{"id":154764,"date":"2018-09-30T06:34:54","date_gmt":"2018-09-29T22:34:54","guid":{"rendered":"\/\/m.iemloyee.com\/?p=154764"},"modified":"2018-09-28T21:32:42","modified_gmt":"2018-09-28T13:32:42","slug":"%e4%b9%94%e4%b8%96%e7%92%8badv-energy-mater-%e7%a1%92%e5%8c%96%e9%92%b4%e5%82%ac%e5%8c%96%e5%89%82%e7%94%b5%e8%8d%b7%e6%80%81%e8%b0%83%e6%8e%a7%e5%8f%8a%e5%85%b6%e5%85%a8%e5%88%86%e8%a7%a3%e6%b5%b7","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=154764","title":{"rendered":"\u4e54\u4e16\u748bAdv. Energy Mater. :\u7852\u5316\u94b4\u50ac\u5316\u5242\u7535\u8377\u6001\u8c03\u63a7\u53ca\u5176\u5168\u5206\u89e3\u6d77\u6c34"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7852\u5316\u94b4\uff0c\u4f5c\u4e3a\u4e00\u79cd\u5178\u578b\u7684\u8fc7\u6e21\u91d1\u5c5e\u786b\u65cf\u5316\u7269\u7535\u50ac\u5316\u5242\uff0c\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u7535\u50ac\u5316\u6d3b\u6027\u4ee5\u53ca\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5f15\u8d77\u4e86\u7814\u7a76\u4eba\u5458\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7852\u5316\u94b4\u7684\u7535\u50ac\u5316\u6d3b\u6027\u4e3b\u8981\u5f52\u56e0\u4e8e\u9002\u5b9c\u7684\u8868\u9762\u6d3b\u6027\u4f4d\u70b9\uff0c\u4f7f\u5f97Se\/Co\u7269\u79cd\u80fd\u591f\u4e0e\u7535\u89e3\u6c34\u53cd\u5e94\u4e2d\u95f4\u4f53\u5f62\u6210\u9002\u5f53\u7684\u5316\u5b66\u952e\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u7852\u5316\u94b4\u53ef\u901a\u8fc7\u6c34\u70ed\/\u6eb6\u5242\u70ed\u3001\u7535\u5316\u5b66\u6c89\u79ef\u4ee5\u53ca\u76f4\u63a5\u7852\u5316\u6cd5\u5236\u5907\uff0c\u7136\u800c\u4e0a\u8ff0\u65b9\u6cd5\u96be\u4ee5\u63a7\u5236\u94b4\u7684\u4ef7\u6001\uff0c\u4e0d\u5229\u4e8e\u8c03\u8282\u50ac\u5316\u5242\u7684\u7535\u50ac\u5316\u6027\u80fd\u3002\u6b64\u5916\uff0c\u62a5\u9053\u6700\u591a\u7684\u7528\u4e8e\u5206\u89e3\u6c34\u7684\u7852\u5316\u94b4\u7535\u50ac\u5316\u5242\u662fCoSe2<\/sub>\u57fa\u6750\u6599\uff0c\u4ec5\u5c11\u6570\u62a5\u9053\u662f\u5173\u4e8eCo0.85<\/sub>Se\u548cCo3<\/sub>Se4<\/sub>\u4f5c\u4e3a\u7535\u50ac\u5316\u5242\u7684\u7814\u7a76\uff0c\u800c\u5173\u4e8e\u7852\u5316\u94b4\u7535\u50ac\u5316\u5242\u5728\u6d77\u6c34\u5206\u89e3\u4e2d\u7684\u5e94\u7528\u5219\u5c1a\u672a\u62a5\u9053\u3002\u56e0\u6b64\uff0c\u4e9f\u5f85\u5f00\u53d1\u4e00\u79cd\u7b80\u4fbf\u53ef\u63a7\u7684\u65b9\u6cd5\u6765\u5236\u5907\u5177\u6709\u53ef\u63a7\u94b4\u4ef7\u6001\u4ee5\u53ca\u53ef\u7535\u50ac\u5316\u5206\u89e3\u6d77\u6c34\u7684\u65b0\u578b\u7852\u5316\u94b4\u7535\u50ac\u5316\u5242\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6fb3\u5927\u5229\u4e9a\u963f\u5fb7\u83b1\u5fb7\