{"id":147396,"date":"2018-07-27T06:30:07","date_gmt":"2018-07-26T22:30:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=147396"},"modified":"2018-07-26T22:08:25","modified_gmt":"2018-07-26T14:08:25","slug":"%e5%8d%97%e5%bc%80%e5%8d%9c%e6%98%be%e5%92%8cadv-energy-mater-mof%e8%a1%8d%e7%94%9f%e6%b0%ae%e6%8e%ba%e6%9d%82%e8%a4%b6%e7%9a%b1%e7%a2%b3%e7%ae%94%e5%9c%a8%e5%82%a8%e9%92%a0%e4%b8%ad%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=147396","title":{"rendered":"\u5357\u5f00\u535c\u663e\u548cAdv. Energy Mater. : MOF\u884d\u751f\u6c2e\u63ba\u6742\u8936\u76b1\u78b3\u7b94\u5728\u50a8\u94a0\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5177\u6709\u9ad8\u5ea6\u6709\u5e8f\u5b54\u9699\u548c\u5747\u5300\u91d1\u5c5e\u4f4d\u70b9\u7684\u91d1\u5c5e-\u6709\u673a\u6846\u67b6(MOF)\u662f\u7528\u4e8e\u6784\u5efa\u78b3\u6846\u67b6\u6750\u6599\u7684\u65b0\u578b\u524d\u9a71\u4f53\uff0c\u5176\u5177\u6709\u6613\u4e8e\u8c03\u8282\u7684\u7279\u70b9\u3002\u5176\u4e2d\uff0c2D MOF\u7eb3\u7c73\u7ed3\u6784\u5df2\u7ecf\u5f15\u8d77\u4e86\u5bf9\u6784\u5efaMOF\u884d\u751f\u78b3\u6750\u6599\u7684\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u5174\u8da3\u3002\u4e0e\u5757\u72b6MOF\u6676\u4f53\u76f8\u6bd4\uff0c2D MOF\u6750\u6599\u4f5c\u4e3a\u524d\u9a71\u4f53\u5177\u6709\u66f4\u591a\u4f18\u52bf\uff0c\u5982\u66f4\u5927\u7684\u8868\u9762\u79ef\u4ee5\u53ca\u66f4\u4e30\u5bcc\u7684\u6d3b\u6027\u4f4d\u70b9\u3002\u6b64\u5916\uff0c\u5b83\u4eec\u80fd\u591f\u5728\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u9632\u6b62\u6750\u6599\u805a\u96c6\uff0c\u5e76\u4e14\u6709\u5229\u4e8e\u6784\u5efa\u591a\u91cd\u5b54\u9699\u3002\u6700\u8fd1\u7684\u7814\u7a76\u8868\u660e\uff0c\u5c062D\u6750\u6599\u96c6\u6210\u52303D\u5b8f\u89c2\u7ed3\u6784\u4e2d\uff0c\u59823D\u5927\u5b54MXene\u30013D\u77f3\u58a8\u70ef\u548c3D\u4e8c\u786b\u5316\u94bc\uff0c\u53ef\u4ee5\u4e3a\u7535\u6781\u6750\u6599\u4e2d\u79bb\u5b50\u548c\u7535\u5b50\u4f20\u8f93\u4e0d\u826f\u7684\u95ee\u9898\u63d0\u4f9b\u826f\u597d\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u8fdb\u800c\u5236\u5907\u51fa\u9ad8\u6027\u80fd\u5668\u4ef6\u3002\u56e0\u6b64\uff0c\u6210\u529f\u5236\u59072D MOF\u884d\u751f\u78b3\u6750\u6599\u5c06\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5357\u5f00\u5927\u5b66\u535c\u663e\u548c\u6559\u6388(\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u5236\u5907\u4e86\u7531MOF\u7eb3\u7c73\u7247\u884d\u751f\u7684\u591a\u7ea7\u5b54\u6c2e\u63ba\u6742\u8936\u76b1\u78b3\u7b94\uff0c\u5c06\u5176\u7528\u4f5c\u9ad8\u6027\u80fd\u94a0\u50a8\u5b58\u6750\u6599\uff0c\u5e76\u5728Adv. Energy Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cNitrogen-Doped Wrinkled Carbon Foils Derived from MOF Nanosheets for Superior Sodium Storage<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u65b0\u578b\u6c2e\u63ba\u6742\u78b3\u7eb3\u7c73\u6750\u6599\u662f\u901a\u8fc7\u70ed\u89e32D \u9530\u57faMOF\u5408\u6210\u7684\u30022D MOF\u901a\u8fc7\u5355\u9f7f\u914d\u4f53\u76d0\u7684\u8f85\u52a9\u4ea7\u751f\uff0c\u4ee5\u5b9e\u73b0MOF\u7684\u5e73\u9762\u751f\u957f\u3002\u968f\u540e\u5728\u6c28\u6c14\u6c14\u6c1b\u4e0b\u70ed\u89e3\uff0c 2D MOF\u7684\u8868\u9762\u5f62\u6210Na2<\/sub>CO3<\/sub>\u7684\u4fdd\u62a4\u5c42\uff0c\u9530\u79bb\u5b50\u5219\u8f6c\u5316\u6210MnO\u9897\u7c92\u3002\u8fdb\u4e00\u6b65\u5730\u7528\u9178\u6eb6\u6db2\u4e2d\u6d17\u53bb\u4e8c\u8005\u5373\u53ef\u4ea7\u751f\u5206\u7ea7\u5b54\u9699\u548c\u901a\u9053\uff0c\u4ee5\u5141\u8bb8\u5feb\u901f\u7684\u79bb\u5b50\u4f20\u8f93\u3002\u6240\u5f97\u6750\u6599\u7528\u4f5c\u94a0\u79bb\u5b50\u7535\u5bb9\u5668\u8d1f\u6781\u6750\u6599\u65f6\u5c55\u73b0\u51fa\u9ad8\u500d\u7387\u6027\u80fd(\u7535\u6d41\u5bc6\u5ea6\u4e3a8\u548c10 A\u00b7g-1<\/sup>\u65f6\u5206\u522b\u4e3a165\u548c150 mA h\u00b7g-1<\/sup>)\uff0c\u9ad8\u7a33\u5b9a\u6027(1.0 A\u00b7g-1<\/sup> 1000\u6b21\u5faa\u73af\u540e\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a72.8%)\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 \u6c2e\u63ba\u6742\u8936\u76b1\u78b3\u7b94(NC-1)\u7684\u5236\u5907\u8fc7\u7a0b<\/strong><\/p>\n

