{"id":155000,"date":"2018-09-29T06:41:37","date_gmt":"2018-09-28T22:41:37","guid":{"rendered":"\/\/m.iemloyee.com\/?p=155000"},"modified":"2019-04-26T18:08:42","modified_gmt":"2019-04-26T10:08:42","slug":"%e5%82%ac%e5%8c%96%e5%89%82%e6%9d%90%e6%96%99%e7%9a%84%e7%94%b5%e5%8c%96%e5%ad%a6%e8%a1%a8%e5%be%81%e6%96%b9%e6%b3%95","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=155000","title":{"rendered":"\u68b3\u7406\uff1a\u50ac\u5316\u6750\u6599\u7535\u5316\u5b66\u8868\u5f81\u65b9\u6cd5"},"content":{"rendered":"<p>\u8fd1\u5e74\u6765\uff0c\u4f34\u968f\u7740\u793e\u4f1a\u7684\u53d1\u5c55\u548c\u4eba\u7c7b\u7684\u8fdb\u6b65\uff0c\u65e5\u76ca\u4e25\u5cfb\u7684\u80fd\u6e90\u4e0e\u73af\u5883\u95ee\u9898\u6210\u4e3a\u4e9f\u5f85\u89e3\u51b3\u7684\u4e16\u754c\u6027\u96be\u9898\u3002\u4eba\u4eec\u81f4\u529b\u4e8e\u5bfb\u6c42\u65b0\u80fd\u6e90\u7684\u6709\u6548\u5229\u7528\u65b9\u5f0f\u548c\u73af\u5883\u7684\u957f\u6548\u51c0\u5316\u65b9\u6cd5\uff0c\u76ee\u524d\u5e7f\u4e3a\u7814\u7a76\u7684\u4fc3\u8fdb\u80fd\u6e90\u8f6c\u5316\u4e0e\u73af\u5883\u51c0\u5316\u7684\u6709\u6548\u9014\u5f84\u6d89\u53ca\u8bf8\u591a\u65b9\u5411\uff0c\u6bd4\u5982\u71c3\u6599\u7535\u6c60\u5f00\u53d1\uff0c\u5236\u6c22\u53cd\u5e94\uff0cCO<sub>2<\/sub>\u8d44\u6e90\u5316\uff0c\u6709\u673a\u5e9f\u6c14\u50ac\u5316\u8f6c\u5316\u7b49\u3002\u9a71\u52a8\u8fd9\u4e9b\u80fd\u6e90\u8f6c\u5316\u4e0e\u73af\u5883\u51c0\u5316\u9014\u5f84\u7684\u5173\u952e\u65b9\u6cd5\u4e4b\u4e00\u5f53\u5c5e\u7535\u50ac\u5316\u53cd\u5e94\u6280\u672f\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u65b9\u6cd5\u7684\u4f7f\u7528\u4f5c\u4e3a\u7406\u8bba\u6307\u5bfc\u4e3a\u7535\u50ac\u5316\u5242\u6027\u80fd\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u5408\u7406\u5316\u7684\u89e3\u91ca\u624b\u6bb5\u3002\u672c\u6587\u603b\u7ed3\u4e86\u51e0\u79cd\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5e38\u7528\u5230\u7684\u7535\u5316\u5b66\u6d4b\u8bd5\u65b9\u6cd5\u3002<\/p>\n<p>\u56fe0 \u53ef\u6301\u7eed\u80fd\u6e90\u8f6c\u5316\u7535\u50ac\u5316\u8fc7\u7a0b<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-155001 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724710-6.png\" alt=\"\" width=\"628\" height=\"473\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724710-6.png 628w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724710-6-300x226.png 