{"id":149115,"date":"2018-08-11T06:59:25","date_gmt":"2018-08-10T22:59:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=149115"},"modified":"2018-08-09T22:00:11","modified_gmt":"2018-08-09T14:00:11","slug":"%e5%8d%8e%e5%8d%97%e7%90%86%e5%b7%a5%e7%a7%a6%e5%ae%89%e5%86%9b%e6%95%99%e6%8e%88%e5%94%90%e6%9c%ac%e5%bf%a0%e9%99%a2%e5%a3%abmacromolecules-%e4%b8%89%e9%94%ae%e5%8d%95%e4%bd%93%e4%ba%8c%e5%bc%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=149115","title":{"rendered":"\u534e\u5357\u7406\u5de5\u79e6\u5b89\u519b\u6559\u6388&\u5510\u672c\u5fe0\u9662\u58ebMacromolecules: \u4e09\u952e\u5355\u4f53\u4e8c\u5f02\u6c30\u57fa\u4e59\u9178\u916f\u7684\u5355\u7ec4\u5206\u805a\u5408\u53cd\u5e94\u5236\u5907\u805a\u54aa\u5511"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011
\n <\/strong><\/p>\n

\u53cc\u952e\u5355\u4f53\u7684\u805a\u5408\u662f\u73b0\u5728\u9ad8\u5206\u5b50\u5408\u6210\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u4f46\u6240\u5f97\u805a\u5408\u7269\u7531\u4e8e\u9971\u548c\u7684\u4e3b\u94fe\u7ed3\u6784\u4f7f\u7535\u5b50\u79bb\u57df\u8f83\u56f0\u96be\uff0c\u56e0\u6b64\u5728\u5149\u7535\u7b49\u9886\u57df\u7684\u5e94\u7528\u53d7\u5230\u4e86\u9650\u5236\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\u548c\u5236\u5907\u66f4\u5177\u529f\u80fd\u6027\u7684\u6750\u6599\uff0c\u9ad8\u5206\u5b50\u79d1\u5b66\u5bb6\u628a\u76ee\u5149\u8f6c\u5411\u4e09\u952e\u5355\u4f53\u7684\u805a\u5408\u53cd\u5e94\uff0c\u5df2\u7ecf\u5236\u5907\u51fa\u4e86\u805a\u4e59\u7094\u548c\u5176\u4ed6\u5171\u8f6d\u805a\u5408\u7269\uff0c\u5e76\u5df2\u7ecf\u5728\u4e0d\u540c\u9886\u57df\u5f97\u4ee5\u5e94\u7528\u3002\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u8005\u88ab\u4e09\u952e\u5355\u4f53\u7684\u805a\u5408\u53cd\u5e94\u7684\u591a\u6837\u6027\u548c\u4ea7\u7269\u7684\u591a\u529f\u80fd\u6027\u6240\u5438\u5f15\uff0c\u81f4\u529b\u4e8e\u5f00\u53d1\u65b0\u578b\u805a\u5408\u53cd\u5e94\uff0c\u5e76\u53d6\u5f97\u4e86\u663e\u8457\u7684\u8fdb\u5c55\uff0c\u7279\u522b\u662f\u78b3\u78b3\u4e09\u952e\u5355\u4f53\u7684\u805a\u5408\u53cd\u5e94\u3002\u7136\u800c\uff0c\u53e6\u4e00\u7c7b\u4e09\u952e\u5355\u4f53\uff0c\u4f8b\u5982\u78b3\u6c2e\u4e09\u952e\u5355\u4f53\u805a\u5408\u6240\u5f97\u805a\u5408\u7269\u542b\u6709\u6c2e\u5143\u7d20\uff0c\u5177\u6709\u72ec\u7279\u7684\u6027\u8d28\uff0c\u5374\u5f88\u5c11\u88ab\u62a5\u9053\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u5357\u7406\u5de5\u5927\u5b66<\/strong>\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f\u79e6\u5b89\u519b\u6559\u6388\u7b49<\/strong>\u62a5\u9053\u4e86\u4e8c\u5f02\u6c30\u57fa\u4e59\u9178\u916f\u7684\u65b0\u578b\u805a\u5408\u53cd\u5e94\u3002\u8be5\u53cd\u5e94\u4ee5\u918b\u9178\u94f6\u4e3a\u50ac\u5316\u5242\uff0c\u5728\u4e59\u8148\u6216DMF\u4e2d\uff0c\u4e8e\u5ba4\u6e29\u4e0b\u53cd\u5e942 