{"id":149535,"date":"2018-08-07T11:31:19","date_gmt":"2018-08-07T03:31:19","guid":{"rendered":"\/\/m.iemloyee.com\/?p=149535"},"modified":"2018-08-08T11:32:24","modified_gmt":"2018-08-08T03:32:24","slug":"%e9%99%88%e6%b0%b8%e8%83%9c%e6%95%99%e6%8e%88%e8%af%be%e9%a2%98%e7%bb%84%ef%bc%9a%e5%9f%ba%e4%ba%8e%e6%b0%af%e4%bb%a3%e5%b0%8f%e5%88%86%e5%ad%90%e5%8f%97%e4%bd%93%e6%9d%90%e6%96%99%e7%9a%84%e6%9c%89","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=149535","title":{"rendered":"\u9648\u6c38\u80dc\u6559\u6388\u8bfe\u9898\u7ec4\uff1a\u57fa\u4e8e\u6c2f\u4ee3\u5c0f\u5206\u5b50\u53d7\u4f53\u6750\u6599\u7684\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u8d85\u8fc714%"},"content":{"rendered":"<p>\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5177\u6709\u8d28\u91cf\u8f7b\u3001\u6210\u672c\u4f4e\u3001\u53ef\u5927\u9762\u79ef\u5236\u5907\u548c\u53ef\u6eb6\u6db2\u5904\u7406\u7b49\u8bf8\u591a\u4f18\u70b9\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u5728\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u53d1\u5c55\u8fc7\u7a0b\u4e2d\uff0c\u6d3b\u6027\u5c42\u6750\u6599\u7684\u7814\u53d1\u5bf9\u63d0\u9ad8\u5668\u4ef6\u7efc\u5408\u6027\u80fd\u5177\u6709\u91cd\u8981\u7684\u610f\u4e49\u3002\u4f20\u7edf\u7684\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4e3b\u8981\u662f\u57fa\u4e8e\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u7535\u5b50\u53d7\u4f53\u6750\u6599\u5c55\u5f00\u7684\uff0c\u4f46\u662f\u8be5\u7c7b\u53d7\u4f53\u6750\u6599\u7531\u4e8e\u5408\u6210\u6210\u672c\u9ad8\u3001\u7ed3\u6784\u548c\u80fd\u7ea7\u4e0d\u6613\u8c03\u63a7\u7b49\u4e0d\u8db3\u9650\u5236\u4e86\u5176\u8fdb\u4e00\u6b65\u53d1\u5c55\u3002\u8fd1\u5e74\u6765\uff0c\u5177\u6709\u62c9\u7535\u5b50\u5355\u5143-\u7ed9\u7535\u5b50\u5355\u5143-\u62c9\u7535\u5b50\u5355\u5143\uff08A-D-A\uff09\u7ed3\u6784\u7684\u975e\u5bcc\u52d2\u70ef\u5c0f\u5206\u5b50\u53d7\u4f53\u6750\u6599\u7531\u4e8e\u5176\u7ed3\u6784\u786e\u5b9a\u3001\u80fd\u7ea7\u53ca\u5438\u6536\u8303\u56f4\u6613\u8c03\u63a7\u7b49\u4f18\u70b9\u5728\u63a8\u52a8\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u53d1\u5c55\u4e2d\u53d1\u6325\u4e86\u91cd\u8981\u7684\u4f5c\u7528\u3002\u57fa\u4e8e\u8be5\u7c7b\u975e\u5bcc\u52d2\u70ef\u53d7\u4f53\u6750\u6599\u7684\u5668\u4ef6\u901a\u5e38\u6709\u8f83\u4f4e\u7684\u80fd\u91cf\u635f\u5931\u548c\u5bbd\u7684\u5149\u8c31\u5438\u6536\u8303\u56f4\uff0c\u4ece\u800c\u5177\u6709\u66f4\u597d\u7684\u5668\u4ef6\u7efc\u5408\u6548\u7387\u3002\u524d\u671f\u5de5\u4f5c\u4e2d\uff0c\u5357\u5f00\u5927\u5b66\u9648\u6c38\u80dc\u6559\u6388\u8bfe\u9898\u7ec4\u9996\u6b21\u62a5\u9053\u4e86\u57fa\u4e8e\u82ef\u5e76\u4e8c\u567b\u5429\uff08BDT\uff09\u7684\u7a20\u73af\u5355\u5143\u7684\u5c0f\u5206\u5b50\u53d7\u4f53\u6750\u6599NFBDT\uff0c\u968f\u540e\u5bf9\u5176\u4e2d\u95f4\u5355\u5143\u548c\u672b\u7aef\u5355\u5143\u540c\u65f6\u8fdb\u884c\u4f18\u5316\u62a5\u9053\u4e86A-D-A\u578b\u7684\u5c0f\u