{"id":146001,"date":"2018-07-14T06:30:07","date_gmt":"2018-07-13T22:30:07","guid":{"rendered":"\/\/m.iemloyee.com\/?p=146001"},"modified":"2018-07-12T18:26:26","modified_gmt":"2018-07-12T10:26:26","slug":"%e4%b8%ad%e5%8d%97%e5%a4%a7%e5%ad%a6nano-energy%ef%bc%9a%e5%85%b7%e6%9c%89%e7%a8%b3%e5%ae%9a%e7%bb%93%e6%9e%84%e5%92%8c%e5%bf%ab%e9%80%9f%e7%a6%bb%e5%ad%90%e6%89%a9%e6%95%a3%e9%80%9a%e9%81%93%e7%9a%84","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=146001","title":{"rendered":"\u4e2d\u5357\u5927\u5b66Nano Energy\uff1a\u5177\u6709\u7a33\u5b9a\u7ed3\u6784\u548c\u5feb\u901f\u79bb\u5b50\u6269\u6563\u901a\u9053\u7684\u9492\u9178\u94be\u4f5c\u4e3a\u53ef\u5145\u7535\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u6b63\u6781"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08ZIBs\uff09\u5177\u6709\u4f4e\u6210\u672c\u3001\u5b89\u5168\u3001\u73af\u5883\u53cb\u597d\u7b49\u7279\u70b9\u3002\u76ee\u524d\u7814\u7a76\u7684\u6c34\u7cfbZn\/MnO<sub>2<\/sub>\u7535\u6c60\uff0c\u867d\u7136\u5bb9\u91cf\u53ef\u8fbe200 mA h g<sup>-1<\/sup>\u4ee5\u4e0a\uff0c\u4f46\u5faa\u73af\u6027\u80fd\u9700\u8981\u8fdb\u4e00\u6b65\u6539\u5584\u3002\u53e6\u4e00\u79cd\u5177\u6709\u5f00\u653e\u5f0f\u7ed3\u6784\u7684\u6c34\u7cfbZIBs\u6b63\u6781\u6750\u6599\u2014\u2014\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u4e5f\u8868\u73b0\u51fa\u5bb9\u91cf\u4f4e\u3001\u500d\u7387\u6027\u80fd\u8f83\u5dee\u7684\u7279\u70b9\uff0c\u4e0d\u80fd\u6ee1\u8db3\u5927\u89c4\u6a21\u50a8\u80fd\u7684\u9700\u8981\u3002\u7814\u7a76\u8868\u660e\uff0c\u5177\u6709\u7a33\u5b9a\u7ed3\u6784\u7684\u7eb3\u7c73\u91d1\u5c5e\u9492\u9178\u76d0\uff08A<sub>x<\/sub>V<sub>m<\/sub>O<sub>n<\/sub>\uff0cA=\u91d1\u5c5e\u9633\u79bb\u5b50\uff09\u53ef\u4ee5\u5e94\u7528\u4e8e\u6c34\u7cfb\u548c\u975e\u6c34\u7cfb\u9502\u79bb\u5b50\/\u94a0\u79bb\u5b50\u7535\u6c60\u3002\u5176\u7eb3\u7c73\u7ed3\u6784\u53ef\u4ee5\u7f29\u77ed\u79bb\u5b50\u7684\u6269\u6563\u8def\u5f84\uff0c\u589e\u52a0\u7535\u89e3\u8d28\u548c\u6d3b\u6027\u7269\u8d28\u4e4b\u95f4\u7684\u63a5\u89e6\u9762\u79ef\u3002\u8fd9\u4e9b\u4f18\u52bf\u4f7f\u5176\u5728\u6c34\u7cfbZIBs\u6b63\u6781\u6750\u6599\u9886\u57df\u5341\u5206\u5177\u6709\u524d\u666f\u3002K<sup>+<\/sup>\u7684\u534a\u5f84(0.138 nm)\u5927\u4e8eLi<sup>+<\/sup> (0.076 nm)\u3001Na<sup>+<\/sup> (0.102 nm)\u7684\u534a\u5f84\uff0c\u5176\u5728\u9492\u6c27\u5c42\u95f4\u53ef\u4ee5\u8d77\u5230\u66f4\u5f3a\u7684\u652f\u6491\u4f5c\u7528\uff0c\u4ece\u800c\u53ef\u4ee5\u63d0\u9ad8\u6750\u6599\u7684\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u76f8\u6bd4\u4e8e\u5176\u4ed6\u9492\u57fa\u6750\u6599\uff0c\u94be\u79bb\u5b50\u63d2\u5c42\u7684\u9492\u6c27\u5316\u7269\u53ef\u4ee5\u4e3aZn<sup>2+<\/sup>(0.074 