{"id":153183,"date":"2018-09-10T08:00:23","date_gmt":"2018-09-10T00:00:23","guid":{"rendered":"\/\/m.iemloyee.com\/?p=153183"},"modified":"2018-09-09T20:40:41","modified_gmt":"2018-09-09T12:40:41","slug":"%e7%87%95%e5%b1%b1%e5%a4%a7%e5%ad%a6angew-chem-int-ed-%e7%94%b5%e5%8c%96%e5%ad%a6%e7%94%b5%e9%95%80%e5%88%b6%e5%a4%87%e7%a9%ba%e6%b0%94%e4%b8%ad%e7%a8%b3%e5%ae%9a%e9%94%82%e7%90%83%e4%bd%9c","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=153183","title":{"rendered":"\u71d5\u5c71\u5927\u5b66Angew. Chem. Int. Ed. : \u7535\u5316\u5b66\u7535\u9540\u5236\u5907\u7a7a\u6c14\u4e2d\u7a33\u5b9a\u9502\u7403\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\n \u91d1\u5c5e\u9502(Li)\u5177\u6709\u975e\u5e38\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf(3860 mAh\u00b7g-1<\/sup>)\uff0c\u6709\u671b\u4f5c\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u7528\u4e8e\u7535\u52a8\u6c7d\u8f66\u548c\u7535\u7f51\u5b58\u50a8\u3002\u4e0e\u9502\u7b94\u76f8\u6bd4\uff0c\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u7684\u538b\u5236\u9502\u7c89\u672b\u57fa\u8d1f\u6781\u7531\u4e8e\u5176\u8f83\u9ad8\u7684\u8868\u9762\u79ef\uff0c\u53ef\u4ee5\u6709\u6548\u5730\u51cf\u5c11\u9502\u679d\u6676\u7684\u5f62\u6210\uff0c\u4ece\u800c\u964d\u4f4e\u5145\/\u653e\u7535\u671f\u95f4\u7684\u771f\u5b9e\u7535\u6d41\u5bc6\u5ea6\u3002\u7136\u800c\uff0c\u7eaf\u9502\u7c89\u672b\u66b4\u9732\u4e8e\u7535\u89e3\u8d28\u6216\u7a7a\u6c14\u65f6\u4e0d\u7a33\u5b9a\uff0c\u5177\u6709\u5b89\u5168\u9690\u60a3\u3002\u56e0\u6b64\uff0c\u5236\u5907\u5b89\u5168\u4e14\u6613\u4e8e\u5904\u7406\u7684\u7a33\u5b9a\u9502\u7c89\u672b\u7535\u6781\u6750\u6599\u5bf9\u4e8e\u63d0\u9ad8\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5b89\u5168\u6027\u548c\u6548\u7387\u4ee5\u53ca\u964d\u4f4e\u5904\u7406\u3001\u52a0\u5de5\u7684\u6210\u672c\u662f\u975e\u5e38\u91cd\u8981\u7684\u3002\u76ee\u524d\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u81f4\u529b\u4e8e\u901a\u8fc7\u63a7\u5236\u7535\u6781\u51e0\u4f55\u5f62\u72b6\u6216\u7535\u6781\u8868\u9762\u6765\u7a33\u5b9a\u9502\u7535\u6781\u3002\u7136\u800c\uff0c\u901a\u8fc7\u7535\u5316\u5b66\u7535\u9540\u5408\u6210\u7a7a\u6c14\u7a33\u5b9a\u7684\u9502\u7c89\u672b\u6216\u7403\u4f53\u8fc4\u4eca\u5c1a\u672a\u89c1\u62a5\u9053\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\n \u8fd1\u65e5\uff0c\u71d5\u5c71\u5927\u5b66\u4e9a\u7a33\u6750\u6599\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u6e05\u6d01\u7eb3\u7c73\u80fd\u6e90\u7814\u7a76\u4e2d\u5fc3\u9ec4\u5efa\u5b87\u6559\u6388\u3001\u5510\u6c38\u798f\u526f\u6559\u6388\u3001\u6c88\u540c\u5fb7\u6559\u6388\u3001\u4e2d\u56fd\u77f3\u6cb9\u5927\u5b66(\u5317\u4eac)\u5f20\u5229\u5f3a\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5728\u5148\u8fdb\u7684\u50cf\u5dee\u6821\u6b63\u73af\u5883\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u5185\u3001CO2<\/sub>\u6c14\u6c1b\u4e0b\u901a\u8fc7\u7535\u5316\u5b66\u7535\u9540\u5236\u5907\u4e86\u7a7a\u6c14\u7a33\u5b9a\u7684\u9502\u7403(ASLSs)\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cAir-Stable Lithium Spheres Produced by Electrochemical Plating<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u535a\u58eb\u7814\u7a76\u751f\u6768\u5a77\u5a77\u3001\u8d3e\u9e4f\u3001\u5218\u79cb\u7537\u3001\u675c\u806a\u806a\u4e3a\u8be5\u5de5\u4f5c\u7684\u5171\u540c\u7b2c\u4e00\u4f5c\u8005\u3002ASLSs\u4e3a\u9502\u6838\u548c\u78b3\u9178\u9502\u58f3\u7ec4\u6210\u7684\u6838-\u58f3\u7ed3\u6784\u3002\u5728\u5927\u6c14\u4e2d\uff0cASLSs\u4e0d\u4f1a\u4e0e\u6c34\u5206\u53d1\u751f\u53cd\u5e94\u5e76\u4fdd\u6301\u5176\u6838\u58f3\u7ed3\u6784\u3002\u6b64\u5916\uff0cASLSs\u53ef\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u7684\u8d1f\u6781\uff0c\u5176\u8868\u73b0\u51fa\u4e0e\u91d1\u5c5e\u9502\u7c7b\u4f3c\u7684\u7535\u5316\u5b66\u884c\u4e3a\uff0c\u8bc1\u5b9e\u8868\u9762\u7684Li2<\/sub>CO3<\/sub>\u5c42\u662f\u826f\u597d\u7684\u9502\u79bb\u5b50\u5bfc\u4f53\u3002 ASLSs\u7684\u7a7a\u6c14\u7a33\u5b9a\u6027\u5e94\u5f52\u56e0\u4e8e\u8868\u9762\u78b3\u9178\u9502\u5c42\uff0c\u5176\u5728\u5ba4\u6e29\u4e0b\u51e0\u4e4e\u4e0d\u6eb6\u4e8e\u6c34\u5e76\u4e14\u4e0d\u4e0e\u7a7a\u6c14\u4e2d\u7684\u6c27\u548c\u6c2e\u53cd\u5e94\uff0c\u56e0\u6b64\u949d\u5316\u4e86\u9502\u6838\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 ASLSs\u7684\u5236\u5907\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5b9e\u9a8c\u88c5\u7f6e\u793a\u610f\u56fe\uff0c\u9502\u7535\u9540\u88c5\u7f6e\u7531CNT\u9634\u6781\u3001\u6c27\u5316\u9502\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u9502\u9633\u6781\u7ec4\u6210\uff1b
\n b-e) CO2<\/sub>\u73af\u5883\u4e2dASLS\u7684\u751f\u6210\u8fc7\u7a0b\u3002\u5728\u65bd\u52a0\u8d1f\u7535\u4f4d\u65f6\uff0c\u5728CNT\u3001Li2<\/sub>O\u548cCO2<\/sub>\u4e09\u76f8\u4ea4\u754c\u70b9\u51fa\u73b0\u9502\u7403\u3002\u5177\u6709\u6838-\u58f3\u7ed3\u6784\u7684\u7403\u4f53\u968f\u7740\u65f6\u95f4\u7684\u5ef6\u957f\uff0c\u5176\u5c3a\u5bf8\u9010\u6e10\u589e\u5927\u3002<\/p>\n

\u56fe2 ASLS\u7684\u6676\u4f53\u7ed3\u6784\u4e0e\u7ec4\u6210\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a-c) \u539f\u59cbASLSs\u7684TEM\u56fe\u50cf\u3001\u7535\u5b50\u884d\u5c04\u56fe\u50cf\u3001\u6697\u573a\u50cf\uff1b
\n d-f) \u66b4\u9732\u5728\u7a7a\u6c14\u4e2d30 min\u7684ASLSs\u7684TEM\u56fe\u50cf\u3001\u7535\u5b50\u884d\u5c04\u56fe\u50cf\u3001\u6697\u573a\u50cf\uff1b
