{"id":153847,"date":"2018-09-19T06:46:07","date_gmt":"2018-09-18T22:46:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=153847"},"modified":"2018-09-18T18:30:41","modified_gmt":"2018-09-18T10:30:41","slug":"%e4%b8%ad%e5%8d%97%e5%a4%a7%e5%ad%a6%e6%a2%81%e5%8f%94%e5%85%a8%e3%80%81%e5%91%a8%e6%b1%9f%e5%8f%97%e9%82%80%e5%9c%a8acs-energy-letters%e5%8f%91%e8%a1%a8-%e6%b0%b4%e7%b3%bb%e9%94%8c%e7%a6%bb%e5%ad%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=153847","title":{"rendered":"\u4e2d\u5357\u5927\u5b66\u6881\u53d4\u5168\u3001\u5468\u6c5fACS Energy Letters\u7efc\u8ff0\uff1a\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6700\u65b0\u8fdb\u5c55"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/span>\u3011<\/strong><\/p>\n

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\u56fe 2 <\/b><\/strong>\u57fa\u4e8eZn<\/b><\/strong>2+<\/b><\/sup><\/strong>\u00a0\u5d4c\u5165\/\u8131\u51fa\u673a\u5236\u7684\u5178\u578b\u4f8b\u5b50\uff08\u4ee5\u9530\u57fa\u6b63\u6781\u6750\u6599\u4e3a\u4f8b\uff09<\/b><\/strong><\/span><\/p>\n

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\u7535\u89e3\u6db2\u7684\u5316\u5b66\u548c\u7269\u7406\u6027\u8d28\uff0c\u5982\u6eb6\u5242\u79cd\u7c7b\u3001\u950c\u76d0\u79cd\u7c7b\u3001\u6d53\u5ea6\u4ee5\u53ca\u6dfb\u52a0\u5242\u7b49\uff0c\u5bf9\u6c34\u7cfbZIBs\u7684\u7535\u5316\u5b66\u6027\u80fd\u6709\u7740\u5341\u5206\u91cd\u5927\u7684\u5f71\u54cd\u3002\u56e0\u6b64\u5f00\u53d1\u6c34\u7cfb\u7535\u89e3\u6db2\u7684\u539f\u5219\u5728\u4e8e\u8c03\u6574\u5176\u7279\u6027\uff0c\u4ee5\u4fdd\u8bc1\u9ad8\u6548\u7684Zn\u6c89\u79ef\/\u5265\u79bb<\/b><\/strong><\/span>\uff0c\u4ee5\u53ca\u6709\u6548\u5730\u6291\u5236\u950c\u91d1\u5c5e\u8868\u9762\u679d\u6676\u751f\u957f<\/b><\/strong>\u3002<\/span><\/p>\n

\u00a0<\/b><\/strong>\u3010<\/b><\/strong>\u603b\u7ed3\u4e0e\u5c55\u671b<\/b><\/strong>\u3011<\/b><\/strong><\/span><\/p>\n