300w\" sizes=\"(max-width: 628px) 100vw, 628px\" \/><\/p>\n<p><strong><b>\u4e00\u3001\u5faa\u73af\u4f0f\u5b89\u6cd5<\/b><\/strong><\/p>\n<p>\u5faa\u73af\u4f0f\u5b89\u6cd5(CV\uff0c Cyclic Voltammetry)\u4f5c\u4e3a\u4e00\u79cd\u7528\u4ee5\u8bc4\u4ef7\u672a\u77e5\u7684\u7535\u5316\u5b66\u4f53\u7cfb\u6700\u4e3a\u5e38\u7528\u7684\u7814\u7a76\u65b9\u6cd5\uff0c\u4e3b\u8981\u901a\u8fc7\u63a7\u5236\u7535\u6781\u7535\u52bf\u4ee5\u4e0d\u540c\u7684\u901f\u7387\uff0c\u968f\u65f6\u95f4\u4ee5\u4e09\u89d2\u6ce2\u5f62\u4e00\u6b21\u6216\u591a\u6b21\u53cd\u590d\u626b\u63cf\u83b7\u5f97\u7684\u7535\u6d41-\u7535\u52bf\u66f2\u7ebf(i-E)\u3002\u5728\u4e0d\u540c\u7684\u7535\u52bf\u8303\u56f4\u5185\uff0c\u7535\u6781\u4e0a\u80fd\u591f\u4ea4\u66ff\u53d1\u751f\u4e0d\u540c\u7684\u8fd8\u539f\u548c\u6c27\u5316\u53cd\u5e94\uff0c\u6839\u636e\u66f2\u7ebf\u5f62\u72b6\u53ef\u4ee5\u5224\u65ad\u7535\u6781\u53cd\u5e94\u7684\u53ef\u9006\u7a0b\u5ea6\uff1b\u6839\u636e\u7279\u5b9a\u7535\u52bf\u8303\u56f4\u5185\u53cd\u5e94\u7269\u7684\u5438\u9644\u3001\u8131\u9644\u5cf0\u53ef\u4ee5\u7528\u6765\u8bc4\u4ef7\u7535\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u9762\u79ef\uff0c\u4e5f\u53ef\u7528\u4e8e\u83b7\u5f97\u590d\u6742\u7535\u6781\u53cd\u5e94\u7684\u6709\u7528\u4fe1\u606f\u3002<\/p>\n<p>\u56fe1.1 \u626b\u63cf\u7535\u6d41\u7535\u52bf\u54cd\u5e94\u66f2\u7ebf<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-155002 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724711-5.png\" alt=\"\" width=\"384\" height=\"239\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724711-5.png 384w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724711-5-300x187.png 300w\" sizes=\"(max-width: 384px) 100vw, 384px\" \/><\/p>\n<p>\u5982\u56fe1.1\u6240\u793a\uff0c\u524d\u534a\u90e8\u5206\u7535\u4f4d\u5411\u9634\u6781\u65b9\u5411\u626b\u63cf\uff0c\u7535\u6d3b\u6027\u7269\u8d28\u5728\u7535\u6781\u4e0a\u8fd8\u539f\uff0c\u4ea7\u751f\u8fd8\u539f\u6ce2\uff0c\u540e\u534a\u90e8\u5206\u7535\u4f4d\u5411\u9633\u6781\u626b\u63cf\u65f6\uff0c\u8fd8\u539f\u4ea7\u7269\u53c8\u4f1a\u91cd\u65b0\u518d\u7535\u6781\u4e0a\u6c27\u5316\uff0c\u4ea7\u751f\u6c27\u5316\u6ce2\u3002\u5faa\u73af\u4f0f\u5b89\u6cd5i-E\u66f2\u7ebf\u7684\u4e24\u4e2a\u6709\u7528\u7684\u53c2\u6570\uff0c\u662f\u5cf0\u7535\u6d41\u6bd4i<sub>pa<\/sub>\/i<sub>pc<\/sub>\u548c\u5cf0\u7535\u52bf\u5deeE<sub>pa<\/sub>-E<sub>pc<\/sub>\u3002\u5bf9\u7a33\u5b9a\u4ea7\u7269\u7684Nernst\u6ce2\uff0c\u5cf0\u7535\u6d41\u6bd4i<sub>pa<\/sub>\/i<sub>pc<\/sub>= 