{"id":146660,"date":"2018-07-21T14:00:15","date_gmt":"2018-07-21T06:00:15","guid":{"rendered":"\/\/m.iemloyee.com\/?p=146660"},"modified":"2018-07-19T14:18:58","modified_gmt":"2018-07-19T06:18:58","slug":"%e5%86%af%e6%96%b0%e4%ba%aenat-commun-%ef%bc%9a%e9%93%81%e7%a3%81%e4%ba%8c%e7%bb%b4%e9%87%91%e5%b1%9e%e6%a1%86%e6%9e%b6%ef%bc%882d-mof%ef%bc%89%e5%8d%8a%e5%af%bc%e4%bd%93","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=146660","title":{"rendered":"\u51af\u65b0\u4eaeNat. Commun.\uff1a\u94c1\u78c1\u4e8c\u7ef4\u91d1\u5c5e\u6846\u67b6\uff082D MOF\uff09\u534a\u5bfc\u4f53"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08metal-organic framework, MOF\uff09\u662f\u7531\u91d1\u5c5e\u79bb\u5b50\u6216\u56e2\u7c07\u548c\u6709\u673a\u914d\u4f53\u7ec4\u88c5\u800c\u6210\u7684\u4e00\u7c7b\u6676\u6001\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\u3002\u5176\u5177\u6709\u9ad8\u6bd4\u8868\u9762\u79ef\u3001\u7ed3\u6784\u548c\u529f\u80fd\u591a\u6837\u53ef\u63a7\u7b49\u7279\u6027\uff0c\u56e0\u800c\u53d7\u5230\u4e86\u5e7f\u6cdb\u7684\u5173\u6ce8\u3002\u8fd1\u4e9b\u5e74\u6765\uff0cMOFs\u5728\u6c14\u4f53\u5b58\u50a8\u3001\u5206\u79bb\u3001\u50ac\u5316\u4ee5\u53ca\u6c34\u51c0\u5316\u7b49\u8bf8\u591a\u9886\u57df\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\uff0c\u5982\u4f55\u63d0\u9ad8MOF \u7684\u5bfc\u7535\u6027\u5e76\u8d4b\u4e88\u5176\u78c1\u6027\u3001\u534a\u5bfc\u4f53\u7b49\u6027\u8d28\uff0c\u4f7f\u4e4b\u5728\u7535\u5b50\u3001\u78c1\u5b66\u5668\u4ef6\u9886\u57df\u6709\u6240\u4f5c\u4e3a\u4ecd\u7136\u5177\u6709\u6311\u6218\u6027\uff0c\u4e5f\u6210\u4e3a\u4f17\u591a\u5316\u5b66\u5bb6\u3001\u6750\u6599\u5b66\u5bb6\u548c\u7269\u7406\u5b66\u5bb6\u7684\u7814\u7a76\u76ee\u6807\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u5fb7\u56fd\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\u7684\u51af\u65b0\u4eae\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u548c\u8463\u4eba\u8c6a\u535a\u58eb\uff08\u7b2c\u4e00\u4f5c\u8005\uff09<\/strong>\u7b49\u5728Nat. Commun.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3aA coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior<\/strong>\u7684\u6587\u7ae0\uff0c\u8be5\u56e2\u961f\u91c7\u7528\u6eb6\u5242\u70ed\u6cd5\u4f7f\u7528\u5168\u786b\u9187\u5316\u7684\u516d\u82ef\u5e76\u82ef(perthiolated coronene, PTC)\u4f5c\u4e3a\u914d\u4f53\u4e0e\u94c1\u76d0\u7edc\u5408\uff0c\u5408\u6210\u5177\u6709\u5c42\u5806\u53e0\u7ed3\u6784\u7684\u516d\u65b9\u6709\u5e8f\u7684\u4e8c\u7ef4MOF\u6750\u6599(PTC-Fe)\u3002\u7531\u4e8e\u5927\u03c0\u5e73\u9762\u5206\u5b50\u548c\u56db\u65b9\u5e73\u9762FeS4<\/sub>\u8282\u70b9\u7684\u7ed3\u5408\uff0c\u8be52D MOF\u8868\u73b0\u51fa\u9ad8\u5ea6\u7684\u03c0-d\u5171\u8f6d\u548c\u7535\u5b50\u5168\u79bb\u57df\u5316\u3002\u8303\u5fb7\u5821\u56db\u70b9\u6d4b\u91cf\u6cd5(van der Pauw method)\u8868\u660e\u8be52D MOF\u5728300 K\u65f6\u5177\u6709~10 S cm-1<\/sup>\u7684\u9ad8\u5bfc\u7535\u7387\uff0c\u5e76\u8868\u73b0\u51fa\u5178\u578b\u7684\u534a\u5bfc\u4f53\u6027\u8d28\u3002\u7406\u8bba\u8ba1\u7b97(DFT method)\u8868\u660e\u5355\u5c42\u7684PTC-Fe\u5177\u6709~0.2 eV\u7684\u5e26\u9699\u3002\u53d8\u6e29\u78c1\u5316\u7387\u548c57<\/sup>Fe\u7a46\u65af\u5821\u5c14\u8c31\u6d4b\u91cf\u8bc1\u660e\u4e86PTC-Fe\u4e2d\u7eb3\u7c73\u78c1\u6027\u56e2\u7c07\u572820 K\u4ee5\u4e0b\u7684\u94c1\u78c1\u6027\u6f14\u53d8\u3002\u8fd9\u4e00\u94c1\u78c1\u884c\u4e3a\u662f\u7531\u4e8eFe\u4e2d\u5fc3\u81ea\u65cb\u7535\u5b50\u901a\u8fc7\u79bb\u57df\u03c0\u7535\u5b50\u7684\u95f4\u63a5\u4ea4\u6362\u76f8\u4e92\u4f5c\u7528\u53d1\u751f\u8026\u5408\u800c\u5bfc\u81f4\u3002\u4ed6\u4eec\u7684\u7ed3\u679c\u8868\u660e\uff0c\u5171\u8f6d2D MOF\u5177\u6709\u4f5c\u4e3a\u65b0\u4e00\u4ee3\u94c1\u78c1\u534a\u5bfc\u4f53\u7684\u6f5c\u529b\uff0c\u5728\u81ea\u65cb\u7535\u5b50\u5b66\u5e94\u7528\u4e2d\u5177\u6709\u8bf1\u4eba\u7684\u524d\u666f\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1<\/strong>\uff1a<\/strong>PTC-Fe 2D MOF<\/strong>\u7684\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a): \u00a0PTC-Fe\u7684\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

