{"id":147451,"date":"2018-07-28T06:30:35","date_gmt":"2018-07-27T22:30:35","guid":{"rendered":"\/\/m.iemloyee.com\/?p=147451"},"modified":"2018-07-28T14:39:45","modified_gmt":"2018-07-28T06:39:45","slug":"%e5%8c%97%e7%a7%91%e5%a4%a7adv-funct-mater-%e9%87%91%e5%b1%9e%e9%92%b4-%e7%a2%b3%e5%a4%8d%e5%90%88%e6%9d%90%e6%96%99%e4%bd%9c%e4%b8%ba%e5%8f%af%e5%9b%9e%e6%94%b6%e5%92%8c%e5%8f%af%e9%80%86%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=147451","title":{"rendered":"\u5317\u79d1\u5927Small: \u91d1\u5c5e\u94b4-\u78b3\u590d\u5408\u6750\u6599\u4f5c\u4e3a\u53ef\u56de\u6536\u548c\u53ef\u9006\u7684\u78c1\u6027\u5149\u50ac\u5316\u5242\u7528\u4e8e\u9ad8\u6548\u51cf\u5c11\u4e8c\u6c27\u5316\u78b3\u6392\u653e"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/b><\/strong><\/p>\n

\u7531\u4e8e\u5316\u77f3\u71c3\u6599\u7684\u67af\u7aed\u548c\u65e5\u5e38\u9700\u6c42\u7684\u589e\u52a0\uff0c\u5de5\u4e1a\u751f\u4ea7\u548c\u65e5\u5e38\u751f\u6d3b\u76f8\u5173\u7684\u5927\u91cf\u4eba\u4e3a\u4e8c\u6c27\u5316\u78b3\u7684\u6392\u653e\u5bfc\u81f4\u4e86\u5168\u7403\u53d8\u6696\u548c\u73af\u5883\u5371\u673a\u3002\u56e0\u6b64\uff0c\u5c06\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u589e\u503c\u5316\u5b66\u71c3\u6599\u662f\u89e3\u51b3\u5f53\u524d\u548c\u672a\u6765\u80fd\u6e90\u4f9b\u5e94\u9700\u6c42\u7684\u8ff7\u4eba\u7684\u65b9\u6cd5\u3002\u592a\u9633\u80fd\u9a71\u52a8\u7684\u5149\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u6210\u5316\u5b66\u71c3\u6599\u88ab\u8ba4\u4e3a\u662f\u89e3\u51b3\u80fd\u6e90\u548c\u73af\u5883\u95ee\u9898\u7684\u6700\u4f73\u65b9\u6cd5\u4e4b\u4e00\u3002\u5c3d\u7ba1\u5df2\u7ecf\u62a5\u9053\u4e86\u8bb8\u591a\u592a\u9633\u80fd\u6d3b\u6027\u50ac\u5316\u5242\u7528\u4e8eCO2<\/sub>\u8fd8\u539f\uff0c\u4f46\u662f\u5b83\u4eec\u4e2d\u7684\u5927\u591a\u6570\u5177\u6709\u4f4e\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff0c\u4e0d\u53ef\u63a7\u5236\u7684\u9009\u62e9\u6027\u548c\u4e0d\u7a33\u5b9a\u6027\u3002\u975e\u5747\u76f8\u534a\u5bfc\u4f53\u50ac\u5316\u5242\u5728\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u4e2d\u8868\u73b0\u51fa\u8f83\u5dee\u7684\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u5bbd\u7684\u80fd\u5e26\u9699\u6027\u8d28\uff0c\u4ec5\u5141\u8bb8\u5438\u6536\u4e00\u5c0f\u90e8\u5206\u592a\u9633\u5149\u8c31\u3002\u540c\u65f6\uff0c\u5747\u76f8\u5206\u5b50\u50ac\u5316\u5242\u8fd8\u63d0\u4f9b\u4e86\u5149\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u7684\u66ff\u4ee3\u7b56\u7565\uff0c\u56e0\u4e3a\u5b83\u4eec\u5177\u6709\u66f4\u597d\u7684\u5149\u5229\u7528\u6548\u7387\u548c\u5bf9CO2<\/sub>\u8fd8\u539f\u7684\u4f4e\u6d3b\u5316\u8981\u6c42\u3002\u7136\u800c\uff0c\u5747\u76f8\u50ac\u5316\u4f53\u7cfb\u81ea\u8eab\u5b58\u5728\u4e00\u4e9b\u7f3a\u70b9\uff0c\u4f8b\u5982\u6d89\u53ca\u9ad8\u6210\u672c\uff0c\u8017\u65f6\u7684\u5408\u6210\u7a0b\u5e8f\uff0c\u4e0d\u7a33\u5b9a\u548c\u4e0d\u53ef\u91cd\u590d\u4f7f\u7528\uff0c\u8fd9\u4e25\u91cd\u963b\u788d\u4e86\u5b83\u4eec\u5728\u5149\u50ac\u5316\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u5177\u6709\u9ad8\u8f6c\u6362\u6548\u7387\u548c\u4e8c\u6c27\u5316\u78b3\u51cf\u6392\u9009\u62e9\u6027\u7684\u9ad8\u6d3b\u6027\u548c\u521b\u65b0\u578b\u5149\u50ac\u5316\u7cfb\u7edf\u7684\u8bbe\u8ba1\u548c\u5236\u9020\u4ecd\u7136\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe\u4e00\u00a0<\/b><\/strong>Co74s<\/b><\/strong>\u548c<\/b><\/strong>PMMCoCC-1200<\/b><\/strong>\u7684<\/b><\/strong>\u7269\u76f8\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

