{"id":150665,"date":"2018-08-16T06:30:38","date_gmt":"2018-08-15T22:30:38","guid":{"rendered":"\/\/m.iemloyee.com\/?p=150665"},"modified":"2018-08-14T12:42:11","modified_gmt":"2018-08-14T04:42:11","slug":"%e4%b8%8a%e6%b5%b7%e4%ba%a4%e5%a4%a7%e9%82%ac%e5%89%91%e6%b3%a2%e6%9c%b1%e8%99%b9adv-mater-mos2-fe5ni4s8%e5%bc%82%e8%b4%a8%e8%80%a6%e5%90%88%e7%95%8c%e9%9d%a2%e7%9a%84%e6%9e%84%e7%ad%91","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=150665","title":{"rendered":"\u4e0a\u6d77\u4ea4\u5927\u90ac\u5251\u6ce2&\u6731\u8679Adv. Mater. : MoS2\/Fe5Ni4S8\u5f02\u8d28\u8026\u5408\u754c\u9762\u7684\u6784\u7b51\u53ca\u5176\u9ad8\u6548\u7535\u50ac\u5316\u5206\u89e3\u6c34"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7535\u5316\u5b66\u6790\u6c22\u53cd\u5e94(HER)\u548c\u4ea7\u6c27\u53cd\u5e94(OER)\u662f\u5206\u89e3\u6c34\u7684\u4e24\u4e2a\u5173\u952e\u8fc7\u7a0b\u3002\u5bf9\u4e8e\u6790\u6c22\u53cd\u5e94\u6765\u8bf4\uff0c\u4e8c\u786b\u5316\u94bc(MoS2<\/sub>)\u662f\u5176\u4e2d\u4e00\u79cd\u975e\u5e38\u6709\u524d\u666f\u7684\u6750\u6599\uff0c\u8fd9\u4e00\u70b9\u5df2\u7ecf\u901a\u8fc7\u5b9e\u9a8c\u7ed3\u679c\u548c\u7406\u8bba\u8ba1\u7b97\u5f97\u5230\u8bc1\u660e\u30022D\u6750\u6599\u5177\u6709\u5de8\u5927\u7684\u4f18\u52bf\uff0c\u5305\u62ec\u9ad8\u6bd4\u8868\u9762\u79ef\u548c\u7279\u6b8a\u7684\u9762\u5185\u7535\u5b50\u8f6c\u79fb\u6a21\u5f0f\u3002\u7279\u522b\u5730\uff0c2D MoS2<\/sub> NSs\u8fb9\u7f18\u5904\u7684\u786b\u539f\u5b50\u7684\u6c22\u5438\u9644\u80fd\u91cf\u63a5\u8fd1\u96f6\uff0c\u8868\u660e\u5176\u6f5c\u5728\u6d3b\u6027\u5e94\u4e0ePt\u76f8\u5f53\u3002\u540c\u65f6\uff0c\u5bf9\u4e8e\u4ea7\u6c27\u53cd\u5e94\uff0c\u6839\u636e\u6700\u8fd1\u7684\u7814\u7a76\uff0c\u94c1\/\u954d\u57fa\u5316\u5408\u7269\u8868\u73b0\u51fa\u4f18\u5f02\u7684OER\u6027\u80fd\u3002\u94c1\u954d\u5408\u91d1(FeNi)\u6ce1\u6cab\u5177\u6709\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\uff0c\u5927\u7684\u6bd4\u8868\u9762\u79ef\u548c\u9ad8\u5bfc\u7535\u6027\uff0c\u662f\u9ad8\u6548\u50ac\u5316OER\u7684\u5907\u9009\u6750\u6599\u3002\u4e3a\u4e86\u4fc3\u8fdb\u4e24\u79cd\u5206\u89e3\u6c34\u53cd\u5e94\uff0c\u6700\u8fd1\u7684\u7814\u7a76\u96c6\u4e2d\u5728\u5404\u79cd\u65b9\u6cd5\u4e0a\uff0c\u5305\u62ec\u6574\u5408\u