\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u6211\u4eec\u7740\u91cd\u4e8e\u6c34\u7cfbZIBs\u7684\u6700\u65b0\u8fdb\u5c55\uff0c\u5e76\u5c31\u5176\u6240\u6d89\u53ca\u7684\u4e3b\u8981\u65b9\u9762\u63d0\u4f9b\u4e86\u6df1\u5165\u8ba8\u8bba\u3002\u7cfb\u7edf\u603b\u7ed3\u4e86\u6c34\u7cfbZIBs\u4f53\u7cfb\u4e2d\u4e3b\u8981\u7684\u4e09\u79cd\u50a8\u80fd\u673a\u5236\uff1a\uff081\uff09Zn2+<\/sup>\u5d4c\u5165\/\u8131\u5d4c\u53cd\u5e94\u673a\u5236\uff1b\uff082\uff09\u5316\u5b66\u8f6c\u5316\u53cd\u5e94\u673a\u5236\uff083\uff09H+<\/sup>\/Zn2+<\/sup>\u5171\u5d4c\u5165\/\u8131\u5d4c\u53cd\u5e94\u673a\u5236\u3002\u8fd8\u5168\u9762\u7efc\u8ff0\u4e86\u5404\u79cd\u7c7b\u578b\u6b63\u6781\u3001\u950c\u8d1f\u6781\u4ee5\u53ca\u7535\u89e3\u6db2\u7684\u4f18\u7f3a\u70b9\u4ee5\u53ca\u76ee\u524d\u7684\u4f18\u5316\u7b56\u7565\u3002\u7136\u800c\uff0c\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u60f3\u83b7\u5f97\u9ad8\u6027\u80fd\u6c34\u7cfbZIBs\u7684\u91cd\u5927\u7a81\u7834\u4ecd\u7136\u5b58\u5728\u4e25\u5cfb\u6311\u6218\u3002\u5728\u8fd9\u91cc\uff0c\u6211\u4eec\u5c31\u6c34\u7cfbZIBs\u672a\u6765\u7684\u53d1\u5c55\u63d0\u51fa\u4e86\u51e0\u70b9\u5c55\u671b\uff0c\u5305\u62ec1\uff09\u6df1\u5165\u4e86\u89e3\u50a8\u80fd\u673a\u7406<\/b><\/strong>\uff1b2\uff09\u7535\u89e3\u6db2\u7684\u4f18\u5316<\/b><\/strong>\uff1b3\uff09\u5bfb\u6c42\u9ad8\u5ea6\u53ef\u9006\u7684\u950c\u8d1f\u6781<\/b><\/strong>\uff1b4\uff09\u6b63\u6781\u6750\u6599\u7684\u65b0\u7b56\u7565<\/b><\/strong>\uff1b5\uff09\u8bbe\u8ba1\u67d4\u6027\u7684\u6c34\u7cfbZIBs<\/b><\/strong>\u3002<\/span><\/p>\n

\u00a0<\/b><\/strong><\/span>\u6587\u732e\u94fe\u63a5\uff1aRecent Advances in Aqueous Zinc-ion Batteries<\/span><\/b><\/strong>\uff08ACS Energy Letters, 2018, DOI: 10.1021\/acsenergylett.8b01426\uff09<\/p>\n

\u3010\u4f5c\u8005\u7b80\u4ecb<\/strong>\u3011<\/span><\/p>\n

\u6881\u53d4\u5168\uff0c\u6559\u6388\uff0c\u535a\u5bfc\uff0c\u4e2d\u5357\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u5b66\u9662\u9662\u957f\u3002\u8299\u84c9\u5b66\u8005\uff0c\u4eab\u53d7\u56fd\u52a1\u9662\u7279\u6b8a\u6d25\u8d34\u4e13\u5bb6\u3002\u5728\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001863\u8ba1\u5212\u3001973\u8ba1\u5212\u7b49\u652f\u6301\u8d44\u52a9\u4e0b\uff0c\u4ece\u4e8b\u6750\u6599\u5408\u6210\u3001\u7ed3\u6784\u5206\u6790\u4e0e\u6027\u80fd\u7814\u7a76\uff0c\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u9ad8\u6c34\u5e73\u8bba\u6587 100 \u4f59\u7bc7\uff0c\u5176\u4e2d\u5305\u62ec\u56fd\u9645\u8457\u540d\u6743\u5a01\u5b66\u672f\u520a\u7269\uff1aEnergy & Environmental Science\uff0cAdvanced Energy Materials, Journal of American Ceramic Society, Journal of European Ceramic Society\u7b49\uff0c\u7533\u8bf7\u4e13\u5229 20 \u4f59\u9879\u3002\u66fe\u83b7\u56fd\u5bb6\u79d1\u6280\u8fdb\u6b65\u4e8c\u7b49\u5956\u3001\u6fb3\u5927\u5229\u4e9aMonash\u5927\u5b66\u5de5\u7a0b\u5b66\u7ea6\u7ff0\u83ab\u7eb3\u58eb\u7235\u58eb\u5956\u7ae0\u3001\u6e56\u5357\u7701\u4eba\u6c11\u653f\u5e9c\u6559\u5b66\u6210\u679c\u4e00\u7b49\u5956\u3001\u6e56\u5357\u7701\u4f18\u79c0\u6559\u5e08\u7b49\u5956\u52b1\u6216\u8363\u8a89\u3002<\/p>\n

