/b><\/strong>\u8fde\u63a5\u7269\u7684\u5316\u5b66\u7ed3\u6784\u548c<\/b><\/strong>MOF<\/b><\/strong>\u7684\u5355\u6676\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff081\uff09\u7f51\u72b6\u6269\u5c55<\/p>\n

\u7f51\u72b6\u6269\u5c55\u662f\u901a\u8fc7\u589e\u52a0\u76f8\u4f3c\u914d\u4f53\u7684\u957f\u5ea6\uff0c\u6269\u5c55\u76f8\u540c\u62d3\u6251\u7ed3\u6784\u6765\u5236\u5907\u8d85\u5927\u5b54\u7684MOFs\u3002\u8fd9\u4e2a\u65b9\u6cd5\u901a\u5e38\u53ef\u4ee5\u7528\u6765\u6269\u5927\u5b54\u5f84\u3001\u589e\u52a0\u8868\u9762\u79ef\u548c\u6539\u53d8\u5b54\u8868\u9762\u4fee\u9970\u3002<\/p>\n

\uff082\uff09\u57fa\u4e8e\u62d3\u6251\u7ed3\u6784\u7684\u8bbe\u8ba1<\/p>\n

\u8fd9\u4e2a\u65b9\u6cd5\u6700\u521d\u662f\u4e3a\u4e86\u907f\u514d\u7531\u4e8e\u5408\u6210\u73af\u5883\u53d8\u5316\u548c\u914d\u4f53\u4f4d\u963b\u589e\u52a0\u800c\u5bfc\u81f4\u7684MOFs\u7684\u76f8\u4e92\u8d2f\u7a7f\u3002\u5728\u8fd9\u4e2a\u65b9\u6cd5\u4e2d\uff0c\u7528\u6765\u6784\u5efaMOFs\u7684\u6a21\u677f\u662f\u57fa\u4e8e\u62d3\u6251\u7ed3\u6784\u7684\u201c\u975e\u76f8\u4e92\u8d2f\u7a7f\u201d\u6027\uff0c\u53ca\u5176\u5408\u6210\u6761\u4ef6\u3002\u5728\u57fa\u4e8e\u62d3\u6251\u7ed3\u6784\u7684\u8bbe\u8ba1\u4e2d\uff0cMOFs\u7684\u6784\u578b\u4f9d\u8d56\u4e8e\u542b\u91d1\u5c5e\u7684\u6784\u7b51\u5355\u5143\u3001\u6709\u673a\u914d\u4f53\u548c\u539f\u59cb\u7f51\u7edc\u7684\u5bf9\u79f0\u6027\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>2<\/b><\/strong>.<\/b><\/strong>\u51e0\u79cd\u4ee3\u8868\u6027\u7684\u7f51\u72b6\u62d3\u6251\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff083\uff09\u8c03\u8282\u5408\u6210<\/p>\n

\u8c03\u8282\u5408\u6210\u662f\u6307\u901a\u8fc7\u4f7f\u7528\u4e00\u4e9b\u8c03\u8282\u6027\u7684\u8bd5\u5242\u6765\u63a7\u5236MOFs\u751f\u957f\u4e2d\u7684\u914d\u4f4d\u5e73\u8861\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>3<\/b><\/strong>.<\/b><\/strong>\u51e0\u79cd<\/b><\/strong>MOFs<\/b><\/strong>\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff084\uff09\u540e\u5408\u6210\u4fee\u9970<\/p>\n

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Figure<\/b><\/strong>\u00a0<\/b><\/strong>4<\/b><\/strong>.<\/b><\/strong>\u901a\u8fc7\u70b9\u51fb\u53cd\u5e94\u7684\u5171\u4ef7\u540e\u5408\u6210\u4fee\u9970<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff085\uff09\u5171\u4ef7\u540e\u5408\u6210\u4fee\u9970<\/p>\n

\u540e\u5408\u6210\u4fee\u9970\u7684\u6982\u5ff5\u662f\u7531Robson\u4e8e1990\u5e74\u63d0\u51fa\uff0c\u4f46\u662f\u79d1\u5b66\u5bb6\u901a\u8fc7\u5341\u5e74\u7684\u52aa\u529b\u624d\u62a5\u5bfc\u4e86\u7b2c\u4e00\u4f8b\u5171\u4ef7\u540e\u4fee\u9970\u5408\u6210\u3002<\/p>\n

\uff086\uff09\u91d1\u5c5e\u5316\u4fee\u9970<\/p>\n

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\uff087\uff09\u53bb\u4fdd\u62a4\u4fee\u9970<\/p>\n

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\uff088\uff09\u914d\u4f4d\u4fee\u9970<\/p>\n