1\uff0c\u4e0e\u626b\u63cf\u901f\u5ea6\u3001\u6269\u6563\u7cfb\u6570\u3001\u6362\u5411\u7535\u52bf\u65e0\u5173\u3002\u5f53\u9634\u6781\u626b\u63cf\u505c\u6b62\uff0c\u4f7f\u7535\u6d41\u8870\u9000\u52300\u540e\u8fdb\u884c\u53cd\u5411\u626b\u63cf\uff0c\u5f97\u5230\u7684i-E\u66f2\u7ebf\u4e0e\u9634\u6781\u66f2\u7ebf\u5f62\u72b6\u5b8c\u5168\u76f8\u540c\uff0c\u53ea\u662f\u7ed8\u5728I\u5750\u6807\u548cE\u5750\u6807\u7684\u76f8\u53cd\u65b9\u5411\u3002\u6bd4\u503ci<sub>pa<\/sub>\/i<sub>pc<\/sub>\u504f\u79bb1\uff0c\u9884\u793a\u7740\u7535\u6781\u8fc7\u7a0b\u5e76\u975e\u5b8c\u5168\u53ef\u9006\u53cd\u5e94\u8fc7\u7a0b\uff0c\u5176\u4e2d\u6d89\u53ca\u5747\u76f8\u52a8\u529b\u5b66\u6216\u5b58\u5728\u5176\u4ed6\u590d\u6742\u6027\u3002\u901a\u8fc7\u53cd\u5e94\u5cf0\u9ad8\u548c\u5cf0\u9762\u79ef\u53ef\u4ee5\u7528\u6765\u4f30\u7b97\u5982\u7535\u6d3b\u6027\u7269\u79cd\u6d53\u5ea6\u6216\u5076\u5408\u5747\u76f8\u53cd\u5e94\u7684\u901f\u5ea6\u5e38\u6570\u7b49\u4f53\u7cfb\u53c2\u6570\uff0c\u7136\u800c\uff0cCV\u66f2\u7ebf\u4e0d\u662f\u4e00\u79cd\u7406\u60f3\u7684\u5b9a\u91cf\u65b9\u6cd5\uff0c\u5b83\u5f3a\u5927\u7684\u7528\u9014\u66f4\u591a\u5728\u4e8e\u5b83\u7684\u5b9a\u6027\u534a\u5b9a\u91cf\u5224\u65ad\u80fd\u529b\u3002<\/p>\n<p><strong><b>\u4e8c\u3001\u8109\u51b2\u4f0f\u5b89\u6cd5<\/b><\/strong><\/p>\n<p>\u8109\u51b2\u4f0f\u5b89\u6cd5\u662f\u4e00\u79cd\u57fa\u4e8e\u6781\u8c31\u7535\u6781\u884c\u4e3a\u7684\u7535\u5316\u5b66\u6d4b\u91cf\u624b\u6bb5\uff0c\u88ab\u5e94\u7528\u4e8e\u7814\u7a76\u5404\u79cd\u4ecb\u8d28\u4e2d\u7684\u6c27\u5316\u8fd8\u539f\u8fc7\u7a0b\uff0c\u50ac\u5316\u5242\u6750\u6599\u8868\u9762\u7269\u8d28\u5438\u9644\u7814\u7a76\u4ee5\u53ca\u5316\u5b66\u4fee\u9970\u7535\u6781\u8868\u9762\u7535\u5b50\u8f6c\u79fb\u673a\u5236\u7b49\uff0c\u5bf9\u4e8e\u75d5\u91cf\u68c0\u6d4b\u5c24\u4e3a\u6709\u6548\u3002\u6839\u636e\u7535\u538b\u626b\u63cf\u65b9\u5f0f\u7684\u4e0d\u540c\uff0c\u8109\u51b2\u4f0f\u5b89\u6cd5\u5305\u62ec\u9636\u68af\u4f0f\u5b89\u6cd5\u3001\u5e38\u89c4\u8109\u51b2\u4f0f\u5b89\u6cd5\u3001\u5dee\u5206\u8109\u51b2\u4f0f\u5b89\u6cd5\u548c\u65b9\u6ce2\u4f0f\u5b89\u6cd5\u7b49\u3002\u5176\u4e2d\uff0c\u9636\u68af\u4f0f\u5b89\u6cd5\u4e0e\u7535\u52bf\u626b\u63cf\u65b9\u6cd5\u7c7b\u4f3c\uff0c\u5927\u90e8\u5206\u4f53\u7cfb\u5bf9\u8f83\u9ad8\u5206\u8fa8 (\u0394E&lt;5 mV) \u9636\u68af\u4f0f\u5b89\u7684\u54cd\u5e94\uff0c\u4e0e\u540c\u6837\u626b\u63cf\u901f\u5ea6\u7684\u7ebf\u6027\u626b\u63cf\u5b9e\u9a8c\u7ed3\u679c\u975e\u5e38\u76f8\u4f3c\u3002<\/p>\n<p><strong><b>\u4e09\u3001\u7535\u5316\u5b66\u963b\u6297\u8c31<\/b><\/strong><\/p>\n<p>\u7535\u5316\u5b66\u963b\u6297\u8c31\u7684\u662f\u7ed9\u7535\u5316\u5b66\u7cfb\u7edf\u65bd\u52a0\u4e00\u4e2a\u6270\u52a8\u7535\u4fe1\u53f7\uff0c\u4e0e\u7ebf\u6027\u626b\u63cf\u6cd5\u4e0d\u540c\uff0c\u6b64\u65f6\u7684\u7535\u5316\u5b66\u7cfb\u7edf\u8fdc\u79bb\u5e73\u8861\u6001\uff0c\u7136\u540e\u6765\u89c2\u6d4b\u7cfb\u7edf\u7684\u54cd\u5e94\uff0c\u5229\u7528\u54cd\u5e94\u7535\u4fe1\u53f7\u5206\u6790\u7cfb\u7edf\u7684\u7535\u5316\u5b66\u6027\u8d28\u3002\u7535\u5316\u5b66\u963b\u6297\u8c31\u5e38\u5e38\u7528\u6765\u5206\u6790\uff0cPEM\u71c3\u6599\u7535\u6c60\u4e2d\u7684ORR\u53cd\u5e94\uff0c\u8868\u5f81\u50ac\u5316\u5242\u6750\u6599\u8868\u9762\u7684\u6269\u6563\u635f\u8017\uff0c\u4f30\u8ba1\u6b27\u59c6\u7535\u963b\uff0c\u4ee5\u53ca\u7535\u8377\u8f6c\u79fb\u963b\u6297\u548c\u53cc\u5c42\u7535\u5bb9\u7b49\u7279\u6027\uff0c\u8bc4\u4f30\u5e76\u4f18\u5316\u819c\u7535\u6781\u7ec4\u4ef6\u3002<\/p>\n<p>\u963b\u6297\u8c31\u901a\u5e38\u662f\u7ed8\u5236\u6210\u535a\u5fb7\u56fe\u548c\u5948\u594e\u65af\u7279\u56fe\u7684\u5f62\u5f0f\u3002\u5728\u535a\u5fb7\u56fe\u4e2d\uff0c\u963b\u6297\u7684\u5e45\u503c\u548c\u76f8\u4f4d\u7ed8\u5236\u6210\u9891\u7387\u51fd\u6570\uff1b\u5728\u5948\u594e\u65af\u7279\u56fe\u4e2d\uff0c\u963b\u6297\u7684\u865a\u90e8\u662f\u76f8\u5bf9\u4e8e\u5b9e\u90e8\u5728\u6bcf\u4e2a\u9891\u7387\u70b9\u4e0a\u7ed8\u5236\u3002\u9ad8\u9891\u7535\u5f27\u53cd\u6620\u4e86\u50ac\u5316\u5242\u5c42\u7684\u53cc\u5c42\u7535\u5bb9\u3001\u6709\u6548\u7535\u8377\u8f6c\u79fb\u963b\u6297\u4ee5\u53ca\u6b27\u59c6\u7535\u963b\u7684\u7ec4\u5408\uff0c\u4f4e\u9891\u7535\u5f27\u662f\u53cd\u6620\u8d28\u91cf\u4f20\u8f93\u4ea7\u751f\u7684\u963b\u6297\u3002\u5bf9\u4e8e\u7ed9\u5b9a\u7684\u4f53\u7cfb\uff0c\u4e24\u4e2a\u533a\u57df\u6709\u65f6\u4e0d\u592a\u597d\u5b9a\u4e49\u3002<\/p>\n<p>\u56fe3.1\u7535\u5316\u5b66\u4f53\u7cfb\u7684\u963b\u6297\u8c31<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-155003 