5206\u5b50\u53d7\u4f53NCBDT\uff0c\u5e76\u83b7\u5f97\u4e86\u8d85\u8fc712%\u7684\u5668\u4ef6\u6548\u7387\u3002<\/p>\n<p>\u8fd1\u671f\uff0c\u9648\u6c38\u80dc\u6559\u6388\u8bfe\u9898\u7ec4\u548c\u4e2d\u56fd\u79d1\u5b66\u9662\u5316\u5b66\u7814\u7a76\u6240\u4faf\u5251\u8f89\u7814\u7a76\u5458\u8bfe\u9898\u7ec4\u5408\u4f5c\uff0c\u901a\u8fc7\u5bf9A-D-A\u578b\u5c0f\u5206\u5b50\u53d7\u4f53\u6750\u6599\u7684\u672b\u7aef\u57fa\u56e2\u8fdb\u884c\u8c03\u63a7\uff0c\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4ee5\u57fa\u4e8eBDT\u7684\u7a20\u73af\u7ed3\u6784\uff08CBDT\uff09\u4f5c\u4e3a\u4e2d\u95f4\u5355\u5143\u3001\u4ee5\u6c2f\u4ee3\u6c30\u57fa\u831a\u6ee1\u4e8c\u916e\u4f5c\u4e3a\u672b\u7aef\u5355\u5143\u7684\u975e\u5bcc\u52d2\u70ef\u5c0f\u5206\u5b50\u53d7\u4f53\u6750\u6599NCBDT-4Cl\uff08\u5982\u56fe\u6240\u793a\uff09\u3002\u672b\u7aef\u62c9\u7535\u5b50\u7684\u6c2f\u539f\u5b50\u7684\u5f15\u5165\u4f7f\u8be5\u5206\u5b50\u5177\u6709\u8f83\u4f4e\u7684LUMO\u548cHOMO\u80fd\u7ea7\uff0c\u5176\u5149\u8c31\u5438\u6536\u8303\u56f4\u4e3b\u8981\u4f4d\u4e8e600-900 nm\uff0c\u901a\u8fc7\u5438\u6536\u622a\u6b62\u8fb9\u8ba1\u7b97\u5f97\u5230\u7684\u5149\u5b66\u5e26\u4e3a1.40 eV\u3002\u4ece\u80fd\u7ea7\u548c\u5149\u8c31\u5438\u6536\u5339\u914d\u7684\u89d2\u5ea6\u51fa\u53d1\uff0c\u9009\u7528\u4e86\u7531\u4faf\u5251\u8f89\u7814\u7a76\u5458\u56e2\u961f\u62a5\u9053\u7684\u5bbd\u5e26\u9699\u805a\u5408\u7269PBDB-T-SF\u4f5c\u4e3a\u7535\u5b50\u7ed9\u4f53\u6750\u6599\u3002\u8be5\u805a\u5408\u7269\u5177\u6709\u8f83\u4f4eHOMO\u80fd\u7ea7\uff0c\u5176\u4e0e\u53d7\u4f53\u6750\u6599\u7684HOMO\u80fd\u7ea7\u5dee\u4ec5\u4e3a0.18 eV\uff0c\u4f46\u662f\u5e76\u4e0d\u5f71\u54cd\u7ed9\u4f53\u6750\u6599\u548c\u53d7\u4f53\u6750\u6599\u4e4b\u95f4\u7684\u7535\u8377\u4ea7\u751f\u8fc7\u7a0b\uff1bPBDB-T-SF\u7684\u5438\u6536\u5149\u8c31\u4e3b\u8981\u5728450-700 nm\uff0c\u56e0\u6b64PBDB-T-SF:NCBDT-4Cl\u5171\u6df7\u8584\u819c\u5177\u6709\u5bbd\u800c\u6709\u6548\u7684\u5438\u6536\u8303\u56f4\uff0c\u5229\u4e8e\u6240\u5236\u5907\u5668\u4ef6\u83b7\u5f97\u9ad8\u7684\u77ed\u8def\u7535\u6d41\u5bc6\u5ea6\u3002<\/p>\n<p>\u57fa\u4e8e\u6b64\uff0c\u4f5c\u8005\u5236\u5907\u4e86\u4ee5PBDB-T-SF:NCBDT-4Cl\u4e3a\u6d3b\u6027\u5c42\u6750\u6599\u7684\u6b63\u5411\u5668\u4ef6\uff0c\u5e76\u5bf9\u5668\u4ef6\u5236\u5907\u5de5\u827a\u8fdb\u884c\u4e86\u63a2\u7d22\u4f18\u5316\u3002\u5668\u4ef6\u5728\u4e0d\u7ecf\u8fc7\u4efb\u4f55\u540e\u5904\u7406\u65f6\u83b7\u5f97\u4e8613.1%\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff0c\u8fd9\u662f\u76ee\u524d\u6587\u732e\u62a5\u9053\u4e2d\u4e0d\u7ecf\u8fc7\u540e\u5904\u7406\u7684\u6700\u9ad8\u5668\u4ef6\u6548\u7387\uff1b\u5176\u5f00\u8def\u7535\u538b\u4e3a0.885 V\uff0c\u80fd\u91cf\u635f\u5931\u4ec5\u4e3a0.52 eV\u3002\u968f\u540e\u901a\u8fc7\u6eb6\u5242\u6dfb\u52a0\u5242\uff08DIO\uff09\u548c\u70ed\u9000\u706b\u5bf9\u5668\u4ef6\u8fdb\u884c\u4f18\u5316\uff0c\u53d1\u73b0\u5f53DIO\u7684\u6dfb\u52a0\u91cf\u4e3a0.2%\uff08<em>v<\/em>\/<em>v<\/em>\uff09\uff0c\u518d\u5728110 <sup>o<\/sup>C\u8fdb\u884c\u70ed\u9000\u706b10\u5206\u949f\u65f6\uff0c\u5668\u4ef6\u6548\u7387\u8fdb\u4e00\u6b65\u63d0\u9ad8\u81f314.1%\uff0c\u5176\u4e2d\u5f00\u8def\u7535\u538b\u4e3a0.851 V\uff0c\u77ed\u8def\u7535\u6d41\u5bc6\u5ea6\u4e3a22.35 mA cm<sup>-2<\/sup>\uff0c\u586b\u5145\u56e0\u5b50\u63a5\u8fd175%\u3002\u57fa\u4e8e\u8be5\u4f18\u5316\u5668\u4ef6\u7684\u80fd\u91cf\u635f\u5931\u4e5f\u4ec5\u4e3a0.55 eV\u3002\u901a\u8fc7AFM\u3001TEM\u548cGIXD\u6d4b\u8bd5\u5206\u6790\u5e76\u5bf9\u6bd4\u53d1\u73b0\uff0c\u5668\u4ef6\u6027\u80fd\u7684\u63d0\u9ad8\u4e3b\u8981\u662f\u7531\u4e8e\u66f4\u52a0\u4f18\u5316\u7684\u6d3b\u6027\u5c42\u5f62\u8c8c\u548c\u66f4\u9ad8\u6548\u7684\u5149\u7535\u8f6c\u6362\u8fc7\u7a0b\u3002\u8003\u8651\u5230\u53d7\u4f53\u6750\u6599\u548c\u7ed9\u4f53\u6750\u6599\u7684\u5316\u5b66\u7ed3\u6784\u7684\u591a\u6837\u6027\uff0c\u901a\u8fc7\u5bf9\u6750\u6599\u7ed3\u6784\u4ee5\u53ca\u5668\u4ef6\u7684\u4f18\u5316\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u5668\u4ef6\u7684\u80fd\u91cf\u635f\u5931\u548c\u62d3\u5bbd\u6d3b\u6027\u5c42\u6750\u6599\u7684\u5438\u6536\u8303\u56f4\uff0c\u6709\u52a9\u4e8e\u5b9e\u73b0\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u7684\u66f4\u5927\u7a81\u7834\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-149536 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/\u65e0\u6807\u9898-4.png\" alt=\"\" width=\"600\" height=\"553\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/\u65e0\u6807\u9898-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/\u65e0\u6807\u9898-4-300x277.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u8be5\u9879\u6210\u679c\u4ee5\u201cA Chlorinated Low-Bandgap Small-Molecule Acceptor for Organic Solar Cells With 14.1% Efficiency and Low Energy Loss\u201d\u4e3a\u9898\uff0c\u5728\u7ebf\u53d1\u8868\u4e8e<em>Science China Chemistry<\/em>\uff08DOI: 10.1007\/s11426-018-9334-9\uff09\u3002<\/p>\n<p><strong>\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb\u3011<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-149537 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/1-12.png\" alt=\"\" width=\"600\" height=\"746\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/1-12.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/1-12-241x300.png 241w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p><strong>\u9648\u6c38\u80dc\u6559\u6388:<\/strong>\u81ea2003\u5e74\u8d77\u4efb\u5357\u5f00\u5927\u5b66\u7279\u8058\u6559\u6388\u3001\u5357\u5f00\u5927\u5b66\u7eb3\u7c73\u79d1\u5b66\u4e0e\u6280\u672f\u7814\u7a76\u4e2d\u5fc3\u4e3b\u4efb\u3002\u81f3\u4eca\u5df2\u5728<em>Science, Nature, Nature Photon., Nature Commun., Acc. Chem. Res., J. Am. Chem. Soc., Nano Lett., Adv. Mater.