\u914d\u4f4d\u4fee\u9970\u662f\u6307\u901a\u8fc7\u4e00\u79cd\u914d\u4f53\u4e0e\u91d1\u5c5e\u7684\u914d\u4f4d\u4f5c\u7528\u6765\u66ff\u4ee3\u6389\u539f\u672c\u7684\u914d\u4f53\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>5<\/b><\/strong>.<\/b><\/strong>\u901a\u8fc7<\/b><\/strong>Ti<\/b><\/strong>\u548c<\/b><\/strong>Hf<\/b><\/strong>\u66ff\u4ee3<\/b><\/strong>UiO-66<\/b><\/strong>\u4e2d\u7684<\/b><\/strong>Zr<\/b><\/strong>\u5236\u5907<\/b><\/strong>UiO-66\uff08Zr\/Ti\uff09<\/b><\/strong>\u548c<\/b><\/strong>UiO-66\uff08Zr\/Hf\uff09<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff089\uff09\u540e\u5408\u6210\u4ea4\u6362<\/p>\n

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Figure<\/b><\/strong>\u00a0<\/b><\/strong>6<\/b><\/strong>.<\/b><\/strong>\u56fe\u793a\u6eb6\u5242\u8f85\u52a9\u8fde\u63a5\u7269\u4ea4\u6362<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>7<\/b><\/strong>.<\/b><\/strong>\u901a\u8fc7<\/b><\/strong>SALE<\/b><\/strong>\u6269\u5927<\/b><\/strong>MOFs<\/b><\/strong>\u7684\u5b54\u5f84<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>8<\/b><\/strong>.<\/b><\/strong>\u901a\u8fc7\u540e\u5408\u6210\u4fee\u9970\u7684\u65b9\u6cd5\u8d85\u5927\u5b54\u4f53\u79ef\u548c\u8868\u9762\u79ef\u7684<\/b><\/strong>MOFs<\/b><\/strong><\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

2<\/b><\/strong>.<\/b><\/strong>MOFs\u7684\u7a33\u5b9a<\/b><\/strong><\/p>\n

MOFs\u548c\u5176\u4ed6\u591a\u5b54\u6750\u6599\u76f8\u6bd4\uff0c\u5b58\u5728\u7684\u6700\u4e3b\u8981\u7684\u95ee\u9898\u662f\u7531\u4e8e\u914d\u4f53\u7684\u4e0d\u7a33\u5b9a\u6240\u5bfc\u81f4\u7684\u7a33\u5b9a\u6027\u8f83\u4f4e\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u901a\u5e38\u4f7f\u7528\u7684\u4e24\u79cd\u65b9\u6cd5\u662f\u4f7f\u7528\u57fa\u4e8e\u7fa7\u57fa\u7684\u8fde\u63a5\u7269\u548c\u57fa\u4e8e\u6c2e\u6742\u73af\u7684\u8fde\u63a5\u7269\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>9<\/b><\/strong>.<\/b><\/strong>\u5404\u79cd\u6cb8\u77f3\u54aa\u5511\u916f\u6846\u67b6<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>10<\/b><\/strong>.<\/b><\/strong>\u5728\u78b1\u6027\u73af\u5883\u4e2d\u6781\u5176\u7a33\u5b9a\u7684<\/b><\/strong>Ni<\/b><\/strong>2+<\/b><\/sup><\/strong>–<\/b><\/strong>\u5421\u5511<\/b><\/strong>MOFs<\/b><\/strong><\/p>\n

\"\"<\/p>\n

3<\/b><\/strong>.<\/b><\/strong>\u591a\u7ec4\u5206MOFs<\/b><\/strong><\/p>\n

\u591a\u7ec4\u5206MOFs\u4e3b\u8981\u5206\u4e3a\u6df7\u5408\u8fde\u63a5\u7269MOFs\u548c\u6df7\u5408\u91d1\u5c5eMOFs<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>11<\/b><\/strong>.PCN-700\u53ca\u5176\u884d\u751f\u7269\u7684\u5355\u6676\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff081\uff09\u6df7\u5408\u8fde\u63a5\u7269MOFs<\/p>\n

\u6df7\u5408\u8fde\u63a5\u7269MOFs\u53ef\u4ee5\u4e3aMOFs\u7684\u540e\u4fee\u9970\u63d0\u4f9b\u5f88\u5927\u7684\u4fbf\u6377\u3002\u5728\u8fd9\u7c7bMOFs\u4e2d\uff0c\u5b54\u5185\u73af\u5883\u548c\u7ed3\u6784\u7f3a\u9677\u90fd\u53ef\u4ee5\u901a\u8fc7\u8fde\u63a5\u7269\u7684\u63d2\u5165\u548c\u79fb\u9664\u6765\u6539\u53d8\uff0c\u4ece\u800c\u83b7\u53d6\u4e00\u5b9a\u7684\u529f\u80fd\u3002<\/p>\n