\n g,i) \u539f\u59cbASLSs\u7684\u4f4e\u80fd\u635f\u5931\u8c31\u548c\u5185\u58f3\u5c42\u6fc0\u53d1\u8c31\uff0c\u5176\u4e2d\u7ea2\u8272\u4e3a\u58f3\u5c42\uff0c\u84dd\u8272\u4e3a\u6838\u5c42(\u4e0b\u540c)\uff1b
\n h,j) \u66b4\u9732\u5728\u7a7a\u6c14\u4e2d30 min\u7684ASLSs\u7684\u4f4e\u80fd\u635f\u5931\u8c31\u548c\u5185\u58f3\u5c42\u6fc0\u53d1\u8c31\u3002<\/p>\n

\u56fe3 ASLSs\u7684\u5236\u5907\u53ef\u91cd\u590d\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a-c) \u91cd\u65b0\u5236\u5907\u7684\u539f\u59cbASLSs\u7684TEM\u56fe\u50cf\uff1b
\n d) \u91cd\u65b0\u5236\u5907\u7684\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d30 min\u7684TEM\u56fe\u50cf\uff1b
\n e) \u91cd\u65b0\u5236\u5907\u7684\u539f\u59cbASLSs\u7684\u6697\u573a\u50cf\uff1b
\n f) \u91cd\u65b0\u5236\u5907\u7684\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d30 min\u7684\u6697\u573a\u50cf\uff1b
\n g) \u91cd\u65b0\u5236\u5907\u7684\u539f\u59cbASLSs\u7684\u7535\u5b50\u884d\u5c04\u56fe\u50cf\uff1b
\n h) \u91cd\u65b0\u5236\u5907\u7684\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d30 min\u7684ASLSs\u7684\u7535\u5b50\u884d\u5c04\u56fe\u50cf\u3002<\/p>\n

\u56fe4 ASLSs\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u7684\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

\u4e3a\u4e86\u6d4b\u8bd5ASLS\u662f\u5426\u53ef\u4ee5\u7528\u4f5c\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8d1f\u6781\uff0c\u4f5c\u8005\u4ee5ASLS\u4f5c\u4e3a\u8d1f\u6781\uff0c\u4ee5Li2<\/sub>CO3<\/sub>\u3001Li2<\/sub>O\u58f3\u5c42\u4f5c\u4e3a\u7535\u89e3\u8d28\uff0c\u4ee5Au\u6d82\u8986\u7684CuO\u7eb3\u7c73\u7ebf\u4f5c\u4e3a\u6b63\u6781\uff0c\u5728ETEM\u4e2d\u6784\u5efa\u7eb3\u7c73\u7535\u6c60\u8fdb\u884c\u6d4b\u8bd5\u3002
\n a) \u539f\u59cbASLSs\u7684TEM\u56fe\u50cf\uff1b
\n b) \u66b4\u9732\u5728\u7a7a\u6c14\u4e2d30 min\u7684TEM\u56fe\u50cf\uff1b
\n c-f) \u5728\u5bf9Au\u6d82\u8986\u7684CuO\u7eb3\u7c73\u7ebf\u65bd\u52a0\u8d1f\u7535\u4f4d\u65f6\uff0c\u7eb3\u7c73\u7ebf\u8fc5\u901f\u9502\u5316\u5e76\u4f53\u79ef\u81a8\u80c0\uff1b
\n g,h) \u65bd\u52a0\u8d1f\u7535\u4f4d\u540e\uff0cCuO\u8f6c\u53d8\u4e3aLi2<\/sub>O\u3001Cu\u548cLiAu\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u5728\u50cf\u5dee\u6821\u6b63\u73af\u5883\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\u4e2d\u3001CO2<\/sub>\u6c14\u6c1b\u4e0b\u5229\u7528\u7535\u5316\u5b66\u7535\u9540\u65b9\u6cd5\u5236\u5907\u4e86\u7a7a\u6c14\u7a33\u5b9a\u7684\u9502\u7403(ASLS)\u3002\u4e3a\u4e86\u6d4b\u8bd5ASLSs\u5728\u9502\u7535\u6c60\u4e2d\u7684\u5b9e\u9645\u9002\u7528\u6027\uff0c\u4f5c\u8005\u5229\u7528\u7535\u5316\u5b66