{"id":154101,"date":"2018-10-03T06:49:33","date_gmt":"2018-10-02T22:49:33","guid":{"rendered":"\/\/m.iemloyee.com\/?p=154101"},"modified":"2018-10-01T20:50:02","modified_gmt":"2018-10-01T12:50:02","slug":"%e4%b8%ad%e5%b1%b1%e5%a4%a7%e5%ad%a6%e8%8b%8f%e6%88%90%e5%8b%87%e6%9d%8e%e5%85%89%e7%90%b4adv-energy-mater-mof%e7%94%b5%e5%ad%90%e7%bb%93%e6%9e%84%e8%b0%83%e6%8e%a7%e5%8f%8a%e5%85%b6%e5%a2%9e","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=154101","title":{"rendered":"\u4e2d\u5c71\u5927\u5b66\u82cf\u6210\u52c7&\u674e\u5149\u7434Adv. Energy Mater. : MOF\u7535\u5b50\u7ed3\u6784\u8c03\u63a7\u53ca\u5176\u589e\u5f3a\u7535\u50ac\u5316OER\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u4e8e\u5176\u72ec\u7279\u7684\u7ed3\u6784\u4f18\u70b9\uff0c\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOF)\u5df2\u6210\u4e3a\u6700\u6709\u6f5c\u529b\u7684\u529f\u80fd\u6750\u6599\u4e4b\u4e00\uff0c\u5728\u6c14\u4f53\u50a8\u5b58\u548c\u5206\u79bb\u3001\u751f\u7269\u4f20\u611f\u5668\u548c\u50ac\u5316\u7b49\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u6700\u8fd1\uff0c2D MOF\u3001\u7c7b\u6c22\u6c27\u5316\u7269MOF\u3001\u590d\u5408MOF\u548c\u4e09\u91d1\u5c5eMOF\u5747\u5df2\u6709\u62a5\u9053\u53ef\u4f5c\u4e3a\u6709\u6548\u7684OER\u7535\u50ac\u5316\u5242\u3002\u7136\u800c\uff0cMOF\u4ecd\u7136\u5b58\u5728\u5bfc\u7535\u6027\u5dee\u3001\u5b54\u5f84\u5c0f\u4ee5\u53ca\u6709\u673a\u914d\u4f53\u5305\u8986\u6d3b\u6027\u91d1\u5c5e\u4e2d\u5fc3\u7b49\u95ee\u9898\uff0c\u9650\u5236\u4e86\u5176\u5728\u7535\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5236\u5b9a\u6709\u6548\u7684\u7b56\u7565\u4ee5\u63d0\u9ad8MOF\u7684\u7535\u50ac\u5316\u6027\u80fd\u4ecd\u7136\u5b58\u5728\u7740\u5de8\u5927\u7684\u6311\u6218\u3002\u4e00\u822c\u6765\u8bf4\uff0c\u529f\u80fd\u6750\u6599\u7684\u5fae\u89c2\u7ed3\u6784\u663e\u8457\u5f71\u54cd\u5176\u50ac\u5316\u6d3b\u6027\uff0c\u56e0\u6b64\u5bf9\u50ac\u5316\u5242\u7684\u7ed3\u6784\u8fdb\u884c\u8c03\u63a7\u6709\u671b\u7cbe\u786e\u8c03\u8282\u5176\u6027\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u5c71\u5927\u5b66\u82cf\u6210\u52c7\u6559\u6388\u3001\u674e\u5149\u7434\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u901a\u8fc7\u91d1\u5c5e\u3001\u5bf9\u82ef\u4e8c\u7532\u9178(A)\u548c2-\u6c28\u57fa\u5bf9\u82ef\u4e8c\u7532\u9178\u914d\u4f53(B)\u7684\u7ec4\u88c5\u5236\u5907\u4e86\u5f02\u8d28\u91d1\u5c5e-\u6709\u673a\u6846\u67b6(MOF)(\u8bb0\u4e3aA2.7<\/sub>B-MOF-FeCo1.6<\/sub>)\uff0c\u5176\u5177\u6709\u4f18\u5f02\u7684\u7535\u50ac\u5316OER\u6d3b\u6027\uff0c\u5e76\u5728Adv. Energy Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cModulating Electronic Structure of Metal-Organic Framework for Efficient Electrocatalytic Oxygen Evolution<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4e0a\u8ff0MOF\u572810 mA\u00b7cm-2<\/sup>\u4e0b\u5177\u6709288 mV\u7684\u8d85\u4f4e\u8fc7\u7535\u52bf\u4ee5\u53ca39 mV\u00b7dec-1<\/sup>\u7684Tafel\u659c\u7387\u3002\u4f18\u8d8a\u7684\u7535\u50ac\u5316OER\u6027\u80fd\u5e94\u5f52\u529f\u4e8e\u901a\u8fc7\u91d1\u5c5e\u8282\u70b9\u548c\u8fde\u63a5\u4f53\u7684\u8c03\u63a7\u5bf9MOF\u4e2d\u672c\u5f81\u50ac\u5316\u4e2d\u5fc3\u7684\u7535\u5b50\u7ed3\u6784\u4f18\u5316\u3002\u8be5\u5de5\u4f5c\u4e0d\u4ec5\u4e3a\u7eafMOF\u5728\u7535\u50ac\u5316\u4e2d\u7684\u5e94\u7528\u63d0\u4f9b\u4e86\u53c2\u8003\uff0c\u800c\u4e14\u8fd8\u63d0\u4f9b\u4e86\u4e00\u79cd\u901a\u8fc7\u8c03\u63a7MOF\u4e2d\u50ac\u5316\u6d3b\u6027\u4e2d\u5fc3\u7684\u7535\u5b50\u7ed3\u6784\u6765\u63d0\u9ad8\u7535\u50ac\u5316\u6027\u80fd\u7684\u6709\u6548\u7b56\u7565\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u5f02\u8d28MOF\u7684\u5236\u5907\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

