{"id":151227,"date":"2018-08-17T08:52:44","date_gmt":"2018-08-17T00:52:44","guid":{"rendered":"\/\/m.iemloyee.com\/?p=151227"},"modified":"2018-08-17T08:52:44","modified_gmt":"2018-08-17T00:52:44","slug":"%e4%bb%8a%e6%97%a5science%ef%bc%9a%e9%93%88%e7%9b%90%e5%85%89%e5%82%ac%e5%8c%96%e5%89%82-%e9%ab%98%e6%95%88%e4%bd%bf%e7%94%a8%e5%a4%a9%e7%84%b6%e6%b0%94%e7%9a%84%e7%a6%8f%e9%9f%b3","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=151227","title":{"rendered":"\u4eca\u65e5Science\uff1a\u94c8\u76d0\u5149\u50ac\u5316\u5242-\u9ad8\u6548\u4f7f\u7528\u5929\u7136\u6c14\u7684\u798f\u97f3"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u5e74\u6765\u968f\u7740\u5929\u7136\u6c14\u4ea7\u91cf\u7684\u98d9\u5347\uff0c\u5229\u7528\u7532\u70f7\u548c\u5176\u4ed6\u8f7b\u70c3\u539f\u6599\u4f5c\u4e3a\u5408\u6210\u8f6c\u5316\u7684\u539f\u6750\u6599\u5df2\u5f97\u5230\u76f8\u5f53\u7684\u91cd\u89c6\u3002\u4e3a\u4e86\u964d\u4f4e\u8fd0\u8f93\u6210\u672c\u548c\u6392\u653e\u91cf\u548c\u589e\u52a0\u7ecf\u6d4e\u548c\u751f\u6001\u6548\u76ca\uff0c\u901a\u8fc7\u4f7f\u7528\u521b\u65b0\u7684\u5747\u76f8\u50ac\u5316\u5de5\u827a\u5c06\u6c14\u6001\u70c3\u7c7b\u76f4\u63a5\u8f6c\u5316\u4e3a\u9ad8\u9644\u52a0\u503c\u7684\u6db2\u6001\u5316\u5b66\u54c1\u4e5f\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u7532\u70f7\u548c\u5176\u4ed6\u6c14\u6001\u70f7\u70c3\u4e2dC-H\u952e\u7684\u56fa\u6709\u60f0\u6027\u7ed9\u50ac\u5316\u4f53\u7cfb\u5e26\u6765\u4e86\u6781\u5927\u7684\u6311\u6218\uff0c\u4e0d\u4ec5\u5728\u6d3b\u5316\u9636\u6bb5\uff0c\u800c\u4e14\u5728\u63a7\u5236\u5316\u5b66\u9009\u62e9\u6027\u9636\u6bb5\u5728\u5fc5\u8981\u7684\u82db\u523b\u6761\u4ef6\u4e0b\u8981\u907f\u514d\u6eb6\u5242\u5b98\u80fd\u5316\u548c\u8fc7\u5ea6\u5b98\u80fd\u5316\uff08\u9ad8\u6e29\uff0c\u8d85\u5f3a\u9178\u4ecb\u8d28\uff0c\u5f3a\u6c27\u5316\u5242\uff09\u3002\u800c\u4e14\uff0c\u6c14\u6001\u5e95\u7269\u5728\u5927\u591a\u6570\u6eb6\u5242\u4e2d\u7684\u4f4e\u6eb6\u89e3\u5ea6\u4e5f\u7ed9\u5b9e\u9645\u5e94\u7528\u5e26\u6765\u4e86\u5f88\u5927\u7684\u56f0\u96be\u3002\u6700\u8fd1\u62a5\u9053\u4e86\u4f7f\u7528\u8fc7\u6e21\u91d1\u5c5e\u5982Pd\u3001Ir\u3001Rh\u548cRu\u7684\u50ac\u5316\u4f53\u7cfb\uff1b\u7136\u800c\uff0c\u5f00\u53d1\u5728\u73af\u5883\u6761\u4ef6\u4e0b\u8fd0\u884c\u7684\u9ad8\u6548\u3001\u542b\u91cf\u4e30\u5bcc\u7684\u50ac\u5316\u5242\u4ecd\u7136\u662f\u4e00\u4e2a\u6311\u6218\u3002<\/p>\n<p><strong><b>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n<p>\u4eca\u65e5\uff0c\u5728<strong><b>\u4e0a\u6d77\u79d1\u6280\u5927\u5b66\u5de6\u667a\u4f1f\u7814\u7a76\u5458<\/b><\/strong><strong><b>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u56e2\u961f\u7684\u5e26\u9886\u4e0b\uff0c\u5c06\u914d\u4f4d\u4f53\u4e0e\u91d1\u5c5e\u7684\u7535\u8377\u8f6c\u79fb\uff08LMCT\uff09\u50ac\u5316\u5e94\u7528\u4e8e\u9187\u539f\u6599\u7684\u76f4\u63a5\u6d3b\u5316\uff0c\u4f7f\u5f97\u70f7\u6c27\u57fa\u81ea\u7531\u57fa\u4ecb\u5bfc\u7684\u73af\u72b6\u9187\u7684\u9aa8\u67b6\u91cd\u6392\u548c\u901a\u8fc7\u6c22\u539f\u5b50\u8f6c\u79fb\uff08HAT\uff09