{"id":153194,"date":"2018-09-10T06:01:05","date_gmt":"2018-09-09T22:01:05","guid":{"rendered":"\/\/m.iemloyee.com\/?p=153194"},"modified":"2018-09-09T10:02:47","modified_gmt":"2018-09-09T02:02:47","slug":"%e7%8e%8b%e5%8f%8c%e5%8d%b0%e5%91%a8%e6%80%80%e5%a8%9fnat-commun-%e5%85%b7%e6%9c%89%e6%a2%af%e5%ba%a6%e6%b0%a7%e7%bc%ba%e9%99%b7%e7%9a%84%e7%bb%93%e6%99%b6tio2%e4%bf%9d%e6%8a%a4%e5%b1%82%e5%8f%8a","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=153194","title":{"rendered":"\u738b\u53cc\u5370&#038;\u5468\u6000\u5a1fNat. Commun. : \u5177\u6709\u68af\u5ea6\u6c27\u7f3a\u9677\u7684\u7ed3\u6676TiO2\u4fdd\u62a4\u5c42\u53ca\u5176\u5728\u9ad8\u6548\u3001\u7a33\u5b9a\u7845\u57fa\u5149\u9634\u6781\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u5149\u7535\u5316\u5b66(PEC)\u5206\u89e3\u6c34\u662f\u4e00\u79cd\u5c06\u6c34\u548c\u9633\u5149\u76f4\u63a5\u8f6c\u5316\u4e3a\u6c22\u6c14\u548c\u6c27\u6c14\u7684\u53ef\u6301\u7eed\u65b9\u6cd5\u3002\u5176\u4e2d\uff0c\u7a84\u5e26\u9699\u548c\u5f3a\u8f7d\u6d41\u5b50\u8fd0\u8f93\u80fd\u529b\u7684Si\u88ab\u89c6\u4e3a\u7406\u60f3\u7684\u9ad8\u6548\u5149\u7535\u9634\u6781\u6750\u6599\u4e4b\u4e00\u3002\u7136\u800c\uff0cSi\u57fa\u5149\u7535\u9634\u6781\u5728\u5149\u7167\u4e0b\u6781\u6613\u4e0e\u7535\u89e3\u8d28\u6eb6\u6db2(\u5c24\u5176\u662f\u5f3a\u78b1\u7535\u89e3\u8d28)\u53d1\u751f\u8150\u8680\u548c\u949d\u5316\uff0c\u9650\u5236\u4e86\u5176\u5728\u5149\u7535\u5316\u5b66\u4e2d\u5e94\u7528\u3002\u5728Si\u8868\u9762\u6d82\u8986\u4e00\u5c42\u65e0\u5b9a\u5f62\u6c27\u5316\u7269\u4fdd\u62a4\u5c42\u662f\u5f53\u524d\u6539\u5584Si\u57fa\u5149\u7535\u6781\u7a33\u5b9a\u6027\u7684\u5e38\u7528\u624b\u6bb5\u3002\u7136\u800c\uff0c\u8fd9\u4e9b\u65e0\u5b9a\u5f62\u6c27\u5316\u7269\/Si\u57fa\u534a\u5bfc\u4f53\u5149\u7535\u9634\u6781\u4ecd\u7136\u5b58\u5728\u7740\u660e\u663e\u7684\u7a33\u5b9a\u6027\u4e0e\u6548\u7387\u7684\u8026\u5408\u95ee\u9898\u3002\u540c\u65f6\uff0c\u65e0\u5b9a\u5f62\u6c27\u5316\u7269\u4fdd\u62a4\u5c42\u56fa\u6709\u7684\u758f\u677e\u7ed3\u6784\u96be\u4ee5\u4e3a\u5149\u7535\u9634\u6781\u63d0\u4f9b\u957f\u4e45\u7684\u4f7f\u7528\u5bff\u547d\u3002\u56e0\u6b64\uff0c\u4e3a\u4e86\u5728\u5f3a\u78b1\u7535\u89e3\u6db2\u4e2d\u5b9e\u73b0Si\u57fa\u5149\u7535\u9634\u6781\u80fd\u9ad8\u6548\u4e14\u7a33\u5b9a\u5730\u8fd0\u884c\uff0c\u8bbe\u8ba1\u5408\u9002\u4fdd\u62a4\u5c42\u53bb\u9664\u6216\u8005\u524a\u5f31Si\u57fa\u5149\u7535\u9634\u6781\u6548\u7387\u548c\u7a33\u5b9a\u6027\u7684\u8026\u5408\u4f5c\u7528\u523b\u4e0d\u5bb9\u7f13\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u76f8\u6bd4\u4e8e\u65e0\u5b9a\u5f62\u6c27\u5316\u7269\uff0c\u7ed3\u6676\u6c27\u5316\u7269\u5177\u6709\u66f4\u9ad8\u7684\u8010\u78b1\u6027\uff0c\u80fd\u591f\u63d0\u9ad8Si\u5149\u7535\u9634\u6781\u7684\u7a33\u5b9a\u6027\uff0c\u7136\u800c\u5dee\u7684\u8f7d\u6d41\u5b50\u4f20\u5bfc\u80fd\u