u5927\u5b66\u4e54\u4e16\u748b\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5728\u771f\u7a7a\u5bc6\u5c01\u5b89\u74ff\u74f6\u4e2d\u4e00\u6b65\u7145\u70e7\u94b4\u7b94\u4e0e\u7852\u7c89\u5236\u5907\u4e86\u5177\u6709CoSe\u548cCo9<\/sub>Se8<\/sub>\u76f8\u76843D\u7852\u5316\u94b4\u7535\u6781\uff0c\u901a\u8fc7\u63a7\u5236\u94b4\u4e0e\u7852\u7684\u8d28\u91cf\u6bd4\u6765\u63a7\u5236\u94b4\u7684\u4ef7\u6001\u4ee5\u53ca\u50ac\u5316\u5242\u7684\u7535\u50ac\u5316\u6027\u80fd\uff0c\u5e76\u5728Adv. Energy Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cCharge State Manipulation of Cobalt Selenide Catalyst for Overall Seawater Electrolysis<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u673a\u7406\u7814\u7a76\u8868\u660e\uff0c\u5bf9\u4e8e\u4e0a\u8ff0\u7852\u5316\u94b4\u7535\u50ac\u5316\u5242\u6765\u8bf4\uff0c\u9ad8\u94b4\u7535\u8377\u6001(Co-Se1)\u6709\u5229\u4e8e\u6790\u6c27\u53cd\u5e94\u6d3b\u6027\u63d0\u5347\uff0c\u800c\u4f4e\u94b4\u7535\u8377\u6001(Co-Se4)\u53ef\u4fc3\u8fdb\u6790\u6c22\u53cd\u5e94\u8fdb\u884c\u3002\u6240\u5f97\u6750\u6599\u53ef\u4f5c\u4e3a\u72ec\u7acb\u7684\u53cc\u529f\u80fd\u7535\u50ac\u5316\u7535\u6781\u7528\u4e8e\u78b1\u6027\u4ecb\u8d28\u4e2d\u7684\u6790\u6c27\u53cd\u5e94\u548c\u6790\u6c22\u53cd\u5e94\u3002\u6b64\u5916\uff0c\u4ee5\u5408\u6210\u7684\u7852\u5316\u94b4\u7535\u6781\u4f5c\u4e3a\u9633\u6781\u548c\u9634\u6781\u7528\u4e8e\u5168\u5206\u89e3\u6d77\u6c34\uff0c1.8V\u4e0b\u5b9e\u73b0\u4e8610.3 mA\u00b7cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u662f\u76f8\u540c\u7535\u538b\u4e0b\u8d35\u91d1\u5c5e\u57fa\u7535\u50ac\u5316\u5242\u7684\u4e09\u500d(2.9 mA\u00b7cm-2<\/sup>)\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u7852\u5316\u94b4\u7535\u6781\u7684\u7535\u50ac\u5316\u6027\u80fd\u660e\u663e\u9ad8\u4e8eNi\/Ir-C\u548cNi\/Pt-C\u590d\u5408\u7535\u6781\u3002\u56e0\u6b64\uff0c\u4e0a\u8ff0\u65b0\u578b\u53cc\u529f\u80fd\u7535\u6781\u6709\u671b\u5728\u5b9e\u9645\u5927\u89c4\u6a21\u7535\u89e3\u6c34\u5f97\u5230\u5e94\u7528\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u7852\u5316\u94b4\u50ac\u5316\u5242\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) Co-Se1\u7684TEM\u56fe\u50cf\u4ee5\u53ca\u76f8\u5e94\u7684SAED\u56fe\u8c31(\u5185\u63d2)\uff1b
\n b) Co-Se1\u7684HRTEM\u56fe\u50cf\u4ee5\u53caSEM\u56fe\u50cf\u3001\u76f8\u5e94\u7684\u5143\u7d20\u5206\u5e03(\u5185\u63d2)\uff1b
\n c) Co-Se4\u7684TEM\u56fe\u50cf\u4ee5\u53ca\u76f8\u5e94\u7684SAED\u56fe\u8c31(\u5185\u63d2)\uff1b
\n d) Co-Se4\u7684HRTEM\u56fe\u50cf\u4ee5\u53caSEM\u56fe\u50cf\u3001\u76f8\u5e94\u7684\u5143\u7d20\u5206\u5e03(\u5185\u63d2)\u3002<\/p>\n