9ad8\u6548HER\u6750\u6599\u548c\u9ad8\u6548OER\u6750\u6599\u7684\u4f18\u52bf\u3001\u589e\u52a0\u5bfc\u7535\u6027\u3001\u63d0\u9ad8\u8868\u9762\u79ef\u7b49\u3002\u56e0\u6b64\uff0c\u5efa\u7acb\u5177\u6709\u9ad8\u6548HER\/OER\u50ac\u5316\u5242\u8026\u5408\u754c\u9762\u7684\u65b0\u9896\u5f02\u8d28\u7ed3\u6784\u6709\u671b\u8fdb\u4e00\u6b65\u4fc3\u8fdb\u5206\u89e3\u6c34\u53cd\u5e94\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u90ac\u5251\u6ce2\u7814\u7a76\u5458\u3001\u6731\u8679\u7814\u7a76\u5458(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u5236\u5907FeNi\u886c\u5e95\u4e0a\u5782\u76f4\u751f\u957fMoS2<\/sub> NS\u7684\u540c\u65f6\u83b7\u5f97\u4e86\u5728MoS2<\/sub>\u754c\u9762\u5904\u539f\u4f4d\u751f\u957fFe5<\/sub>Ni4<\/sub>S8<\/sub>(FNS)\uff0c\u5e76\u5728Adv. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cCoupling Interface Constructions of MoS2<\/sub>\/Fe5<\/sub>Ni4<\/sub>S8<\/sub> Heterostructures for Efficient Electrochemical Water Splitting<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u5bf9\u4e8e\u6790\u6c22\u53cd\u5e94\uff0c\u6240\u5f97\u7684MoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u4ec5\u9700120mV\u7684\u8fc7\u7535\u4f4d\u5373\u53ef\u8fbe\u523010mA\u00b7cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\uff1b\u540c\u65f6\u5bf9\u4e8e\u4ea7\u6c27\u53cd\u5e94\uff0c\u4ec5\u9700204mV\u7684\u6781\u4f4e\u8fc7\u7535\u4f4d\u5373\u53ef\u83b7\u5f97\u76f8\u540c\u7684\u7535\u6d41\u5bc6\u5ea6\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8fdb\u4e00\u6b65\u63ed\u793a\u4e86MoS2<\/sub>\u548cFNS\u4e4b\u95f4\u6784\u5efa\u7684\u8026\u5408\u754c\u9762\u4fc3\u8fdb\u4e86H\u539f\u5b50\u548cOH\u57fa\u56e2\u7684\u5438\u9644\uff0c\u4ece\u800c\u63d0\u9ad8\u4e86HER\u548cOER\u7684\u6027\u80fd\u3002\u4e0a\u8ff0\u4f18\u8d8a\u7684\u6027\u80fd\u4ece\u4fa7\u9762\u5370\u8bc1\u4e86\u72ec\u7279\u7684\u7ed3\u6784\u662f\u8bbe\u8ba1\u5148\u8fdb\u7535\u50ac\u5316\u5242\u7684\u5173\u952e\u56e0\u7d20\u4e4b\u4e00\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 MoS2<\/sub>\/FNS\/FeNi\u6750\u6599\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u5782\u76f4\u751f\u957fMoS2<\/sub>\/FNS \u5f02\u8d28\u7ed3\u6784\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