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\uff08e\uff09PMMCoCC-1200\u7684XRD\u56fe\u8c31\uff08\u63d2\u56fe\u662f\u91d1\u5c5e\u94b4\u7684\u6676\u4f53\u7ed3\u6784\uff09<\/p>\n

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\u56fe\u4e8c PMMCoCC-1200\u7684\u57fa\u672c\u7279\u6027<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

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\uff08b\uff09\u62c9\u66fc\u5149\u8c31\uff08\u6fc0\u53d1\u6ce2\u957f\u4e3a514nm\uff09<\/p>\n

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\uff08f\uff09\u78c1\u6ede\u56de\u7ebf\u56fe\u50cf<\/p>\n

\u56fe\u4e09\u00a0<\/b><\/strong>\u50ac\u5316\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/p>\n

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\uff08d\uff09\u57281mol L-1 HCl\u4e2d\u8680\u523b\u540e\uff0cPMMCoCC-1200\u5f97\u5230CO\u548cH2<\/sub><\/p>\n

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\uff08f\uff09\u57281200\u2103\u4e0b\u5728Ar\u6c14\u6c1b\u4e2d\u884d\u751f\u81eaFe-MOF74\uff0cNi-MOF74\uff0cMn-MOF74\u548cCo-Fe-MOF74\u7684\u78b3\u5316\u4ea7\u7269\u7528\u4e8e\u5149\u50ac\u5316<\/p>\n

\u56fe\u56db\u00a0<\/b><\/strong>\u50ac\u5316\u673a\u7406\u4e0e\u7406\u8bba\u8ba1\u7b97<\/b><\/strong><\/p>\n

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\uff08b\uff09\u80fd\u7ea7\u7684\u793a\u610f\u56fe\uff0c\u663e\u793a\u4eceRu(bpy)3<\/sub>\u00a02+<\/sup>\u5230PMMCoCC-1200\u7684\u7535\u5b50\u8f6c\u79fb\u3002 EF\uff1a\u8d39\u7c73\u6c34\u5e73; LUMO\uff1a\u6700\u4f4e\u672a\u5360\u5206\u5b50\u8f68\u9053; HOMO\uff1a\u6700\u9ad8\u5360\u636e\u5206\u5b50\u8f68\u9053<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/b><\/strong>Metallic Cobalt\u2013Carbon Composite as Recyclable and Robust Magnetic Photocatalyst for Efficient CO2 Reduction<\/b><\/u><\/strong><\/a>\u201d(<\/b><\/strong>Small<\/b><\/strong>. <\/b><\/strong>DOI: 10.1002\/smll.201800762<\/b><\/strong>)<\/b><\/strong><\/p>\n

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