529b\u963b\u788d\u4e86\u5176\u4f5c\u4e3a\u4fdd\u62a4\u5c42\u7684\u5e94\u7528\u3002\u800c\u5728\u524d\u671f\u7684\u7814\u7a76\u4e2d\uff0c\u6539\u53d8\u7f3a\u9677\u7684\u6d53\u5ea6\u548c\u5f62\u5f0f\u80fd\u591f\u8c03\u63a7\u539a\u7684\u65e0\u5b9a\u5f62\u6c27\u5316\u7269\u8f7d\u6d41\u5b50\u4f20\u8f93\u80fd\u529b\u3002\u6709\u9274\u4e8e\u6b64\uff0c<strong>\u6e56\u5357\u5927\u5b66\u738b\u53cc\u5370\u6559\u6388\u3001\u4e2d\u79d1\u9662\u4e0a\u6d77\u7845\u9178\u76d0\u6240\u5468\u6000\u5a1f\u535a\u58eb(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u3001\u7b2c\u4e00\u4f5c\u8005\u90d1\u5efa\u4e91\u535a\u58eb\u7b49<\/strong>\u901a\u8fc7\u4f7f\u7528\u5177\u6709\u68af\u5ea6\u6c27\u7f3a\u9677\u7684\u7ed3\u6676TiO<sub>2<\/sub>\u4f5c\u4e3a\u4fdd\u62a4\u5c42\uff0c\u5b9e\u73b0\u4e86\u6548\u7387\u548c\u7a33\u5b9a\u6027\u7684\u53bb\u8026\u5408\u4f5c\u7528\uff0c\u83b7\u5f97\u4e86\u9ad8\u6548\u4e14\u7a33\u5b9a\u7684Si\u57fa\u5149\u7535\u6781\u3002\u57fa\u4e8e\u6b64\u6210\u679c\u5728<strong>Nat. Commun.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201c<strong>Crystalline TiO<sub>2<\/sub> protective layer with graded oxygen defects for efficient and stable silicon-based photocathode<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u7ed3\u6676\u4fdd\u62a4\u5c42\u5177\u6709\u9ad8\u5bc6\u5ea6\u7ed3\u6784\uff0c\u4e3a\u5149\u7535\u9634\u6781\u63d0\u4f9b\u597d\u7684\u7a33\u5b9a\u6027\uff0c\u540c\u65f6\uff0c\u4fdd\u62a4\u5c42\u5185\u90e8\u7684\u68af\u5ea6\u6c27\u7f3a\u9677\u4e3a\u8f7d\u6d41\u5b50\u63d0\u4f9b\u4f20\u8f93\u901a\u9053\uff0c\u6ee1\u8db3\u5149\u7535\u9634\u6781\u7684\u9ad8\u6548\u9700\u6c42\u3002\u5728\u6b64\u7ed3\u6784\u4e0b\uff0c\u6700\u4f18Si\u57fa\u5149\u7535\u9634\u6781\u663e\u793a\u4e8635.3 mA\u00b7cm<sup>-2<\/sup>\u7684\u9971\u548c\u5149\u7535\u6d41\u5bc6\u5ea6\uff0c\u540c\u65f6\u5728\u5f3a\u78b1\u7535\u89e3\u8d28\u6eb6\u6db2\u548c10 mA\u00b7cm<sup>-2<\/sup>\u5149\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7a33\u5b9a\u8fd0\u884c\u8d85\u8fc7100 h\u3002\u4e0a\u8ff0\u5b9e\u9a8c\u7ed3\u679c\u4e3a\u8fdb\u4e00\u6b65\u5f00\u53d1\u7845\u57fa\u5149\u7535\u6781\u63d0\u4f9b\u4e86\u91cd\u8981\u53c2\u8003\uff0c\u5e76\u4e3a\u6784\u5efa\u9ad8\u6548\u8010\u7528\u7684\u5149\u7535\u5316\u5b66\u88c5\u7f6e\u63d0\u4f9b\u4e86\u53ef\u80fd\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\n <strong>\u56fe1 b-Si\u5149\u9634\u6781\u8868\u9762\u4fdd\u62a4\u7b56\u7565<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-153195\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig1_HTML.png\" alt=\"\" width=\"600\" height=\"391\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig1_HTML.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig1_HTML-300x196.