{"id":151895,"date":"2018-08-27T08:00:09","date_gmt":"2018-08-27T00:00:09","guid":{"rendered":"\/\/m.iemloyee.com\/?p=151895"},"modified":"2018-08-28T00:07:41","modified_gmt":"2018-08-27T16:07:41","slug":"%e9%a6%99%e6%b8%af%e5%9f%8e%e5%a4%a7%e6%9c%b1%e5%89%91%e8%b1%aanano-energy%ef%bc%9ani%e6%8e%ba%e6%9d%82%e9%9d%9e%e6%99%b6fep%e7%ba%b3%e7%b1%b3%e9%a2%97%e7%b2%92%e8%b4%9f%e8%bd%bd%e7%9a%84tin%e7%ba%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=151895","title":{"rendered":"\u9999\u6e2f\u57ce\u5927\u6731\u5251\u8c6aNano Energy\uff1aNi\u63ba\u6742\u975e\u6676FeP\u7eb3\u7c73\u9897\u7c92\u8d1f\u8f7d\u7684TiN\u7eb3\u7c73\u7ebf\u9635\u5217\u7528\u4e8e\u78b1\u6027\u4f53\u7cfbHER"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u5728\u7535\u89e3\u6c34\u4ea7\u6c22\uff08HER\uff09\u50ac\u5316\u5242\u4e2d\uff0c\u8d35\u91d1\u5c5e\u94c2\u65cf\u50ac\u5316\u5242\u7684\u50ac\u5316\u6027\u80fd\u6700\u4f18\u5f02\uff0c\u4f46\u7531\u4e8e\u50a8\u91cf\u5c11\u3001\u4ef7\u683c\u6602\u8d35\u7b49\u56e0\u7d20\u9650\u5236\u5176\u5927\u89c4\u6a21\u63a8\u5e7f\u4f7f\u7528\u3002\u56e0\u6b64\uff0c\u8fd1\u5e74\u6765\u5f00\u53d1\u5177\u6709\u4f4e\u6210\u672c\u3001\u9ad8\u50ac\u5316\u6d3b\u6027\u548c\u957f\u5bff\u547d\u7684\u975e\u8d35\u91d1\u5c5e\u57fa\u50ac\u5316\u5242\u6750\u6599\u6210\u4e3aHER\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u548c\u91cd\u70b9\u3002\u94c1\u57fa\u50ac\u5316\u5242\uff0c\u5c24\u5176\u662f\u78f7\u5316\u94c1\uff0c\u7531\u4e8e\u50a8\u91cf\u4e30\u5bcc\u3001\u4ef7\u683c\u4f4e\u5ec9\u3001\u9002\u7528\u4e8e\u5bbdpH\u8303\u56f4\u4f53\u7cfb\uff0c\u56e0\u800c\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u975e\u5e38\u5177\u6709\u524d\u666f\u7684HER\u50ac\u5316\u5242\u3002\u7136\u800c\u5728\u4ee5\u5f80\u62a5\u9053\u4e2d\uff0c\u5173\u4e8e\u78f7\u5316\u94c1HER\u7684\u7814\u7a76\u5de5\u4f5c\u4e3b\u8981\u96c6\u4e2d\u5728\u9178\u6027\u4f53\u7cfb\u4e2d\u3002\u9178\u6027\u7535\u89e3\u6c34\u4f53\u7cfb\u5bf9\u7cfb\u7edf\u7684\u786c\u4ef6\u8bbe\u65bd\u9632\u8150\u6027\u80fd\u8981\u6c42\u8f83\u9ad8\u4e14\u5bb9\u6613\u9020\u6210\u73af\u5883\u6c61\u67d3\uff0c\u56e0\u6b64\u78b1\u6027\u4ecb\u8d28\u4e2dHER\u6700\u8fd1\u53d7\u5230\u66f4\u591a\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u4e0d\u540c\u4e8e\u9178\u6027\u4f53\u7cfb\uff0c\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u8bf8\u591a\u50ac\u5316\u5242\u7684HER\u52a8\u529b\u5b66\u8fc7\u7a0b\u7f13\u6162\u3001\u50ac\u5316\u6d3b\u6027\u4f4e\u7b49\u5bfc\u81f4\u6cd5\u62c9\u7b2c\u6548\u7387\u8f83\u4f4e\u3002\u7531\u4e8eNi-Fe-P\u53cc\u91d1\u5c5e\u5316\u5408\u7269\u53ef\u8868\u73b0\u51fa\u8f83\u5355\u91d1\u5c5e\u5316\u5408\u7269\u6709\u66f4\u9ad8\u7684HER\u6d3b\u6027\uff1b\u4ea6\u6709\u76f8\u5f53\u62a5\u9053\uff0c\u975e\u6676\u6001\u50ac\u5316\u5242\u8868\u73b0\u51fa\u6bd4\u7ed3\u6676\u6001