{"id":15051,"date":"2016-05-23T17:00:47","date_gmt":"2016-05-23T09:00:47","guid":{"rendered":"\/\/m.iemloyee.com\/?p=15051"},"modified":"2016-05-24T18:49:33","modified_gmt":"2016-05-24T10:49:33","slug":"nature%ef%bc%9a%e5%9f%83%e9%bb%98%e9%87%8c%e5%a4%a7%e5%ad%a6%e9%87%87%e7%94%a8%e6%96%b0%e5%9e%8b%e5%8f%8c%e9%93%91%e5%82%ac%e5%8c%96%e5%89%82%e5%ae%9e%e7%8e%b0%e7%a2%b3%e6%b0%a2%e9%94%ae%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=15051","title":{"rendered":"Nature\uff1a\u57c3\u9ed8\u91cc\u5927\u5b66\u91c7\u7528\u65b0\u578b\u53cc\u94d1\u50ac\u5316\u5242\u5b9e\u73b0\u78b3\u6c22\u952e\u7684\u5b98\u80fd\u5316"},"content":{"rendered":"

\"\"<\/p>\n

 <\/p>\n

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\u6587\u732e\u56fe\u89e3\uff1a<\/strong><\/p>\n

\u56fe1<\/strong>\u00a0 \u901a\u8fc7\u4f9b\u4f53\/\u53d7\u4f53\u78b3\u70ef(\u5361\u5bbe)\u5b98\u80fd\u5316\u7684\u5177\u6709\u4f4d\u7f6e\u9009\u62e9\u6027\u7684\u78b3\u6c22\u952e<\/strong><\/p>\n

\"nature17651-f1\"
\na, \u901a\u8fc7\u4f9b\u4f53\/\u53d7\u4f53\u78b3\u70ef\u5b9e\u73b0\u94d1\u50ac\u5316\u7684\u5b98\u80fd\u5316\u78b3\u6c22\u952e\u7684\u4f4d\u7f6e\u9009\u62e9\u6027\u8d8b\u52bf\uff0c\u53ef\u7531\u7a7a\u95f4\u4f4d\u963b\u548c\u7535\u5b50\u6548\u5e94\u4e4b\u95f4\u76f8\u4e92\u4f5c\u7528\u7684\u5e73\u8861\u6765\u63a7\u5236.
\nb, \u5148\u524d\u7684\u7814\u7a76\u8868\u660e\u6d3b\u5316\u540e\u7684\u78b3\u6c22\u952e\u4f4d\u7f6e\u9009\u62e9\u6027\u4e0e\u50ac\u5316\u5242\u7684\u6027\u8d28\u6709\u5173. Rh2(S-DOSP)2\u5bb9\u6613\u4f7f\u4e8c\u7ea7\u3001\u4e09\u7ea7\u78b3\u6c22\u952e\u5b98\u80fd\u5316\uff0c\u800cRh2(R-p-PhTPCP)4\u5219\u6613\u4f7f\u521d\u7ea7\u78b3\u6c22\u952e\u5b98\u80fd\u5316.
\nC, \u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u65b0\u7684\u50ac\u5316\u5242Rh2[R-3,5-di(p-tBuC6H4)TPCP]4\u80fd\u591f\u4f7f\u672a\u6fc0\u6d3b\u7684\u78b3\u6c22\u952e\u5b98\u80fd\u5316\uff0c\u4f7f\u5176\u5177\u6709\u4f4d\u7f6e\u9009\u62e9\u6027\u548c\u7acb\u4f53\u9009\u62e9\u6027.
\n[\u5c0f\u7f16\u6ce8\uff1a\u6587\u4e2d\u672a\u660e\u786e\u7ed9\u51faTPCP\u5177\u4f53\u542b\u4e49\uff0c\u6839\u636e\u6587\u7ae0\u5185\u5bb9\u672c\u6587\u4e2d\u7684TPCP\u4ee3\u8868\u7684\u662f\uff1a\u4e09\u82b3\u57fa\u73af\u4e19\u70f7\u7fa7\u9178(\u6216\u7fa7\u9178\u76d0)]<\/p>\n

\u56fe2 \u00a0TPCP\u7fa7\u9178\u76d0\u53cc\u94d1\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5408\u6210<\/strong><\/p>\n

\"nature17651-f2\"
\na, TPCP\u7fa7\u9178\u76d0\u53cc\u94d1\u91d1\u5c5e\u50ac\u5316\u5242\u539f\u59cb\u7684\u5408\u6210\u65b9\u6cd5.
\nb, TPCP\u7fa7\u9178\u76d0\u53cc\u94d1\u91d1\u5c5e\u50ac\u5316\u5242\u5408\u6210\u7684\u65b0\u9014\u5f84\uff1a\u4f7f\u9884\u5148\u51c6\u5907\u7684\u53cc\u94d1\u7edc\u5408\u7269\u53d1\u751f\u94af\u50ac\u5316\u5076\u8054\u53cd\u5e94. \u8be6\u7ec6\u7684\u5408\u6210\u7ec6\u8282\u89c1\u8865\u5145\u6750\u6599(Supplementary Information<\/a>).<\/p>\n