\u7528\u4e8e\u7535\u50ac\u5316OER\u7684\u5f02\u8d28MOF\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 \u5f02\u8d28MOF\u7684\u5f62\u8c8c\u3001\u5143\u7d20\u7ec4\u6210\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) A2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684SEM\u56fe\u50cf\uff1b
\n b) A2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684TEM\u56fe\u50cf\uff1b
\n c) A2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684HAADF-STEM\u56fe\u50cf\u548cSTEM-EDS\u56fe\u50cf\u3002<\/p>\n

\u56fe3 \u5f02\u8d28MOF\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) A-MOF-Fe(Co)\u3001A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684LSV\u66f2\u7ebf\uff1b
\n b) A-MOF-Fe(Co)\u3001A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684Tafel\u659c\u7387\uff1b
\n c) \u5728O2<\/sub>\u9971\u548c1 M KOH\u4e2dA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684RRDE \u6d4b\u8bd5\uff1b
\n d)\u572810 mA\u00b7cm-2<\/sup>\u4e0b\u30011 M KOH\u4e2dA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684\u8ba1\u65f6\u7535\u4f4d\u66f2\u7ebf\u3002<\/p>\n

\u56fe4 \u5f02\u8d28MOF\u7535\u5316\u5b66\u6027\u80fd\u589e\u5f3a\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

a) A-MOF-Fe(Co)\u3001A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684Cdl<\/sub>\u6d4b\u8bd5\uff1b
\n b) A-MOF-Fe(Co)\u3001A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684EIS\u6d4b\u8bd5\u3002<\/p>\n

\u56fe5 \u5f02\u8d28MOF\u7684\u8868\u9762\u5143\u7d20\u4ef7\u6001<\/strong><\/p>\n