\u50ac\u5316\u5242\u66f4\u4f18\u5f02\u7684\u6027\u80fd\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u5728<strong><b>\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u7b49\u79bb\u5b50\u4f53<\/b><\/strong><strong><b>\u5b9e\u9a8c\u5ba4<\/b><\/strong><strong><b>\u6731\u5251\u8c6a\u6559\u6388<\/b><\/strong>\u548c<strong><b>\u6b66\u6c49\u5de5\u7a0b\u5927\u5b66\u5149\u7535\u4e0e\u65b0\u80fd\u6e90\u6750\u6599\u7814\u7a76\u6240\u5f6d\u7965\u535a\u58eb<\/b><\/strong><strong><b>\uff08<\/b><\/strong><strong><b>\u5171\u540c<\/b><\/strong><strong><b>\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u56e2\u961f\u7684\u5e26\u9886\u4e0b\uff0c\u4e0e<strong><b>\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u970d\u5f00\u5bcc<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong>\u548c<strong><b>\u9999\u6e2f\u7406\u5de5\u5927\u5b66Kwok<\/b><\/strong><strong><b>-yin Wong<\/b><\/strong><strong><b>\u6559\u6388<\/b><\/strong>\u5408\u4f5c\uff0c\u901a\u8fc7\u9ad8\u80fd\u91d1\u5c5e\u79bb\u5b50\u6ce8\u5165\u6cd5\u9996\u6b21\u5b9e\u73b0\u4e86\u5bf9\u8d1f\u8f7d\u5728\u591a\u5b54\u5bfc\u7535\u57fa\u4f53TiN\u7eb3\u7c73\u7ebf\u9635\u5217\u4e0a\u7684FeP\u7eb3\u7c73\u9897\u7c92\u540c\u65f6\u8fdb\u884c\u53ef\u63a7\u954d\u63ba\u6742\u548c\u8868\u9762\u975e\u6676\u5316\u5904\u7406\uff0c\u6210\u529f\u8bbe\u8ba1\u548c\u6784\u5efa\u4e86\u954d\u63ba\u6742\u975e\u6676FeP\u7eb3\u7c73\u9897\u7c92\u8d1f\u8f7d\u7684\u6c2e\u5316\u949b\u7eb3\u7c73\u7ebf\u9635\u5217\uff08Ni-FeP\/TiN\/CC\uff09\u590d\u5408\u6750\u6599\u3002\u8be5\u590d\u5408\u6750\u6599\u5728\u78b1\u6027\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684HER\u6027\u80fd\u3002\u8fbe\u523010 mA\/cm<sup>2<\/sup>\u7684\u6790\u6c22\u7535\u6d41\u4ec5\u9700\u898175mV\u7684\u8fc7\u7535\u4f4d\uff0c\u5e76\u4e14\u5177\u6709\u4e0e\u5546\u7528Pt\/C\u50ac\u5316\u5242\u63a5\u8fd1\u7684Tafel\u659c\u7387\uff1b\u5728300 mV\u7684\u9ad8\u8fc7\u7535\u4f4d\u4e0b\u8fde\u7eed\u6790\u6c2210\u5c0f\u65f6\u5176\u7535\u6d41\u503c\u4ecd\u80fd\u4fdd\u6301\u521d\u59cb\u503c\u768493%\uff0c\u800c\u4e14\u50ac\u5316\u5242\u7684\u5f62\u8c8c\u4e5f\u6ca1\u6709\u53d1\u751f\u660e\u663e\u53d8\u5316\u3002\u4e3a\u6df1\u5165\u7406\u89e3\u8be5\u50ac\u5316\u5242\u9ad8\u6548HER\u7684\u5185\u5728\u673a\u5236\uff0c\u7814\u7a76\u4eba\u5458\u4ece\u6750\u6599\u7684\u5bfc\u7535\u6027\u3001\u7535\u5316\u5b66\u6d3b\u6027\u9762\u79ef\u3001Ni-Fe\u534f\u540c\u4f5c\u7528\u7b49\u65b9\u9762\u8fdb\u884c\u4e86\u8be6\u7ec6\u7684\u63a2\u8ba8\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong><b>Ni-Doped Amorphous Iron Phosphide Nanoparticles on TiN Nanowire Arrays: An Advanced Alkaline Hydrogen Evolution Electrocatalyst<\/b><\/strong>\u201d\u53d1\u8868\u5728\u4e86<strong><b>Nano Energy<\/b><\/strong>\u4e0a\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe1 \u5236\u5907\u5206\u7ea7Ni-FeP\/TiN\/CC\u7535\u50ac\u5316\u5242\u7684\u793a\u610f\u56fe<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151896\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/1-48.jpg\" alt=\"\" width=\"600\" height=\"436\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/1-48.