{"id":148036,"date":"2018-08-02T06:30:47","date_gmt":"2018-08-01T22:30:47","guid":{"rendered":"\/\/m.iemloyee.com\/?p=148036"},"modified":"2018-08-01T22:34:46","modified_gmt":"2018-08-01T14:34:46","slug":"%e6%b8%85%e5%8d%8e%e6%9d%8e%e4%ba%9a%e6%a0%8b%e7%8e%8b%e5%ae%9a%e8%83%9cadv-funct-mater-%e7%94%9f%e7%89%a9%e8%b4%a8%e7%ad%96%e7%95%a5%e5%8a%a9%e5%8a%9b%e5%90%88%e6%88%90%e9%ab%98%e6%af%94","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=148036","title":{"rendered":"\u6e05\u534e\u674e\u4e9a\u680b&\u738b\u5b9a\u80dcAdv. Funct. Mater. : \u751f\u7269\u8d28\u7b56\u7565\u52a9\u529b\u5408\u6210\u9ad8\u6bd4\u8868\u9762\u94b4\u5355\u539f\u5b50\u50ac\u5316\u5242"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u78b3\u6c22\u5316\u7269\u7684\u9009\u62e9\u6027\u6c27\u5316\u662f\u975e\u5e38\u91cd\u8981\u7684\u751f\u4ea7\u9ad8\u9644\u52a0\u503c\u6c27\u5316\u4ea7\u7269\u7684\u5316\u5b66\u8fc7\u7a0b\u3002\u7136\u800c\uff0c\u7531\u4e8eC-H\u952e\u7684\u60f0\u6027\u4ee5\u53ca\u9644\u5e26\u53d1\u751f\u7684\u8fc7\u5ea6\u6c27\u5316\uff0c\u78b3\u6c22\u5316\u7269\u7684\u9009\u62e9\u6027\u6c27\u5316\u9762\u4e34\u7740\u8f6c\u5316\u7387\u4f4e\u548c\u9009\u62e9\u6027\u5dee\u7684\u95ee\u9898\uff0c\u56e0\u6b64\u5bfb\u627e\u9ad8\u6548\u7684\u50ac\u5316\u5242\u5df2\u6210\u4e3a\u76ee\u524d\u7814\u7a76\u4eba\u5458\u7684\u4e3b\u8981\u4efb\u52a1\u3002\u6700\u8fd1\uff0c\u591a\u5b54M-N-C(M\u4e3aFe\uff0cCo\u548cNi)\u6750\u6599\u6210\u4e3a\u4f18\u5f02\u7684\u975e\u5747\u76f8\u50ac\u5316\u5242\uff0c\u4e3b\u8981\u662f\u56e0\u4e3a\u5176\u5177\u6709\u5982\u4e0b\u7279\u6027\uff1ai)\u77f3\u58a8\u78b3\u8f7d\u4f53\u5728\u82db\u523b\u50ac\u5316\u6761\u4ef6\u4e0b\u5177\u6709\u826f\u597d\u7684\u7a33\u5b9a\u6027\uff1bii)\u6742\u539f\u5b50\u6c2e\u7a33\u5b9a\u7684\u9ad8\u6d3b\u6027\u91d1\u5c5e\u4e2d\u5fc3\uff1biii)\u5177\u6709\u9ad8\u8868\u9762\u79ef\u7684\u53ef\u63a7\u591a\u5b54\u7ed3\u6784\u80fd\u591f\u4fc3\u8fdb\u53cd\u5e94\u5e95\u7269\u7684\u5438\u9644\u548c\u4f20\u8d28\u3002\u5c3d\u7ba1\u5df2\u7ecf\u53d6\u5f97\u4e86\u4e00\u5b9a\u7684\u8fdb\u5c55\uff0c\u4f46\u5df2\u62a5\u9053\u7684M-N-C\u50ac\u5316\u5242\u6548\u7387\u5c1a\u5dee\u5f3a\u4eba\u610f\uff0c\u5e76\u4e14\u53cd\u5e94\u901a\u5e38\u9700\u8981\u572880-140\u2103\u4e0b\u8fdb\u884c\u3002\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u8fdb\u884c\u9009\u62e9\u6027\u6c27\u5316C-H\u952e\u53cd\u5e94\u662f\u4