\"\"<\/p>\n

a) A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7B-MOF-FeCo1.6<\/sub>\u7684O 1s XPS\u5149\u8c31\uff1b
\n b) A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7B-MOF-FeCo1.6<\/sub>\u7684Fe 2p3\/2<\/sub> XPS\u5149\u8c31\uff1b
\n c) A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7B-MOF-FeCo1.6<\/sub>\u7684Co 2p3\/2<\/sub> \u5149\u8c31\u3002<\/p>\n

\u56fe6 \u5f02\u8d28MOF\u7684\u7406\u8bba\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

a) A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u7684DOS\u8ba1\u7b97\uff1b
\n b) A(B)-MOF-FeCo1.6<\/sub>\u548cA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u4e2d\u6bcf\u4e2a\u94b4\u539f\u5b50\u76843d\u8f68\u9053\u7535\u5b50\u6570\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong>
\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u7b80\u5355\u7684\u6eb6\u5242\u70ed\u6cd5\u5f15\u5165\u590d\u5408\u91d1\u5c5e\/\u6709\u673a\u8fde\u63a5\u4f53\u5236\u5907\u4e86\u5f02\u8d28MOF(A2.7<\/sub>B-MOF-FeCo1.6<\/sub>)\u3002\u901a\u8fc7\u5bf9\u91d1\u5c5e\u548c\u8fde\u63a5\u4f53\u7684\u7ec4\u5408\u8c03\u63a7\u53ef\u6781\u5927\u6539\u5584MOF\u7684\u7535\u50ac\u5316\u6027\u80fd\u3002\u56e0\u6b64\uff0cA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u53ef\u4f5c\u4e3aOER\u7684\u6709\u6548\u7535\u50ac\u5316\u5242\uff0c\u572810 mA \u00b7cm-2<\/sup>\u4e0b\u5177\u6709\u4f4e\u81f3288 mV\u7684\u8fc7\u7535\u4f4d\u4ee5\u53ca39 mV\u00b7dec-1<\/sup>\u7684Tafel\u659c\u7387\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u5728\u6ce1\u6cab\u954d(NF)\u4e0a\u539f\u4f4d\u751f\u957f\u4e86A2.7<\/sub>B-MOF-FeCo1.6<\/sub>(\u8bb0\u4e3aA2.7<\/sub>B-MOF-FeCo1.6<\/sub>-NF)\uff0c\u5176\u5728\u7535\u6d41\u5bc6\u5ea6\u4e3a10\u548c100 mA\u00b7cm-2<\/sup>\u65f6\u5206\u522b\u5b9e\u73b0\u4e86192\u548c281 mV\u7684\u8d85\u4f4e\u8fc7\u7535\u4f4d\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0cA2.7<\/sub>B-MOF-FeCo1.6<\/sub>\u4f18\u8d8a\u7684\u50ac\u5316\u6d3b\u6027\u5e94\u5f52\u56e0\u4e8e\u7535\u5b50\u7ed3\u6784\u8c03\u8282\u6240\u5e26\u6765\u7684\u50ac\u5316\u4e2d\u5fc3\u672c\u5f81\u6d3b\u6027\u63d0\u5347\u3002\u8be5\u5de5\u4f5c\u63d0\u4f9b\u4e86\u4e00\u79cd\u5229\u7528\u91d1\u5c5e\/\u8fde\u63a5\u4f53\u7684\u7ec4\u5408\u8c03\u63a7\u6765\u8bbe\u8ba1MOF\u7684\u65b0\u7b56\u7565\uff0c\u53ef\u5bf9MOF\u7684\u7535\u5b50\u7ed3\u6784\u548c\u50ac\u5316\u6d3b\u6027\u8fdb\u884c\u8c03\u63a7\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aModulating Electronic Structure of Metal-Organic Framework for Efficient Electrocatalytic Oxygen Evolution<\/a><\/strong>\u00a0(Adv. Energy Mater.<\/strong>, 2018, DOI: 10.1002\/aenm.201801564)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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