\u56fe3 \u00a0 \u50ac\u5316\u5242\u7684\u4f18\u5316\u7814\u7a76<\/strong><\/p>\n

\"nature17651-f3\"
\n\u620a\u70f7\u78b3\u6c22\u952e\u5b98\u80fd\u5316\u6240\u7528\u7684TPCP\u53cc\u94d1\u50ac\u5316\u5242\u7684\u6027\u80fd\u6d4b\u5b9a\u548c\u8bc4\u4f30. \u5728C2\u4f4d\u7684\u4f4d\u7f6e\u9009\u62e9\u6027\u3001\u4e0d\u5bf9\u6620\u7acb\u4f53\u9009\u62e9\u6027\u3001\u5bf9\u6620\u9009\u62e9\u6027\u548c\u4ea7\u51fa\u91cf\u7684\u7efc\u5408\u6027\u80fd\u4e2d\u6700\u4f18\u50ac\u5316\u5242\u4e3a\u50ac\u5316\u524215\uff0c\u5373Rh2[R-3,5-di(p-tBuC6H4)TPCP]4. \u4ee5\u51b7\u5374\u56de\u6d41\u7eaf\u5316\u7684\u620a\u70f7\u4e2d\u6dfb\u52a01mol%\u7684\u50ac\u5316\u5242\u4e3a\u6807\u51c6\u53cd\u5e94.
\n\u8be6\u7ec6\u5b9e\u9a8c\u7ec6\u8282\u89c1\u8865\u5145\u6750\u6599. \u5176\u4e2dn.d.\u8868\u793a\u672a\u6d4b\u5b9a\u542b\u91cf\u3002<\/p>\n

\u56fe4 \u00a0 \u70f7\u70c3\u548c\u53d6\u4ee3\u6b63\u6784\u70f7\u70c3\u78b3\u6c22\u952e\u7684\u5b98\u80fd\u5316<\/strong><\/p>\n

\"nature17651-f4\"
\na-c, \u620a\u70f7\u548c\u53d6\u4ee3\u6b63\u6784\u70f7\u70c3\u4f7f\u7528Rh2[R-3,5-di(p-tBuC6H4)TPCP]4\u50ac\u5316\u6240\u5f97\u5b98\u80fd\u5316\u7684\u78b3\u6c22\u952e\u7684\u8303\u56f4\u7684\u6d4b\u5b9a\u548c\u8bc4\u4f30.
\na, \u5316\u5408\u726920-22\u4e3a\u916f\u57fa\u7684\u5f71\u54cd
\nb, \u5316\u5408\u726923-25\u4e3a\u4fee\u9970\u4e86\u7684\u4f9b\u4f53\u57fa\u56e2\u7684\u5f71\u54cd
\nc, \u5316\u5408\u726926-34\u4e3a\u70f7\u57fa\u53d6\u4ee3\u57fa\u7684\u5f71\u54cd
\n\u4e0e\u620a\u70f7\u7684\u53cd\u5e94\u4ee5\u620a\u70f7\u4e3a\u6eb6\u5242\uff0c\u4e0e\u53d6\u4ee3\u7684\u70f7\u70c3\u53cd\u5e94\u662f\u4ee5\u53d6\u4ee3\u70f7\u70c33\u5f53\u91cf\u7684\u4e8c\u6c2f\u7532\u70f7\u4e3a\u6eb6\u5242.
\n\u5b8c\u6574\u7684\u5b9e\u9a8c\u7ec6\u8282\u89c1\u8865\u5145\u4fe1\u606f\u3002<\/p>\n

\u56fe5 \u00a0 \u4e8c\u94d1\u50ac\u5316\u5242\u7684\u7ed3\u6784\u4fe1\u606f<\/strong><\/p>\n

\"nature17651-f5\"
\na, \u03b1,\u03b2, \u03b1,\u03b2\u578bRh2(S-3,5-diPhTPCP)4\u50ac\u5316\u5242\u7684\u7684\u8ba1\u7b97\u7ed3\u6784
\nb, \u03b1,\u03b1,\u03b1,\u03b1\u578bRh2(S-3,5-diPhTPCP)4\u50ac\u5316\u5242\u7684\u7684\u8ba1\u7b97\u7ed3\u6784\uff08\u7a33\u5b9a\u6027\u6bd4\u03b1,\u03b2, \u03b1,\u03b2\u578b\u5c115.0kcal\/mol\uff09
\nc, \u00a0Rh2[S-3,5-di(p-tBuC6H4)TPCP]4\u50ac\u5316\u5242\u7684X\u5c04\u7ebf\u6676\u4f53\u7ed3\u6784,\u5176\u4e2d\u4f4d\u4e0a\u9876\u9762\u7684\u4e24\u4e2a3,5-di(p-tBuC6H4)C6H3-\u57fa\u56e2\u7528\u9ec4\u8272\u6807\u51fa\u3002<\/p>\n