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>b-Si\u5149\u9634\u6781\u8868\u9762\u4fdd\u62a4\u7b56\u7565\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>\u56fe2 \u6837\u54c1\u7684\u7ed3\u6784\u3001\u5149\u5b66\u548c\u6da6\u6e7f\u6027\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-153196\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig2_HTML.png\" alt=\"\" width=\"600\" height=\"474\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig2_HTML.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig2_HTML-300x237.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) b-Si\u3001c-TiO<sub>2<\/sub>\/b-Si\u3001b1-TiO<sub>2<\/sub>\/b-Si\u548cb2-TiO<sub>2<\/sub>\/b-Si(\u6df1\u7eff\u8272)\u7684XRD\u8c31\u56fe\uff1b<br \/>\n b) \u5ba4\u6e29\u4e0bc-TiO<sub>2<\/sub>\/b-Si\u3001b1-TiO<sub>2<\/sub>\/b-Si\u548cb2-TiO<sub>2<\/sub>\/b-Si\u7684EPR\u5149\u8c31\uff1b<br \/>\n c) \u6240\u6709\u6837\u54c1\u5728\u7a7a\u6c14\u4e2d\u7684\u603b\u534a\u7403\u5149\u5b66\u53cd\u5c04\u7387\uff0c\u5185\u63d2\u56fe\u4e3a\u5149\u5438\u6536\u7cfb\u6570\u968f\u5165\u5c04\u5149\u5b50\u80fd\u91cf\u7684\u53d8\u5316\uff1b<br \/>\n d) c-TiO<sub>2<\/sub>\/b-Si\u3001b1-TiO<sub>2<\/sub>\/b-Si\u548cb2-TiO<sub>2<\/sub>\/b-Si\u5728\u7d2b\u5916-\u53ef\u89c1\u5149\u7167\u5c0430 min\u524d\u540e\u7684\u63a5\u89e6\u89d2\u6d4b\u8bd5\u3002<\/p>\n<p><strong>\u56fe3 Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684\u5fae\u89c2\u7ed3\u6784\u548c\u7ec4\u6210\u5206\u5e03<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-153197\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig3_HTML.png\" alt=\"\" width=\"600\" height=\"536\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig3_HTML.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig3_HTML-300x268.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684\u6a2a\u622a\u9762(HR)TEM\u56fe\u50cf\uff1b<br \/>\n b) Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684HADDF-STEM\u56fe\u50cf\u53ca\u5176\u5143\u7d20\u5206\u5e03\u56fe\u50cf\u3002<\/p>\n<p><strong>\u56fe4 Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684XPS\u6df1\u5ea6\u5206\u5e03<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-153198\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig4_HTML.png\" alt=\"\" width=\"600\" height=\"476\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig4_HTML.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig4_HTML-300x238.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u8868\u9762\u7684Ti 2p XPS\u5149\u8c31\uff1b<br \/>\n b) Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u5185\u90e8(\u523b\u8680\u6df1\u5ea6\u4e3a20nm)\u7684Ti 2p XPS\u5149\u8c31\uff1b<br \/>\n c) Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684\u5143\u7d20\u6df1\u5ea6\u5206\u5e03\uff1b<br \/>\n d) Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684\u8868\u9762\u548c\u5185\u90e8(\u523b\u8680\u6df1\u5ea6\u4e3a20 nm)\u7684VBXPS\u5149\u8c31\u3002<\/p>\n<p><strong>\u56fe5 Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7cfb\u5217\u6750\u6599\u7684PEC\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-153199\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig5_HTML.png\" alt=\"\" width=\"600\" height=\"466\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig5_HTML.