e00\u4e2a\u957f\u671f\u76ee\u6807\uff0c\u5b9e\u73b0\u8fd9\u4e00\u76ee\u6807\u7684\u5173\u952e\u662f\u589e\u52a0\u66b4\u9732\u7684\u6d3b\u6027\u4f4d\u70b9\u7684\u6570\u91cf\uff0c\u5e76\u63d0\u9ad8\u6bcf\u4e2a\u4f4d\u70b9\u7684\u5185\u5728\u6d3b\u6027\u3002\u8d1f\u8f7d\u578b\u5355\u539f\u5b50\u50ac\u5316\u5242\u6709\u671b\u6210\u4e3a\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u7684\u6709\u6548\u9014\u5f84\uff0c\u5176\u4e2d\u5177\u6709\u6d3b\u6027\u91d1\u5c5e\u5355\u4e00\u4f4d\u70b9\u7684\u591a\u5b54M-N-C\u50ac\u5316\u5242\u662f\u6700\u6709\u5e0c\u671b\u7684\u5907\u9009\u6750\u6599\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6e05\u534e\u5927\u5b66\u674e\u4e9a\u680b\u9662\u58eb\u3001\u738b\u5b9a\u80dc\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u70ed\u89e3\u751f\u7269\u8d28\u884d\u751f\u7684\u58f3\u805a\u7cd6\u6765\u5236\u5907\u514b\u7ea7\u7684\u94b4\u5355\u539f\u5b50\u50ac\u5316\u5242 (Co-ISA\/CNB)\u7684\u65b9\u6cd5\uff0c\u5e76\u5728Adv. Funct. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cScale-Up Biomass Pathway to Cobalt Single-Site Catalysts Anchored on N-Doped Porous Carbon Nanobelt with Ultrahigh Surface Area<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4f7f\u7528ZnCl2<\/sub>\u548cCoCl2<\/sub>\u76d0\u4f5c\u4e3a\u6709\u6548\u7684\u6d3b\u5316\u5242\u548c\u77f3\u58a8\u5316\u5242\u53ef\u4ee5\u4ea7\u751f\u5177\u6709\u8d85\u9ad8\u6bd4\u8868\u9762\u79ef(2513 m2<\/sup>\u00b7g-1<\/sup>)\u548c\u9ad8\u5ea6\u77f3\u58a8\u5316\u7684\u591a\u5b54\u5e26\u72b6\u78b3\u7eb3\u7c73\u7ed3\u6784\u3002\u7403\u5dee\u6821\u6b63\u7535\u5b50\u663e\u5fae\u955c\u548cX\u5c04\u7ebf\u5438\u6536\u7cbe\u7ec6\u7ed3\u6784\u5206\u6790\u8868\u660e\uff0cCo\u5143\u7d20\u4f5c\u4e3a\u5b64\u7acb\u7684\u5355\u4e00\u4f4d\u70b9\u5b58\u5728\uff0c\u88ab\u6c2e\u7a33\u5b9a\u540e\u5f62\u6210CoN4<\/sub>\u7ed3\u6784\u3002\u4e0a\u8ff0\u7279\u6027\u4f7f\u5f97Co-ISA\/CNB\u6210\u4e3a\u5728\u5ba4\u6e29\u4e0b\u9009\u62e9\u6027\u6c27\u5316\u82b3\u70c3\u7684\u6709\u6548\u50ac\u5316\u5242\u3002\u5bf9\u4e8e\u4e59\u82ef\u6c27\u5316\u53cd\u5e94\uff0cCo-ISA\/CNB\u50ac\u5316\u5242\u8f6c\u5316\u7387\u9ad8\u8fbe98%\uff0c\u9009\u62e9\u6027\u4e3a99%\uff0c\u800cCo\u7eb3\u7c73\u9897\u7c92\u51e0\u4e4e\u4e0d\u80fd\u50ac\u5316\u8be5\u53cd\u5e94\u3002\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u8868\u660e\uff0c\u5728\u5b64\u7acb\u7684Co\u5355\u4e00\u4f4d\u70b9\u4e0a\u4ea7\u751f\u7684Co=O\u4e2d\u5fc3\u662f\u9ad8\u50ac\u5316\u6548\u7387\u7684\u539f\u56e0\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 