\u7684\u4f2f\u9187\u5b9e\u73b0C-H\u5b98\u80fd\u5316\u3002\u5229\u7528\u5438\u6536\u7684\u5149\u80fd\u901a\u8fc7\u77ac\u65f6\u914d\u4f4d\u7684Ce(IV)-\u9187\u76d0\u7684\u5747\u88c2\u4fc3\u8fdb\u9776\u5411\u6c27\u5316\uff0c\u5728\u6e29\u548c\u4e14\u64cd\u4f5c\u7b80\u5355\u7684\u6761\u4ef6\u4e0b\u7528\u5ec9\u4ef7\u7684\u94c8\uff08III\uff09\u76d0\u4f5c\u4e3a\u524d\u9a71\u5149\u50ac\u5316\u5242\uff0c\u5b9e\u73b0\u4e86\u9ad8\u50ac\u5316\u6548\u7387\uff08\u7532\u70f7\u7684\u8f6c\u5316\u6570\u9ad8\u8fbe2900\uff0c\u4e59\u70f7\u7684\u8f6c\u5316\u6570\u4e3a9700\uff09\u548c\u9009\u62e9\u6027\u3002\u914d\u4f53-\u91d1\u5c5e\u7535\u8377\u8f6c\u79fb\u6fc0\u53d1\u4ea7\u751f\u4e8e\u7b80\u5355\u9187\u751f\u6210\u7684\u70f7\u6c27\u57fa\uff0c\u5176\u53cd\u8fc7\u6765\u5145\u5f53HAT\u50ac\u5316\u5242\u3002\u6df7\u5408\u76f8\u6c14\/\u6db2\u53cd\u5e94\u9002\u5408\u4e8e\u8fde\u7eed\u6d41\u52a8\uff0c\u4f7f\u6c14\u4f53\u539f\u6599\u5728\u5149\u50ac\u5316\u8f6c\u5316\u4e2d\u5f97\u5230\u6709\u6548\u5229\u7528\u3002\u8fd9\u79cd\u5149\u50ac\u5316\u5e73\u53f0\u5df2\u7ecf\u5b9e\u73b0\u4e86\u7532\u70f7\u548c\u5176\u4ed6\u7b80\u5355\u70c3\u7684\u51e0\u79cd\u76f4\u63a5\u8f6c\u5316\uff0c\u5305\u62ec\u80fa\u5316\uff0c\u70f7\u57fa\u5316\u548c\u82b3\u57fa\u5316\uff0c\u5e76\u4e3a\u539f\u6599\u70f7\u70c3\u7684\u8fdb\u4e00\u6b65\u5b98\u80fd\u5316\u63d0\u4f9b\u4e86\u53ef\u9760\u7684\u673a\u4f1a\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong><b>Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis<\/b><\/strong>\u201d\u53d1\u8868\u5728\u4e86<strong><b>Science<\/b><\/strong>\u4e0a\u3002<\/p>\n<p><strong><b>\u00a0<\/b><\/strong><strong><b>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe1 \u70f7\u6c27\u57fa\u81ea\u7531\u57fa\u4ecb\u5bfc\u7684HAT\u6d3b\u5316\u80fd\u591f\u5b9e\u73b0\u6c14\u6001\u70f7\u70c3\u7684\u591a\u79cd\u9009\u62e9\u6027\u5b98\u80fd\u5316<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151228\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F1.large_-3.jpg\" alt=\"\" width=\"600\" height=\"305\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F1.large_-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F1.large_-3-300x153.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u00a0<\/b><\/strong><strong><b>\u56fe2 \u7532\u70f7\u548c\u5176\u4ed6\u6c14\u6001\u70f7\u70c3\u7684\u94c8\u50ac\u5316C<\/b><\/strong><strong><b>(<\/b><\/strong><strong><b>sp<\/b><\/strong><strong><sup><b>3<\/b><\/sup><\/strong><strong><b>)<\/b><\/strong><strong><b>-H\u5b98\u80fd\u5316\u7684\u673a\u7406<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151229\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F2.large_-3.jpg\" alt=\"\" width=\"600\" height=\"449\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F2.large_-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F2.large_-3-300x225.