nm)\u7684\u53ef\u9006\u5d4c\u5165\/\u8131\u51fa\u63d0\u4f9b\u4e86\u8f83\u5927\u7684\u7a7a\u95f4\uff0c\u56e0\u6b64\u5728\u6c34\u7cfbZIBs\u6b63\u6781\u6750\u6599\u9886\u57df\u5177\u6709\u5f88\u5927\u7684\u6f5c\u529b\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u4e2d\u5357\u5927\u5b66\u6881\u53d4\u5168\u6559\u6388\u548c\u5468\u6c5f\u7279\u8058\u6559\u6388\u7b49\u4eba<\/strong>\u9996\u6b21\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u9492\u9178\u94be\u7eb3\u7c73\u6750\u6599\uff08K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\uff0cK<sub>0.25<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\uff0cK<sub>2<\/sub>V<sub>6<\/sub>O<sub>16<\/sub>\u00b71.57H<sub>2<\/sub>O\u548cKV<sub>3<\/sub>O<sub>8<\/sub>\uff09\u4f5c\u4e3a\u6c34\u7cfbZIBs\u7684\u6b63\u6781\u6750\u6599\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u4e0e\u7ed3\u6784\u5bb9\u6613\u574d\u584c\u7684\u5c42\u72b6KV<sub>3<\/sub>O<sub>8<\/sub>\u548cK<sub>2<\/sub>V<sub>6<\/sub>O<sub>16<\/sub>\u00b71.57H<sub>2<\/sub>O\u76f8\u6bd4\uff0c\u5177\u6709\u96a7\u9053\u7ed3\u6784\u7684K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u548cK<sub>0.25<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\u6709\u52a9\u4e8e\u950c\u79bb\u5b50\u6269\u6563\uff0c\u5e76\u4e14\u53ef\u4ee5\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u4fdd\u6301\u7a33\u5b9a\u7684\u7ed3\u6784\u3002K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u6b63\u6781\u5177\u6709\u6700\u4f73\u7684\u50a8\u950c\u6027\u80fd\uff0c\u57280.3 A g<sup>-1<\/sup>\u65f6\uff0c\u5177\u6709247 mA h g<sup>-1<\/sup>\u7684\u9ad8\u5bb9\u91cf\uff1b\u57286 A g<sup>-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af300\u6b21\u7684\u5bb9\u91cf\u8fd8\u53ef\u4fdd\u6301\u5728128mA h g<sup>-1<\/sup>\uff0c\u5177\u6709\u4f18\u5f02\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u3002\u6b64\u5916\uff0c\u901a\u8fc7GITT\u3001\u975e\u539f\u4f4dX\u5c04\u7ebf\u7b49\u8868\u5f81\u624b\u6bb5\u8868\u660eK<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6781\u5177\u6709\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4e0e\u7ed3\u6784\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0cK<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u662f\u4e00\u79cd\u975e\u5e38\u6709\u524d\u666f\u7684\u6c34\u7cfbZIBs\u6b63\u6781\uff0c\u5177\u6709\u7c7b\u4f3c\u7ed3\u6784\u7684\u03b2-Na<sub>0.33<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\uff0cLi<sub>0.3<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\uff0cAg<sub>0.33<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\u7b49\u6750\u6599\u4ea6\u53ef\u63a8\u5e7f\u4f5c\u4e3a\u6c34\u7cfbZIBs\u6b63\u6781\u6750\u6599\u3002\u8be5\u6210\u679c\u5b8c\u6210\u4eba\u4e3a\u5510\u535a\u96c5\u7855\u58eb\u3001\u65b9\u56fd\u8d75\u535a\u58eb\uff08\u5171\u540c\u4e00\u4f5c\uff09\uff0c\u5468\u6c5f\u7279\u8058\u6559\u6388\u3001\u6881\u53d4\u5168\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u7b49\u4eba\uff0c\u5e76\u4ee5<strong>\u201c<\/strong><strong>Potassium vanadates with