Co-ISA\/CNB\u50ac\u5316\u5242\u7684\u5236\u5907\u53ca\u5176\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) Co-ISA\/CNB\u50ac\u5316\u5242\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b
\n b) Co-ISA\/CNB\u50ac\u5316\u5242\u7684STEM \u56fe\u50cf\uff1b
\n c) Co-ISA\/CNB\u50ac\u5316\u5242\u7684HRTEM\u56fe\u50cf\uff1b
\n d) Co-ISA\/CNB\u50ac\u5316\u5242\u7684EDX\u5143\u7d20\u5206\u5e03\u56fe\u50cf\uff1b
\n e) Co-ISA\/CNB\u50ac\u5316\u5242\u7684AC-HAADF-STEM\u56fe\u50cf\u3002<\/p>\n

\u56fe2 Co-ISA\/CNB\u50ac\u5316\u5242\u7684\u540c\u6b65\u8f90\u5c04XAFS\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a) \u94b4K\u8fb9XANES\u5149\u8c31\uff1b
\n b) \u94b4K\u8fb9FT-EXAFS\u5149\u8c31\uff1b
\n c) WT-EXAFS\u56fe\u8c31\uff1b
\n d,e) \u5728k\u548cR\u573a\u7684EXAFS\u62df\u5408\u66f2\u7ebf\uff0c\u63d2\u56fe\u4e3a\u5206\u5b50\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe3 Co-ISA\/CNB\u50ac\u5316\u5242\u50ac\u5316\u4e59\u82ef\u9009\u62e9\u6027\u6c27\u5316\u53cd\u5e94\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) \u4e59\u82ef\u9009\u62e9\u6027\u6c27\u5316\u53cd\u5e94\u5f0f\uff1b
\n b) Co-ISA\/CNB\u3001NC\u3001Co-NPs\u548c\u7a7a\u767d\u6761\u4ef6\u4e0b\u4e59\u82ef\u9009\u62e9\u6027\u6c27\u5316\u53cd\u5e94\u50ac\u5316\u6d3b\u6027\u6bd4\u8f83\uff1b
\n c) Co-ISA\/CNB\u50ac\u5316\u5242\u7684\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u56fe4 \u53cd\u5e94\u5e95\u7269\u5728\u50ac\u5316\u5242\u4e0a\u7684\u51e0\u4f55\u7ed3\u6784\u4f18\u5316<\/strong><\/p>\n

\"\"<\/p>\n

a) TBHP\u5728Co-ISA\/CNB\u8868\u9762\u4e0a\u7684\u51e0\u4f55\u7ed3\u6784\u4f18\u5316\uff1b
\n b) TBHP\u5728Co(0001)\u8868\u9762\u4e0a\u7684\u51e0\u4f55\u7ed3\u6784\u4f18\u5316\uff1b
\n c) \u4e59\u82ef\u5728Co-ISA\/CNB\u4e2dCoN4<\/sub>O\u4f4d\u70b9\u4e0a\u7684\u51e0\u4f55\u7ed3\u6784\u4f18\u5316\uff1b
\n d) \u4e59\u82ef\u5728Co-ISA\/CNB\u4e2dCoN4<\/sub>\u4f4d\u70b9\u4e0a\u7684\u51e0\u4f55\u7ed3\u6784\u4f18\u5316\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u63d0\u51fa\u4e00\u79cd\u751f\u7269\u8d28\u7b56\u7565\u6765\u5236\u5907\u6c2e\u63ba\u6742\u7684\u591a\u5b54\u78b3\u7eb3\u7c73\u5e26\u8d1f\u8f7d\u94b4\u5355\u539f\u5b50\u50ac\u5316\u5242(Co-ISA\/CNB)\uff0c\u5e76\u5c06\u5176\u4f5c\u4e3a\u5728\u5ba4\u6e29\u4e0b\u3001\u6db2\u76f8\u4e2d\u9009\u62e9\u6027\u6c27\u5316\u82b3\u70c3\u7684\u6709\u6548\u50ac\u5316\u5242\u3002\u6240\u5f97Co-ISA\/CNB\u50ac\u5316\u5242\u663e\u793a\u51fa\u8d85\u9ad8\u6bd4\u8868\u9762\u79ef(2513 