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig5_HTML-300x233.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) \u4e00\u4e2a\u592a\u9633\u5149\u5f3a\u7167\u5c04\u65f6\uff0c1.0M NaOH\u4e2d\u7cfb\u5217\u6837\u54c1\u7684\u7535\u6d41\u5bc6\u5ea6(J)-\u7535\u4f4d(V)\u66f2\u7ebf(\u626b\u901f\u4e3a0.01 V\u00b7s<sup>-1<\/sup>)\uff0c\u5185\u63d2\u4e3a\u6807\u8bb0\u533a\u57df\u7684\u653e\u5927\u56fe\u50cf\uff1b<br \/>\n b) 1.0M NaOH\u4e2d\u3001-0.22V (vs RHE)\u4e0bPd\/b1-TiO<sub>2<\/sub>\/b-Si\u548cPd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684IPCE\u66f2\u7ebf\uff1b<br \/>\n c) \u4e00\u4e2a\u592a\u9633\u5149\u5f3a\u7167\u5c04\u65f6\uff0c1.0M NaOH\u4e2d\u3001-0.012V(vs RHE)\u4e0bPd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684J-t\u66f2\u7ebf\uff0c\u4e0a\u5185\u63d2\u4e3a\u4e00\u4e2a\u592a\u9633\u5149\u5f3a\u7167\u5c04\u65f6\u30010.5M H<sub>2<\/sub>SO<sub>4<\/sub>\u4e2d\u3001-0.124V(vs RHE)\u4e0b Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684J-t\u66f2\u7ebf\uff0c\u4e0b\u5185\u63d2\u4e3a1.0M NaOH\u4e2dPEC\u5206\u89e3\u6c34100 h\u540ePd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684\u6a2a\u622a\u9762FESEM\u56fe\u50cf\uff1b<br \/>\n d) \u4e0d\u540c\u5149\u7535\u9634\u6781\u7a33\u5b9a\u6027\u6bd4\u8f83\u3002<\/p>\n<p><strong>\u56fe6 \u7845\u57fa\u5149\u7535\u9634\u6781\u8f7d\u6d41\u5b50\u52a8\u529b\u5b66\u548c\u8f6c\u79fb\u8def\u5f84\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-153200\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig6_HTML.png\" alt=\"\" width=\"600\" height=\"492\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig6_HTML.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig6_HTML-300x246.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a) Pd\/b-Si\u3001Pd\/c-TiO<sub>2<\/sub>\/b-Si\u3001Pd\/b1-TiO<sub>2<\/sub>\/b-Si\u548cPd\/b2-TiO<sub>2<\/sub>\/b- Si\u7684\u5ba4\u6e29PL\u5149\u8c31\uff1b<br \/>\n b) Pd\/b2-TiO2\/b-Si\u7684\u5ba4\u6e29\u65f6\u95f4\u5206\u8fa8PL\u5149\u8c31\uff0c\u56fe\u4e2d\u5b9e\u7ebf\u8868\u793a\u4f7f\u7528\u53cc\u6307\u6570\u8870\u51cf\u6a21\u578b\u7684\u52a8\u529b\u5b66\u62df\u5408\uff0c\u5185\u63d2\u4e3aPd\/c-TiO<sub>2<\/sub>\/b-Si\u7684\u65f6\u95f4\u5206\u8fa8PL\u5149\u8c31\uff1b<br \/>\n c) Pd\/b2-TiO<sub>2<\/sub>\/b-Si\u7684AFM\u56fe\u50cf\u4ee5\u53ca\u6807\u6ce8\u4f4d\u7f6e\u7684\u5178\u578bI-V\u66f2\u7ebf\u3002<\/p>\n<p><strong>\u56fe7 Pd\/b-TiO<sub>2<\/sub>\/b-Si\u7684\u7ed3\u6784\u548c\u53cd\u5e94\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-153201\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig7_HTML.png\" alt=\"\" width=\"600\" height=\"538\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig7_HTML.