c) MoS2<\/sub>\/FNS \u5f02\u8d28\u7ed3\u6784\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

d) MoS2<\/sub>\/FNS\u754c\u9762\u7684HAADF-STEM\u56fe\u50cf\uff0c\u5185\u63d2\u4e3aFNS\u7684\u539f\u5b50\u7ed3\u6784\uff0c\u5176\u4e2d\u9ec4\u8272\u7403\u4ee3\u8868\u786b\u539f\u5b50\uff0c\u7d2b\u8272\u7403\u4ee3\u8868\u94c1\/\u954d\u539f\u5b50\uff1b<\/p>\n

e-i) MoS2<\/sub>\/FNS\u754c\u9762\u7684\u5143\u7d20\u5206\u5e03\u56fe\u50cf\uff0c\u767d\u8272\u865a\u7ebf\u4e3aMoS2<\/sub>\u548cFNS\u4e4b\u95f4\u7684\u754c\u9762\u3002<\/p>\n

\u56fe2 MoS2<\/sub>\/FNS\/FeNi\u6750\u6599\u7684\u8868\u9762\u5143\u7d20\u4ef7\u6001<\/strong><\/p>\n

\"\"<\/p>\n

a) MoS2<\/sub>\/FNS\/FeNi\u6750\u6599\u7684Mo 3d XPS\u5149\u8c31\uff1b<\/p>\n

b) MoS2<\/sub>\/FNS\/FeNi\u6750\u6599\u7684S 2p XPS\u5149\u8c31\uff1b<\/p>\n

c) MoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u7684Fe 2p XPS\u5149\u8c31\uff1b<\/p>\n

d) MoS2<\/sub>\/FNS\/FeNi\u7b94\u7684Fe 2p XPS\u5149\u8c31\u3002<\/p>\n

\u56fe3 MoS2<\/sub>\/FNS\/FeNi\u7cfb\u5217\u6750\u6599\u7684\u7535\u50ac\u5316HER\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) 1 M KOH\u4e2d\uff0cMoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u3001FNS\/FeNi\u6ce1\u6cab\u3001 FeNi\u6ce1\u6cab\u548cMoS2<\/sub>\/FTO\u7684\u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

b) 10 mA\u00b7cm-2<\/sup>\u65f6\uff0cMoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u548c\u5176\u4ed6\u50ac\u5316\u5242HER\u8fc7\u7535\u52bf\u7684\u6bd4\u8f83\uff1b<\/p>\n

c) \u76f8\u5e94\u7684HER Tafel\u659c\u7387\uff1b<\/p>\n

d) -122 mV\u65f6MoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u548c-281 mV\u65f6MoS2<\/sub>\/FNS\/FeNi\u7b94\u7684\u8ba1\u65f6\u66f2\u7ebf\u3002<\/p>\n

\u56fe4 MoS2<\/sub>\/FNS\/FeNi\u7cfb\u5217\u6750\u6599\u7684\u7535\u50ac\u5316OER\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) 1 M KOH\u4e2d\uff0cMoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u3001FNS\/FeNi\u6ce1\u6cab\u3001 FeNi\u6ce1\u6cab\u548cMoS2<\/sub>\/FTO\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

b) 10 mA\u00b7cm-2<\/sup>\u65f6\uff0cMoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u548c\u5176\u4ed6\u50ac\u5316\u5242OER\u8fc7\u7535\u52bf\u7684\u6bd4\u8f83\uff1b<\/p>\n

c) \u76f8\u5e94\u7684OER Tafel\u659c\u7387\uff1b<\/p>\n

d) 204 mV\u65f6MoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u548c251 mV\u65f6MoS2<\/sub>\/FNS\/FeNi\u7b94\u7684\u8ba1\u65f6\u66f2\u7ebf\u3002<\/p>\n

\u56fe5 \u7406\u8bba\u8ba1\u7b97\u4e0e\u673a\u7406\u89e3\u91ca<\/strong><\/p>\n

\"\"<\/p>\n

a) MoS2<\/sub>\u3001Fe9<\/sub>S8<\/sub>\u3001Ni9<\/sub>S8<\/sub>\u3001MoS2<\/sub>\/FNS(Fe, Ni-MoS2<\/sub>\u6a21\u578b)\u3001 MoS2<\/sub>\/Fe9<\/sub>S8<\/sub>(Mo-Fe9<\/sub>S8<\/sub>\u6a21\u578b)\u548cMoS2<\/sub>\/Ni9<\/sub>S8<\/sub>(Mo-Ni9<\/sub>S8<\/sub>\u6a21\u578b)\u5f02\u8d28\u7ed3\u7684\u5316\u5b66\u5438\u9644\u6a21\u578b\u4ee5\u53ca\u76f8\u5e94\u7684\u8868\u9762H\u548cOH\u5438\u9644\u80fd\uff1b<\/p>\n