stable structure and fast ion diffusion channel as cathode for rechargeable aqueous zinc-ion batteries<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728<strong>Nano Energy<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong> 1 <\/strong><strong>\u56db\u79cd\u9492\u9178\u94be\u7684\u7535\u6c60\u6027\u80fd\u5bf9\u6bd4\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-146007\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/2-37.jpg\" alt=\"\" width=\"600\" height=\"550\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/2-37.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/2-37-300x275.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09Zn\/K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u6c34\u7cfb\u53ef\u5145\u7535\u7535\u6c60\u7684\u5145\u7535\/\u653e\u7535\u8fc7\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n<p>\uff08b\uff09\u5728500 mA g<sup>-1<\/sup>\u4e0b\uff0cK<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6781\u5177\u6709\u8f83\u9ad8\u7684\u521d\u59cb\u6bd4\u5bb9\u91cf\u4e3a216 mAh g<sup>-1<\/sup>\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a90%\uff0c\u8fdc\u4f18\u4e8eK<sub>0.25<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\uff0cK<sub>2<\/sub>V<sub>6<\/sub>O<sub>16<\/sub>\u00b71.57H<sub>2<\/sub>O\u548cKV<sub>3<\/sub>O<sub>8<\/sub>\uff1b<\/p>\n<p>\uff08c\uff090.1 mV s<sup>-1<\/sup>\u4e0b\uff0c\u56db\u79cd\u9492\u9178\u94be\u7684CV\u66f2\u7ebf\u3002\u5728\u9996\u6b21\u5faa\u73af\u4e2d\uff0cK<sub>2<\/sub>V<sub>6<\/sub>O<sub>16<\/sub>\u00b71.57H<sub>2<\/sub>O\u548cKV<sub>3<\/sub>O<sub>8<\/sub>\u57280.7 V\u5de6\u53f3\u51fa\u73b0\u4e86\u4e0d\u53ef\u9006\u5cf0\uff0c\u8868\u660e\u5faa\u73af\u8fc7\u7a0b\u4e2d\u53ef\u9006\u6027\u5dee\uff0c\u5bf9\u5e94\u5176\u5feb\u901f\u7684\u5bb9\u91cf\u8870\u51cf\uff1b<\/p>\n<p>\uff08d\uff09\u5728500 mA g<sup>-1<\/sup>\u4e0b\uff0c\u56db\u79cd\u9492\u9178\u94be\uff08K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\uff0cK<sub>0.25<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\uff0cK<sub>2<\/sub>V<sub>6<\/sub>O<sub>16<\/sub>\u00b71.57H<sub>2<\/sub>O\u548cKV<sub>3<\/sub>O<sub>8<\/sub>\uff09\u7684\u5145\u653e\u7535\u66f2\u7ebf\u56fe\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong> 2 Zn\/K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub><\/strong><strong>\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-146006\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/3-38.jpg\" alt=\"\" width=\"600\" height=\"370\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/3-38.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/3-38-300x185.