h\u5373\u53ef\u751f\u6210\u91cd\u5747\u5206\u5b50\u91cf\u9ad8\u8fbe32500\u7684\u53ef\u6eb6\u6027\u7684\u805a\u54aa\u5511\uff0c\u4ea7\u7387\u9ad8\u8fbe94%\u3002\u503c\u5f97\u6307\u51fa\u7684\u662f\uff0c\u8be5\u53cd\u5e94\u4ee5\u5355\u7ec4\u5206\u7684\u5f62\u5f0f\u8fdb\u884c\uff0c\u548c\u4e00\u822c\u7684\u53cc\u7ec4\u5206\u6216\u591a\u7ec4\u5206\u7684\u5f62\u5f0f\u76f8\u6bd4\uff0c\u5177\u6709\u8bf8\u5982\u64cd\u4f5c\u7b80\u4fbf\u3001\u65e0\u9700\u8003\u8651\u5355\u4f53\u6bd4\u4f8b\u7b49\u4f18\u70b9\u3002\u6b64\u5916\uff0c\u805a\u5408\u4ea7\u7269\u805a\u54aa\u5511\u53ef\u4ee5\u540c\u5364\u4ee3\u5316\u5408\u7269\u53cd\u5e94\uff0c\u901a\u8fc7\u4e00\u6b65\u7b80\u5355\u7684\u540e\u4fee\u9970\uff0c\u6210\u529f\u5730\u5b9e\u73b0\u5176\u79bb\u5b50\u5316\uff0c\u6210\u529f\u5236\u5907\u4e86\u805a\u7535\u89e3\u8d28\u3002\u4e0d\u4ec5\u5982\u6b64\uff0c\u4ed6\u4eec\u901a\u8fc7\u5c06\u5177\u6709\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149(AIE)\u7279\u6027\u7684\u56db\u82ef\u57fa\u4e59\u70ef\uff08TPE\uff09\u57fa\u5143\u5f15\u5165\u805a\u5408\u7269\u94fe\u4e2d\uff0c\u5236\u5907\u4e86\u5177\u6709AIE\u6027\u8d28\u7684\u805a\u5408\u7269\u3002\u8be5\u53cd\u5e94\u662f\u5236\u5907\u805a\u54aa\u5511\u6709\u529b\u7684\u5de5\u5177\uff0c\u6709\u671b\u5728\u6750\u6599\u548c\u751f\u7269\u7b49\u9886\u57df\u5f97\u4ee5\u5e94\u7528\u3002\u4e0a\u8ff0\u6210\u679c\u4ee5\u201cSingle Component Polymerization of Diisocyanoacetates toward Polyimidazoles<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u9ad8\u5206\u5b50\u8457\u540d\u671f\u520aMacromolecules<\/strong>\u4e0a\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3a\u534e\u5357\u7406\u5de5\u5927\u5b66\u535a\u58eb\u751f\u7a0b\u5929\u5b87\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u6a21\u578b\u53cd\u5e94\u53ca\u6a21\u578b\u5316\u5408\u72692\u7684\u5236\u5907\u8def\u7ebf\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u5355\u4f53<\/strong>\u4e8c\u5f02\u6c30\u57fa\u4e59\u9178\u916f<\/strong>M1<\/strong>\u2014<\/strong>M5<\/strong>\u7684\u5408\u6210\u8def\u7ebf\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u5355\u4f53<\/b><\/strong>M1\u2014M5\u901a\u8fc7\u805a\u5408\u53cd\u5e94\u751f\u6210\u805a\u54aa\u5511PI\u2014PV<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe1 \u00a0\u5355\u4f53M2\uff08A\uff09\u548c<\/b><\/strong>\u5bf9\u5e94\u7684\u805a\u5408\u7269PII\uff08B\uff09\u7684\u7ea2\u5916\u5149\u8c31\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2<\/b><\/strong>\u00a0\u00a0\u5229\u7528<\/b><\/strong>\u5728\u7ebf\u7ea2\u5916\uff08<\/b><\/strong>reactIR<\/b><\/strong>\uff09\u5bf9\u805a\u5408\u53cd\u5e94\u673a\u7406\u7684\u7814\u7a76<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe3 \u00a0M2(A)\u3001PII\uff08B\uff09\u548c\u6a21\u578b\u5316\u5408\u7269<\/b><\/strong>2<\/b><\/strong>\uff08C\uff09\u7684<\/b><\/strong>1<\/b><\/sup><\/strong>H NMR<\/b><\/strong>\u8c31\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe4<\/b><\/strong>\u00a0\u00a0M2(A)\u3001PII\uff08B\uff09\u548c\u6a21\u578b\u5316\u5408\u7269<\/b><\/strong>2<\/b><\/strong>\uff08C\uff09\u7684<\/b><\/strong>1<\/b><\/sup><\/strong>3<\/b><\/sup><\/strong>C<\/b><\/strong>\u00a0NMR<\/b><\/strong>\u8c31\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe5 \u00a0\u805a\u54aa\u5511\u4e2d\u201c\u4e00\u79cd\u7ed3\u6784\uff0c\u4e24\u79cd\u91cd\u590d\u5355\u5143\u201d\u7684\u5f62\u6210\u8fc7\u7a0b<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u867d\u7136\u5728\u805a\u5408\u53cd\u5e94\u4e2d\u53ea\u751f\u6210\u4e00\u79cd\u7ed3\u6784\u7684\u91cd\u590d\u5355\u5143\uff0c\u4f46\u7531\u4e8e\u91cd\u590d\u5355\u5143\u5728\u9ad8\u5206\u5b50\u4e3b\u94fe\u4e0a\u7684\u8fde\u63a5\u65b9\u5f0f\u4e0d\u540c\uff0c\u5f62\u6210\u4e86\u4e24\u79cd\u91cd\u590d\u5355\u5143\u3002<\/p>\n

