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APTS\u6dfb\u52a0\u5242\u4e4b\u540e\uff0c\u5faa\u73af\u6027\u80fd\u5f97\u5230\u5927\u5e45\u63d0\u5347\uff0c\u5e93\u4f26\u6548\u7387\u4e5f\u7a33\u5b9a\u5728100%\u5de6\u53f3\u3002<\/p>\n<p><strong>\u56fe2\uff1aLi<sub>1.2<\/sub>Mn<sub>0.55<\/sub>Ni<sub>0.15<\/sub>Co<sub>0.1<\/sub>O<sub>2<\/sub>\/Li\u7535\u6c60\u5728\u5747\u542b600ppmHF\u7684\u4e0d\u540c\u7535\u89e3\u6db2\u4e2d\u7684\u5faa\u73af\u6027\u80fd \uff08a\uff09\u4e0e\u5e93\u4f26\u6548\u7387\uff08b\uff09\u3002<\/strong><\/p>\n<p><strong>\u00a0<a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/2-20.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154364\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/2-20.png\" alt=\"\" width=\"547\" height=\"205\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/2-20.png 547w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/2-20-300x112.png 300w\" sizes=\"(max-width: 547px) 100vw, 547px\" \/><\/a><\/strong><\/p>\n<p><strong>\u4e3a\u4e86\u63a2\u7a76HF\u9178\u5bf9<\/strong>Li<sub>1.2<\/sub>Mn<sub>0.55<\/sub>Ni<sub>0.15<\/sub>Co<sub>0.1<\/sub>O<sub>2<\/sub>\/Li\u7535\u6c60\u6027\u80fd\u7684\u5f71\u54cd\u4ee5\u53caAPTS\u6dfb\u52a0\u5242\u5728HF\u9178\u7684\u4f5c\u7528\uff0c\u7814\u7a76\u4eba\u5458\u5728STD\u4ee5\u53ca\u542bAPTS\u7684\u7535\u89e3\u6db2\u4e2d\u5747\u52a0\u5165600 ppm \u7684HF\u9178\uff0c\u5bf9\u6bd4\u5176\u5faa\u73af\u6027\u80fd\u3002\u53ef\u4ee5\u770b\u51fa\uff0c\u4e0e\u6ca1\u6709\u52a0HF\u9178\u7684\u76f8\u6bd4\uff08\u56fe1\uff09\uff0c\u52a0\u4e86HF\u9178\u4e4b\u540e\uff0c\u5728STD\u7535\u89e3\u6db2\u5faa\u73af\u7535\u6c60\u572860\u6b21\u5faa\u73af\u5c31\u51fa\u73b0\u5927\u5e45\u4e0b\u964d\uff0c\u8868\u660eHF\u9178\u5bf9Li<sub>1.2<\/sub>Mn<sub>0.55<\/sub>Ni<sub>0.15<\/sub>Co<sub>0.1<\/sub>O<sub>2<\/sub>\/Li\u7535\u6c60\u6027\u80fd\u6709\u7740\u4e25\u91cd\u7684\u7834\u574f\u4f5c\u7528\u3002\u76f8\u53cd\uff0c\u52a0\u4e86APTS\u6dfb\u52a0\u5242\u4e4b\u540e\uff0c\u5faa\u73af\u6027\u80fd\u4f9d\u65e7\u7a33\u5b9a\uff0c\u8868\u660eAPTS\u80fd\u591f\u6d88\u9664HF\u9178\u5bf9\u7535\u6c60\u7684\u8d1f\u9762\u4f5c\u7528\u3002<\/p>\n<p>\u7814\u7a76\u4eba\u5458\u6700\u540e\u603b\u7ed3\u4e86APTS\u7684\u4f5c\u7528\u673a\u7406\u56fe\u3002\u5728STD\u4e2d\uff0c\u7535\u89e3\u6db2\u5728\u6b63\u6781\u8868\u9762\u53d1\u751f\u6c27\u5316\u5206\u89e3\uff0c\u4ea7\u751f\u4e00\u7cfb\u5217\u7684\u526f\u4ea7\u7269\uff0c\u4ea7\u751f\u6709\u5bb3\u7684HF\u9178\uff0c\u8bf1\u5bfc\u8fc7\u5ea6\u91d1\u5c5e\u79bb\u5b50\u6eb6\u89e3\uff0c\u7834\u574f\u6676\u683c\u7ed3\u6784\uff1b\u8986\u76d6\u5728\u6750\u6599\u8868\u9762\u7684\u805a\u5408\u7269\u964d\u4f4e\u4e86\u9502\u79bb\u5b50\u7684\u4f20\u5bfc\uff0c\u589e\u52a0\u4e86\u7535\u5316\u5b66\u963b\u6297\uff0c\u6700\u7ec8\u5bfc\u81f4\u7535\u6c60\u5faa\u73af\u6027\u80fd\u7684\u8870\u51cf\u3002\u5728\u7535\u89e3\u6db2\u52a0\u5165APTS\u6dfb\u52a0\u5242\u4e4b\u540e\uff0c\u6dfb\u52a0\u5242\u4f18\u5148\u4e0e\u7535\u89e3\u6db2\u4e2d\u7684HF\u9178\u7edc\u5408\uff0c\u6d88\u9664\u6709\u5bb3\u7684HF\u9178\uff1b\u6240\u4ea7\u751f\u