\u56fe2 \u7852\u5316\u94b4\u50ac\u5316\u5242\u7684\u6676\u4f53\u7ed3\u6784\u53ca\u8868\u9762\u5143\u7d20\u4ef7\u6001<\/strong><\/p>\n

\"\"<\/p>\n

a) Co-Se1\u548cCo-Se4\u7684XRD\u56fe\u8c31\uff1b
\n b) Co-Se1\u7684Co 2p XPS\u5149\u8c31\uff1b
\n c) Co-Se4\u7684Co 2p XPS\u5149\u8c31\uff1b
\n d) Co-Se1\u548cCo-Se4\u540c\u6b65\u8f90\u5c04\u57faCo K\u8fb9XANES\u5149\u8c31\u4ee5\u53ca\u653e\u5927\u7684\u8fd1\u8fb9\u7ed3\u6784(\u5185\u63d2)\uff1b
\n e) Co-Se1\u548cCo-Se4\u5085\u91cc\u53f6\u53d8\u6362\u7684EXAFS\u5149\u8c31\u3002<\/p>\n

\u56fe3 \u7852\u5316\u94b4\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) 1.0 M KOH\u4e2d\uff0cNi\/Ir-C\u3001Co-Se1\u3001Co-Se4\u548c\u94b4\u7b94\u7684OER\u6027\u80fd\uff1b
\n b) \u76f8\u5e94\u7684Tafel\u659c\u7387\u53ca\u7ebf\u6027\u62df\u5408\uff1b
\n c) Co-Se1\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5185\u63d2\u4e3aNi\/Ir-C\u548cCo-Se1\u57281.0 M KOH\u4e2d\u53ca1.57 V (vs RHE)\u6052\u7535\u538b\u4e0b\u7535\u6d41\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff1b
\n d) 1.0 M KOH\u4e2dNi\/Pt-C\u3001Co-Se1\u3001Co-Se4\u548c\u94b4\u7b94\u7684HER\u6027\u80fd\uff1b
\n e) \u76f8\u5e94\u7684Tafel\u659c\u7387\u53ca\u7ebf\u6027\u62df\u5408\uff1b
\n f) Co-Se4\u7684\u5faa\u73af\u7a33\u5b9a\u6027\uff0c\u5185\u63d2\u4e3aNi\/Pt-C\u548cCo-Se4\u57281.0 M KOH\u4e2d\u3001\u6052\u7535\u538b\u4e0b\u7535\u6d41\u968f\u65f6\u95f4\u7684\u53d8\u5316\u3002<\/p>\n

\u56fe4 \u7852\u5316\u94b4\u50ac\u5316\u5242\u7684\u7535\u50ac\u5316\u5168\u5206\u89e3\u6d77\u6c34\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) \u626b\u901f5 mV\u00b7s-1<\/sup>\u4e0b\uff0cCo-Se1\/\/Co-Se4\u548cIr-C\/\/Pt-C\u57281.0 M KOH\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\uff1b
\n b) \u626b\u901f5 mV\u00b7s-1<\/sup>\u4e0b\uff0cCo-Se1\/\/Co-Se4\u548cIr-C\/\/Pt-C\u5728\u7f13\u51b2\u6eb6\u6db2\u548c\u6d77\u6c34\u4e2d\u7684\u6781\u5316\u66f2\u7ebf\u3002<\/p>\n

