{"id":147130,"date":"2018-07-26T14:00:25","date_gmt":"2018-07-26T06:00:25","guid":{"rendered":"\/\/m.iemloyee.com\/?p=147130"},"modified":"2018-07-23T10:09:32","modified_gmt":"2018-07-23T02:09:32","slug":"%e6%b5%99%e6%b1%9f%e7%90%86%e5%b7%a5%e5%a4%a7%e5%ad%a6macromolecules%ef%bc%9a%e9%80%9a%e8%bf%87%e7%95%8c%e9%9d%a2%e9%9d%9e%e5%85%b1%e4%bb%b7%e7%9b%b8%e4%ba%92%e4%bd%9c%e7%94%a8%e6%9d%a5%e6%8f%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=147130","title":{"rendered":"\u6d59\u6c5f\u7406\u5de5\u5927\u5b66Macromolecules\uff1a\u901a\u8fc7\u754c\u9762\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u6765\u63d0\u9ad8\u805a\u82ef\u4e59\u70ef\u7684\u70ed\u7a33\u5b9a\u6027"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u56fa\u4f53\u57fa\u5e95\u4e0a\u5438\u9644\u7684\u9ad8\u5206\u5b50\u819c\u5728\u591a\u79cd\u524d\u8a00\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u548c\u4ef7\u503c\uff0c\u6bd4\u5982\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff0c\u751f\u7269\u4f20\u611f\u5668\uff0c\u534a\u5bfc\u4f53\u82af\u7247\u7b49\u3002\u7814\u7a76\u8868\u660e\u9ad8\u5206\u5b50\u94fe\u7684\u5c40\u90e8\u6784\u8c61\u548c\u677e\u5f1b\u5bf9\u9ad8\u5206\u5b50\u819c\u7684\u52a8\u529b\u5b66\u884c\u4e3a\u5177\u6709\u91cd\u8981\u7684\u5f71\u54cd\uff0c\u5c3d\u7ba1\u8fd9\u79cd\u5f71\u54cd\u8fd8\u6ca1\u6709\u5f97\u5230\u5b8c\u5168\u7684\u7406\u89e3\u3002\u4f17\u6240\u5468\u77e5\uff0c\u9664\u4e86\u8303\u5fb7\u534e\u76f8\u4e92\u4f5c\u7528\u4ee5\u5916\uff0c\u82ef\u73af\u4e4b\u95f4\u7684\u03c0\u2212\u03c0\u76f8\u4e92\u4f5c\u7528\u4e5f\u662f\u5f71\u54cd\u5206\u5b50\u7ec4\u88c5\u548c\u6750\u6599\u52a8\u529b\u5b66\u884c\u4e3a\u7684\u4e00\u4e2a\u91cd\u8981\u56e0\u7d20\u3002\u7136\u800c\uff0c\u591a\u6570\u7684\u7814\u7a76\u90fd\u805a\u7126\u5728\u529f\u80fd\u57fa\u56e2\u4e4b\u95f4\u7684\u5316\u5b66\u76f8\u4e92\u4f5c\u7528\uff0c\u5bf9\u754c\u9762\u4e0a\u9ad8\u5206\u5b50\u6750\u6599\u4e2d\u7684\u03c0\u2212\u03c0\u76f8\u4e92\u4f5c\u7528\u7814\u7a76\u751a\u5c11\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6d59\u6c5f\u7406\u5de5\u5927\u5b66\u738b\u65b0\u5e73\u6559\u6388<\/strong>\u8bfe\u9898\u7ec4\u4e0e\u65e5\u672c\u4e5d\u5dde\u5927\u5b66<\/strong>Keiji Tanaka<\/strong>\u6559\u6388<\/strong>\u5408\u4f5c\uff0c\u5229\u7528\u4e00\u79cd\u5148\u8fdb\u7684\u754c\u9762\u8868\u5f81\u6280\u672f\u548c\u9891\u751f\u6210\uff08SFG\uff09\u632f\u52a8\u5149\u8c31\u6765\u8003\u5bdf\u57fa\u5e95\u4e0a\u805a\u82ef\u4e59\u70ef\u6750\u6599\u4e2d\u7684\u03c0\u2212\u03c0\u76f8\u4e92\u4f5c\u7528\uff0c\u5e76\u9610\u8ff0\u4e86\u03c0\u2212\u03c0\u76f8\u4e92\u4f5c\u7528\u5bf9\u4e8e\u5438\u9644\u5728\u57fa\u5e95\u8868\u9762\u4e0a\u805a\u82ef\u4e59\u70ef\u5206\u5b50\u94fe\u7684\u5c40\u90e8\u6784\u8c61\u548c\u677e\u5f1b\u7684\u5f71\u54cd\u3002\u56e0\u6b64\uff0c\u8be5\u7814\u7a76\u63ed\u793a\u4e86\u754c\u9762\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u5728\u8c03\u63a7\u754c\u9762\u5206\u5b50\u7ed3\u6784\u548c\u52a8\u529b\u5b66\u884c\u4e3a\u65b9\u65b9\u9762\u7684\u4f5c\u7528\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Enhanced Thermal Stability of Polystyrene by Interfacial Noncovalent Interactions”<\/strong>\u53d1\u8868\u5728\u9ad8\u5206\u5b50\u9886\u57df\u8457\u540d\u671f\u520aMacromolecules<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\u82ef\u57fa\u4e09\u7532\u6c27\u57fa\u7845\u70f7(PTS)\u4fee\u9970\u57fa\u5e95\u7684\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5177\u6709\u4e0d\u540c\u82ef\u57fa\u542b\u91cf\u7684PTS\u4fee\u9970\u57fa\u5e95\u7684XPS\u8c31\u56fe\uff1b<\/p>\n