\"\"<\/p>\n

\u7531\u5757\u4f53Mn-MOF\u5236\u5907\u6c2e\u63ba\u6742\u8936\u76b1\u78b3\u7b94(NC-1)\u7684\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 \u4e0d\u540c\u6750\u6599\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,e) \u5757\u4f53Mn-MOF\u7684SEM\u56fe\u50cf\u548cTEM\u56fe\u50cf\uff1b<\/p>\n

b,f) 2D Mn-MOF\u7684SEM\u56fe\u50cf\u548cTEM\u56fe\u50cf\uff0c\u5185\u63d2\u4e3a\u7535\u5b50\u884d\u5c04\u56fe\u50cf\uff1b<\/p>\n

c,g) MNC-1\u7684SEM\u56fe\u50cf\u548cTEM\u56fe\u50cf\uff1b<\/p>\n

d,h) NC-1\u7684SEM\u56fe\u50cf\u548cTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe3 NC-1\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b) NC-1\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

c,d) NC-1\u7684TEM\u548cHRTEM\u56fe\u50cf\u3002<\/p>\n

\u56fe4 \u4e0d\u540c\u6750\u6599\u7684\u5143\u7d20\u5206\u5e03<\/strong><\/p>\n

\"\"<\/p>\n

a) MNC-1\u7684STEM\u56fe\u50cf\u53ca\u5176\u76f8\u5e94\u7684EDS\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

b) NC-1\u7684STEM\u56fe\u50cf\u53ca\u5176\u76f8\u5e94\u7684EDS\u5143\u7d20\u5206\u5e03\u3002<\/p>\n

\u56fe5 \u6750\u6599\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5757\u4f53Mn-MOF\u30012D Mn-MOF\u3001MNC-1\u548cNC-1\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

b) NC-1\u3001MNC-1\u548c2D Mn-MOF\u7684FTIR\u5149\u8c31\uff1b<\/p>\n

c) NC-1\u548cMNC-1\u7684N2\u5438-\u8131\u9644\u66f2\u7ebf\uff1b<\/p>\n

d) NC-1\u548cMNC-1\u7684\u5b54\u5f84\u5c3a\u5bf8\u5206\u5e03\u3002<\/p>\n

\u56fe6 \u6750\u6599\u7684\u8868\u9762\u5143\u7d20\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) C-1\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