(b): \u5b9e\u9a8c\u548c\u6a21\u62dfPXRD\u7ed3\u679c\uff1b<\/p>\n

(c): \u4f4e\u500d\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c\uff08TEM\uff09\u56fe\u50cf\uff1b\u63d2\u56fe\uff1a\u7535\u5b50\u884d\u5c04\u56fe\u6848\uff1b<\/p>\n

(d): \u9ad8\u5206\u8fa8\u7387\u7684\u5e73\u9762\u7ed3\u6784TEM\u56fe\u50cf\uff1b\u63d2\u56fe\uff1a\u5085\u91cc\u53f6\u53d8\u6362\u56fe\u6848\uff1b<\/p>\n

(e):\u9ad8\u5206\u8fa8\u7387\u7684\u4fa7\u89c6\u7ed3\u6784TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong>2<\/strong>\uff1a<\/strong>PTC-Fe 2D MOF<\/strong>\u7684\u7ec4\u6210\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a): \u00a0PTC-Fe\u53ca\u5176\u5bf9\u6bd4\u6837\u54c1\u7684XANES\u5149\u8c31\uff1b<\/p>\n

(b): PTC-Fe\u53ca\u5176\u5bf9\u6bd4\u6837\u54c1Fe2<\/sub>O3<\/sub>\u548cTTB-Fe\u4e2dFe K\u8fb9\u7f18\u5904\u7684EXAFS\u5085\u91cc\u53f6\u53d8\u6362\u5149\u8c31\uff1b<\/p>\n

(c) \u548c\uff08d\uff09: 294 K\u548c5 K\u4e0b\u768457<\/sup>Fe M\u00f6ssbauer\u5149\u8c31\u3002<\/p>\n