(b) \u5177\u6709\u4e0d\u540c\u82ef\u57fa\u542b\u91cf\u7684PTS\u4fee\u9970\u57fa\u5e95\u7684SFG\u8c31\u56fe\u3002<\/p>\n

\u56fe2 \u5438\u9644\u5728PTS\u4fee\u9970\u57fa\u5e95\u4e0a\u805a\u82ef\u4e59\u70ef(PS)\u94fe\u7684\u5c40\u90e8\u6784\u8c61<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u805a\u82ef\u4e59\u70ef\u5438\u9644\u5c42\u7684\u539a\u5ea6\u4e0e\u57fa\u5e95\u8868\u9762\u4e0a\u82ef\u57fa\u542b\u91cf\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

(b) PTS\u4fee\u9970\u57fa\u5e95\u4e0a\u5355\u5206\u6563\u805a\u82ef\u4e59\u70ef(h<\/em>PS)\u5438\u9644\u5c42\u7684SFG\u8c31\u56fe\u3002<\/p>\n

\u56fe3 \u6c18\u4ee3\u805a\u82ef\u4e59\u70ef\u5438\u9644\u5c42\u7684\u8868\u5f81\u53ca\u94fe\u6784\u8c61\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u672a\u4fee\u9970\u548c\u4fee\u9970PTS\u57fa\u5e95\u4e0a\u5438\u9644\u6c18\u4ee3\u805a\u82ef\u4e59\u70ef\u7684SFG\u8c31\u56fe\uff1b<\/p>\n

(b) \u57fa\u5e95\u8868\u9762\u4e0a\u5438\u9644\u805a\u82ef\u4e59\u70ef\u7684\u7ec3\u6784\u8c61\u793a\u610f\u56fe\uff1b<\/p>\n

(c) \u672a\u4fee\u9970\u548c\u4fee\u9970PTS\u57fa\u5e95\u4e0a\u5438\u9644\u6c18\u4ee3\u805a\u82ef\u4e59\u70efSFG\u8c31\u56fe\u4e2dC-D\u57fa\u56e2\u533a\u57df\u7684\u653e\u5927\u56fe\u3002<\/p>\n

\u56fe<\/strong>4 PTS-0<\/strong>\u548c<\/strong>PTS-4<\/strong>\u57fa\u5e95\u4e0a\u805a\u82ef\u4e59\u70ef\u5438\u9644\u5c42\u7684\u8868\u9762\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

(a) PTS-0\u57fa\u5e95\u4e0a1.9\u7eb3\u7c73\u539a\u5ea6\u5438\u9644\u5c42\u7684AFM\u56fe\u50cf\uff1b<\/p>\n

(b) PTS-4\u57fa\u5e95\u4e0a3.5\u7eb3\u7c73\u539a\u5ea6\u5438\u9644\u5c42\u7684AFM\u56fe\u50cf\uff1b<\/p>\n

(c) PTS-4\u57fa\u5e95\u4e0a2.2\u7eb3\u7c73\u539a\u5ea6\u5438\u9644\u5c42\u7684AFM\u56fe\u50cf\u3002<\/p>\n

\u56fe5 PTS-0\u548cPTS-4\u57fa\u5e95\u4e0a\u6c18\u4ee3\u805a\u82ef\u4e59\u70ef\u5438\u9644\u5c42\u7684SFG ssp\u8c31\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) PTS-0\u548cPTS-4\u57fa\u5e95\u4e0a\u6c18\u4ee3\u805a\u82ef\u4e59\u70ef\u5438\u9644\u5c42\u5728\u6709\u65e0433K\u70ed\u5904\u740648\u5c0f\u65f6\u6761\u4ef6\u4e0b\u7684SFG ssp\u8c31\u56fe\uff1b<\/p>\n