\u7535\u9540\u88c5\u7f6e\u5408\u6210\u4e86\u6beb\u514b\u7ea7ASLSs\u3002\u5c06\u6beb\u514b\u7ea7ASLSs\u9540\u5728\u94dc\u7b94\u4e0a\uff0c\u5e76\u5c06\u8be5\u7ec4\u4ef6\u7528\u4f5c\u7ebd\u6263\u7535\u6c60\u9502\u79bb\u5b50\u7535\u6c60\u7684\u9633\u6781\u3002\u7535\u5316\u5b66\u6d4b\u8bd5\u8868\u660e\uff0c\u76f8\u6bd4\u7eaf\u9502\u7535\u6781\uff0cASLS\u7535\u6781\u7684\u9996\u5708\u5faa\u73af\u5bb9\u91cf\u66f4\u9ad8\uff0c\u8fdb\u800c\u8bc1\u5b9eASLS\u53ef\u4f5c\u4e3a\u9502\u7535\u6c60\u901a\u7528\u8d1f\u6781\u6750\u6599\u3002\u6b64\u5916\uff0c\u77f3\u58a8\u8868\u9762\u4e0a\u7684Li2<\/sub>CO3<\/sub>\u6d82\u5c42\u53ef\u4ee5\u9632\u6b62\u5728\u7535\u6781\u8868\u9762\u53d1\u751f\u673a\u68b0\u635f\u4f24\uff0c\u4ee5\u514d\u5728\u9502\u79bb\u5b50\u7535\u6c60\u7684\u9996\u5708\u5faa\u73af\u4e2d\u9020\u6210\u5267\u70c8\u7684\u5bb9\u91cf\u635f\u5931(\u5373\u7535\u5316\u5b66\u51b2\u51fb)\u3002\u56e0\u6b64\uff0cASLS\u6709\u671b\u6210\u4e3a\u4e0b\u4e00\u4ee3\u9502\u7535\u6c60\u5b89\u5168\u9ad8\u6548\u7684\u8d1f\u6781\u6750\u6599\u3002\u8be5\u5de5\u4f5c\u4e2d\u5c55\u793a\u7684\u7535\u5316\u5b66\u7535\u9540\u65b9\u6cd5\u4e3a\u5236\u5907\u5177\u6709\u4e0e\u5e38\u89c4\u9502\u8d1f\u6781\u53cd\u5e94\u6d3b\u6027\u7c7b\u4f3c\u7684ASLSs\u63d0\u4f9b\u4e86\u6709\u6548\u7684\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAir-Stable Lithium Spheres Produced by Electrochemical Plating<\/a><\/strong>\u00a0(Angew. Chem. Int. Ed.<\/strong>, 2018, DOI: 10.1002\/anie.201807355)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u91d1\u5c5e\u9502(Li)\u5177\u6709\u975e\u5e38\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf(3860 mAh\u00b7g-1)\uff0c\u6709\u671b\u4f5c\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7684\u8d1f\u6781\u6750\u6599\u7528\u4e8e\u7535\u52a8\u6c7d\u8f66\u548c\u7535\u7f51\u5b58\u50a8\u3002\u4e0e\u9502\u7b94\u76f8\u6bd4\uff0c\u7528\u4e8e\u9502\u79bb\u5b50…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3556,2614],"class_list":["post-153183","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-3556","tag-2614"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/153183"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=153183"}],"version-history":[{"count":2,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/153183\/revisions"}],"predecessor-version":[{"id":153253,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/153183\/revisions\/153253"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=153183"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=153183"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=153183"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}