\u00a0<\/em>\u7b49\u8457\u540d\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u6587280\u4f59\u7bc7\uff0c\u5176\u4e2d40\u4f59\u7bc7\u5165\u9009ESI\u9ad8\u88ab\u5f15\u8bba\u6587\uff08top 1%\uff09\uff0c5 \u7bc7\u5165\u9009\u201c\u4e2d\u56fd\u767e\u7bc7\u6700\u5177\u5f71\u54cd\u56fd\u9645\u5b66\u672f\u8bba\u6587\u201d\uff0c\u603b\u88ab\u5f15\u8d85\u8fc735000\u6b21\uff0cH\u56e0\u5b5087\uff082018\u5e743\u6708\uff0cGoogle Scholar\uff09\uff0c2014-2017\u5e74\u8fde\u7eed\u5165\u9009\u6c64\u68ee\u8def\u900f\u5168\u7403\u9ad8\u88ab\u5f15\u79d1\u5b66\u5bb6\u540d\u5f55\u3002\u76ee\u524d\u62c5\u4efb<em>Carbon<\/em>\uff0c<em>Science China Chemistry\uff0c<\/em><em>Science China Materials\uff0c<\/em><em>2D Materials<\/em>\uff0c<em>Energy Storage Materials\uff0c<\/em>\u300a\u5316\u5b66\u5b66\u62a5\u300b\u7b49\u671f\u520a\u7f16\u59d4\u3002\u7814\u7a76\u65b9\u5411\u4e3b\u8981\u6709\uff1a1\uff09\u78b3\u7eb3\u7c73\u6750\u6599\uff0c\u5305\u62ec\u77f3\u58a8\u70ef\u548c\u78b3\u7eb3\u7c73\u7ba1\u7b49\u7684\u5236\u5907\u3001\u4fee\u9970\u548c\u5e94\u7528\uff1b2\uff09\u6709\u673a\u5149\u7535\u6750\u6599\uff1b3\uff09\u65b0\u4e00\u4ee3\u7eff\u8272\u80fd\u6e90\u5668\u4ef6\uff0c\u5305\u62ec\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7b49\u3002\u66f4\u591a\u8be6\u60c5\u8bf7\u89c1\u8bfe\u9898\u7ec4\u4e3b\u9875\uff1ananocenter.nankai.edu.cn\u3002<\/p>\n<p>\u672c\u6587\u7531Sci.China Chem \u7f16\u8f91\u90e8\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\"><strong><b>\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/b><\/strong><\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong><b>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/b><\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong><u><b>\u6d4b\u8bd5\u8c37<\/b><\/u><\/strong><\/a><strong><b>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u56e0\u5177\u6709\u8d28\u91cf\u8f7b\u3001\u6210\u672c\u4f4e\u3001\u53ef\u5927\u9762\u79ef\u5236\u5907\u548c\u53ef\u6eb6\u6db2\u5904\u7406\u7b49\u8bf8\u591a\u4f18\u70b9\u800c\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u5728\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u7684\u53d1\u5c55\u8fc7\u7a0b\u4e2d\uff0c\u6d3b\u6027\u5c42\u6750\u6599\u7684\u7814\u53d1\u5bf9\u63d0\u9ad8\u5668\u4ef6\u7efc\u5408\u6027\u80fd\u5177\u6709\u91cd\u8981\u7684&#8230;<\/p>\n","protected":false},"author":9133,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-149535","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/149535"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/9133"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=149535"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/149535\/revisions"}],"predecessor-version":[{"id":149783,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/149535\/revisions\/149783"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=149535"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=149535"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=149535"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}