\u6587\u732e\u5c0f\u7ed3<\/strong><\/p>\n

\u4f5c\u8005\u5229\u7528\u65b0\u578b\u7684\u53cc\u94d1\u50ac\u5316\u5242\u5b9e\u73b0\u4e86\u5bf9\u672a\u6d3b\u5316\u78b3\u6c22\u952e\u7684\u5b98\u80fd\u5316\uff0c\u4e0d\u4ec5\u4f7f\u78b3\u6c22\u952e\u5177\u6709\u5f3a\u4f4d\u7f6e\u9009\u62e9\u6027\uff0c\u800c\u4e14\u5177\u6709\u5bf9\u6620\u9009\u62e9\u6027\u548c\u4e0d\u5bf9\u6620\u9009\u62e9\u6027\uff0c\u5e76\u4e14\u4e0d\u9700\u8981\u5b9a\u5411\u57fa\u56e2\u6216\u951a\u5b9a\u57fa\u56e2\u7684\u5b58\u5728\u3002\u7814\u7a76\u8868\u660e\uff0c\u901a\u8fc7\u8bbe\u8ba1\u50ac\u5316\u5242\u80fd\u591f\u5f62\u6210\u7279\u5b9a\u7684\u6709\u624b\u6027\u53e3\u888b\u6765\u63a7\u5236\u78b3\u70ef\u8bf1\u5bfc\u7684\u5b98\u80fd\u5316\u78b3\u6c22\u952e\u7684\u4f4d\u7f6e\u9009\u62e9\u6027\u3001\u5bf9\u6620\u9009\u62e9\u6027\u548c\u4e0d\u5bf9\u6620\u9009\u62e9\u6027\uff0c\u8fd9\u5bf9\u5177\u6709\u9009\u62e9\u6027\u7684\u5b98\u80fd\u5316\u7684\u78b3\u6c22\u952e\u7684\u7814\u7a76\u6709\u7740\u6df1\u8fdc\u7684\u5f71\u54cd\uff0c\u4e3a\u78b3\u6c22\u952e\u7684\u6d3b\u5316\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u539f\u6587\u94fe\u63a5\uff1aSite-selective and stereoselective functionalization of unactivated C-H bonds<\/a><\/p>\n

\u6587\u732e\u8865\u5145\u6750\u6599\u94fe\u63a5\uff1aSupplementary Information<\/a><\/p>\n

[\u5c0f\u6807\u6ce8\uff1a\u6587\u732e\u7684\u8865\u5145\u6750\u6599\u5185\u5bb9\u5341\u5206\u8be6\u5c3d(\u5c06\u8fd1250\u9875)\uff0c\u5f3a\u70c8\u63a8\u8350\u7ed9\u5bf9\u78b3\u6c22\u952e\u5b98\u80fd\u5316\u611f\u5174\u8da3\u7684\u8bfb\u8005!]<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5c09\u8c37\u96e8\u63d0\u4f9b\u7d20\u6750\uff0c\u674e\u5353\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

  \u5b9e\u9a8c\u5ba4\u4e2d\u5bf9\u4e8e\u590d\u6742\u6709\u673a\u5206\u5b50\u7684\u5408\u6210\u4e3b\u8981\u4f9d\u8d56\u4e8e\u8bf8\u5982\u78b3\u6c27\u952e\u6216\u78b3\u5364\u952e\u7b49\u529f\u80fd\u57fa\u56e2\u7684\u5f15\u5165\u548c\u5904\u7406\u3002\u7531\u4e8e\u78b3\u6c22\u952e\u6d3b\u6027\u4f4e\uff0c\u4e0d\u5177\u6709\u4f4d\u7f6e\u9009\u62e9\u6027\u96be\u4ee5\u6d3b\u5316\u3002\u800c\u5c06\u78b3\u6c22\u952e\u5b98\u80fd\u5316\u4f7f\u5176…<\/p>\n","protected":false},"author":22,"featured_media":15053,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[293,42],"class_list":["post-15051","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji","tag-nature","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/15051"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/22"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=15051"}],"version-history":[{"count":7,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/15051\/revisions"}],"predecessor-version":[{"id":15136,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/15051\/revisions\/15136"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/15053"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=15051"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=15051"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=15051"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}