(b) PTS-0\u548cPTS-4\u57fa\u5e95\u4e0a\u6c18\u4ee3\u805a\u82ef\u4e59\u70ef\u5438\u9644\u5c42\u5728\u6709\u65e0433K\u70ed\u5904\u740648\u5c0f\u65f6\u6761\u4ef6\u4e0b\u7684\u7684SFG ssp\u8c31\u56fe\u3002<\/p>\n

\u56fe6 PTS\u4fee\u9970\u57fa\u5e95\u4e0a\u805a\u82ef\u4e59\u70ef\u8584\u819c\u7684\u70ed\u81a8\u80c0\u884c\u4e3a<\/strong><\/p>\n

\"\"<\/p>\n

\u8be5\u56fe\u663e\u793a\u5177\u6709\u4e0d\u540c\u82ef\u57fa\u542b\u91cf\u7684PTS\u4fee\u9970\u57fa\u5e95\u4e0a\u805a\u82ef\u4e59\u70ef\u8584\u819c\u572812\u7eb3\u7c73\u539a\u5ea6\u6761\u4ef6\u4e0b\u5f52\u4e00\u5316\u539a\u5ea6\u5bf9\u6e29\u5ea6\u4f9d\u8d56\u6027\uff0c\u7ed3\u679c\u8868\u660e\u7531\u4e8e\u70ed\u81a8\u80c0\u884c\u4e3a\u5bfc\u81f4\u968f\u7740\u6e29\u5ea6\u5347\u9ad8\u8584\u819c\u7684\u539a\u5ea6\u4e5f\u968f\u4e4b\u589e\u5927\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u5229\u7528\u548c\u9891\u751f\u6210\u632f\u52a8\u5149\u8c31\u8868\u5f81\u4e86\u5728\u8986\u76d6\u6709\u82ef\u57fa\u7684\u4e8c\u6c27\u5316\u7845\u57fa\u5e95\u4e0a\u5438\u9644\u7684\u805a\u82ef\u4e59\u70ef\u5206\u5b50\u94fe\u7684\u5c40\u90e8\u6784\u8c61\uff0c\u5e76\u9996\u6b21\u8bc1\u5b9e\u57fa\u5e95\u8868\u9762\u548c\u9ad8\u5206\u5b50\u529f\u80fd\u57fa\u56e2\u4e4b\u95f4\u5b58\u5728\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u3002\u7814\u7a76\u7ed3\u679c\u03c0\u2212\u03c0\u76f8\u4e92\u4f5c\u7528\u80fd\u591f\u964d\u4f4e\u805a\u82ef\u4e59\u70ef\u5206\u5b50\u94fe\u7684\u81ea\u7531\u80fd\uff0c\u4ece\u800c\u5b9e\u73b0\u4e86\u805a\u82ef\u4e59\u70ef\u5206\u5b50\u94fe\u5728\u57fa\u5e95\u8868\u9762\u7684\u8fdb\u4e00\u6b65\u7a33\u5b9a\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u5c06\u80fd\u591f\u4fc3\u8fdb\u7406\u89e3\u57fa\u5e95\u754c\u9762\u4e0a\u9ad8\u5206\u5b50\u94fe\u7684\u805a\u96c6\u7ed3\u6784\u548c\u52a8\u529b\u5b66\u884c\u4e3a\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aEnhanced Thermal Stability of Polystyrene by Interfacial Noncovalent Interactions<\/a>\u00a0(Macromolecules 2018, DOI: 10.1021\/acs.macromol.8b01012)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u548c\u751f\u7269\u5b66\u672f\u7ec4Gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u5ba1\u6838\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u7ad9\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u53ca\u884c\u4e1a\u4ece\u4e1a\u5458\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaorenkefu\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/a>\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong>\u00a0<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u56fa\u4f53\u57fa\u5e95\u4e0a\u5438\u9644\u7684\u9ad8\u5206\u5b50\u819c\u5728\u591a\u79cd\u524d\u8a00\u9886\u57df\u5177\u6709\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u548c\u4ef7\u503c\uff0c\u6bd4\u5982\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff0c\u751f\u7269\u4f20\u611f\u5668\uff0c\u534a\u5bfc\u4f53\u82af\u7247\u7b49\u3002\u7814\u7a76\u8868\u660e\u9ad8\u5206\u5b50\u94fe\u7684\u5c40\u90e8\u6784\u8c61\u548c\u677e\u5f1b\u5bf9\u9ad8\u5206\u5b50…<\/p>\n","protected":false},"author":7746,"featured_media":147133,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3436,42],"class_list":["post-147130","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-3436","tag-gaofenzi"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/147130"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7746"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=147130"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/147130\/revisions"}],"predecessor-version":[{"id":147311,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/147130\/revisions\/147311"}],"wp:featuredmedia":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/media\/147133"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=147130"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=147130"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=147130"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}