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09Zn\/K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6c60\u7684\u500d\u7387\u6027\u80fd\u56fe\uff1b<\/p>\n<p>\uff08b\uff09\u57281 A g<sup>-1<\/sup>\u548c2 A g<sup>-1<\/sup>\u4e0b\uff0cZn\/K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6c60\u5faa\u73af100\u5708\u540e\u5bb9\u91cf\u53ef\u5206\u522b\u4fdd\u6301\u5728185mA h g<sup>-1<\/sup>\u4e0e152 mA h g<sup>-1<\/sup>\uff1b<\/p>\n<p>\uff08c\uff09Zn\/K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6c60\u5177\u6709\u826f\u597d\u7684\u9ad8\u6e29\u6027\u80fd\uff0850\u00b0C\uff09\uff1b<\/p>\n<p>\uff08d\uff09\u57286 A g<sup>-1<\/sup>\u4e0b\uff0cZn\/K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6c60\u5faa\u73af300\u6b21\u7684\u5bb9\u91cf\u8fd8\u53ef\u4fdd\u6301\u5728128 mA h g<sup>-1<\/sup>\uff0c\u5177\u6709\u4f18\u79c0\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong> 3 <\/strong><strong>\u56db\u79cd<\/strong><strong>\u9492\u9178\u94be\u7684<\/strong><strong>GITT<\/strong><strong>\u66f2\u7ebf\u548c\u5176\u8ba1\u7b97\u7684\u6269\u6563\u7cfb\u6570\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-146005\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/4-38.jpg\" alt=\"\" width=\"600\" height=\"345\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/4-38.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/4-38-300x173.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff0ce\uff09K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7684GITT\u66f2\u7ebf\u548c\u5176\u8ba1\u7b97\u7684\u6269\u6563\u7cfb\u6570\u56fe\uff1b<\/p>\n<p>\uff08b\uff0cf\uff09K<sub>0.25<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\u7684GITT\u66f2\u7ebf\u548c\u5176\u8ba1\u7b97\u7684\u6269\u6563\u7cfb\u6570\u56fe\uff1b<\/p>\n<p>\uff08c\uff0cg\uff09K<sub>2<\/sub>V<sub>6<\/sub>O<sub>16<\/sub>\u00b71.57H<sub>2<\/sub>O\u7684GITT\u66f2\u7ebf\u548c\u5176\u8ba1\u7b97\u7684\u6269\u6563\u7cfb\u6570\u56fe\uff1b<\/p>\n<p>\uff08d\uff0ch\uff09KV<sub>3<\/sub>O<sub>8<\/sub>\u7684\u6269\u6563\u7cfb\u6570\u7684GITT\u66f2\u7ebf\u548c\u5176\u8ba1\u7b97\u7684\u6269\u6563\u7cfb\u6570\u56fe\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong> 4 <\/strong><strong>K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub><\/strong><strong>\u7535\u6781\u7684<\/strong><strong>CV<\/strong><strong>\u66f2\u7ebf\u56fe\u53ca\u5176\u8d5d\u7535\u5bb9\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-146004\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/5-28.jpg\" alt=\"\" width=\"600\" height=\"498\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/5-28.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/5-28-300x249.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff09K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6781\u5728\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\u7684CV\u66f2\u7ebf\u56fe\uff1b<\/p>\n<p>\uff08b\uff09Zn\/K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6c60\u4e2d\uff0c\u5cf0\u503c\u7535\u6d41\u7684log(i)\u4e0elog(v)\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n<p>\uff08c\uff09\u4e0d\u540c\u626b\u63cf\u901f\u7387\u4e0b\uff0c\u6269\u6563\u63a7\u5236\u7684Zn<sup>2+<\/sup>\u5d4c\u5165\u8d21\u732e\u5bb9\u91cf\u548c\u8d5d\u7535\u5bb9\u884c\u4e3a\u8d21\u732e\u5bb9\u91cf\u7684\u5360\u6bd4\u56fe\uff1b<\/p>\n<p>\uff08d\uff09Zn\/K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6c60\u57280. 