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724712-4.png\" alt=\"\" width=\"372\" height=\"264\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724712-4.png 372w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724712-4-300x213.png 300w\" sizes=\"(max-width: 372px) 100vw, 372px\" \/><\/p>\n<p>\u56fe3.1 \u7ed9\u51fa\u4e86\u52a8\u529b\u5b66\u63a7\u5236\u548c\u4f20\u8d28\u63a7\u5236\u7684\u6781\u9650\u7279\u70b9\u3002\u7136\u800c\uff0c\u5bf9\u4e8e\u4efb\u610f\u7ed9\u5b9a\u7684\u4f53\u7cfb\uff0c\u4e24\u4e2a\u533a\u57df\u5f88\u53ef\u80fd\u4e0d\u662f\u5f88\u597d\u5b9a\u4e49\u7684\u3002\u51b3\u5b9a\u56e0\u7d20\u662f\u7535\u8377\u8f6c\u79fb\u7535\u963b\u4e0e\u4f20\u8f93\u963b\u6297\u7684\u5173\u7cfb\uff0c\u5982\u679c\u5316\u5b66\u4f53\u7cfb\u52a8\u529b\u5b66\u4e0a\u8f83\u6162\uff0c\u5b83\u5c06\u663e\u793a\u6709\u4e00\u4e2a\u5927\u7684R<sub>ct<\/sub>\uff0c\u8868\u73b0\u4e3a\u53ef\u80fd\u51fa\u73b0\u4e00\u4e2a\u975e\u5e38\u6709\u9650\u7684\u9891\u7387\u533a\u57df\uff0c\u5f53\u4f53\u7cfb\u5728\u52a8\u529b\u5b66\u4e0a\u5f88\u5feb\uff0c \u7269\u8d28\u4f20\u9012\u603b\u662f\u8d77\u4e3b\u5bfc\u4f5c\u7528\uff0c\u534a\u5706\u533a\u57df\u5f88\u96be\u5b9a\u4e49\u3002<\/p>\n<p><strong><b>\u56db\u3001\u8ba1\u65f6\u7535\u6d41\u6cd5<\/b><\/strong><\/p>\n<p>\u8ba1\u65f6\u7535\u6d41\u6cd5\u662f\u4e00\u79cd\u6682\u6001\u63a7\u5236\u65b9\u6cd5\uff0c\u53ef\u4ee5\u7528\u6765\u8bc4\u4ef7\u50ac\u5316\u5242\u8868\u9762\u7684\u5438\u9644\u548c\u6269\u6563\u60c5\u51b5\u3002\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\u4e3b\u8981\u901a\u8fc7\u5bf9\u7535\u5316\u5b66\u4f53\u7cfb\u65bd\u52a0\u7535\u4f4d\u9636\u8dc3\uff0c\u6d4b\u91cf\u7535\u6d41\u54cd\u5e94\u4fe1\u53f7\u968f\u65f6\u95f4\u7684\u53d8\u5316\u6765\u83b7\u5f97\u3002\u5f53\u7ed9\u5230\u4e00\u4e2a\u7535\u52bf\u9636\u8dc3\uff0c\u5176\u57fa\u672c\u6ce2\u5f62\u793a\u4e8e\u56fe4.1(a)\uff0c\u5206\u6790\u5728\u56fa\u4f53\u7535\u6781\u8868\u9762\u4e0e\u542b\u6709\u7535\u6d3b\u6027\u7269\u8d28\u3002\u65bd\u52a0\u7535\u52bf\u9636\u8dc3\u540e\uff0c\u7535\u6781\u8868\u9762\u9644\u8fd1\u7684\u7535\u6d3b\u6027\u7269\u8d28\u9996\u5148\u88ab\u8fd8\u539f\u4e3a\u7a33\u5b9a\u7684\u9634\u79bb\u5b50\u81ea\u7531\u57fa\uff0c\u7531\u4e8e\u8be5\u8fc7\u7a0b\u5728\u9636\u8dc3\u77ac\u95f4\u7acb\u5373\u53d1\u751f\uff0c\u9700\u8981\u5f88\u5927\u7684\u7535\u6d41\u3002\u968f\u540e\u6d41\u8fc7\u7684\u7535\u6d41\u7528\u4e8e\u4fdd\u6301\u7535\u6781\u8868\u9762\u