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/09\/41467_2018_5580_Fig7_HTML-300x269.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Pd\u7eb3\u7c73\u9897\u7c92\/\u9ed1\u8272TiO<sub>2<\/sub>\/b-Si\u5149\u7535\u9634\u6781\u8fd8\u539f\u6c34\u7684\u673a\u7406\u793a\u610f\u56fe\uff0c\u5de6\u4fa7\u63d2\u56fe(\u84dd\u8272\u865a\u7ebf\u77e9\u5f62\u6846)\u4e3a\u5149\u7535\u9634\u6781\u4fa7\u89c6\u793a\u610f\u56fe\uff0c\u53f3\u4fa7\u63d2\u56fe(\u6a59\u8272\u865a\u7ebf\u77e9\u5f62\u6846)\u4e3aPd\u7eb3\u7c73\u9897\u7c92\/\u9ed1\u8272TiO<sub>2<\/sub>\/b-Si\u5149\u7535\u9634\u6781\u7684\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<br \/>\n<\/strong><br \/>\n \u8be5\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u53ef\u884c\u7684\u7b56\u7565\u53bb\u6d88\u9664\u7845\u57fa\u5149\u7535\u9634\u6781\u7684\u6548\u7387\u548c\u7a33\u5b9a\u6027\u7684\u8026\u5408\u4f5c\u7528\u3002\u5728\u8fd9\u4e2a\u7b56\u7565\u4e2d\uff0c\u4fdd\u62a4\u5c42\u7684\u9ad8\u5bc6\u5ea6\u7ed3\u6676\u7ed3\u6784\u548c\u68af\u5ea6\u6c27\u7f3a\u9677\u6210\u5206\u88ab\u6709\u6548\u5730\u7ed3\u5408\uff0c\u5206\u522b\u4e3aSi\u57fa\u5149\u7535\u9634\u6781\u63d0\u4f9b\u957f\u4e45\u7684\u5bff\u547d\u548c\u4f18\u5f02\u7684PEC\u6027\u80fd\u3002\u4e0a\u8ff0\u5b9e\u9a8c\u7ed3\u679c\u4e3a\u5728\u5f3a\u78b1\u7535\u89e3\u8d28\u4e2d\u5b9e\u73b0\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u71c3\u6599\u7684\u5149\u7535\u5316\u5b66\u7cfb\u7edf\u63d0\u4f9b\u4e86\u6539\u826f\u65b9\u5411\u3002<\/p>\n<p><strong>\u3010\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n<p><strong>\u738b\u53cc\u5370<\/strong>\uff0c\u6e56\u5357\u5927\u5b66\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c\u4e2d\u7ec4\u90e8\u201c\u9752\u5e74\u5343\u4eba\u8ba1\u5212\u201d\u5165\u9009\u8005\uff0c\u82f1\u56fd\u201c\u739b\u4e3d\u5c45\u91cc\u5b66\u8005\u201d\u83b7\u5f97\u8005\uff0c\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u7684\u201c\u9762\u4e0a\u9879\u76ee\u201d\u548c\u201c\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\u201d\u7b49\u591a\u4e2a\u9879\u76ee\u3002\u957f\u671f\u4ece\u4e8b\u50ac\u5316\u5242\u7684\u6210\u5206\u548c\u7ed3\u6784\u7684\u7f3a\u9677\u53ef\u63a7\u6784\u9020\u548c\u5206\u6790\u3001\u80fd\u6e90\u8f6c\u5316\u548c\u5b58\u50a8\u7b49\u9886\u57df\u7684\u7814\u7a76\u3002\u8fd1\u5e74\u6765\uff0c\u5728J. Am. Chem. Soc.\u3001Nat. Commun.\u3001Angew. Chem. Int. Ed.\u3001Adv. Mater.