7684\u7684APTS-F- \u7edc\u5408\u7269\u5177\u6709\u6700\u4f4e\u7684\u6c27\u5316\u7535\u4f4d\uff0c\u4f18\u5148\u5728\u6b63\u6781\u6750\u6599\u8868\u9762\u5f62\u6210\u4e00\u5c42\u8f83\u8584\u7684\u754c\u9762\u4fdd\u62a4\u819c\uff0c\u8fd9\u4e2a\u6210\u819c\u8fc7\u7a0b\u540c\u65f6\u5c06\u7535\u89e3\u6db2\u4e2d\u7684\u6709\u5bb3F<sup>&#8211; <\/sup>\u8f6c\u79fb\u5230\u4fdd\u62a4\u819c\u4e2d\uff0cF<sup>&#8211; <\/sup>\u7684\u53c2\u4e0e\u6709\u6548\u589e\u52a0\u4e86\u754c\u9762\u819c\u7684\u7a33\u5b9a\u6027\u3002\u4fdd\u62a4\u819c\u6709\u6548\u63d0\u9ad8\u4e86\u7535\u6781\/\u7535\u89e3\u6db2\u754c\u9762\u7684\u7a33\u5b9a\u6027\uff0c\u6709\u6548\u63d0\u9ad8\u4e86LMR\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>\u56fe3\uff1a\u4e0d\u540c\u7535\u89e3\u6db2\u7684\u6838\u78c1\uff08NMR\uff09<sup>19<\/sup>F\u8c31\u3002<\/strong><\/p>\n<p><strong>\u00a0<a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/3-21.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154365\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/3-21.png\" alt=\"\" width=\"554\" height=\"420\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/3-21.png 554w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/3-21-300x227.png 300w\" sizes=\"(max-width: 554px) 100vw, 554px\" \/><\/a><\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u901a\u8fc7NMR\u8fdb\u4e00\u6b65\u63a2\u7a76\u4e86APTS \u6dfb\u52a0\u5242\u4e0eHF\u9178\u7684\u76f8\u4e92\u4f5c\u7528\u3002\u4eced\u56fe\u53ef\u4ee5\u770b\u51fa\uff0c\u52a0\u4e86\u6dfb\u52a0\u5242\u4e4b\u540e\uff0cHF\u9178\u7684\u7279\u5f81\u5cf0\u660e\u663e\u6d88\u5931\uff08\u4e0eb\u56fe\u76f8\u6bd4\uff09\uff0c\u8868\u660eAPTS\u80fd\u591f\u7edc\u5408\u6d88\u9664\u7535\u89e3\u6db2\u4e2d\u7684HF\u9178\u3002<\/p>\n<p><strong>\u56fe4\uff1aX-HF\uff08a\uff09\uff0cX- F<sup>&#8211;<\/sup>\uff08b\uff09\uff0cX- H<sup>+<\/sup>\uff08c\uff09\uff0cX-Li<sup>+<\/sup>\uff08d\uff09\uff0cX-PF<sub>6<\/sub><sup>&#8211;<\/sup>\uff08e\uff09\u7684\u4f18\u5316\u7ed3\u6784\u4e0e\u7ed3\u5408\u80fd\uff08Eb=KJ\/mol\uff09\uff0cX=EC, EMC, DEC \u548cAPTS\u3002<\/strong><\/p>\n<p><strong>\u00a0<a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/4-19.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154366\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/4-19.png\" alt=\"\" width=\"525\" height=\"804\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/4-19.png 525w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/4-19-196x300.png 196w\" sizes=\"(max-width: 525px) 100vw, 525px\" \/><\/a><\/strong><\/p>\n<p>\u4e3a\u4e86\u63a2\u7a76APTS\u4e0eHF\u7edc\u5408\u7684\u673a\u7406\uff0c\u7814\u7a76\u4eba\u5458\u8fd8\u901a\u8fc7\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u7814\u7a76\u4e86\u4e0d\u540c\u7269\u8d28\u4e4b\u95f4\u7684\u7ed3\u5408\u80fd\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4e0eEC\u3001EMC\u548cDEC\u76f8\u6bd4\uff0cAPTS\u4e0eHF\u3001H<sup>+<\/sup>\u548cF<sup>&#8211;<\/sup> \u5177\u6709\u76f8\u5bf9\u8f83\u5927\u7684\u7ed3\u5408\u80fd\uff0c\u4ee5\u4e3a\u7740APTS\u80fd\u591f\u4f18\u5148