2 mV s<sup>-1<\/sup>\u4e0b\uff0c\u9634\u5f71\u533a\u663e\u793a\u8d5d\u7535\u5bb9\u5206\u5e03\u7684CV\u66f2\u7ebf\u56fe\u3002<\/p>\n<p><strong>\u56fe<\/strong><strong> 5 <\/strong><strong>K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub><\/strong><strong>\u7535\u6781\u7684\u50a8<\/strong><strong>Zn<\/strong><strong>\u673a\u7406\u5206\u6790<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-146003\" src=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/6-20.jpg\" alt=\"\" width=\"600\" height=\"286\" srcset=\"\/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/6-20.jpg 600w, \/\/m.iemloyee.com\/wp-content\/uploads\/2018\/07\/6-20-300x143.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<ul>\n<li>\u5728100 mA g<sup>-1<\/sup>\u4e0b\uff0c\u9996\u5708\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\u56fe\uff1b<\/li>\n<li>\u9996\u5708\u4e0d\u540c\u653e\u7535\/\u5145\u7535\u72b6\u6001\u4e0b\u53ca50\u6b21\u5faa\u73af\u540e\u7684\u975e\u539f\u4f4dXRD\u56fe\u8c31\uff1b<\/li>\n<li>\u5728\u9996\u6b21\u5b8c\u5168\u653e\u7535\/\u5145\u7535\u72b6\u6001\u4e0b\uff0cZn 2p\u548c\uff08d\uff09V 2p\u7684\u975e\u539f\u4f4dXPS\u5149\u8c31\u56fe\uff1b<\/li>\n<\/ul>\n<p>\uff08e, f\uff09\u5728\u9996\u6b21\u5b8c\u5168\u653e\u7535\/\u5145\u7535\u72b6\u6001\u4e0b\uff0cK<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u7535\u6781\u7684TEM\u3001HRTEM\u548cSEAD\u56fe\u50cf\u3002<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p><strong>\u8be5\u5de5\u4f5c\u9996\u6b21<\/strong>\u5bf9\u4e00\u7cfb\u5217\u9492\u9178\u94be\uff08K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\uff0cK<sub>0.25<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\uff0cK<sub>2<\/sub>V<sub>6<\/sub>O<sub>16<\/sub>\u00b71.57H<sub>2<\/sub>O\u548cKV<sub>3<\/sub>O<sub>8<\/sub>\uff09\u4f5c\u4e3a\u53ef\u5145\u7535\u6c34\u7cfbZIB\u6b63\u6781\u6750\u6599\u8fdb\u884c\u4e86\u7cfb\u7edf\u7684\u7814\u7a76\u3002\u8fd9\u4e9b\u5316\u5408\u7269\u90fd\u80fd\u591f\u50a8\u5b58\u950c\u79bb\u5b50\uff0c\u8868\u73b0\u51fa\u591a\u6b65\u950c\u5d4c\u5165\/\u8131\u5d4c\u53cd\u5e94\u3002\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0c\u96a7\u9053\u7ed3\u6784\u7684K<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u548cK<sub>0.25<\/sub>V<sub>2<\/sub>O<sub>5<\/sub>\u80fd\u591f\u63d0\u4f9b\u66f4\u5feb\u7684\u79bb\u5b50\u6269\u6563\u8def\u5f84\uff0c\u5176\u7ed3\u6784\u4e5f\u6bd4\u5c42\u72b6\u7684KV<sub>3<\/sub>O<sub>8<\/sub>\u548cK<sub>2<\/sub>V<sub>6<\/sub>O<sub>16<\/sub>\u00b71.57H<sub>2<\/sub>O\u66f4\u7a