\u5468\u6c5f\uff0c\u4e2d\u5171\u515a\u5458\uff0c\u4e2d\u5357\u5927\u5b66\u7279\u8058\u6559\u6388\u3002\u4e2d\u5357\u5927\u5b66-\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66(NTU)\u8054\u5408\u57f9\u517b\u535a\u58eb\uff0c\u5408\u4f5c\u5bfc\u5e08Hua Zhang\u6559\u6388\uff1b\u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662(MIT)\u535a\u58eb\u540e\uff0c\u5408\u4f5c\u5bfc\u5e08Ju Li\u6559\u6388\u3002\u7814\u7a76\u5174\u8da3\u4e3a\u9502(\u94a0)\u79bb\u5b50\u7535\u6c60\u3001\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u3002\u4ee5\u4e00\u4f5c\u6216\u901a\u8baf\u4f5c\u8005\u5728Energy\u00a0Environ.\u00a0Sci.,\u00a0Adv. Energy Mater., ACS Energy Lett., Nano Energy, Adv. Sci., Energy Storage Mater.\u7b49\u56fd\u9645\u671f\u520a\u53d1\u8868\u5b66\u672f\u8bba\u658740\u4f59\u7bc7\u3002<\/p>\n

\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u5c0f\u7ed3<\/strong>\u3011<\/span><\/p>\n

\u4e2d\u5357\u5927\u5b66\u6881\u53d4\u5168\u3001\u5468\u6c5f\u6559\u6388\u56e2\u961f\u5728\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u9886\u57df\u4e2d\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u8fdb\u5c55\u3002<\/p>\n

\u901a\u8fc7\u4e00\u6b65\u6c34\u70ed\u6cd5\u5b9e\u73b0\u4e86\u9502\u79bb\u5b50\uff08Li+<\/sup>\uff09\u5728\u542b\u6c34\u4e94\u6c27\u5316\u4e8c\u9492\uff08V2<\/sub>O5<\/sub>\u2022n<\/i><\/em>H2<\/sub>O\uff09\u7ed3\u6784\u7684\u5c42\u95f4\u5d4c\u5165\uff0c\u5e76\u901a\u8fc7\u7119\u70e7\u8fc7\u7a0b\u63d0\u9ad8\u5176\u7ed3\u6676\u6027\uff0c\u8fdb\u800c\u6210\u529f\u5236\u5907\u51fa\u4e00\u79cd\u9002\u7528\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u91d1\u5c5eLi+<\/sup>\u63ba\u6742\u4e0e\u7ed3\u6784\u6c34\u4fdd\u7559\u7684\u68c9\u82b1\u72b6Lix<\/i><\/sub><\/em>V2<\/sub>O5<\/sub>\u00b7n<\/i><\/em>H2<\/sub>O\uff08LVO-250\uff09\uff0c\u6709\u6548\u7684\u89e3\u51b3\u4e86\u4f20\u7edfV2<\/sub>O5<\/sub>\u4f5c\u4e3a\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u79bb\u5b50\u6269\u6563\u7f13\u6162\u3001\u6750\u6599\u7ed3\u6784\u4e0d\u7a33\u5b9a\u7b49\u74f6\u9888\u95ee\u9898\u3002\uff08Energy & Environmental Science,\u00a02018, DOI:\u00a010.1039\/C8EE01651H\uff09<\/p>\n