\u4e8e\u78b3\u9178\u916f\u6eb6\u5242\u4e0eHF\u9178\u7edc\u5408\uff0c\u6d88\u9664HF\u3002\u76f8\u53cd\uff0cAPTS\u5374\u4e0d\u5bb9\u6613\u4e0eLi<sup>+<\/sup>\u3001PF<sub>6<\/sub><sup>&#8211;<\/sup>\u7ed3\u5408\uff0c\u6709\u5229\u4e8e\u5176\u66f4\u5bb9\u6613\u805a\u96c6\u5728\u6b63\u6781\u8868\u9762\u6c27\u5316\uff0c\u51cf\u5c11PF<sub>6<\/sub><sup>&#8211;<\/sup> \u7684\u5206\u89e3\u3002<\/p>\n<p><strong>\u56fe5\uff1a\u5728\u542b\u6216\u4e0d\u542b\u6709HF\u9178\u7684\u7535\u89e3\u6db2\u7684\u9996\u6b21\u5145\u653e\u7535\u66f2\u7ebf\uff08a\uff0cc\uff09\u4ee5\u53ca\u7ebf\u6027\u626b\u63cf\u66f2\u7ebf\uff08b\uff0cd\uff09\u3002<\/strong><\/p>\n<p><strong>\u00a0<a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/5-12.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154367\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/5-12.png\" alt=\"\" width=\"528\" height=\"384\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/5-12.png 528w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/5-12-300x218.png 300w\" sizes=\"(max-width: 528px) 100vw, 528px\" \/><\/a><\/strong><\/p>\n<p>\u901a\u8fc7\u9996\u6b21\u5145\u653e\u7535\u66f2\u7ebf\u4ee5\u53caLSV\uff0c\u7814\u7a76\u4eba\u5458\u63a2\u7a76\u4e86\u4e0d\u540c\u7535\u89e3\u6db2\u7684\u6c27\u5316\u884c\u4e3a\u3002\u53ef\u4ee5\u770b\u51fa\uff0c\u6dfb\u52a0\u5242\u57284.25V\u5c31\u5f00\u59cb\u6c27\u5316\uff08\u56feb\uff09\uff0c\u800cSTD\u7535\u89e3\u6db2\u5219\u662f4.5\u5f00\u59cb\u6c27\u5316\uff0c\u8868\u660eAPTS\u80fd\u591f\u4f18\u5148\u4e8e\u78b3\u9178\u916f\u6eb6\u5242\u53d1\u751f\u6c27\u5316\u53cd\u5e94\uff0c\u5f62\u6210\u754c\u9762\u4fdd\u62a4\u819c\u3002\u52a0\u4e86600 ppm\u4e4b\u540e\uff0c\u76f8\u6bd4\u4e8e\u56feb\uff0c\u4e24\u8005\u7535\u89e3\u6db2\u7684\u6c27\u5316\u7535\u4f4d\u5747\u6709\u6240\u63d0\u524d\uff08\u56fed\uff09\uff0c\u8868\u660eHF\u9178\u4fc3\u8fdb\u4e86\u7535\u89e3\u6db2\u7684\u6c27\u5316\u5206\u89e3\u3002\u5e78\u8fd0\u5730\u662f\uff0c\u542bAPTS\u7535\u89e3\u6db2\u7684\u6c27\u5316\u7535\u4f4d\uff084.09 V\uff09\u4f9d\u65e7\u6bd4STD\uff084.35 V\uff09\u7684\u66f4\u5c0f\uff0c\u8868\u660e\u5728HF\u9178\u7684\u5b58\u5728\uff0cAPTS\u6dfb\u52a0\u5242\u4e5f\u80fd\u591f\u4f18\u5148\u6c27\u5316\u3002<\/p>\n<p><strong>\u56fe6\uff1a<\/strong><strong>X (a), X-PF<sub>6<\/sub><sup>&#8211;<\/sup> (b), X-HF (c), X- H<sup>+<\/sup> (d), <\/strong><strong>\u548c X-F<sup>&#8211;<\/sup> (e), (X = EC, EMC, DEC, APTS)\u5931\u53bb\u4e00\u4e2a\u7535\u5b50<\/strong><strong>\u7684\u4f18\u5316\u7ed3\u6784\u4ee5\u53ca\u7535\u79bb\u80fd\uff08AIE, kJ mol<sup>\u22121<\/sup>\uff09\u3002<\/strong><\/p>\n<p><strong>\u00a0<a href=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/6-11.