{"id":147024,"date":"2018-07-31T06:30:30","date_gmt":"2018-07-30T22:30:30","guid":{"rendered":"\/\/m.iemloyee.com\/?p=147024"},"modified":"2018-07-30T18:11:54","modified_gmt":"2018-07-30T10:11:54","slug":"%e3%80%90%e6%b5%8b%e8%af%95%e6%8a%80%e6%9c%af%e4%b8%93%e6%a0%8f%e3%80%91%e7%94%b5%e5%8c%96%e5%ad%a6%e5%be%aa%e7%8e%af%e4%bc%8f%e5%ae%89%e6%b3%95%e5%89%96%e6%9e%90","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=147024","title":{"rendered":"\u3010\u6d4b\u8bd5\u6280\u672f\u4e13\u680f\u3011\u7535\u5316\u5b66\u5faa\u73af\u4f0f\u5b89\u6cd5\u5256\u6790"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-148186\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/ceshi-s-2.png\" alt=\"\" width=\"700\" height=\"388\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/ceshi-s-2.png 700w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/ceshi-s-2-300x166.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" 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KNO<sub>3<\/sub>\uff0c\u4f5c\u4e3a\u652f\u6301\u7535\u89e3\u8d28\u3002\u652f\u6301\u7535\u89e3\u8d28\u7684\u6d53\u5ea6\u5b9e\u9645\u4e0a\u4e5f\u5bf9\u5b9e\u9a8c\u6709\u5f71\u54cd\uff0c\u6b64\u5904\u6682\u4e0d\u8003\u8651)\u3002\u63d2\u5165\u5de5\u4f5c\u7535\u6781\u3001\u94c2\u4e1d\u8f85\u52a9\u7535\u6781\u548c\u9971\u548c\u7518\u6c5e\u7535\u6781\u3002\u8bbe\u7f6e\u7535\u5316\u5b66\u5de5\u4f5c\u7ad9\u4e2d\u7684\u53c2\u6570\uff0c\u53c2\u6570\u7684\u8bbe\u5b9a\u9700\u8981\u4e0d\u65ad\u7684\u5c1d\u8bd5\uff0c\u6839\u636e\u7535\u5316\u5b66\u5de5\u4f5c\u7ad9\u7a97\u53e3\u663e\u793a\u7684\u56fe\u5f62\u8c03\u8282\u51fa\u5408\u9002\u7684\u53c2\u6570\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-147026 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/\u56fe\u72476-9.png\" alt=\"\" width=\"600\" height=\"523\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/\u56fe\u72476-9.png 600w, 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center;\"><strong><b>\u56fe\u4e00<\/b><\/strong><strong><b>\uff1aK<\/b><\/strong><strong><sub><b>3<\/b><\/sub><\/strong><strong><b>Fe(CN)<\/b><\/strong><strong><sub><b>6<\/b><\/sub><\/strong><strong><b>\u6eb6\u6db2\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/b><\/strong><\/p>\n<p>\u56fe\u4e00\u7684<em><i>i-E<\/i><\/em>\u66f2\u7ebf\u5373\u4e3a\u5faa\u73af\u4f0f\u5b89\u56fe\u3002\u4ece\u5faa\u73af\u4f0f\u5b89\u56fe\u4e2d\u53ef\u4ee5\u770b\u51fa\u6709\u4e24\u4e2a\u5cf0\u7535\u6d41\u548c\u4e24\u4e2a\u5cf0\u7535\u4f4d\uff0c\u9634\u6781\u5cf0\u7535\u6d41<em><i>i<\/i><\/em>pc\uff0c\u5cf0\u7535\u4f4d\u4ee5<em><i>E<\/i><\/em>pc(jpc)\u8868\u793a\uff1b\u9633\u6781\u5cf0\u7535\u6d41<em><i>i<\/i><\/em>pa\uff0c\u5cf0\u7535\u4f4d\u4ee5<em><i>E<\/i><\/em>pa\u8868\u793a\u3002<em><i>i<\/i><\/em>pc\u6216<em><i>i<\/i><\/em>pa\u7684\u4e0b