\u56fe<\/strong>3<\/strong>\uff1a\u8d39\u7c73\u80fd\u7ea7\u9644\u8fd1<\/strong>PTC-Fe<\/strong>\u7684\u7535\u5b50\u80fd\u5e26\u7ed3\u6784\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

(a): \u5355\u5c42PTC-Fe\u7684\u603b\u6001\u5bc6\u5ea6\uff1b<\/p>\n

(b): \u5355\u5c42PTC-Fe\u81ea\u65cb\u5411\u4e0a\u548c\u81ea\u65cb\u5411\u4e0b\u7684\u603b\u6001\u5bc6\u5ea6\uff1b<\/p>\n

(c): AB\u5c42\u5806\u53e0PTC-Fe\u7684\u603b\u6001\u5bc6\u5ea6\uff1b<\/p>\n

(d): AB\u5c42\u5806\u53e0PTC-Fe\u7684\u81ea\u65cb\u5411\u4e0a\u548c\u81ea\u65cb\u5411\u4e0b\u7684\u603b\u6001\u5bc6\u5ea6\u3002<\/p>\n

\u56fe<\/strong>4<\/strong>\uff1a<\/strong>PTC-Fe 2D MOF<\/strong>\u7684\u7535\u5b50\u5bfc\u7535\u6027\u6d4b\u91cf<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

(a): \u7535\u5bfc\u7387\uff08\u03c3\uff09\u4e0e\u6e29\u5ea6\u5173\u7cfb\u66f2\u7ebf\uff1b\u63d2\u56fe\uff1a\u538b\u7247\u6837\u54c1\u56fe\u3002<\/p>\n

(b): \u7535\u5bfc\u7387\uff08ln<\/em>\u03c3\uff09\u4e0e\u6e29\u5ea6\u5012\u6570\u7684\u5173\u7cfb\u66f2\u7ebf\u3002\u6d3b\u5316\u80fd0.2 eV\u3002\u63d2\u56fe\uff1aln\u03c3 \u4e0eT-1\/4<\/sup>\u572865-130K\u6e29\u5ea6\u8303\u56f4\u533a\u95f4\u7684\u5173\u7cfb\u66f2\u7ebf\uff0c\u7b26\u5408Mott-VRH\u6a21\u578b\u3002<\/p>\n

\u56fe<\/strong>5<\/strong>\uff1a<\/strong>PTC-Fe<\/strong>\u7684\u78c1\u6027\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a): \u4e0d\u540c\u6e29\u5ea6\u4e0b\u53d8\u78c1\u573a\uff08H\uff09\u7684\u78c1\u5316\u7387\u53d8\u5316\u66f2\u7ebf\uff1b<\/p>\n

(b): \u5728\u573a\u51b7\uff08FC\uff09\u548c\u96f6\u573a\u51b7\u5374\uff08ZFC\uff09\u6761\u4ef6\u4e0b\uff0c PTC-Fe\u7684\u78c1\u5316\u7387\u4e0e\u6e29\u5ea6\u53d8\u5316\u7684\u5173\u7cfb\u66f2\u7ebf\u3002\u63d2\u56fe\uff1a\u53d8\u6e29\u5269\u4f59\u78c1\u5316\u5f3a\u5ea6\u6d4b\u91cf\uff1b<\/p>\n

