{"id":148861,"date":"2018-08-03T06:30:08","date_gmt":"2018-08-02T22:30:08","guid":{"rendered":"\/\/m.iemloyee.com\/?p=148861"},"modified":"2018-08-03T14:09:22","modified_gmt":"2018-08-03T06:09:22","slug":"%e4%b8%ad%e7%a7%91%e5%a4%a7%e8%82%96%e7%bf%80%e3%80%81%e8%b0%a2%e6%af%85%e5%9b%a2%e9%98%9fchem%e7%bb%bc%e8%bf%b0%e6%96%b0%e8%a7%a3%e4%ba%8c%e7%bb%b4%e7%94%b5%e5%82%ac%e5%8c%96%e6%b0%b4%e8%a3%82","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=148861","title":{"rendered":"\u4e2d\u79d1\u5927\u8096\u7fc0\u3001\u8c22\u6bc5\u56e2\u961fChem\u7efc\u8ff0\u65b0\u89e3\u4e8c\u7ef4\u7535\u50ac\u5316\u6c34\u88c2\u89e3\u6750\u6599\uff1a\u73a9\u8f6c\u7535\u8377\u548c\u81ea\u65cb\u5e8f"},"content":{"rendered":"<p><strong><b>\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n<p>\u57fa\u4e8e\u5316\u77f3\u71c3\u6599\u7684\u80fd\u6e90\u7ed3\u6784\u7684\u8870\u9000\u548c\u4e0d\u65ad\u589e\u52a0\u7684\u73af\u5883\u6c61\u67d3\uff0c\u4f7f\u5f97\u5f00\u53d1\u65b0\u578b\u6e05\u6d01\u53ef\u518d\u751f\u7684\u80fd\u6e90\u50a8\u5b58\u548c\u8f6c\u6362\u7cfb\u7edf\u8feb\u5728\u7709\u776b\uff0c\u8fd9\u662f\u6750\u6599\u5316\u5b66\u5bb6\u7684\u4e00\u9879\u91cd\u5927\u4f7f\u547d\u3002\u4ece\u5316\u5b66\u89d2\u5ea6\u6765\u770b\uff0c\u5728\u5916\u573a\uff08\u4f8b\u5982\u70ed\uff0c\u7535\uff0c\u78c1\u6216\u5149\uff09\u4f5c\u7528\u4e0b\u5316\u5b66\u952e\u65ad\u88c2\u548c\u7684\u91cd\u5efa\u662f\u8fdb\u884c\u80fd\u91cf\u8f6c\u6362\u548c\u50a8\u5b58\u7684\u6709\u6548\u7b56\u7565\u3002\u800c\u6c34\u88c2\u89e3\u53cd\u5e94\u4f5c\u4e3a\u4e00\u7cfb\u5217\u91cd\u8981\u7684\u80fd\u6e90\u8f6c\u6362\u6280\u672f\uff08\u4f8b\u5982\u6c22\u6c27\u71c3\u6599\u7535\u6c60\u3001\u91d1\u5c5e-\u7a7a\u6c14\u7535\u6c60\u548c\u7535\u89e3\u6c60\uff09\u7684\u6838\u5fc3\uff0c\u6025\u9700\u9ad8\u6548\u7a33\u5b9a\u7684\u50ac\u5316\u5242\u6765\u964d\u4f4e\u53cd\u5e94\u7684\u80fd\u5792\uff0c\u52a0\u5feb\u53cd\u5e94\u8fc7\u7a0b\u3002\u5177\u6709\u7279\u6b8a\u539f\u5b50\u548c\u7535\u5b50\u7ed3\u6784\u7684\u4e8c\u7ef4\uff082D\uff09\u8d85\u8584\u56fa\u4f53\u5728\u8ffd\u6c42\u9ad8\u6548\u7535\u50ac\u5316\u6027\u80fd\u65b9\u9762\u5177\u6709\u65e0\u9650\u7684\u6f5c\u529b\uff0c\u5e76\u5df2\u88ab\u786e\u5b9a\u4e3a\u7814\u7a76\u50ac\u5316\u5242\u6784\u6548\u5173\u7cfb\u7684\u5b8c\u7f8e\u5e73\u53f0\u3002\u6700\u8fd1\uff0c\u4e2d\u56fd\u79d1\u5b66\u4e0e\u6280\u672f\u5927\u5b66\u7684\u8096\u7fc0\u6559\u6388\u548c\u8c22\u6bc5\u9662\u58eb\uff08\u901a\u8baf\u4f5c\u8005\uff09\u56e2\u961f\u5728\u5316\u5b66\u9886\u57df\u9876\u7ea7\u671f\u520aChem\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cRegulating 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center;\"><strong>\u56fe3 \u00a0\u5728\u4e8c\u7ef4\u56fa\u4f53\u7535\u50ac\u5316\u5242\u4e2d\u901a\u8fc7\u7f3a\u9677\u5de5\u7a0b\u8c03\u8282\u53cd\u5e94\u80fd\u5792<\/strong><\/p>\n<p><strong><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-148865 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/4-5.png\" alt=\"\" width=\"600\" height=\"541\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/4-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/4-5-300x271.