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe3<\/b><\/strong><strong><b>\u00a0<\/b><\/strong><strong><b>\u4f7f\u7528\u7532\u70f7\u548c\u4e59\u70f7\u7684\u5149\u50ac\u5316\u70f7\u57fa\u5316<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151230\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F3.large_-3.jpg\" alt=\"\" width=\"600\" height=\"479\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F3.large_-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F3.large_-3-300x240.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>4 <\/b><\/strong><strong><b>\u7528\u4e8e<\/b><\/strong><strong><b>\u5927\u89c4\u6a21<\/b><\/strong><strong><b>\u5e94\u7528\u7684\u8fde\u7eed\u6d41\u52a8\u53cd\u5e94\u5668\u4e2d\u70f7\u70c3\u7684\u5149\u50ac\u5316\u80fa\u5316<\/b><\/strong><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-151231\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F4.large_-3.jpg\" alt=\"\" width=\"600\" height=\"340\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F4.large_-3.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/F4.large_-3-300x170.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p><strong><b>\u6587\u732e\u94fe\u63a5<\/b><\/strong><strong><b>\uff1a<\/b><\/strong><a href=\"http:\/\/science.sciencemag.org\/content\/361\/6403\/668\" target=\"_blank\" rel=\"noopener\"><u>Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis<\/u><\/a>\uff08Science, 2018, DOI\uff1a10.1126\/science.aat9750\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4<strong><b>\u6728\u6587\u97ec<\/b><\/strong>\u7ffb\u8bd1\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\"><strong><u><b>\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/b><\/u><\/strong><\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong><u><b>\u6d4b\u8bd5\u8c37<\/b><\/u><\/strong><\/a><strong><b>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u8fd1\u5e74\u6765\u968f\u7740\u5929\u7136\u6c14\u4ea7\u91cf\u7684\u98d9\u5347\uff0c\u5229\u7528\u7532\u70f7\u548c\u5176\u4ed6\u8f7b\u70c3\u539f\u6599\u4f5c\u4e3a\u5408\u6210\u8f6c\u5316\u7684\u539f\u6750\u6599\u5df2\u5f97\u5230\u76f8\u5f53\u7684\u91cd\u89c6\u3002\u4e3a\u4e86\u964d\u4f4e\u8fd0\u8f93\u6210\u672c\u548c\u6392\u653e\u91cf\u548c\u589e\u52a0\u7ecf\u6d4e\u548c\u751f\u6001\u6548\u76ca\uff0c\u901a\u8fc7\u4f7f\u7528\u521b\u65b0\u7684\u5747&#8230;<\/p>\n","protected":false},"author":2109,"featured_media":151231,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2922],"class_list":["post-151227","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-2922"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/151227"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/2109"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=151227"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/151227\/revisions"}],"predecessor-version":[{"id":151234,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/151227\/revisions\/151234"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/151231"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=151227"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=151227"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=151227"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}