(c): PTC-Fe\u7684\u94c1\u78c1\u6001\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u56e2\u961f\u5408\u6210\u4e86\u4e00\u79cd\u57fa\u4e8e\u5168\u786b\u9187\u5316\u516d\u82ef\u4e19\u82ef\uff08PTC\uff09\u548cFe\u91d1\u5c5e\u4e2d\u5fc3\u7684\u5171\u8f6d2D MOF\uff0c\u5176\u5728\u5ba4\u6e29\u4e0b\u5177\u6709\u8f83\u9ad8\u7684\u5bfc\u7535\u7387\uff0c\u5e76\u5c55\u73b0\u51fa\u5178\u578b\u7684\u534a\u5bfc\u4f53\u6027\u8d28\u548c\u4f4e\u6e29\u94c1\u78c1\u884c\u4e3a\u3002\u7ee7\u800c\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u5408\u6210\u5177\u6709\u9ad8\u5ea6\u79bb\u57df\u03c0\u7535\u5b50\u76842D MOF\u662f\u5f00\u53d1\u65b0\u578b\u94c1\u78c1MOF\u534a\u5bfc\u4f53\u7684\u6709\u6548\u65b9\u6cd5\u3002\u5b9e\u9a8c\u7ed3\u679c\u6709\u671b\u6fc0\u53d1\u79d1\u7814\u4eba\u5458\u5bf9MOF\u6750\u6599\u5728\u94c1\u78c1\u548c\u534a\u5bfc\u4f53\u7279\u6027\u4ee5\u53ca\u81ea\u65cb\u7535\u5b50\u5e94\u7528\u8fdb\u884c\u66f4\u591a\u7684\u7269\u7406\u7814\u7a76\uff0c\u5e76\u901a\u8fc7\u7ed3\u5408\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u65b9\u6cd5\uff08CVD\uff09\u548c\u754c\u9762\u534f\u52a9\u5408\u6210\u65b9\u6cd5\uff08interface-assisted synthesis\uff09\u751f\u957f\u5355\u6676MOF\u6216\u539a\u5ea6\u53ef\u8c03\u3001\u5927\u5c3a\u5bf8\u6676\u7574\u7684\u4e8c\u7ef4MOF\u8584\u819c\u4ee5\u8fdb\u4e00\u6b65\u5b9e\u73b0\u5176\u4f18\u5f02\u7684\u7535\u78c1\u6027\u8d28\u8868\u73b0\u548c\u53ef\u9760\u7684\u7ed3\u6784\u6027\u8d28\u5173\u7cfb\u7406\u89e3\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior<\/a> (Nat.Commun., 2018, DOI: 10.1038\/s41467-018-05141-4)<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u51af\u65b0\u4eae\u6559\u6388\u662f\u5fb7\u56fd\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\u5316\u5b66\u7cfb\u5206\u5b50\u529f\u80fd\u6750\u6599\u7814\u7a76\u6240\u6559\u6388\uff0c\u7814\u7a76\u65b9\u5411: \u57fa\u4e8e\u82b3\u9999\u8026\u8054\u7684\u6709\u673a\u5408\u6210\u65b9\u6cd5\u5b66\u7814\u7a76; \u5171\u8f6dpi-\u4f53\u7cfb\u5206\u5b50\u7684\u8bbe\u8ba1\u548c\u5408\u6210\u53ca\u5176\u8d85\u5206\u5b50\u7ec4\u88c5; \u57fa\u4e8e\u81ea\u4e0b\u800c\u4e0a\u7b56\u7565\u53ef\u63a7\u5408\u6210\u77f3\u58a8\u70ef\u7eb3\u7c73\u5e26; \u8bbe\u8ba1\u5408\u6210\u5171\u8f6d\u5be1\u805a\u7269\u548c\u9ad8\u5206\u5b50\u4ee5\u53ca\u5728\u6709\u673a\u7535\u5b50\u5668\u4ef6\u7684\u6d4b\u8bd5\u548c\u8868\u5f81\u7814\u7a76; \u4e8c\u7ef4\u5171\u4ef7\u3001\u914d\u4f4d\u591a\u5b54\u9ad8\u5206\u5b50\u6676\u4f53\u6750\u6599\u7684\u6709\u673a\u5408\u6210\u53ca\u5176\u5728\u5149\u3001\u7535\u3001\u78c1\u3001\u5149\/\u7535\u50ac\u5316\u3001\u4f20\u611f\u3001\u5438\u9644\u548c\u5206\u79bb\u9886\u57df\u7684\u5e94\u7528\u7814\u7a76; \u5b8f\u91cf\u5236\u5907\u9ad8\u8d28\u91cf\u3001\u6eb6\u6db2\u53ef\u52a0\u5de5\u77f3\u58a8\u70ef\u6750\u6599\u4ee5\u53ca\u591a\u6837\u5316\u4e8c\u7ef4\u7eb3\u7c73\u6750\u6599\u5728\u80fd\u6e90\u548c\u7535\u5b50\u5668\u4ef6\u9886\u57df\u7814\u7a76; \u53ef\u63a7\u7eb3\u7c73\u7ed3\u6784\u529f\u80fd\u78b3\u6750\u6599\u3001\u6709\u673a\/\u65e0\u673a\u6742\u5316\u6750\u6599\u7684\u8bbe\u8ba1\u5408\u6210\u53ca\u5176\u5728\u80fd\u6e90\u50a8\u5b58\u548c\u8f6c\u5316\u7684\u5e94\u7528\u7814\u7a76(\u4e3b\u8981\u57fa\u4e8e\u8d85\u7ea7\u7535\u5bb9\u5668\uff0c\u9502\u79bb\u5b50\u7535\u6c60\uff0c\u5149\u89e3\u6c34\uff0c\u71c3\u6599\u7535\u6c60\u7535\u6781\u6750\u6599\u548c\u50ac\u5316\u5242\u7684\u7814\u7a76)\u3002\u5728Nature\u3001Science\u3001Nature Materials\u3001Nature Nanotechnology\u3001Nature Chemistry\u3001J. Am. Chem. Soc.\u3001Angew. Chem. Int. Ed.\u548cAdv. Mater.\u53d1\u8868\u8bba\u6587355\u7bc7\uff0cSCI\u5f15\u752822000\u4f59\u6b21\uff0cH-index\u56e0\u5b5072\uff0c2014\u30012015\u548c2016\u5165\u9009\u5316\u5b66\u548c\u6750\u6599\u9886\u57df\u9ad8\u5f15\u7528\u79d1\u5b66\u5bb6\uff08\u6c64\u59c6\u68ee\u8def\u900f\u96c6\u56e2\uff09\u3002<\/p>\n