\u6807\u7684a\u4ee3\u8868anode\uff0cc\u4ee3\u8868cathode\u3002\u6211\u4eec\u53ef\u77e5\u9053\uff0c<em><i>\u0394E<\/i><\/em>p=<em><i>E<\/i><\/em>pa-<em><i>E<\/i><\/em>pc=56\/n\uff08\u5355\u4f4d\uff1amV\uff09\uff08n\u4e3a\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u7684\u5f97\u5931\u7535\u5b50\u6570\uff09\uff0c<em><i>i<\/i><\/em>pc\u4e0e<em><i>i<\/i><\/em>pa\u7684\u6bd4\u503c\u8d8a\u63a5\u8fd1\u4e8e1\uff0c\u5219\u8be5\u4f53\u7cfb\u7684\u53ef\u9006\u7a0b\u5ea6\u5c31\u8d8a\u9ad8\u3002\u8fd9\u662f\u5224\u65ad\u53ef\u9006\u4f53\u7cfb\u7684\u6700\u76f4\u63a5\u7684\u65b9\u6cd5\u3002<\/p>\n<p>\u4ece\u7535\u5316\u5b66\u5de5\u4f5c\u7ad9\u7684\u5de5\u4f5c\u754c\u9762\uff0c\u53ef\u4ee5\u5f97\u51fa\u6c27\u5316\u5cf0\u7535\u4f4d\u4e3a<em><i>E<\/i><\/em>pa=227mV,\u5cf0\u7535\u6d41\u4e3a<em><i>i<\/i><\/em>pa=-1.91\u00b410<sup>-6<\/sup>A\uff1b\u8fd8\u539f\u5cf0\u7535\u4f4d\u662f<em><i>E<\/i><\/em>pc=170mV\uff0c\u5cf0\u7535\u6d41\u662f<em><i>i<\/i><\/em>pc=1.9\u00b410<sup>-6<\/sup>A\u3002\u6c27\u5316\u5cf0\u4e0e\u8fd8\u539f\u5cf0\u7535\u4f4d\u5dee\u4e3a57mV\uff08\u76f4\u63a5\u6bd4\u8f83\u6a2a\u5750\u6807\u6570\u503c\u5373\u53ef\uff09\uff0c\u5cf0\u7535\u6d41\u7684\u6bd4\u503c\u4e3a\uff1a<em><i>i<\/i><\/em>pa\/<em><i>i<\/i><\/em>pc=1.005\u22481\u3002\u7531\u6b64\u53ef\u77e5\uff0cpH=7\u65f6\uff0c\u94c1\u6c30\u5316\u94be\u4f53\u7cfb\uff08Fe(CN)<sub>6<\/sub><sup>3-\/4-<\/sup>\uff09\u7684\u7535\u5316\u5b66\u53cd\u5e94\u662f\u4e00\u4e2a\u53ef\u9006\u8fc7\u7a0b\u3002\uff08\u901a\u5e38\u90fd\u662f\u501f\u52a9\u8be5\u4f53\u7cfb\u4e0e\u5176\u5b83\u4f53\u7cfb\u8fdb\u884c\u6bd4\u8f83\uff0c\u9274\u522b\u7535\u6781\u7684\u4f18\u52a3\u4ee5\u53ca\u53cd\u5e94\u53ef\u9006\u7a0b\u5ea6\uff09\u3002<\/p>\n<p>\u63a5\u4e0b\u6765\uff0c\u6211\u4eec\u6765\u7814\u7a76\u626b\u901f\u4e0e\u5cf0\u7535\u6d41\u53ca\u5cf0\u7535\u4f4d\u7684\u5173\u7cfb\u3002\u672c\u5b9e\u9a8c\u5ba4\u901a\u5e38\u9009\u62e9\u94c1\u6c30\u5316\u94be\u4f5c\u4e3a\u5b9e\u9a8c\u5bf9\u8c61\u3002\u4e0d\u540c\u626b\u63cf\u901f\u7387100\u3001200\u3001300\u3001400mV\/s\uff0c\u5206\u522b\u8bb0\u5f55\u4ece-200\uff5e+600mV\u626b\u63cf\u7684\u5faa\u73af\u4f0f\u5b89\u56fe\u3002\u8bb0\u5f55\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\uff0c\u89c2\u5bdf\u5cf0\u7535\u4f4d\u548c\u5cf0\u7535\u6d41\uff0c\u5224\u65ad\u7535\u6781\u6d3b\u6027\u3002<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-147027 aligncenter\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/\u56fe\u72477-5.png\" alt=\"\" width=\"600\" height=\"434\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/\u56fe\u72477-5.png 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/\u56fe\u72477-5-300x217.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p style=\"text-align: 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