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/strong><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe4 \u00a0\u540c\u65f6\u8c03\u8282\u4e8c\u7ef4\u56fa\u4f53\u7535\u50ac\u5316\u5242\u4e2d\u7684\u7535\u5bfc\u7387\u548c\u53cd\u5e94\u80fd\u5792<\/strong><\/p>\n<p><strong><b>\u3010\u8c03\u8282\u81ea\u65cb\u5e8f\u3011<\/b><\/strong><\/p>\n<p>\u81ea\u65cb\u5e8f\u662f\u7535\u5b50\u7ed3\u6784\u7684\u53e6\u4e00\u4e2a\u5185\u5728\u5c5e\u6027\uff0c\u901a\u8fc7\u6676\u683c\u8026\u5408\u4ea7\u751f\u5927\u91cf\u65b0\u7684\u91cf\u5b50\u73b0\u8c61\u3002\u6839\u636e\u6676\u4f53\u573a\u7406\u8bba\uff0cd\u8f68\u9053\u4e2d\u7684\u7535\u5b50\u548c\u914d\u4f53\u4e2d\u7684\u7535\u5b50\u7531\u4e8e\u76f8\u540c\u7535\u8377\u4e4b\u95f4\u7684\u6392\u65a5\u800c\u76f8\u4e92\u6392\u65a5\u3002\u56e0\u6b64\uff0c\u66f4\u9760\u8fd1\u914d\u4f53\u7684d\u7535\u5b50\u6bd4\u8fdc\u79bb\u914d\u4f53\u7684d\u7535\u5b50\u5177\u6709\u66f4\u9ad8\u7684\u80fd\u91cf\uff0c\u5bfc\u81f4d\u8f68\u9053\u80fd\u91cf\u5206\u88c2\u3002\u5728\u516b\u9762\u4f53\u573a\u4e2d\uff0cd\u8f68\u9053\u5206\u88c2\u6210\u5177\u6709\u4e0d\u540c\u80fd\u91cf\u7684\u4e24\u7ec4\uff0c\u4f7f\u5f97d<sub>xy<\/sub>\uff0cd<sub>xz<\/sub>\u548cd<sub>yz<\/sub>\u8f68\u9053\u7684\u80fd\u91cf\u4f4e\u4e8ed<sub>z2<\/sub>\u548cd<sub>x2-y2<\/sub>\u3002\u4e09\u4e2a\u8f83\u4f4e\u80fd\u91cf\u7684\u8f68\u9053\u7edf\u79f0\u4e3at<sub>2g<\/sub>\uff0c\u4e24\u4e2a\u8f83\u9ad8\u80fd\u91cf\u7684\u8f68\u9053\u662fe<sub>g<\/sub>\u3002\u5728\u7535\u50ac\u5316\u9886\u57df\uff0cShao-Horn\u53ca\u5176\u540c\u4e8b\u9996\u5148\u63d0\u51fae<sub>g<\/sub>\u8f68\u9053\u7684\u7535\u5b50\u586b\u5145\u7a0b\u5ea6\uff08e<sub>g 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1\uff09\u7684\u6d3b\u5316\u539f\u5b50\u4e0e\u6c27\u7ed3\u5408\u592a\u5f31\u3002\u56e0\u6b64\uff0c\u8868\u9762\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u7684e<sub>g<\/sub>\u8f68\u9053\u586b\u5145\u4e3a1\u7684\u65f6\u5019\uff0c\u50ac\u5316\u5242\u8868\u73b0\u51fa\u6700\u4f73\u7684\u56fa\u6709OER\u6d3b\u6027\uff0c\u8fd9\u4e3a\u9ad8\u6d3b\u6027\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u63d0\u4f9b\u6307\u5bfc\u3002\u63a5\u4e0b\u6765\uff0c\u4f5c\u8005\u4ecee<sub>g<\/sub>\u8f68\u9053\u7535\u5b50\u586b\u5145\u5de5\u7a0b\uff08\u56fe5\u548c\u56fe6\uff09\u548c\u81ea\u65cb\u8026\u5408\u8c03\u8282\u7535\u5bfc\u7387\u548c\u914d\u4f4d\u7ed3\u6784\uff08\u56fe7\uff09\u4e24\u65b9\u9762\u5bf9\u672c\u8282\u8fdb\u884c\u8be6\u7ec6\u9610\u8ff0\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-148866 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/5-5.png\" alt=\"\" width=\"600\" height=\"416\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/5-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/5-5-300x208.