\u9996\u6b21\u62a5\u9053\u4e86\u4e0d\u540c\u7ed3\u6784\u7684\u9492\u9178\u94a0\u4f5c\u4e3a\u53ef\u5145\u7535\u6c34\u7cfbZIBs\u6b63\u6781\u6750\u6599\uff0c\u5e76\u5bf9\u5176\u5d4c\u950c\u673a\u7406\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u7814\u7a76\uff0c\u63ed\u793a\u4e86\u5c42\u72b6\u7ed3\u6784\u7684NaV3<\/sub>O8<\/sub>\u548c\u96a7\u9053\u7ed3\u6784\u7684\u03b2<\/i><\/em>-Na0.33<\/sub>V2<\/sub>O5<\/sub>\u4e2d\u4e0d\u540c\u7684Zn2+<\/sup>\u50a8\u5b58\u673a\u7406\u3002Zn2+<\/sup>\u5d4c\u5165NaV3<\/sub>O8<\/sub>\u578b\u5c42\u72b6\u7ed3\u6784\u4e2d\u5bfc\u81f4\u7ed3\u6784\u7834\u574f\uff0c\u4f34\u968f\u7740\u7b2c\u4e8c\u76f8\u7684\u5f62\u6210\uff0c\u8fd9\u5c06\u5bfc\u81f4\u5bb9\u91cf\u7684\u8870\u51cf\uff0c\u4f7f\u5f97Na5<\/sub>V12<\/sub>O32<\/sub>\u57282000\u6b21\u5faa\u73af\u540e\u4ec5\u670971\uff05\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u3002\u7531\u4e8e\u03b2<\/i><\/em>-Na0.33<\/sub>V2<\/sub>O5<\/sub>\u578b\u96a7\u9053\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\uff0c\u5728Zn2+<\/sup>\u53ef\u9006\u8131\u5d4c\u8fc7\u7a0b\u4e2d\u6ca1\u6709\u76f8\u53d8\u53d1\u751f\uff0c\u5c3d\u7ba1\u5bb9\u91cf\u4f4e\uff0c\u4f46\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027 (Advanced Energy Materials, 2018, 1801819)\u3002<\/p>\n

\u9996\u6b21\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u9492\u9178\u94be\uff0c\u5305\u62ecK2<\/sub>V8<\/sub>O21<\/sub>\u3001K0.25<\/sub>V2<\/sub>O5<\/sub>\u3001KV3<\/sub>O8<\/sub>\u548cKV3<\/sub>O8<\/sub>\u00b7x<\/i><\/em>H2<\/sub>O\uff0c\u7528\u4f5c\u53ef\u5145\u7535\u6c34\u6027\u950c\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\u3002\u901a\u8fc7\u975e\u539f\u4f4dXRD\u3001XPS\u3001HRTEM\u7b49\u624b\u6bb5\u5bf9\u9492\u9178\u94be\u7684\u50a8\u950c\u673a\u7406\u8fdb\u884c\u4e86\u6df1\u5165\u8868\u5f81\u3001\u8ba8\u8bba\u548c\u5206\u6790\u3002\u53d1\u73b0\u5177\u6709\u96a7\u9053\u7ed3\u6784\u7684K2<\/sub>V8<\/sub>O21<\/sub>\u548cK0.25<\/sub>V2<\/sub>O5<\/sub>\u53ef\u4ee5\u4e3a\u950c\u79bb\u5b50\u63d0\u4f9b\u6709\u6548\u7684\u6269\u6563\u8def\u5f84\uff0c\u5e76\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u4e86\u7ed3\u6784\u7684\u7a33\u5b9a\u6027\uff0c\u800c\u5c42\u72b6\u7ed3\u6784\u7684KV3<\/sub>O8<\/sub>\u548cKV3<\/sub>O8<\/sub>\u00b7x<\/i><\/em>H2<\/sub>O\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4f1a\u906d\u53d7\u4e25\u91cd\u7684\u7ed3\u6784\u7834\u574f\u3002\u56e0\u6b64\uff0c\u5177\u6709\u7a33\u5b9a\u7ed3\u6784\u548c\u5feb\u901f\u79bb\u5b50\u6269\u6563\u901a\u9053\u7684K2<\/sub>V8<\/sub>O21<\/sub>\u548cK0.25<\/sub>V2<\/sub>O5<\/sub>\u6bd4KV3<\/sub>O8<\/sub>\u548cKV3<\/sub>O8<\/sub>\u00b7x<\/i><\/em>H2<\/sub>O\u5177\u6709\u66f4\u597d\u7684\u50a8\u950c\u80fd\u529b\u3002\u53e6\u5916\uff0c\u5b83\u8fd8\u8868\u73b0\u51fa\u826f\u597d\u7684\u9ad8\u6e29\uff0850\u00b0C\uff09\u6027\u80fd (Nano Energy 2018, 51, 579\u2013587).<\/p>\n