33\u5b9a\u3002\u76f8\u6bd4\u4e8e\u4e0e\u6700\u8fd1\u62a5\u9053\u7684\u9492\u57fa\u6750\u6599\uff08VS<sub>2<\/sub>\uff0cZn<sub>3<\/sub>V<sub>2<\/sub>O<sub>7<\/sub>(OH)<sub>2<\/sub>\u00b72H<sub>2<\/sub>O\u548cLiV<sub>3<\/sub>O<sub>8<\/sub>\uff09\u3001\u6c27\u5316\u9530\uff08Mn<sub>3<\/sub>O<sub>4<\/sub>\u548c\u03b1-Mn<sub>2<\/sub>O<sub>3<\/sub>\uff09\u4e0e\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\uff0cK<sub>2<\/sub>V<sub>8<\/sub>O<sub>21<\/sub>\u5177\u6709\u66f4\u9ad8\u7684\u5bb9\u91cf\u548c\u66f4\u597d\u7684\u500d\u7387\u6027\u80fd\u3002\u4e0e\u5e7f\u6cdb\u7528\u4e8e\u6c34\u7cfbZIBs\u7684Zn(CF<sub>3<\/sub>SO<sub>3<\/sub>)<sub>2<\/sub>\u7535\u89e3\u6db2\u76f8\u6bd4\uff0c\u8fd9\u9879\u5de5\u4f5c\u4f7f\u7528ZnSO<sub>4<\/sub>\u7535\u89e3\u6db2\u7684\u6210\u672c\u4f4e\u5f88\u591a\u3002\u8fd9\u79cd\u4f4e\u6210\u672c\u3001\u9ad8\u5b89\u5168\u7684\u6c34\u7cfbZIBs\u4f53\u7cfb\uff0c\u53ef\u4ee5\u5728\u5927\u578b\u50a8\u80fd\u88c5\u7f6e\u5f97\u5230\u5e94\u7528\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<\/strong><strong><a href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S2211285518305032\" target=\"_blank\" rel=\"noopener\">Potassium vanadates with stable structure and fast ion diffusion channel as cathode for rechargeable aqueous zinc-ion batteries<\/a><\/strong>\uff08Nano Energy, 2018, DOI: 10.1016\/j.nanoen.2018.07.014\uff09\u3002<\/p>\n<p><strong>\u3010\u56e2\u961f\u5728\u8be5\u9886\u57df\u7684\u5de5\u4f5c\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u4e2d\u5357\u5927\u5b66<strong>\u6881\u53d4\u5168<\/strong>\u6559\u6388\u3001<strong>\u5468\u6c5f<\/strong>\u7279\u8058\u6559\u6388\u56e2\u961f\u8fd1\u5e74\u6765\u5728\u7eb3\u7c73\u80fd\u6e90\u9886\u57df\u4e2d\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u7814\u7a76\u8fdb\u5c55\u3002<\/p>\n<p><strong>\uff08<\/strong><strong>1<\/strong><strong>\uff09\u5173\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u7684\u7814\u7a76<\/strong><\/p>\n<p>\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u7b56\u7565\uff0c\u7ed3\u5408\u6c34\u70ed\u6cd5\u548c\u51b7\u51bb\u5e72\u71e5\u6280\u672f\u5236\u5907\u4e86\u77f3\u58a8\u70ef\u5305\u8986Na<sub>1.1<\/sub>V<sub>3<\/sub>O<sub>7.9<\/sub>\u7eb3\u7c73\u5e26\uff0cNa<sub>1.1<\/sub>V<sub>3<\/sub>O<sub>7.9<\/sub>\u7eb3\u7c73\u5e26\u4e0e\u77f3\u58a8\u70ef\u7247\u4ea4\u8054\u590d\u5408\uff0c\u5f62\u6210\u4e86\u7a33\u5b9a\u7684\u6be1\u72b6\u7ed3\u6784\u3002\u8be5\u6750\u6599\u9996\u6b21\u5c06\u9492\u9178\u94a0\u5e94\u7528\u4e8e\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff0c\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\uff08Energy Storage Materials 2018, 13, 168\u2013174\uff09\u3002<\/p>\n<p>\u7814\u7a76\u4e86\u65e0\u7c98\u7ed3\u5242\u5c42\u72b6\u7eb3\u7c73\u82b1\u7ed3\u6784Mn<sub>3<\/sub>O<sub>4<\/sub>\u4f5c\u4e3a\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5e76\u7ed3\u5408\u975e\u539f\u4f4d\u8868\u5f81\u63a2\u7d22\u4e86\u5176\u50a8\u950c\u673a\u5236\uff08J. Mater. Chem. A 