\u56fe5 \u7852\u5316\u94b4\u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u6027\u80fd\u589e\u5f3a\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

a) \u626b\u901f5 mV\u00b7s-1<\/sup>\u4e0b\uff0c\u94b4\u7b94\u3001Co-Se1\u3001Co-Se2\u3001Co-Se3\u3001Co-Se4\u548cCo-Se5\u57281.0 M KOH\u4e2d\u7684OER\u6027\u80fd\uff1b
\n b) \u626b\u901f5 mV\u00b7s-1<\/sup>\u4e0b\uff0c\u94b4\u7b94\u3001Co-Se1\u3001Co-Se2\u3001Co-Se3\u3001Co-Se4\u548cCo-Se5\u57281.0 M KOH\u4e2d\u7684HER\u6027\u80fd\uff1b
\n c) \u6240\u5236\u5907\u7852\u5316\u94b4\u8fbe\u5230100 mA\u00b7cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u7684OER\u8fc7\u7535\u52bf\uff1b
\n d) \u6240\u5236\u5907\u7852\u5316\u94b4\u8fbe\u5230100 mA\u00b7cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u7684HER\u8fc7\u7535\u52bf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u63d0\u51fa\u4e86\u4e00\u79cd\u7b80\u4fbf\u3001\u53ef\u6269\u5927\u5316\u7684\u7528\u4e8e\u5236\u5907\u5177\u6709CoSe\u548cCo9<\/sub>Se8<\/sub>\u76f8\u7684\u65b0\u578b3D\u7852\u5316\u94b4\u7535\u6781\u7684\u65b9\u6cd5\uff0c\u901a\u8fc7\u63a7\u5236\u539f\u6599\u7684\u8d28\u91cf\u6bd4\u4ee5\u53ca\u5728\u9ad8\u6e29\u4e0b\u7145\u70e7\u771f\u7a7a\u5bc6\u5c01\u5b89\u74ff\u74f6\u53ef\u5bf9\u6240\u5236\u5907\u7684\u7852\u5316\u94b4\u50ac\u5316\u5242\u7684\u94b4\u4ef7\u6001\u548c\u7535\u50ac\u5316\u6027\u80fd\u8fdb\u884c\u8c03\u63a7\u30023D\u7f51\u7edc\u3001\u5145\u5206\u66b4\u9732\u7684\u7535\u50ac\u5316\u4e2d\u5fc3\u4ee5\u53ca\u5feb\u901f\u7535\u8377\u8f6c\u79fb\u80fd\u529b\u662f\u4e0a\u8ff0\u65b0\u578b\u7535\u6781\u7684\u7535\u50ac\u5316OER\u548cHER\u6d3b\u6027\u548c\u7a33\u5b9a\u6027\u8f83\u9ad8\u7684\u539f\u56e0\uff0c\u8fdb\u800c\u4ea7\u751f\u4e86\u826f\u597d\u7684\u5168\u5206\u89e3\u6d77\u6c34\u6027\u80fd\u3002\u8be5\u5de5\u4f5c\u8fdb\u4e00\u6b65\u53d1\u5c55\u4e86\u7852\u5316\u94b4\u7535\u50ac\u5316\u5242\uff0c\u5e76\u4e3a\u6e05\u6d01\u80fd\u6e90\u7cfb\u7edf\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u89c6\u89d2\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aCharge State Manipulation of Cobalt Selenide Catalyst for Overall Seawater Electrolysis<\/a><\/strong>\u00a0(Adv. Energy Mater.<\/strong>, 2018, DOI: 10.1002\/aenm.201801926)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7852\u5316\u94b4\uff0c\u4f5c\u4e3a\u4e00\u79cd\u5178\u578b\u7684\u8fc7\u6e21\u91d1\u5c5e\u786b\u65cf\u5316\u7269\u7535\u50ac\u5316\u5242\uff0c\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u7535\u50ac\u5316\u6d3b\u6027\u4ee5\u53ca\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u5f15\u8d77\u4e86\u7814\u7a76\u4eba\u5458\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7852\u5316\u94b4\u7684\u7535\u50ac\u5316\u6d3b\u6027\u4e3b\u8981\u5f52\u56e0\u4e8e\u9002\u5b9c\u7684\u8868\u9762…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1414,3592,2569],"class_list":["post-154764","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-qiaoshizhang","tag-3592","tag-2569"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/154764"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=154764"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/154764\/revisions"}],"predecessor-version":[{"id":155050,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/154764\/revisions\/155050"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=154764"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=154764"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=154764"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}