{"id":149799,"date":"2018-08-14T06:30:52","date_gmt":"2018-08-13T22:30:52","guid":{"rendered":"\/\/m.iemloyee.com\/?p=149799"},"modified":"2018-08-14T00:39:09","modified_gmt":"2018-08-13T16:39:09","slug":"acs-catal-%e7%90%86%e8%ae%ba%e8%ae%a1%e7%ae%97%e5%8a%a9%e5%8a%9b%e9%93%81ii%e5%8f%8c%e4%b9%99%e7%82%94%e5%8c%96%e7%89%a9%e9%85%8d%e5%90%88%e7%89%a9%e5%82%ac%e5%8c%96","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=149799","title":{"rendered":"ACS Catal. : \u7406\u8bba\u8ba1\u7b97\u52a9\u529b\u94c1(II)\u53cc(\u4e59\u7094\u5316\u7269)\u914d\u5408\u7269\u50ac\u5316\u672b\u7aef\u7094\u70c3\u6c22\u5b98\u80fd\u5316\u53cd\u5e94"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u94c1\u50ac\u5316\u672b\u7aef\u7094\u70c3Z\u9009\u62e9\u6c22\u7094\u57fa\u5316\u548c\u787c\u6c22\u5316\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe2 \u94c1(II)\u53cc(\u4e59\u7094\u5316\u7269)\u7edc\u5408\u7269\u7684\u5f62\u6210<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe3 \u6d3b\u6027\u7269\u79cd\u6355\u83b7\u5b9e\u9a8c<\/strong><\/p>\n

\"\"<\/p>\n

\u6297\u78c1\u6027\u53cc(\u4e59\u7094\u5316\u7269)\u914d\u5408\u7269\u7684\u6355\u83b7\u5b9e\u9a8c\u4ee5\u53ca\u5316\u5408\u72693a,b\u7684\u7ed3\u6784\u89c6\u56fe\u3002<\/p>\n

\u56fe4 \u4ea4\u53c9\u4e8c\u805a\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

\u5316\u5408\u72691b\u50ac\u5316\u7684\u4ea4\u53c9\u4e8c\u805a\u53cd\u5e94\u3002<\/p>\n

\u56fe5 \u672b\u7aef\u7094\u70c3Z-\u9009\u62e9\u6027\u6c22\u7094\u57fa\u5316\u53ef\u80fd\u7684\u50ac\u5316\u5faa\u73af<\/strong><\/p>\n

\"\"<\/p>\n

\u672b\u7aef\u7094\u70c3Z-\u9009\u62e9\u6027\u6c22\u7094\u57fa\u5316\u53ef\u80fd\u7684\u50ac\u5316\u5faa\u73af\u3002<\/p>\n

\u56fe6 \u672b\u7aef\u7094\u70c3\u6c22\u7094\u57fa\u5316\u7684\u81ea\u7531\u80fd\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(Z)-1,3-\u70ef\u7094(\u84dd\u8272)\u548c(E)-1,3-\u70ef\u7094(\u7ea2\u8272)\u7684\u672b\u7aef\u7094\u70c3\u6c22\u7094\u57fa\u5316\u53cd\u5e94\u81ea\u7531\u80fd\u66f2\u7ebf\u3002<\/p>\n

\u56fe7 \u6784\u8c61\u8f6c\u5316\u7684\u81ea\u7531\u80fd\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe8 \u8fc7\u6e21\u6001TS-EFZ<\/sub>\u548cTS-EFE<\/sub>\u7684\u7ed3\u6784\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

\u8fc7\u6e21\u6001TS-EFZ\u548cTS-EFE\u7684\u7ed3\u6784\u6bd4\u8f83(\u4fa7\u89c6\u56fe)\u3002<\/p>\n

\u56fe9 \u5316\u5408\u72691b\u4e0e2-\u4e59\u7094\u57fa\u5421\u5576\u7684\u53cd\u5e94(1)<\/strong><\/p>\n

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\u56fe10 \u5316\u5408\u72691b\u4e0e2-\u4e59\u7094\u57fa\u5421\u5576\u7684\u53cd\u5e94(2)<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe11 \u672b\u7aef\u7094\u70c3\u787c\u6c22\u5316\u53ef\u80fd\u7684\u50ac\u5316\u5faa\u73af<\/strong><\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

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\"\"<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\n \u7efc\u4e0a\u6240\u8ff0\uff0c\u7814\u7a76\u4eba\u5458\u5bf9\u975e\u7ecf\u5178PNP\u94c1(II)\u591a\u6c22\u5316\u7269\u7edc\u5408\u7269\u50ac\u5316\u7684\u672b\u7aef\u7094\u70c3\u7684Z-\u9009\u62e9\u6027\u6c22\u7094\u57fa\u5316\u548c\u787c\u6c22\u5316\u7684\u8be6\u7ec6\u673a\u7406\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u5728\u5b9e\u9a8c\u7ed3\u679c\u548cDFT\u8ba1\u7b97\u7684\u57fa\u7840\u4e0a\uff0c\u76f8\u5e94\u7684\u94c1(II)\u53cc(\u4e59\u7094\u5316\u7269)\u914d\u5408\u7269\u5728\u4e24\u4e2a\u53cd\u5e94\u4e2d\u5747\u4f5c\u4e3a\u50ac\u5316\u6d3b\u6027\u7269\u8d28\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8bc1\u660e\u4e0a\u8ff0\u6c22\u5b98\u80fd\u5316\u53cd\u5e94\u751a\u81f3\u53ef\u4ee5\u5728\u7b80\u5355\u6613\u5f97\u7684\u94c1(II)\u4e8c\u6eb4\u5316\u7269\u914d\u5408\u7269[Fe(PNP)Br2<\/sub>]\u50ac\u5316\u4e0b\u8fdb\u884c\uff0c\u4e0a\u8ff0\u914d\u5408\u7269[Fe(PNP)Br2<\/sub>]\u5728\u8fc7\u91cf\u7094\u70c3\u5b58\u5728\u4e0b\u52a0\u5165\u5f3a\u78b1\u540e\u88ab\u6d3b\u5316\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u6709\u671b\u4e3a\u6c22\u5b98\u80fd\u5316\u53cd\u5e94\u9886\u57df\u7684\u8fdb\u4e00\u6b65\u53d1\u5c55\u548c\u9009\u62e9\u6027\u50ac\u5316\u4f53\u7cfb\u7684\u5408\u7406\u8bbe\u8ba1\u63d0\u4f9b\u66f4\u591a\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aIron(II) Bis(acetylide) Complexes as Key Intermediates in the Catalytic Hydrofunctionalization of Terminal Alkynes<\/a><\/strong>\u00a0(ACS Catal.<\/strong>, 2018, DOI: 10.1021\/acscatal.8b01942)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

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\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

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