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe5 \u00a0\u7eb3\u7c73\u7247e<sub>g<\/sub>\u8f68\u9053\u4e2d\u7684\u4ef7\u7535\u5b50\u586b\u5145\u5de5\u7a0b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-148867 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/6-4.png\" alt=\"\" width=\"600\" height=\"612\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/6-4.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/6-4-294x300.png 294w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe6 \u00a0NiCo\u53cc\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u4e2d\u901a\u8fc7\u7535\u8377\u8f6c\u79fb\u8fdb\u884ce<sub>g<\/sub>\u7535\u5b50\u586b\u5145\u5de5\u7a0b<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-148868 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/7-1.png\" alt=\"\" width=\"600\" height=\"544\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/7-1.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/08\/7-1-300x272.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: center;\"><strong>\u56fe7 \u00a0CoSe<sub>2<\/sub>\u8d85\u8584\u7eb3\u7c73\u7247\u4e2d\u7684\u975e\u5747\u76f8\u81ea\u65cb\u6001\u8bf1\u5bfcHER\u7684\u7ec6\u5fae\u6676\u683c\u7578\u53d8\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u8c03\u53d8<\/strong><\/p>\n<p><strong><b>\u3010\u603b<\/b><\/strong><strong><b>\u7ed3\u4e0e\u5c55\u671b\u3011<\/b><\/strong><\/p>\n<p>\u5bf9\u7528\u4e8e\u7535\u50ac\u5316\u6c34\u5206\u89e3\u76842D\u8d85\u8584\u56fa\u4f53\u7684\u5927\u91cf\u62a5\u9053\u63a8\u52a8\u4e86\u7814\u7a76\u8005\u4eec\u5bf92D\u8d85\u8584\u56fa\u4f53\u7684\u7535\u5b50\u7ed3\u6784\u8c03\u5236\u7684\u6301\u7eed\u5174\u8da3\u3002\u5728\u8fd9\u7bc7\u7efc\u8ff0\u4e2d\uff0c\u4f5c\u8005\u4eec\u603b\u7ed3\u4e86\u5c062D\u8d85\u8584\u56fa\u4f53\u4e2d\u5bf9\u7535\u8377\u548c\u81ea\u65cb\u5e8f\u7684\u8c03\u8282\u4f5c\u4e3a\u5148\u8fdb\u7535\u50ac\u5316\u6c34\u5206\u89e3\u7684\u65b0\u5174\u7814\u7a76\u5e73\u53f0\u3002\u901a\u8fc7\u6676\u683c\u88c1\u526a\uff08\u4f8b\u5982\u7a7a\u4f4d\u5de5\u7a0b\u3001\u5f02\u539f\u5b50\u63ba\u6742\u3001\u7ef4\u5ea6\u548c\u5e94\u529b\u8c03\u53d8\uff09\u53ef\u4ee5\u6709\u6548\u5730\u63a7\u5236\u5176\u7535\u8377\u548c\u81ea\u65cb\u5e8f\u3002\u7136\u800c\uff0c\u603b\u7684\u6765\u8bf4\uff0c\u7528\u4e8e\u5148\u8fdb\u7535\u50ac\u5316\u6c34\u5206\u89e3\u7684\u53ef\u8c032D\u8d85\u8584\u56fa\u4f53\u7684\u5f00\u53d1\u4ecd\u5904\u4e8e\u8d77\u6b65\u9636\u6bb5\uff0c\u8be5\u9886\u57df\u8fd8\u6709\u5f88\u5927\u7684\u53d1\u5c55\u7a7a\u95f4\u3002<\/p>\n<p>\u9996\u5148\uff0c\u56e0\u4e3a2D\u8d85\u8584\u7eb3\u7c73\u7247\u5177\u6709\u9ad8\u8868\u9762\u80fd\uff0c