6d3b\u6027\u7269\u8d28\u88ab\u5b8c\u5168\u8fd8\u539f\u7684\u6761\u4ef6\uff0c\u521d\u59cb\u7684\u8fd8\u539f\u5728\u7535\u6781\u8868\u9762\u548c\u672c\u4f53\u6eb6\u6db2\u95f4\u9020\u6210\u6d53\u5ea6\u68af\u5ea6\uff08\u5373\u6d53\u5dee\uff09\uff0c\u6d3b\u6027\u7269\u8d28\u56e0\u800c\u5f00\u59cb\u4e0d\u65ad\u5730\u5411\u8868\u9762\u6269\u6563\uff0c\u6269\u6563\u5230\u7535\u6781\u8868\u9762\u7684\u6d3b\u6027\u7269\u8d28\u7acb\u5373\u88ab\u5b8c\u5168\u8fd8\u539f\u3002\u6269\u6563\u6d41\u91cf\uff0c\u4e5f\u5c31\u662f\u7535\u6d41\uff0c\u6b63\u6bd4\u4e8e\u7535\u6781\u8868\u9762\u7684\u6d53\u5ea6\u68af\u5ea6\u3002\u7136\u800c\u6ce8\u610f\u5230\uff0c\u968f\u7740\u53cd\u5e94\u8fdb\u884c\uff0c\u672c\u4f53\u6eb6\u6db2\u4e2d\u7684\u6d3b\u6027\u7269\u8d28\u5411\u7535\u6781\u8868\u9762\u4e0d\u65ad\u6269\u6563\uff0c\u4f7f\u6d53\u5ea6\u68af\u5ea6\u533a\u5411\u672c\u4f53\u6eb6\u6db2\u9010\u6e10\u5ef6\u4f38\u53d8\u539a\uff0c\u56fa\u4f53\u7535\u6781\u8868\u9762\u6d53\u5ea6\u68af\u5ea6\u9010\u6e10\u53d8\u5c0f\uff08\u8d2b\u5316\uff09\uff0c\u7535\u6d41\u4e5f\u9010\u6e10\u53d8\u5c0f\u3002\u6d53\u5ea6\u5206\u5e03\u548c\u7535\u6d41\u968f\u65f6\u95f4\u7684\u53d8\u5316\u793a\u4e8e\u56fe4.1(b)\u548c\u56fe4.1(c)\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-155004 size-full aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724713-5.png\" alt=\"\" width=\"650\" height=\"186\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724713-5.png 650w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/\u56fe\u724713-5-300x86.png 300w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><\/p>\n<p>\u56fe4.1 (a) \u9636\u8dc3\u5b9e\u9a8c\u6ce2\u5f62\uff0c\u53cd\u5e94\u7269O\u5728\u7535\u52bfE<sub>1<\/sub>\u4e0d\u53cd\u5e94\uff0c\u5728E<sub>2<\/sub>\u4ee5\u6269\u6563\u6781\u9650\u901f\u5ea6\u88ab\u8fd8\u539f\uff1b (b) \u5404\u4e0d\u540c\u65f6\u523b\u7684\u6d53\u5ea6\u5206\u5e03\uff1b(c)\u7535\u6d41\u4e0e\u65f6\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf<\/p>\n<p><strong><b>\u4e94\u3001\u65cb\u8f6c\u5706\u76d8\u7535\u6781\u6280\u672f<\/b><\/strong><\/p>\n<p>\u65cb\u8f6c\u5706\u76d8\u7535\u6781\uff08RDE\uff09\u6280\u672f\u5728\u7814\u7a76\u50ac\u5316\u5242\u8868\u9762\u8026\u5408\u5747\u76f8\u53cd\u5e94\u4e2d\u975e\u5e38\u6709\u7528\uff0c\u4f7f\u5f97\u50ac\u5316\u5242\u8868\u9762\u7684\u7535\u5316\u5b66\u53cd\u5e94\u5728\u4