\u56fe6 \u00a0<\/b><\/strong>PII<\/b><\/strong>(A\uff09\u548c\u79bb\u5b50\u5316\u7684<\/b><\/strong>PII<\/b><\/strong>\uff08B\uff09\u7684<\/b><\/strong>1<\/b><\/sup><\/strong>H NMR<\/b><\/strong>\u8c31\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe7 \u00a0\u805a\u54aa\u5511<\/b><\/strong>PVI<\/b><\/strong>\u7684AIE<\/b><\/strong>\u66f2\u7ebf<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\uff08A\uff09\u805a\u5408\u7269PVI\u5728\u4e0d\u540c\u6c34\u542b\u91cf\u7684DMF\/\u6c34\u6df7\u5408\u6eb6\u5242\u4e2d\u7684\u8367\u5149\u5149\u8c31<\/p>\n

\uff08B\uff09\u805a\u5408\u7269PVI\u7684\u76f8\u5bf9\u8367\u5149\u5f3a\u5ea6-\u6c34\u542b\u91cf\u66f2\u7ebf\u3002\u5185\u56fe\uff1a\u6ce2\u957f\u4e3a365nm\u624b\u6301\u5f0fUV\u706f\u7167\u5c04\u4e0b\uff0cPVI\u5728DMF\u6eb6\u6db2\u4e2d\uff08\u5de6\uff09\u548c\u542b\u6c34\u91cf\u4e3a50%\u7684DMF\/\u6c34\u6df7\u5408\u6eb6\u5242\u4e2d\uff08\u53f3\uff09\u7684\u8367\u5149\u7167\u7247\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u672c\u6587\u8bbe\u8ba1\u548c\u5236\u5907\u4e865\u79cd\u5177\u6709\u4e0d\u540c\u7ed3\u6784\u7684\u5355\u4f53\u4e8c\u5f02\u6c30\u57fa\u4e59\u9178\u916f\uff0c\u786e\u5b9a\u4e86\u8fd9\u4e9b\u5355\u4f53\u7684\u805a\u5408\u53cd\u5e94\u7684\u6700\u4f73\u53cd\u5e94\u6761\u4ef6\uff0c\u901a\u8fc7\u7ea2\u5916\u5149\u8c31\u30011<\/sup>H NMR\u8c31\u56fe\u548c1<\/sup>3<\/sup>C\u00a0NMR\u8c31\u56fe\u5bf9\u805a\u5408\u4ea7\u7269\u7684\u7ed3\u6784\u7684\u8868\u5f81\uff0c\u8868\u660e\u5355\u4f53\u901a\u8fc7\u805a\u5408\u53cd\u5e94\u6210\u529f\u5236\u5907\u4e86\u805a\u54aa\u5511\u3002\u672c\u6587\u8fd8\u62a5\u9053\u4e86\u805a\u54aa\u5511\u7684\u540e\u529f\u80fd\u5316\u548c\u5728\u4e3b\u94fe\u4e0a\u5f15\u5165TPE\u57fa\u5143\u540e\u7684AIE\u6027\u8d28\u3002\u56e0\u6b64\uff0c\u672c\u6587\u62a5\u9053\u7684\u805a\u5408\u53cd\u5e94\u6709\u671b\u5e94\u7528\u4e8e\u6750\u6599\u548c\u751f\u7269\u7b49\u9886\u57df\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong>Single Component Polymerization of Diisocyanoacetates toward Polyimidazoles\u00a0<\/a>\uff08Macromolecules. 2018\uff0cDOI:\u00a010.1021\/acs.macromol.8b01179\uff09<\/p>\n