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/1-48-300x218.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe2<\/b><\/strong><strong><b>\u5f62\u8c8c\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151897\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/2-48.jpg\" alt=\"\" width=\"600\" height=\"345\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/2-48.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/2-48-300x173.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a-b\uff09TiN\/CC\u7684SEM\uff1b<\/p>\n<p>\uff08c-d\uff09FeP\/TiN\/CC\u7684SEM\uff1b\u00a0<\/p>\n<p>\uff08e-f\uff09Ni-FeP\/TiN\/CC\u7684SEM\u3002<\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>\u7ed3\u6784\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151898\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/3-47.jpg\" alt=\"\" width=\"600\" height=\"411\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/3-47.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/3-47-300x206.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09TiN\/CC\uff0cFe<sub>3<\/sub>O<sub>4<\/sub>\/TiN\/CC\uff0cFeP\/TiN\/CC\u548cNi-FeP\/TiN\/CC\u7684XRD\u56fe\uff1a@\uff1a\u77f3\u58a8\uff0c$\uff1aTiN\uff0887-0628\uff09\uff0c\uff03\uff1aFe<sub>3<\/sub>O<sub>4<\/sub>\uff0889-0691\uff09\uff0c*\uff1aFeP\uff0889-2746\uff09;<\/p>\n<p>\uff08b\uff09Ni-FeP\/TiN\/CC\u7684TEM\u56fe\u50cf;<\/p>\n<p>\uff08c\uff0cd\uff09\u5206\u522b\u4e3aFeP\/TiN\/CC\u548cNi-FeP\/TiN\/CC\u7684HR-TEM\u56fe\u50cf\u3002<\/p>\n<p><strong><b>\u56fe4 <\/b><\/strong><strong><b>XPS\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151899\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/4-44.jpg\" alt=\"\" width=\"600\" height=\"468\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/4-44.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/4-44-300x234.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09Ni-FeP\/TiN\/CC\u548cFeP\/TiN\/CC\u7684XPS\u5168\u8c31\uff1b<\/p>\n<p>\uff08b\uff09\u7ed3\u5408\u80fd\u5728820\u548c880eV\u8303\u56f4\u5185\u7684Ni-FeP\/TiN\/CC\u548cFeP\/TiN\/CC\u7684XPS\u5168\u8c31\uff1b<\/p>\n<p>\uff08c\uff09Ni-FeP\/TiN\/CC\u4e2dNi\u00a02p\u7684\u9ad8\u5206\u8fa8\u7387XPS\uff1b<\/p>\n<p>\uff08d\uff09FeP\/TiN\/CC\u548cNi-FeP\/TiN\/CC\u4e2dFe\u00a02p\u7684\u9ad8\u5206\u8fa8\u7387XPS\uff1b<\/p>\n<p>\uff08e\uff09Ni-FeP\/TiN\/CC\u4e2dP\u00a02p\u7684\u9ad8\u5206\u8fa8\u7387XPS\u3002<\/p>\n<p><strong><b>\u56fe5<\/b><\/strong><strong><b>\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/b><\/strong><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151900\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/5-35.jpg\" alt=\"\" width=\"600\" height=\"456\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/5-35.