m2<\/sup>\u00b7g-1<\/sup>)\u3001\u5927\u5b54\u4f53\u79ef(2.2 cm3<\/sup>\u00b7g-1<\/sup>)\u548c\u9ad8\u5ea6\u77f3\u58a8\u5316\u3002Co-ISA\/CNB\u50ac\u5316\u5242\u5728\u4e59\u82ef\u6c27\u5316\u53cd\u5e94\u4e2d\u53ef\u4ee5\u5b9e\u73b098%\u8f6c\u5316\u7387\u548c99%\u9009\u62e9\u6027\u7684\u4f18\u5f02\u50ac\u5316\u6548\u7387\uff0c\u800c\u94b4\u7eb3\u7c73\u9897\u7c92\u51e0\u4e4e\u4e0d\u80fd\u50ac\u5316\u8be5\u53cd\u5e94\u3002\u4f5c\u8005\u8fd8\u8fdb\u884c\u4e86DFT\u8ba1\u7b97\u4ee5\u63a2\u7d22\u5b64\u7acb\u7684\u94b4\u5355\u4e00\u4f4d\u70b9\u548c\u94b4\u7eb3\u7c73\u9897\u7c92\u4e4b\u95f4\u7684\u50ac\u5316\u884c\u4e3a\u7684\u5185\u5728\u5dee\u5f02\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aScale-Up Biomass Pathway to Cobalt Single-Site Catalysts Anchored on N-Doped Porous Carbon Nanobelt with Ultrahigh Surface Area<\/a><\/strong>\u00a0(Adv. Funct. Mater.<\/strong>, 2018, DOI: 10.1002\/adfm.201802167)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u78b3\u6c22\u5316\u7269\u7684\u9009\u62e9\u6027\u6c27\u5316\u662f\u975e\u5e38\u91cd\u8981\u7684\u751f\u4ea7\u9ad8\u9644\u52a0\u503c\u6c27\u5316\u4ea7\u7269\u7684\u5316\u5b66\u8fc7\u7a0b\u3002\u7136\u800c\uff0c\u7531\u4e8eC-H\u952e\u7684\u60f0\u6027\u4ee5\u53ca\u9644\u5e26\u53d1\u751f\u7684\u8fc7\u5ea6\u6c27\u5316\uff0c\u78b3\u6c22\u5316\u7269\u7684\u9009\u62e9\u6027\u6c27\u5316\u9762\u4e34\u7740\u8f6c\u5316\u7387\u4f4e\u548c\u9009…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2923,2480],"class_list":["post-148036","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2923","tag-2480"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/148036"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=148036"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/148036\/revisions"}],"predecessor-version":[{"id":149629,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/148036\/revisions\/149629"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=148036"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=148036"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=148036"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}