b) MoS2<\/sub>\/FNS\u8026\u5408\u754c\u9762\u50ac\u5316HER\u548cOER\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u901a\u8fc7\u6539\u53d8CVD\u7684\u53cd\u5e94\u6761\u4ef6\u6210\u529f\u5408\u6210\u4e86\u5728FNS\/FeNi\u6ce1\u6cab\u548c\u5176\u4ed6\u57fa\u5e95\u4e0a\u751f\u957f\u7684\u4e14\u5177\u6709\u53ef\u63a7\u6392\u5217\u7684\u5782\u76f4MoS2<\/sub>\u9635\u5217\u3002\u8fdb\u4e00\u6b65\u7684\u7814\u7a76\u8868\u660e\uff0c\u5bcc\u542b\u8fb9\u7f18\u7684MoS2<\/sub>\u7eb3\u7c73\u7247\u5728\u4e0d\u540c\u7684\u57fa\u5e95\u7684\u5206\u89e3\u6c34\u6548\u7387\u5747\u5f97\u5230\u6539\u5584\u3002\u5176\u4e2d\uff0cMoS2<\/sub>\/FNS\/FeNi\u6ce1\u6cab\u663e\u793a\u51fa\u6700\u4f73\u6027\u80fd\uff0c\u8fbe\u523010 mA\u00b7cm-2<\/sup>\u65f6\u7684HER\u7535\u4f4d\u4e3a120 mV\uff0c OER\u7535\u4f4d\u4e3a204 mV\u3002\u9ad8\u6bd4\u8868\u9762\u79ef\u3001FeNi\u6ce1\u6cab\u7684\u7406\u60f3\u5bfc\u7535\u6027\u3001MoS2<\/sub>\u548cFNS\u4e4b\u95f4\u7684\u8026\u5408\u754c\u9762\u4ee5\u53caMoS2<\/sub>\u7684\u66b4\u9732\u8fb9\u7f18\u5bf9\u4e8e\u7535\u5316\u5b66\u5206\u89e3\u6c34\u5177\u6709\u6709\u5229\u7684\u534f\u540c\u6548\u5e94\u3002\u56e0\u6b64\uff0c\u4e0a\u8ff0\u4f18\u52bf\u4f7f\u5f97MoS2<\/sub>\/FNS\/ FeNi\u6ce1\u6cab\u4f5c\u4e3a\u4e00\u79cd\u524d\u666f\u826f\u597d\u7684\u5206\u89e3\u6c34\u6750\u6599\uff0c\u5176\u5177\u6709\u5408\u6210\u65b9\u6cd5\u7b80\u5355\u3001\u8d44\u6e90\u5ec9\u4ef7\u548c\u6027\u80fd\u4f18\u8d8a\u7b49\u7279\u70b9\uff0c\u4e3a\u5bfb\u627e\u4fbf\u5b9c\u3001\u9ad8\u6548\u3001\u6e05\u6d01\u7684\u5206\u89e3\u6c34\u7535\u6781\u63d0\u4f9b\u4e86\u6709\u76ca\u7684\u53c2\u8003\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aCoupling Interface Constructions of MoS2<\/sub>\/Fe5<\/sub>Ni4<\/sub>S8<\/sub> Heterostructures for Efficient Electrochemical Water Splitting<\/a><\/strong>\u00a0(Adv. Mater.<\/strong>, 2018, DOI: 10.1002\/adma.201803151)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u5316\u5b66\u6790\u6c22\u53cd\u5e94(HER)\u548c\u4ea7\u6c27\u53cd\u5e94(OER)\u662f\u5206\u89e3\u6c34\u7684\u4e24\u4e2a\u5173\u952e\u8fc7\u7a0b\u3002\u5bf9\u4e8e\u6790\u6c22\u53cd\u5e94\u6765\u8bf4\uff0c\u4e8c\u786b\u5316\u94bc(MoS2)\u662f\u5176\u4e2d\u4e00\u79cd\u975e\u5e38\u6709\u524d\u666f\u7684\u6750\u6599\uff0c\u8fd9\u4e00\u70b9\u5df2\u7ecf\u901a\u8fc7\u5b9e…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[1906,2655,2843],"class_list":["post-150665","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-her","tag-oer","tag-2843"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/150665"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=150665"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/150665\/revisions"}],"predecessor-version":[{"id":150708,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/150665\/revisions\/150708"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=150665"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=150665"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=150665"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}