\u6211\u4eec\u9700\u8981\u5c06\u6ce8\u610f\u529b\u96c6\u4e2d\u5728\u6781\u7aef\u7535\u89e3\u8d28\u73af\u5883\u4e2d\u7684\u6750\u6599\u7684\u70ed\u529b\u5b66\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff08\u5bf9\u4e8eHER\u800c\u8a00\u4e3b\u8981\u662f\u5f3a\u9178\uff0c\u5bf9\u4e8eOER\u800c\u8a00\u662f\u5f3a\u78b1\u73af\u5883\uff09\u3002\u5728\u8fd9\u65b9\u9762\uff0c\u4e3a\u4e86\u5e73\u8861\u8868\u9762\u80fd\u548c\u6750\u6599\u7a33\u5b9a\u6027\uff0c\u5728\u4e2d\u6027\u6761\u4ef6\u4e0b\uff08\u4f8b\u5982\u7eaf\u6c34\uff0c\u6d77\u6c34\u7b49\uff09\u5f00\u53d1\u9ad8\u6d3b\u6027\u7535\u50ac\u5316\u5242\u662f\u6781\u5176\u91cd\u8981\u7684\u3002\u6b64\u5916\uff0c\u9009\u62e9\u5408\u9002\u7684\u5e95\u7269\u6765\u6742\u53162D\u8d85\u8584\u7eb3\u7c73\u7247\u7535\u50ac\u5316\u5242\u53ef\u4ee5\u63d0\u4f9b\u524d\u6240\u672a\u6709\u7684\u7a33\u5b9a\u6027\u6765\u5bf9\u6297\u7a7a\u6c14\u6c27\u5316\u548c\u50ac\u5316\u5242\u5d29\u89e3\u3002\u6b64\u5916\uff0c\u5bf9\u7535\u5b50\u8fc1\u79fb\u754c\u9762\u5468\u56f4\u7535\u8377\u5206\u5e03\u7684\u8c03\u8282\u53ef\u4ee5\u8fdb\u4e00\u6b65\u63d0\u9ad8\u6750\u6599\u7684\u7535\u50ac\u5316\u6027\u80fd\uff0c\u5b9e\u73b0\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u548c\u6d3b\u6027\u7684\u540c\u6b65\u4f18\u5316\u3002<\/p>\n<p>\u5176\u6b21\uff0c\u5728\u7535\u50ac\u5316\u53cd\u5e94\u8fc7\u7a0b\u4e2d\uff0c\u76f8\u6bd4\u4e8e\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\uff0c\u4f20\u8d28\u8fc7\u7a0b\u540c\u6837\u8d77\u7740\u91cd\u8981\u7684\u4f5c\u7528\uff0c\u4f46\u5728\u73b0\u6709\u62a5\u544a\u4e2d\u957f\u671f\u4ee5\u6765\u4e00\u76f4\u88ab\u5ffd\u89c6\u3002\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u5177\u6709\u5929\u7136\u7684\u89c4\u5219\u591a\u5b54\u7ed3\u6784\u6765\u4f5c\u4e3a\u4f20\u8d28\u901a\u9053\uff0c\u6240\u4ee5MOF\u6750\u6599\u662f\u8fdb\u884c\u4f20\u8d28\u8fc7\u7a0b\u4f18\u5316\u7684\u4f18\u5f02\u6a21\u578b\u7cfb\u7edf\uff0c\u5c3d\u7ba1\u5b83\u4eec\u7684\u56fa\u6709\u7535\u5bfc\u7387\uff08\u901a\u5e38\u4e3a10<sup>-10 <\/sup>S m<sup>-1<\/sup>\uff09\u8f83\u5dee\u3002\u56e0\u6b64\uff0c\u53d7\u5168\u65e0\u673a\u5316\u5408\u7269\u8c03\u8282\u7684\u542f\u53d1\uff0c2D 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Liu, Chong Xiao*, Pengcheng Huang, Ming Cheng and Yi Xie*.\u00a0Regulating the Charge and Spin Ordering of Two-Dimensional Ultrathin Solids for Electrocatalytic Water Splitting.\u00a0<strong><em><b><i>Chem<\/i><\/b><\/em><\/strong><em><i>,<\/i><\/em>\u00a02018, 4, 1263.<\/p>\n<p><strong><b>\u00a0<\/b><\/strong>\u672c\u6587\u7531\u6750\u6599\u4eba\u4e13\u680f\u7f16\u8f91\u827e\u8d85\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u53ca\u5185\u5bb9\u5408\u4f5c\u8bf7\u52a0\u5fae\u4fe1cailiaokefu\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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