{"id":151116,"date":"2018-08-20T08:00:12","date_gmt":"2018-08-20T00:00:12","guid":{"rendered":"\/\/m.iemloyee.com\/?p=151116"},"modified":"2018-08-19T21:48:20","modified_gmt":"2018-08-19T13:48:20","slug":"adv-mater%ef%bc%9a%e4%bd%bf%e7%94%a8%e7%a2%b3%e5%8c%96%e7%a1%bc%e7%ba%b3%e7%b1%b3%e7%ba%bf%e7%9a%84%e5%8f%8c%e5%8a%9f%e8%83%bd%e9%98%b4%e6%9e%81%e5%9f%ba%e6%9d%bf%e5%88%b6%e5%a4%87%e7%9a%84%e9%95%bf","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=151116","title":{"rendered":"Adv. Mater\uff1a\u4f7f\u7528\u78b3\u5316\u787c\u7eb3\u7c73\u7ebf\u7684\u53cc\u529f\u80fd\u9634\u6781\u57fa\u677f\u5236\u5907\u7684\u957f\u5bff\u547d\u9502\u786b\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u9502-\u786b(Li-S)\u7535\u6c60\u5177\u6709\u6781\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf(1675 mAhg-1<\/sup>)\uff0c\u4e14\u786b\u65e0\u6bd2\uff0c\u4ef7\u683c\u4f4e\u5ec9\uff0c\u88ab\u5e7f\u6cdb\u5730\u8ba4\u4e3a\u662f\u672a\u6765\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u5e94\u7528\u53d1\u5c55\u7684\u65b9\u5411\u3002\u7136\u800c\uff0c\u9502\u786b\u7535\u6c60\u7684\u5546\u4e1a\u5316\u9762\u4e34\u7740\u8bb8\u591a\u6311\u6218\u3002\u4f8b\u5982\uff0c\u786b\u53ca\u5176\u653e\u7535\u4ea7\u7269\u7535\u5bfc\u7387\u4f4e\u4f7f\u5f97\u6d3b\u6027\u6750\u6599\u5229\u7528\u7387\u4f4e\u548c\u52a8\u529b\u5b66\u53cd\u5e94\u53d8\u6162\u3002\u4e0e\u6b64\u540c\u65f6\uff0c\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u4e2d\u95f4\u4f53\u5f62\u6210\u7684\u53ef\u6eb6\u6027\u591a\u786b\u5316\u7269\u5bb9\u6613\u6eb6\u89e3\u5728\u6db2\u4f53\u7535\u89e3\u8d28\u4e2d\u5e76\u4e14\u4e0d\u53ef\u9006\u5730\u4ece\u9634\u6781\u6269\u6563\u5230\u9633\u6781\u533a\u57df\uff0c\u4f7f\u5f97\u7535\u6c60\u5faa\u73af\u5bff\u547d\u53d8\u5dee\u3002\u6240\u4ee5\uff0c\u4f18\u8d28\u786b\u6b63\u6781\u7684\u5f00\u53d1\u5bf9\u4e8e\u5b9e\u73b0\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u548c\u957f\u5faa\u73af\u5bff\u547d\u7684\u9502\u786b\u7535\u6c60\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u786b\u6b63\u6781\u8bbe\u8ba1\u4e2d\u6700\u5e38\u7528\u7684\u65b9\u6cd5\u4e4b\u4e00\u662f\u4f7f\u7528\u78b3\u57fa\u6750\u6599\u4f5c\u4e3a\u6355\u83b7\u591a\u786b\u5316\u7269\u7684\u7269\u7406\u5c4f\u969c\u3002\u7136\u800c\uff0c\u975e\u6781\u6027\u78b3\u4e3b\u4f53\u7684\u7eaf\u7269\u7406\u9650\u5236\u4e0d\u8db3\u4ee5\u4fdd\u8bc1\u5728\u957f\u65f6\u95f4\u5185\u6291\u5236\u591a\u786b\u5316\u7269\u7684\u6269\u6563\uff0c\u5c24\u5176\u662f\u5bf9\u9ad8\u786b\u8d1f\u8f7d\u91cf\u7684\u7535\u6c60\u800c\u8a00\u3002\u901a\u8fc7\u5f15\u5165\u4e86\u529f\u80fd\u6027\u6781\u6027\u57fa\u5e95\u4f5c\u4e3a\u786b\u5bbf\u4e3b\u8fd9\u4e00\u7b56\u7565\uff0c\u901a\u8fc7\u4e0e\u591a\u786b\u5316\u7269\u5f62\u6210\u5316\u5b66\u952e\u5408\u4ee5\u5438\u9644\u591a\u786b\u5316\u7269\u6216\u8005\u662f\u5bf9\u591a\u786b\u5316\u