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-154368\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/6-11.png\" alt=\"\" width=\"526\" height=\"745\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/6-11.png 526w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/6-11-212x300.png 212w\" sizes=\"(max-width: 526px) 100vw, 526px\" \/><\/a><\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u518d\u6b21\u901a\u8fc7DFT\u8ba1\u7b97\u4e0d\u540c\u7edc\u5408\u7269\u7684\u7535\u79bb\u80fd\u7814\u7a76\u4e0a\u8ff0\u73b0\u8c61\u7684\u539f\u56e0\uff0c\u8ba1\u7b97\u7ed3\u679c\u663e\u793a\uff0c\u4e0eEC\u3001EMC\u548cDEC\u76f8\u6bd4\uff0cAPTS\u6dfb\u52a0\u5242\u5177\u6709\u76f8\u5bf9\u8f83\u5c0f\u7684\u7535\u79bb\u80fd\uff0c\u610f\u5473\u7740APTS\u66f4\u5bb9\u6613\u5728\u6b63\u6781\u8868\u660e\u5931\u53bb\u7535\u5b50\u88ab\u6c27\u5316\u3002\u800cPF6<sup>&#8211; <\/sup>\u7684\u5b58\u5728\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u4e86\u78b3\u9178\u916f\u6eb6\u5242\u548cAPTS\u7684\u7535\u79bb\u80fd\uff0c\u52a0\u5feb\u4e86\u5176\u5206\u89e3\u3002\u5f53HF\u5b58\u5728\u7684\u60c5\u51b5\u4e0b\uff0cHF\u5206\u5b50\u548cH+ \u5219\u589e\u52a0\u4e86\u4ed6\u4eec\u7684\u7535\u79bb\u80fd\u3002\u76f8\u53cd\uff0cF- \u7684\u5b58\u5728\uff0c\u5927\u5e45\u964d\u4f4e\u4e86\u6eb6\u5242\u4e0eAPTS\u7684\u7535\u79bb\u80fd\uff0c\u4fc3\u8fdb\u4e86\u5b83\u4eec\u7684\u6c27\u5316\u5206\u89e3\u3002\u8fd9\u4e2a\u7ed3\u8bba\u8868\u660e\u56fe5d\u73b0\u8c61\u80cc\u540e\u7684\u539f\u56e0\u662fF<sup>&#8211;<\/sup> \u4fc3\u8fdb\u4e86\u7535\u89e3\u6db2\u7684\u6c27\u5316\u5206\u89e3\uff0c\u800c\u4e0d\u662fHF\u5206\u5b50\u6216H<sup>+<\/sup>\u3002\u5e78\u8fd0\u7684\u662f\uff0c\u4e0eF<sup>\u2011<\/sup>\u79bb\u5b50\u7edc\u5408\u540e\uff0cAPTS\u6dfb\u52a0\u5242\u7684\u7535\u79bb\u80fd\u6700\u5c0f\uff0c\u8868\u660e APTS-F<sup>&#8211;<\/sup> \u7edc\u5408\u7269\u6700\u5bb9\u6613\u6c27\u5316\uff0c\u5c06F<sup>\u2011<\/sup> \u8f6c\u79fb\u5230\u754c\u9762\u4fdd\u62a4\u819c\u4e2d\u3002<\/p>\n<p><strong>\u56fe7\uff1a\u5faa\u73af\u524d\uff08a, 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\u6587\u732e\u94fe\u63a5 \u3011<\/strong><\/p>\n<p>Changchun Ye, et al. Converting detrimental HF in electrolytes into a highly fluorinated interphase on cathodes, Journal of Materials Chemistry A, 2018, 6, 17642\u201317652. DOI: 10.1039\/c8ta06150e<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com.<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5de5\u4f5c\u4eae\u70b9 \u3011 1.APTS\u4f5c\u4e3a\u65b0\u578b\u6dfb\u52a0\u5242\u6709\u6548\u6d88\u9664\u4e86\u7535\u89e3\u6db2\u4e2d\u6709\u5bb3\u7684HF\u9178 2.\u63d0\u51fa\u4e86\u53ef\u901a\u8fc7\u8f6c\u79fb\u7535\u89e3\u6db2\u4e2d\u6709\u5bb3HF\u9178\u6784\u5efa\u9ad8F\u76f8\u754c\u9762\u4fdd\u62a4\u819c\u7684\u65b0\u578b\u7b56\u7565 3.\u7531APTS\u6784&#8230;<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-154361","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/154361"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=154361"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/154361\/revisions"}],"predecessor-version":[{"id":154373,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/154361\/revisions\/154373"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=154361"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=154361"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=154361"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}