e00\u79cd\u76f8\u5bf9\u7a33\u6001\u7684\u6761\u4ef6\u4e0b\u8fdb\u884c\u3002RDE\u53ef\u4ee5\u63a7\u5236\u6269\u6563\u8f83\u6162\u7684\u7269\u8d28\uff0c\u6bd4\u5982\u6c14\u4f53\u6613\u4e8e\u6269\u6563\u5230\u6eb6\u6db2\u4e2d\uff0c\u51cf\u5c11\u6269\u6563\u5c42\u7684\u5bf9\u7535\u6d41\u5bc6\u5ea6\u5206\u5e03\u7684\u5f71\u54cd\u3002\u4ece\u800c\u5f97\u5230\u7a33\u5b9a\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u4f7f\u5176\u5904\u4e8e\u8fd1\u4f3c\u7a33\u6001\uff0c\u6709\u5229\u4e8e\u7535\u5316\u5b66\u5206\u6790\u7684\u8fc7\u7a0b\uff1bRDE\u901a\u8fc7\u8c03\u63a7\u8f6c\u901f\u53ef\u4ee5\u63a7\u5236\u7535\u89e3\u6db2\u5230\u8fbe\u7535\u6781\u8868\u9762\u7684\u901f\u5ea6\uff0c\u5bf9\u4e0d\u540c\u7684\u8f6c\u901f\u4e0b\u7535\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u7684\u53c2\u6570\u8fdb\u884c\u6d4b\u91cf\u548c\u5206\u6790\u3002<\/p>\n<p>\u968f\u7740\u4eba\u7c7b\u5f00\u53d1\u7528\u4e8e\u6e05\u6d01\u80fd\u6e90\u8f6c\u6362\u7684\u5148\u8fdb\u7535\u50ac\u5316\u5242\u7684\u5174\u8da3\u65e5\u76ca\u6d53\u539a\uff0c\u5bf9\u4e8e\u7535\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u7684\u8868\u5f81\uff0c\u9664\u4e86\u5f3a\u8c03\u4e00\u4e9b\u57fa\u672c\u65b9\u6cd5\u7684\u4f7f\u7528\uff0c\u8fd8\u9700\u8fdb\u4e00\u6b65\u68c0\u9a8c\u6bcf\u4e2a\u53cd\u5e94\u7684\u57fa\u5143\u6b65\u9aa4\uff0c\u4ee5\u786e\u5b9a\u6d89\u53ca\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u3001\u4e2d\u95f4\u4f53\u7684\u8868\u9762\u7684\u7ed3\u5408\u4ee5\u53ca\u6bcf\u4e2a\u57fa\u5143\u53cd\u5e94\u6b65\u9aa4\u7684\u80fd\u91cf\u3002\u7535\u5316\u5b66\u65b9\u6cd5\u7684\u7814\u7a76\u4ecd\u9700\u81f4\u529b\u4e8e\u8fc4\u4eca\u4e3a\u6b62\u4e0d\u751a\u660e\u4e86\u7684\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\u7684\u8bb8\u591a\u7ec6\u8282\u95ee\u9898\uff0c\u6bd4\u5982\u6d89\u53ca\u8d28\u5b50\/\u7535\u5b50\u8f6c\u79fb\u7684\u5173\u952e\u57fa\u5143\u6b65\u9aa4\u7684\u52a8\u529b\u5b66\u548c\u53cd\u5e94\u52bf\u5792\uff1b\u6eb6\u5242\u3001\u9633\u79bb\u5b50\u548c\u53cd\u5e94\u754c\u9762\u9644\u8fd1\u7684\u9634\u79bb\u5b50\u7684\u539f\u5b50\u3001\u5206\u5b50\u7ea7\u7684\u72b6\u6001\u63cf\u8ff0\uff1b\u4ee5\u53ca\u8d2f\u7a7f\u6574\u4e2a\u7535\u5316\u5b66\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u66f4\u4e3a\u5feb\u901f\u548c\u9ad8\u6548\u7684\u4fe1\u53f7\u5b9e\u65f6\u91c7\u96c6\u65b9\u6cd5\u7b49\uff0c\u