\u7b49\u56fd\u9645\u671f\u520a(SCI)\u53d1\u8868\u7814\u7a76\u8bba\u6587100\u4f59\u7bc7\uff0c\u88ab\u5f15\u75286500\u4f59\u6b21\uff0cH\u6307\u657042\u3002<\/p>\n<p> <strong>\u90d1\u5efa\u4e91<\/strong>\uff0c\u6e56\u5357\u5927\u5b66\u535a\u58eb\u540e\uff0c\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u7684\u201c\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u9879\u76ee\u201d\u3002\u4e3b\u8981\u4ece\u4e8b\u4f4e\u7ef4\u6750\u6599\u6784\u7b51\u3001\u5149\u7535\u6781\u8bbe\u8ba1\u548c\u7ec4\u88c5\u3001\u592a\u9633\u80fd\u8f6c\u5316\u548c\u5229\u7528\u7b49\u65b9\u9762\u7684\u7814\u7a76\u3002\u8fd1\u5e74\u6765\uff0c\u4ee5\u7b2c\u4e00\u6216\u8005\u901a\u8baf\u4f5c\u8005\u5728Nat. Commun.\u3001Adv. Mater.\u3001Nano Energy\u3001Appl. Catal. B: Environ.\u7b49\u56fd\u9645\u671f\u520a(SCI)\u53d1\u8868\u7814\u7a76\u8bba\u658720\u4f59\u7bc7\u3002<\/p>\n<p>\n <strong>\u3010\u8fd1\u671f\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u76f8\u5173\u5de5\u4f5c\u3011<\/strong><br \/>\n 1. Jianyun Zheng, Yanhong Lyu, Chao Xie, Ruilun Wang, Li Tao, Haibo Wu, Huaijuan Zhou, Sanping Jiang, and Shuangyin Wang* \u201c<strong><a href=\"https:\/\/doi.org\/10.1002\/adma.201801773\" target=\"_blank\" rel=\"noopener\">Defect-Enhanced Charge Separation and Transfer within Protection Layer\/Semiconductor Structure of Photoanode<\/a><\/strong>\u201d, <strong>Adv. Mater.,<\/strong> 2018, 30, 1801773. (DOI: 10.1002\/adma.201801773)<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41467-018-05580-z\" target=\"_blank\" rel=\"noopener\">Crystalline TiO<sub>2<\/sub> protective layer with graded oxygen defects for efficient and stable silicon-based photocathode<\/a><\/strong> (<strong>Nat. Commun.<\/strong>, 2018, DOI: 10.1038\/s41467-018-05580-z)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n<p><strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/strong><\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u5149\u7535\u5316\u5b66(PEC)\u5206\u89e3\u6c34\u662f\u4e00\u79cd\u5c06\u6c34\u548c\u9633\u5149\u76f4\u63a5\u8f6c\u5316\u4e3a\u6c22\u6c14\u548c\u6c27\u6c14\u7684\u53ef\u6301\u7eed\u65b9\u6cd5\u3002\u5176\u4e2d\uff0c\u7a84\u5e26\u9699\u548c\u5f3a\u8f7d\u6d41\u5b50\u8fd0\u8f93\u80fd\u529b\u7684Si\u88ab\u89c6\u4e3a\u7406\u60f3\u7684\u9ad8\u6548\u5149\u7535\u9634\u6781\u6750\u6599\u4e4b\u4e00\u3002\u7136\u800c\uff0c&#8230;<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2671,3050,1605],"class_list":["post-153194","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2671","tag-3050","tag-wangshuangying"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/153194"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=153194"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/153194\/revisions"}],"predecessor-version":[{"id":153205,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/153194\/revisions\/153205"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=153194"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=153194"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=153194"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}