7269\u8d77\u50ac\u5316\u4f5c\u7528\u52a0\u5feb\u591a\u786b\u5316\u7269\u8f6c\u6362\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u8fc7\u7a0b\uff0c\u8fd9\u5927\u5927\u964d\u4f4e\u4e86\u591a\u786b\u5316\u7269\u5728\u7535\u89e3\u6db2\u7684\u6eb6\u89e3\u6027\u3002\u7136\u800c\uff0c\u5b83\u4eec\u4e2d\u7684\u5927\u591a\u6570\u5177\u6709\u786b\u8d1f\u8f7d\u91cf\u4f4e\u7684\u4e25\u91cd\u7f3a\u70b9\u3002\u56e0\u6b64\uff0c\u5fc5\u987b\u91c7\u7528\u65b0\u7684\u7b56\u7565\u6765\u63a2\u7d22\u8f7b\u8d28\u9ad8\u6548\u6750\u6599\uff0c\u63d0\u9ad8Li-S\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u80fd\u91cf\u5bc6\u5ea6\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821Arumugam Manthiram\u6559\u6388<\/b><\/strong>\u56e2\u961f<\/b><\/strong>\u901a\u8fc7\u50ac\u5316\u8f85\u52a9\u5de5\u827a\u5728\u78b3\u7eb3\u7c73\u7ea4\u7ef4\u4e0a\u539f\u4f4d\u751f\u957f\u78b3\u5316\u787c\u7eb3\u7c73\u7ebf\u4f5c\u4e3a\u9502\u786b\u7535\u6c60\u7684\u6b63\u6781\u57fa\u5e95\u3002\u901a\u8fc7\u5b9e\u9a8c\u6570\u636e\u548c\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u8868\u660e\uff0cB4<\/sub>C\u7eb3\u7c73\u7ebf\u5bf9\u591a\u786b\u5316\u7269\u6709\u7740\u5f88\u5f3a\u7684\u5438\u9644\u4f5c\u7528\u3002\u540c\u65f6\uff0cB4<\/sub>C\u7684\u50ac\u5316\u4f5c\u7528\u4e5f\u52a0\u901f\u4e86\u591a\u786b\u5316\u7269\u8f6c\u5316\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u8fc7\u7a0b\uff0c\u6709\u52a9\u4e8e\u63d0\u9ad8\u500d\u7387\u6027\u80fd\u3002\u7ed3\u679c\uff0c\u4f7f\u7528B4C@CNF\u4f5c\u4e3a\u786b\u7684\u6b63\u6781\u57fa\u5e95\u7684\u7535\u6c60\u5177\u6709\u663e\u8457\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\uff08500\u6b21\u5faa\u73af\u540e\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a80%\uff09\u4ee5\u53ca\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\uff08\u57284C\u4e0b\u5faa\u73af\u7a33\u5b9a\uff09\u3002\u6b64\u5916\uff0cB4<\/sub>C@ CNF\u57fa\u677f\u4f7f\u9634\u6781\u80fd\u591f\u540c\u65f6\u83b7\u5f97\u9ad8\u786b\u542b\u91cf\uff0870wt\uff05\uff09\u548c\u786b\u8d1f\u8f7d\u91cf\uff0810.3mg cm-2<\/sup>\uff09\uff0c\u9762\u79ef\u5bb9\u91cf\u4e3a9mAh cm-2<\/sup>\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cLong-Life Lithium\u2013Sulfur Batteries with a Bifunctional<\/b><\/strong>\u00a0<\/b><\/strong>Cathode Substrate Configured with Boron Carbide Nanowires<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Materials<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe\u4e00\u00a0<\/b><\/strong>B<\/b><\/strong>4<\/b><\/sub><\/strong>C@CNF<\/b><\/strong>\u7684\u5f62\u8c8c\u548c\u6210\u5206\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u901a\u8fc7\u50ac\u5316\u5242\u8f85\u52a9\u5408\u6210B4<\/sub>C@CNF\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\uff08b\uff0cc\uff09\u5408\u6210\u540e\u7684B4<\/sub>C@CNF\u7684SEM\u56fe\u50cf<\/p>\n