8fd9\u4e9b\u95ee\u9898\u4ecd\u7136\u662f\u7535\u50ac\u5316\u53cd\u5e94\u7814\u7a76\u7684\u524d\u6cbf\u3002\u603b\u4e4b\uff0c\u7535\u5316\u5b66\u8868\u5f81\u65b9\u6cd5\u7684\u6df1\u5165\u7814\u7a76\u4e3a\u65b0\u578b\u9ad8\u6548\u50ac\u5316\u5242\u4f53\u7cfb\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u6307\u5bfc\u7b56\u7565\u3002<\/p>\n<p>\u53c2\u8003\u6587\u732e\uff1a<\/p>\n<p>Bard A J, Faulkner L R, \u7535\u5316\u5b66\u65b9\u6cd5\u539f\u7406\u548c\u5e94\u7528, \u5316\u5b66\u5de5\u4e1a\u51fa\u7248\u793e, 2005.<\/p>\n<p>Zhi Wei Seh et al. Combining Theory and Experiment in Electrocatalysis: Insights Into Materials Design[J], Science, 2017.<\/p>\n<p>Frano B, PEM\u71c3\u6599\u7535\u6c60\uff1a\u7406\u8bba\u4e0e\u5b9e\u8df5, \u673a\u68b0\u5de5\u4e1a\u51fa\u7248\u793e, 2005.<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u4e13\u680f\u79d1\u6280\u987e\u95ee\u5510\u5609\u4eea\u6574\u7406\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8fd1\u5e74\u6765\uff0c\u4f34\u968f\u7740\u793e\u4f1a\u7684\u53d1\u5c55\u548c\u4eba\u7c7b\u7684\u8fdb\u6b65\uff0c\u65e5\u76ca\u4e25\u5cfb\u7684\u80fd\u6e90\u4e0e\u73af\u5883\u95ee\u9898\u6210\u4e3a\u4e9f\u5f85\u89e3\u51b3\u7684\u4e16\u754c\u6027\u96be\u9898\u3002\u4eba\u4eec\u81f4\u529b\u4e8e\u5bfb\u6c42\u65b0\u80fd\u6e90\u7684\u6709\u6548\u5229\u7528\u65b9\u5f0f\u548c\u73af\u5883\u7684\u957f\u6548\u51c0\u5316\u65b9\u6cd5\uff0c\u76ee\u524d\u5e7f\u4e3a\u7814\u7a76\u7684\u4fc3&#8230;<\/p>\n","protected":false},"author":10213,"featured_media":174190,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-155000","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-ganhuo"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/155000"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/10213"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=155000"}],"version-history":[{"count":9,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/155000\/revisions"}],"predecessor-version":[{"id":155049,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/155000\/revisions\/155049"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/174190"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=155000"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=155000"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=155000"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}