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/5-35-300x228.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08b\uff09\u5854\u83f2\u5c14\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08c\uff09\u4e0d\u540cNi\u79bb\u5b50\u6ce8\u5165\u91cf\u7684Ni-FeP\/TiN\/CC\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n<p>\uff08d\uff09Ni-FeP\/TiN\/CC\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff0c\u63d2\u56fe\u4e3a\u6d4b\u8bd5\u4e4b\u524d\u548c\u4e4b\u540e\u7684LSV\u66f2\u7ebf\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u5c0f\u7ed3<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u9996\u5148\u5728\u78b3\u5e03\u4e0a\u751f\u957f\u591a\u5b54TiN\u7eb3\u7c73\u7ebf\u9635\u5217\u7ed3\u6784\uff08TiN\/CC\uff09\u4f5c\u4e3a\u6784\u7b51\u4e09\u7ef4\u67d4\u6027\u81ea\u652f\u6491\u7535\u6781\u7684\u57fa\u4f53\u6750\u6599\uff0c\u7136\u540e\u5728\u8be5\u57fa\u4f53\u4e0a\u8d1f\u8f7dFeP\u7eb3\u7c73\u9897\u7c92\uff0c\u6700\u540e\u91c7\u7528\u9ad8\u80fd\u91d1\u5c5e\u79bb\u5b50\u6ce8\u5165\u6cd5\u5bf9FeP\u7eb3\u7c73\u9897\u7c92\u8868\u5c42\u540c\u65f6\u8fdb\u884c\u954d\u63ba\u6742\u548c\u975e\u6676\u5316\u5904\u7406\u5f97\u5230Ni-FeP\/TiN\/CC\u3002\u7ed3\u679c\u8868\u660e\u8be5\u590d\u5408\u6750\u6599\u5728\u78b1\u6027\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684HER\u6027\u80fd\u3002\u4f5c\u8005\u8ba4\u4e3a\u9ad8\u6548HER\u5f52\u56e0\u4e8eNi-Fe-P\u539f\u5b50\u7684\u534f\u540c\u589e\u5f3a\u6548\u5e94\u3001\u9ad8\u6d3b\u6027\u7684\u975e\u6676\u8868\u9762\u3001\u57fa\u4f53\u6750\u6599\u7684\u9ad8\u5bfc\u7535\u6027\u4fdd\u8bc1\u7535\u8377\u7684\u65e0\u969c\u788d\u4f20\u8f93\u3001\u4ee5\u53caNi\u63ba\u6742\u975e\u6676FeP\u7eb3\u7c73\u9897\u7c92\u548c\u5bfc\u7535TiN\/CC\u57fa\u4f53\u7684\u7262\u56fa\u7ed3\u5408\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><strong><b>\u6587\u732e\u94fe\u63a5<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285518305986\" target=\"_blank\" rel=\"noopener\"><u>Ni-Doped Amorphous Iron Phosphide Nanoparticles on TiN Nanowire Arrays: An Advanced Alkaline Hydrogen Evolution Electrocatalyst<\/u><\/a>\uff08Nano Energy, 2018, DOI\uff1a10.1016\/j.nanoen.2018.08.028\uff09<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u56e2\u961f\u4ecb\u7ecd<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u9999\u6e2f\u57ce\u5e02\u5927\u5b66\u7b49\u79bb\u5b50\u4f53\u5b9e\u9a8c\u5ba4<\/p>\n<p><a href=\"http:\/\/www6.cityu.edu.hk\/appkchu\/plasma\/Paul%20Chu\/paul_chu.htm\" target=\"_blank\" 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