\uff08d\uff0cf\uff09\u76f8\u5e94\u7684EDX\u5143\u7d20\u6620\u5c04\u56fe\u50cf<\/p>\n

\uff08g\uff09CNF\u548cB4<\/sub>C@CNF\u7684XRD\u56fe\u8c31<\/p>\n

\uff08h\uff0ci\uff09\u7b49\u6e29\u5438\u9644\u66f2\u7ebf\u548c\u5b54\u5f84\u5206\u5e03\u56fe<\/p>\n

\u56fe\u4e8c\u00a0<\/b><\/strong>B<\/b><\/strong>4<\/b><\/sub><\/strong>C@CNF<\/b><\/strong>\u7684\u7ed3\u6784\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\uff08a\uff09B4<\/sub>C@CNF\u7684TEM\u56fe\u50cf<\/p>\n

\uff08b\uff09\u5bf9\u5e94\u4e8e\uff08a\uff09\u7684EDX\u5143\u7d20\u6620\u5c04\u56fe\u50cf<\/p>\n

\uff08c\uff0cd\uff09SAED\u548cHRTEM<\/p>\n

\uff08e\uff09B4<\/sub>C\u7eb3\u7c73\u7ebf\u7684\u76f8\u5e94\u6a21\u578b<\/p>\n

\u56fe\u4e09\u00a0<\/b><\/strong>B<\/b><\/strong>4<\/b><\/sub><\/strong>C@CNF<\/b><\/strong>\u7684\u591a\u786b\u5316\u7269\u5438\u9644\u6027\u80fd<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\uff08a\uff09\u591a\u786b\u5316\u7269\u5438\u9644\u6d4b\u8bd5\u7684\u6570\u7801\u7167\u7247<\/p>\n

\uff08b\uff0cc\uff09\u7ed3\u5408\u80fd\u548cc\uff09\u5173\u4e8e\u4e0d\u540cB4<\/sub>C@CNF\u9762\u7684S\u539f\u5b50\u7684Bader\u7535\u8377<\/p>\n

\uff08c\uff0cd\uff09\u5f53Li2<\/sub>S4<\/sub>\u5438\u9644\u5728B4<\/sub>C\u7684\u4e0d\u540c\u6676\u9762\u65f6\uff0c\u5176\u7ed3\u6784\u548c\u7535\u5b50\u7535\u8377\u8f6c\u79fb<\/p>\n

\u56fe\u56db \u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\uff08a\uff0ce\uff09\u7ebd\u6263\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1aCV\u66f2\u7ebf\uff1b\u500d\u7387\u6027\u80fd\uff1b\u80fd\u91cf\u6548\u7387\uff1b\u957f\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u5728\u9ad8\u786b\u8d1f\u8f7d\u91cf\u4e0b\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n