\u3010\u5de5\u4f5c\u6c47\u603b\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u51af\u65b0\u4eae\u6559\u6388\u56e2\u961f\u5728\u4e8c\u7ef4\u5171\u4ef7\u3001\u914d\u4f4d\u591a\u5b54\u805a\u5408\u7269\u6676\u4f53\uff082D polymer\u30012D COF\u30012D MOF\uff09\u7684\u6709\u673a\u5408\u6210\u53ca\u5176\u5728\u5149\u3001\u7535\u3001\u78c1\u3001\u80fd\u6e90\u5b58\u50a8\u548c\u8f6c\u6362\u7684\u5e94\u7528\u7814\u7a76\u53d1\u8868\u4e86\u4e00\u7cfb\u5217\u7684\u5de5\u4f5c\u3002<\/p>\n

    \n
  1. R. Dong, T. Zhang, X. Feng, \u201cInterface-Assisted Synthesis of 2D Materials: Trend and Challenges\u201d, Chem. Rev. 2018, 118, 6189\u20136235.<\/a><\/li>\n
  2. X. Feng, D. Schl\u00fcter, \u201cTowards Macroscopic Crystalline 2D Polymers\u201d, Angew. Chem. Int. Ed. 2018, DOI: 10.1002\/anie.201803456.<\/a><\/li>\n
  3. R. Dong, Z. Zhang, D. C Tranca, S. Zhou, M. Wang, P. Adler, Z. Liao, F. Liu, Y. Sun, W. Shi, Z. Zhang, E. Zschech, S. CB Mannsfeld, C. Felser, X. Feng, Nat. Commun. 2018, 9, 2637.<\/a><\/li>\n
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  6. H. Sahabudeen, H. Qi, B. A. Glatz, D. Tranca, R. Dong, Y. Hou, T. Zhang, C. Kuttner, T. Lehnert, G. Seifert, U. Kaiser, A. Fery, Z. Zheng, X. Feng, \u201cWafer-Sized Multifunctional Polyimine-Based Two-Dimensional Conjugated Polymers with High Mechanical Stiffness\u201d, Nat. Commun. 2016, 7, 13461.<\/a><\/li>\n
  7. S. Liu, J. Zhang, R. Dong, P. Gordiichuk, X. Zhuang, Y. Mai, F. Liu, A. Herrmann, X. Feng, \u201cTwo-Dimensional Mesoscale-Ordered Conducting Polymers\u201d, Angew. Chem. Int. Ed. 2016, 55, 12516-12521.<\/a><\/li>\n
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