\uff082\uff09\u6df7\u5408\u91d1\u5c5eMOFs<\/p>\n

\u987e\u540d\u601d\u4e49\uff0c\u6df7\u5408\u91d1\u5c5eMOFs\u542b\u6709\u4e0d\u6b62\u4e00\u79cd\u91d1\u5c5e\u79cd\u7c7b\u3002\u8fd9\u79cd\u7c7b\u578b\u7684MOFs\u5728\u5236\u5907\u4e0a\u5b58\u5728\u4e00\u5b9a\u7684\u96be\u5ea6\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>12<\/b><\/strong>.\u62e5\u6709\u4e0d\u540c\u91d1\u5c5e\u7ec4\u4efd\u7684\u6df7\u5408\u91d1\u5c5ePCN-600\u884d\u751f\u7269<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>13<\/b><\/strong>.PCN-700\u548cPCN-800(Ni)\u7684\u7ed3\u6784<\/b><\/strong><\/p>\n

\"\"<\/p>\n

4<\/b><\/strong>.<\/b><\/strong>MOFs\u4e2d\u7f3a\u9677\u7684\u5f62\u6210\u548c\u8868\u5f81<\/b><\/strong><\/p>\n

\u7814\u7a76MOFs\u4e2d\u7f3a\u9677\u7684\u5f62\u6210\u3001\u6539\u53d8\u548c\u9884\u9632\uff0c\u5bf9\u4e8e\u63a7\u5236MOFs\u4e2d\u7684\u5b54\u5f84\u3001\u5b54\u4f53\u79ef\u548c\u8868\u9762\u79ef\u6709\u5f88\u5927\u7684\u5e2e\u52a9\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>14<\/b><\/strong>.\u5229\u7528\u82ef\u7532\u9178\u5f62\u6210\u7684\u7f3a\u9677<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>15<\/b><\/strong>.\u4e0d\u540c\u6d53\u5ea6\u7684\u4e59\u9178\u5bf9\u7f3a\u9677\u5f62\u6210\u7684\u5f71\u54cd<\/b><\/strong><\/p>\n

\"\"<\/p>\n

5<\/b><\/strong>.<\/b><\/strong>\u6784\u5efa\u591a\u5c42MOFs<\/b><\/strong><\/p>\n

\u591a\u5c42MOFs\u7684\u6784\u5efa\u53ef\u4ee5\u901a\u8fc7\u6a21\u677f\u5408\u6210\u3001\u8fde\u63a5\u7269\u548c\u7247\u6bb5\u81ea\u7ec4\u88c5\u3001\u8fde\u63a5\u7269\u4ea4\u6362\u548c\u5e72\u6270\u8f85\u52a9\u7eb3\u7c73\u878d\u5408\u7b49\u65b9\u6cd5\u5b8c\u6210\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>16<\/b><\/strong>.\u901a\u8fc7\u6a21\u677f\u5408\u6210\u7684\u65b9\u6cd5\u6784\u5efaMOF<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>17<\/b><\/strong>.\u8c03\u5236\u5242\u8bf1\u5bfc\u7684\u591a\u5c42MOF\u4e2d\u7684\u7f3a\u9677\u5f62\u6210<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>18<\/b><\/strong>.PCN-125\u4e2d\u7684\u8fde\u63a5\u7269\u548c\u7247\u6bb5\u81ea\u7ec4\u88c5<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>19<\/b><\/strong>.\u8fde\u63a5\u7269\u4ea4\u6362\u793a\u610f\u56fe\uff0c\u4ee5\u53caMOFs\u4e2d\u7684\u7f3a\u9677<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>20<\/b><\/strong>.HP-CYCU-3\u548c\u65e0\u7f3a\u9677\u7684CYCU-3\u7684\u6d3b\u6027\u5bf9\u6bd4<\/b><\/strong><\/p>\n

\"\"<\/p>\n

6<\/b><\/strong>.<\/b><\/strong>MOF\u590d\u5408\u7269\u7684\u5408\u6210\u53ca\u5e94\u7528<\/b><\/strong><\/p>\n

\u7ecf\u8fc7\u8fd1\u5e74\u6765\u79d1\u5b66\u5bb6\u7684\u52aa\u529b\uff0cMOFs\u4e0e\u5176\u4ed6\u6750\u6599\u7ed3\u5408\u5f62\u6210MOF\u590d\u5408\u7269\u3002\u8fd9\u91cc\u7b80\u8981\u4ecb\u7ecd\u4e00\u4e0b\u8fd9\u7c7b\u590d\u5408\u6750\u6599\u3002<\/p>\n