\uff08f\uff0ch\uff09\u8f6f\u5305\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1af\uff09EIS\u56fe\uff1bg\uff09\u6bcf\u4e2a\u9634\u6781\u786b\u8d28\u91cf\u4e3a40mg\u7684\u5faa\u73af\u6027\u80fd\uff0c\u548ch\uff09\u6bcf\u4e2a\u9634\u6781\u786b\u8d28\u91cf\u4e3a200mg\u7684B4<\/sub>C @ CNF\u7684\u653e\u7535\u5bb9\u91cf<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u603b\u4e4b\uff0c\u672c\u6587\u901a\u8fc7\u53ef\u62d3\u5c55\u7684\u5236\u9020\u5de5\u827a\u5c55\u793a\u4e86\u4e00\u79cd\u72ec\u7279\u7684\u72ec\u7acb\u5f0fB4C @ CNF\u6b63\u6781\u57fa\u5e95\u3002\u53cc\u529f\u80fdB4<\/sub>C\u7eb3\u7c73\u7ebf\u4e3a\u591a\u786b\u5316\u7269\u63d0\u4f9b\u6709\u6548\u7684\u50ac\u5316\u4f4d\u70b9\uff0c\u4e0d\u4ec5\u589e\u5f3a\u4e86\u591a\u786b\u5316\u7269\u5438\u9644\u80fd\u529b\uff0c\u800c\u4e14\u52a0\u901f\u4e86\u5728\u5faa\u73af\u671f\u95f4\u591a\u786b\u5316\u7269\u8f6c\u5316\u7684\u6c27\u5316\u8fd8\u539f\u52a8\u529b\u5b66\u8fc7\u7a0b\u3002\u56e0\u6b64\uff0c\u7528B4<\/sub>C @ CNF\u6b63\u6781\u57fa\u5e95\u5236\u9020\u7684\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u5f97\u5230\u663e\u7740\u6539\u5584\u3002\u6b64\u5916\uff0c\u53d7\u76ca\u4e8eB4<\/sub>C @ CNF\u7ed3\u6784\u7684\u4f18\u8d8a\u6027\uff0c\u5728\u7ebd\u6263\u7535\u6c60\u4e2d\u6210\u529f\u5730\u5b9e\u73b0\u4e86\u9ad8\u786b\u542b\u91cf\u548c\u9ad8\u786b\u8d1f\u8f7d\u91cf\u3002\u6b64\u5916\uff0c\u7528B4<\/sub>C @ CNF\u57fa\u677f\u5236\u9020\u7684Li-S\u8f6f\u5305\u7535\u6c60\u5177\u6709200mg\u7684\u9ad8\u786b\u8d1f\u8f7d\u91cf\uff0c\u5e76\u572850\u6b21\u5faa\u73af\u540e\u63d0\u4f9b125mAh\u7684\u9ad8\u653e\u7535\u5bb9\u91cf\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u5177\u6709\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7684\u5b9e\u7528Li-S\u7535\u6c60\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u65b0\u7684\u89c6\u89d2\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>\u201c<\/b><\/strong>Long-Life Lithium\u2013Sulfur Batteries with a Bifunctional<\/b><\/u><\/strong>\u00a0<\/b><\/u><\/strong>Cathode Substrate Configured with Boron Carbide Nanowires<\/b><\/u><\/strong><\/a>\u201d(<\/b><\/strong>Adv.Mater<\/b><\/strong>.<\/b><\/strong>\u00a0<\/b><\/strong>DOI: 10.1002\/adma.201804149)<\/b><\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu \u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u9502-\u786b(Li-S)\u7535\u6c60\u5177\u6709\u6781\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf(1675 mAhg-1)\uff0c\u4e14\u786b\u65e0\u6bd2\uff0c\u4ef7\u683c\u4f4e\u5ec9\uff0c\u88ab\u5e7f\u6cdb\u5730\u8ba4\u4e3a\u662f\u672a\u6765\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u5e94\u7528\u53d1\u5c55\u7684\u65b9\u5411\u3002\u7136\u800c\uff0c\u9502\u786b\u7535…<\/p>\n","protected":false},"author":7084,"featured_media":151118,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[751],"class_list":["post-151116","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-ls"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/151116"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7084"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=151116"}],"version-history":[{"count":15,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/151116\/revisions"}],"predecessor-version":[{"id":151458,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/151116\/revisions\/151458"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/151118"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=151116"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=151116"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=151116"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}