b) NC-2\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

c) NC-3\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

d) NC-1\u3001NC-2\u3001NC-3\u548cC-1\u7684N 1s XPS\u5149\u8c31\uff1b<\/p>\n

e) NC-1\u3001NC-2\u3001NC-3\u548cC-1\u7684C 1s XPS\u5149\u8c31\uff1b<\/p>\n

f) NC-1\u3001NC-2\u3001NC-3\u548cC-1\u7684Raman\u5149\u8c31\u3002<\/p>\n

\u56fe7 \u6750\u6599\u7684\u7535\u5316\u5b66\u50a8\u94a0\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) NC-1\u521d\u59cb5\u4e2a\u5faa\u73af\u7684CV\u66f2\u7ebf\uff0c\u5185\u63d2\u4e3aNC-1\u521d\u59cb\u5145-\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

b) NC-1\u3001C-1\u548cBC-1\u7684\u500d\u7387\u5bb9\u91cf\uff1b<\/p>\n

c) NC-1\u7535\u6781\u4e0e\u8fd1\u671f\u62a5\u9053\u7684\u5176\u4ed6\u78b3\u57fa\u7535\u6781\u500d\u7387\u5bb9\u91cf\u7684\u6bd4\u8f83\uff1b<\/p>\n

d) 1.0 A\u00b7g-1<\/sup>\u4e0bNC-1\u3001C-1\u548cBC-1\u5faa\u73af\u6027\u80fd\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7efc\u4e0a\u6240\u8ff0\uff0c\u4f5c\u8005\u63d0\u4f9b\u4e86\u4e00\u79cd\u4f7f\u75282D Mn-MOF\u4f5c\u4e3a\u524d\u9a71\u4f53\u5408\u6210\u5177\u6709\u591a\u7ea7\u5b54\u7ed3\u6784\u7684\u6c2e\u63ba\u6742\u76b1\u8936\u78b3\u7b94\u7684\u65b9\u6cd5\u3002\u5728\u6c28\u6c14\u6c14\u6c1b\u4e0b\u7684\u70ed\u89e3\u8fc7\u7a0b\u4e2d\u8bf1\u5bfc\u963b\u6321\u5242\u548c\u9530\u79bb\u5b50\u8f6c\u5316\u4e3aNa2<\/sub>CO3<\/sub>\u548cMnO\u7eb3\u7c73\u9897\u7c92\uff0c\u968f\u540e\u5728\u9178\u8680\u523b\u540e\u4ea7\u751f\u4e86\u4e30\u5bcc\u7684\u5b54\u9053\u3002\u8be5\u6750\u6599\u4e0d\u4ec5\u5c55\u73b0\u51fa\u8936\u76b1\u7684\u7ed3\u6784\uff0c\u800c\u4e14\u5176\u63ba\u6742\u6c2e\u6d3b\u6027\u4f4d\u70b9\u53ef\u8c03\u3002\u5229\u7528\u6709\u6548\u7684\u79bb\u5b50\u4f20\u8f93\u8def\u5f84\u4ee5\u53ca\u4e0d\u95f4\u65ad\u7684\u7535\u5b50\u4f20\u5bfc\u7f51\u7edc\uff0c\u6c2e\u63ba\u6742\u76b1\u8936\u78b3\u7b94\u7535\u6781\u80fd\u591f\u540c\u65f6\u5b9e\u73b0\u9ad8\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u8be5\u7b56\u7565\u4e3a\u5236\u5907\u53ef\u7528\u4e8e\u9ad8\u50a8\u80fd\u7cfb\u7edf\u7684\u6c2e\u63ba\u6742\u78b3\u7535\u6781\u7684\u901a\u7528\u6750\u6599\u8bbe\u8ba1\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aNitrogen-Doped Wrinkled Carbon Foils Derived from MOF Nanosheets for Superior Sodium Storage<\/a><\/strong>\u00a0(Adv. Energy Mater., 2018, DOI: 10.1002\/aenm.201801515)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5177\u6709\u9ad8\u5ea6\u6709\u5e8f\u5b54\u9699\u548c\u5747\u5300\u91d1\u5c5e\u4f4d\u70b9\u7684\u91d1\u5c5e-\u6709\u673a\u6846\u67b6(MOF)\u662f\u7528\u4e8e\u6784\u5efa\u78b3\u6846\u67b6\u6750\u6599\u7684\u65b0\u578b\u524d\u9a71\u4f53\uff0c\u5176\u5177\u6709\u6613\u4e8e\u8c03\u8282\u7684\u7279\u70b9\u3002\u5176\u4e2d\uff0c2D MOF\u7eb3\u7c73\u7ed3\u6784\u5df2\u7ecf\u5f15\u8d77\u4e86\u5bf9…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3446,3450],"class_list":["post-147396","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-mof","tag-3450"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/147396"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=147396"}],"version-history":[{"count":5,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/147396\/revisions"}],"predecessor-version":[{"id":147876,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/147396\/revisions\/147876"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=147396"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=147396"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=147396"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}