\uff081\uff09MOF-\u805a\u5408\u7269\u590d\u5408\u7269<\/p>\n

MOF-\u805a\u5408\u7269\u590d\u5408\u7269\u4e3b\u8981\u53ef\u5206\u4e3a\u4e09\u7c7b\uff1a\u805a\u5408\u7269@MOFs\uff0cMOFs@\u805a\u5408\u7269\u548c\u805aMOFs\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>21<\/b><\/strong>.\u5404\u79cd\u7c7b\u578b\u7684MOF-\u805a\u5408\u7269\u590d\u5408\u7269\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>22<\/b><\/strong>.\u805aMOFs\u7684\u5f62\u6210\u548c\u7ed3\u6784\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff082\uff09MOF-\u7eb3\u7c73\u7c92\u5b50\u590d\u5408\u7269<\/p>\n

MOF-\u7eb3\u7c73\u7c92\u5b50\u590d\u5408\u7269\u53c8\u5206\u4e3a\u4e94\u7c7b\uff1aMOF-\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u590d\u5408\u7269\uff0cMOF-\u91d1\u5c5e\u6c27\u5316\u590d\u5408\u7269\uff0cMOF-\u975e\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u590d\u5408\u7269\uff0cMOF-\u91cf\u5b50\u70b9\u590d\u5408\u7269\uff0cMOF-POM\u590d\u5408\u7269\u3002<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>23<\/b><\/strong>.MCP\u7684\u5408\u6210\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>2<\/b><\/strong>4.\u4e09\u660e<\/b><\/strong>\u6cbb\u5f62\u72b6\u7684MIL-101@Pt@MIL-10<\/b><\/strong>1<\/b><\/strong>\u7684\u5408\u6210\u8def\u5f84<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff083\uff09MOF-\u9176\u590d\u5408\u7269<\/p>\n

Figure<\/b><\/strong>\u00a0<\/b><\/strong>25<\/b><\/strong>.<\/b><\/strong>OPAA<\/b><\/strong>\u5728<\/b><\/strong>Zr-MOF<\/b><\/strong>\u4e2d\u7684\u5d4c\u5165\u793a\u610f\u56fe<\/b><\/strong><\/p>\n

\u00a0\"\"<\/b><\/strong><\/p>\n

\u3010\u7ed3\u8bba\u4e0e\u5c55\u671b\u3011<\/b><\/strong><\/p>\n

MOFs\u662f\u4e00\u79cd\u5728\u7ed3\u6784\u548c\u529f\u80fd\u4e0a\u5f88\u591a\u6837\u7684\u591a\u5b54\u6750\u6599\uff0c\u5728\u6c14\u4f53\u50a8\u5b58\u548c\u5206\u79bb\u3001\u50ac\u5316\u3001\u836f\u7269\u4f20\u9012\u3001\u5316\u5b66\u4f20\u611f\u7b49\u5f88\u591a\u9886\u57df\u90fd\u6709\u91cd\u8981\u7684\u5e94\u7528\u3002MOFs\u7684\u7ed3\u6784\u591a\u6837\u6027\u4e3a\u4ed6\u5728\u529f\u80fd\u4e0a\u7684\u591a\u6837\u5316\u63d0\u4f9b\u4e86\u57fa\u7840\u3002\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u5c31MOFs\u524d\u6cbf\u7814\u7a76\u4e2d\u4e00\u5c0f\u90e8\u5206\u5185\u5bb9\u63d0\u51fa\u4e86\u603b\u7ed3\u548c\u8ba8\u8bba\uff0c\u5305\u62ecMOFs\u7684\u8bbe\u8ba1\u5408\u6210\u3001\u529f\u80fd\u5316\u548c\u7a33\u5b9a\u3002\u76ee\u524d\uff0cMOFs\u7684\u7814\u7a76\u4e0e\u9ad8\u5206\u5b50\u6750\u6599\u3001\u7eb3\u7c73\u79d1\u5b66\u3001\u8ba1\u7b97\u6a21\u62df\u3001\u751f\u7269\u533b\u5b66\u7b49\u9886\u57df\u5f00\u59cb\u4ea4\u53c9\u7ed3\u5408\uff0c\u4e3aMOFs\u7684\u7814\u7a76\u548c\u53d1\u5c55\u5f00\u8f9f\u4e86\u65b0\u7684\u9053\u8def\u3002<\/p>\n

From Fundamentals to Applications: A Toolbox for Robust and Multifunctional MOF Materials<\/a><\/p>\n

\u00a0(Chem. Soc. Rev., 2018, DOI: 10. 1039\/c8cs00688a)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

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