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\u8fd1\u65e5\uff0c\u667a\u5229\u5723\u5730\u4e9a\u54e5\u5927\u5b66Rodrigo del Rio\u6559\u6388\u8054\u5408\u5df4\u897f\u5723\u5361\u6d1b\u65af\u8054\u90a6\u5927\u5b66Nerilso Bocchi\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/b><\/strong>\u8868\u660e\u5f53LiMn2O4\u7684\u7eb3\u7c73\u9897\u7c92\u4f4e\u4e8e\u67d0\u4e00\u4e34\u754c\u5c3a\u5bf8\u65f6\uff0c\u5176\u7535\u5316\u5b66\u6027\u80fd\u5c06\u4f1a\u7531\u4e8e\u5c0f\u5c3a\u5bf8\u800c\u6076\u5316\uff0c\u8fd9\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u9886\u57df\u666e\u904d\u7684\u89c2\u70b9\uff08\u8f83\u5c0f\u5c3a\u5bf8\u7684\u7535\u6781\u6750\u6599\u5bfc\u81f4\u66f4\u597d\u7684\u7535\u6c60\u6027\u80fd\uff09\u76f8\u6096\u3002\u672c\u6587\u901a\u8fc7\u5fae\u6ce2\u8f85\u52a9\u6c34\u70ed\u65b9\u6cd5\u548c\u70ed\u5904\u7406\u83b7\u5f97\u4e86\u7eb3\u7c73\u5c3a\u5bf8\u7684LiMn2O4\u9897\u7c92\uff084, 9, and 14 nm\uff09\u5e76\u5bf9\u5176\u8fdb\u884c\u4e86\u76f8\u5173\u7684\u7269\u76f8\u8868\u5f81\u548c\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81\u3002\u7ed3\u679c\u53d1\u73b0\uff0c\u968f\u7740\u7eb3\u7c73\u9897\u7c92\u7684\u5e73\u5747\u5c3a\u5bf8\u4ece14\u7eb3\u7c73\u51cf\u5c0f\u52301.3\u7eb3\u7c73\uff0c\u4e0e\u9502\u79bb\u5b50\u63d2\u5165\u8fc7\u7a0b\u76f8\u5173\u7684\u6c27\u5316\u8fd8\u539f\u7535\u538b\u53d8\u5f97\u66f4\u9ad8\uff0c\u4ece3.93\u4f0f\u53d8\u4e3a4.64\u4f0f\uff0c\u4ece\u800c\u963b\u788d\u4e86\u8be5\u8fc7\u7a0b\u3002\u8054\u5408\u4ece\u5934\u7b97DFT\u65b9\u6cd5\uff0c\u8bc1\u5b9e\u4e86\u6c27\u5316\u8fd8\u539f\u7535\u538b\u7684\u589e\u52a0\u662f\u7531\u4e8e\u8f83\u5c0f\u7684LMO\u7eb3\u7c73\u6676\u4f53\u4e2d\u9502\u79bb\u5b50\u6269\u6563\u7684\u80fd\u5792\u663e\u7740\u589e\u52a0\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u201cUnderstanding the loss of electrochemical activity of nanosized LiMn2O4 particles: a combined experimental and ab initio DFT study<\/b><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Journal of Materials Chemistry A<\/b><\/strong>\u4e0a\u3002<\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>\u201c<\/b><\/strong>Understanding the loss of electrochemical activity<\/b><\/u><\/strong>\u00a0<\/b><\/u><\/strong>of nanosized LiMn2O4 particles: a combined<\/b><\/u><\/strong>\u00a0<\/b><\/u><\/strong>experimental and ab initio DFT study<\/b><\/u><\/strong><\/a>\u201d(J. Mater. Chem. A, 2018,DOI: 10.1039\/c8ta02703j)<\/b><\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

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