\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u7b56\u7565\uff0c\u7ed3\u5408\u6c34\u70ed\u6cd5\u548c\u51b7\u51bb\u5e72\u71e5\u6280\u672f\u5236\u5907\u4e86\u77f3\u58a8\u70ef\u5305\u8986Na1.1<\/sub>V3<\/sub>O7.9<\/sub>\u7eb3\u7c73\u5e26\uff0cNa1.1<\/sub>V3<\/sub>O7.9<\/sub>\u7eb3\u7c73\u5e26\u4e0e\u77f3\u58a8\u70ef\u7247\u4ea4\u8054\u590d\u5408\uff0c\u5f62\u6210\u4e86\u7a33\u5b9a\u7684\u6be1\u72b6\u7ed3\u6784\u3002\u8be5\u6750\u6599\u9996\u6b21\u5c06\u9492\u9178\u94a0\u5e94\u7528\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff0c\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08Energy Storage Materials 2018, 13, 168\u2013174\uff09\u3002<\/p>\n

\u901a\u8fc7\u6c34\u70ed\u6cd5\u6210\u529f\u5408\u6210\u4e86Ag0.4<\/sub>V2<\/sub>O5<\/sub>\u6750\u6599\uff0c\u5e76\u5c06\u5176\u9996\u6b21\u5e94\u7528\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u3002\u901a\u8fc7\u7535\u5316\u5b66\u673a\u7406\u5206\u6790\u53d1\u73b0\uff0cAg0.4<\/sub>V2<\/sub>O5<\/sub>\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u4f1a\u7ecf\u5386\u53d6\u4ee3\/\u5d4c\u5165\u5171\u53cd\u5e94\uff08Combination Displacement\/Intercalation\uff09\uff0c\u5176\u4e2d\uff0c\u653e\u7535\u8fc7\u7a0b\u4e2d\u6709\u65b0\u76f8\u9492\u9178\u950c\u4e0e\u5355\u8d28\u94f6\u751f\u6210\uff0c\u6709\u5229\u4e8e\u63d0\u5347\u7535\u5316\u5b66\u6027\u80fd\u4e0e\u5bfc\u7535\u6027\u3002\u4ee5Ag0.4<\/sub>V2<\/sub>O5<\/sub>\u4e3a\u6b63\u6781\u7684\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u572810 A g–<\/sup>1<\/sup>\u7684\u9ad8\u7535\u6d41\u5bc6\u5ea6\u4e0b\u80fd\u591f\u7a33\u5b9a\u5faa\u73af2000\u5708\uff0c\u5c55\u73b0\u4e86\u4f18\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002 (Energy Storage Materials, 2018, DOI: 10.1016\/j.ensm.2018.08.008)\u3002<\/p>\n

\u7814\u7a76\u4e86\u65e0\u7c98\u7ed3\u5242\u5c42\u72b6\u7eb3\u7c73\u82b1\u7ed3\u6784Mn3<\/sub>O4<\/sub>\u4f5c\u4e3a\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5e76\u7ed3\u5408\u975e\u539f\u4f4d\u8868\u5f81\u63a2\u7d22\u4e86\u5176\u50a8\u950c\u673a\u5236\uff08J. Mater. Chem. A 2018, 6, 9677\u20139683\uff09\u3002<\/p>\n

\u6b64\u5916\uff0c\u56e2\u961f\u6709\u5173V2<\/sub>O5<\/sub>\u7eb3\u7c73\u6750\u6599\u7528\u4f5c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u7684\u57fa\u7840\u7814\u7a76\u8fdb\u5c55\uff0c\u5728\u81ea\u7136\u6307\u6570\u671f\u520a\u300a\u5316\u5b66\u901a\u8baf\u300b(Chem. Commun., 2018, 54, 4457)\u4e0a\u53d1\u8868\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/b><\/strong>\u3002<\/span><\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/b><\/strong>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

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