\u3010<\/b><\/strong>\u56e2\u961f\u4ecb\u7ecd<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u534e\u5357\u7406\u5de5\u5927\u5b66\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f\u4f9d\u6258\u4e8e\u534e\u5357\u7406\u5de5\u5927\u5b66\u53d1\u5149\u6750\u6599\u4e0e\u5668\u4ef6\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u4e8e2012\u5e74\u6210\u7acb\u3002\u56e2\u961f\u73b0\u6709\u6559\u63884\u4eba\uff0c\u526f\u7814\u7a76\u54581\u4eba\uff0c\u535a\u58eb\u540e2\u4eba\uff0c\u7814\u7a76\u751f\u540c\u5b6660\u4f59\u4eba\u3002\u5176\u4e2d\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u9662\u58eb1\u4eba\uff0c\u56fd\u5bb6\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u80051\u4eba\uff0c\u5e7f\u4e1c\u7701\u81ea\u7136\u79d1\u5b66\u6770\u51fa\u9752\u5e74\u79d1\u5b66\u57fa\u91d1\u83b7\u5f97\u80052\u4eba\u3002\u8fc4\u4eca\u4e3a\u6b62\uff0c\u56e2\u961f\u5df2\u57f9\u517b\u535a\u58eb\u3001\u7855\u58eb\u7814\u7a76\u751f40\u4f59\u4eba\uff0c\u53d1\u8868\u5b66\u672f\u8bba\u6587200\u4f59\u7bc7\uff0c\u6388\u6743\u548c\u7533\u8bf7\u56fd\u5bb6\u53d1\u660e\u4e13\u522940\u4f59\u4ef6\u3002\u56e2\u961f\u4e3b\u8981\u7814\u7a76\u65b9\u5411\u5305\u62ec\uff1a\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u673a\u7406\u7684\u63a2\u7d22\u3001\u65b0\u578b\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u6750\u6599\u7684\u8bbe\u8ba1\u4e0e\u5236\u5907\u4ee5\u53ca\u5176\u5728\u751f\u7269\u6210\u50cf\u3001\u5316\u5b66\u4f20\u611f\u548c\u5149\u7535\u5668\u4ef6\u7b49\u9886\u57df\u7684\u5e94\u7528\uff1b\u57fa\u4e8e\u4e09\u952e\u7684\u9ad8\u5206\u5b50\u5408\u6210\u65b0\u65b9\u6cd5\u7684\u5f00\u53d1\u3001\u5177\u6709\u7279\u6b8a\u5149\u7535\u6027\u8d28\u7684\u7ebf\u5f62\u4e0e\u62d3\u6251\u7ed3\u6784\u805a\u5408\u7269\u7684\u5236\u5907\u53ca\u529f\u80fd\u5e94\u7528\u3002<\/p>\n

\u3010<\/b><\/strong>\u56e2\u961f\u5728\u8be5\u9886\u57df\u5de5\u4f5c\u6c47\u603b<\/b><\/strong>\u3011<\/b><\/strong><\/p>\n

\u5510\u672c\u5fe0\u9662\u58eb\u56e2\u961f\u957f\u671f\u81f4\u529b\u4e8e\u53d1\u5c55\u57fa\u4e8e\u4e09\u952e\u7684\u9ad8\u5206\u5b50\u5408\u6210\u65b0\u65b9\u6cd5\u3002\u6700\u65b0\u7684\u76f8\u5173\u7efc\u8ff0\u53d1\u8868\u4e8eProgress in Polymer Science\u00a0(2018,78,92-138)\u4e0a\u3002\u8bba\u6587\u9898\u4e3a\u201cPolymerizations based on triple-bond building blocks\u201d\u3002<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8kv1004\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0\u611f\u8c22\u534e\u5357\u7406\u5de5\u5927\u5b66\u79e6\u5b89\u519b\u8001\u5e08\u5bf9\u672c\u6587\u7684\u6307\u5bfc\u4fee\u6539\u3002<\/p>\n

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