2018, 6, 9677\u20139683\uff09\u3002<\/p>\n<p>\u6b64\u5916\uff0c\u56e2\u961f\u6709\u5173V<sub>2<\/sub>O<sub>5<\/sub>\u7eb3\u7c73\u6750\u6599\u7528\u4f5c\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u7684\u57fa\u7840\u7814\u7a76\u8fdb\u5c55\uff0c\u5728\u81ea\u7136\u6307\u6570\u671f\u520a\u300a\u5316\u5b66\u901a\u8baf\u300b(Chem. Commun., 2018, 54, 4457)\u4e0a\u53d1\u8868\u3002<\/p>\n<p><strong>\uff08<\/strong><strong>2<\/strong><strong>\uff09\u5173\u4e8e<\/strong><strong>MOFs<\/strong><strong>\u8f6c\u5316\u4e0e\u5e94\u7528\u7814\u7a76\uff1a<\/strong><\/p>\n<p>\u5229\u7528\u53cc\u91d1\u5c5eMOFs\u4e3a\u6a21\u677f\uff0c\u6210\u529f\u5f00\u53d1\u51fa\u4e00\u79cd\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u7684\u6c2e\u63ba\u6742\u78b3\u5305\u8986\u53cc\u91d1\u5c5e\u786b\u5316\u7269\uff0c\u8be5\u6750\u6599\u5177\u6709\u9ad8\u94a0\u79bb\u5b50\u6269\u6563\u7cfb\u6570\uff0c\u4e30\u5bcc\u7684\u6676\u754c\u7f3a\u9677\uff0c\u548c\u8d5d\u7535\u5bb9\u6548\u5e94\u3002\u8be5\u6750\u6599\u6709\u6548\u89e3\u51b3\u4e86\u76ee\u524d\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u5728\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u79bb\u5b50\u6269\u6563\u7f13\u6162\u3001\u6750\u6599\u4f53\u79ef\u81a8\u80c0\u7b49\u74f6\u9888\u95ee\u9898\u3002\u8be5\u7814\u7a76\u6210\u679c\u8fd1\u65e5\u53d1\u8868\u5728\u56fd\u9645\u80fd\u6e90\u9876\u7ea7\u671f\u520a\u300a\u5148\u8fdb\u80fd\u6e90\u6750\u6599\u300b\uff08Adv. Energy Mater. 2018, 8, 1703155\uff09\uff0c\u5e76\u88ab\u9009\u4e3aBack Cover\u8bba\u6587\u3002<\/p>\n<p>\u9996\u6b21\u5229\u7528\u4e8c\u7ef4MOFs\u7eb3\u7c73\u7247\u751f\u957f\u4e09\u7ef4\u5bfc\u7535\u57fa\u5e95\u5408\u6210\u7cfb\u5217\u91d1\u5c5e\u6c27\u5316\u7269\/\u4e09\u7ef4\u57fa\u5e95\u590d\u5408\u6750\u6599\uff0c\u5e76\u6df1\u5165\u7814\u7a76\u4e86\u5176\u6676\u4f53\u6210\u6838\u53ca\u751f\u957f\u673a\u7406\u3002\u8be5\u590d\u5408\u6b63\u6781\u6750\u6599\u6027\u80fd\u4f18\u5f02\uff0c\u653e\u7535\u540e\u5f62\u8c8c\u80fd\u591f\u4fdd\u6301\uff0c\u57285 A g<sup>-1<\/sup>\u548c20 A g<sup>-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u53ef\u4ee5\u5faa\u73af2000\u6b21\u3002\u8be5\u7814\u7a76\u6210\u679c\u53d1\u8868\u5728\u56fd\u9645\u80fd\u6e90\u9876\u7ea7\u671f\u520a\u300a\u7eb3\u7c73\u80fd\u6e90\u300b\uff08Nano Energy, 2016, 26, 57\u201365\uff0cESI\u9ad8\u88ab\u5f15\u8bba\u6587\uff09\u3002<\/p>\n<p>\u5408\u7406\u5730\u8bbe\u8ba1\u4e86\u4e00\u79cd\u591a\u5b54\u6742\u5316\u53cc\u91d1\u5c5e\u6c27\u5316\u7269(Co<sub>3<\/sub>O<sub>4<\/sub>\/ZnO)\u7eb3\u7c73\u7247\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50a8\u9502\u3001\u50a8\u94a0\u6027\u80fd\u3002\u8be5\u5de5\u4f5c\u6210\u4e3a\u300aJ. Mater. Chem. A\u300b\u7684\u5c01\u9762\u6587\u7ae0\uff08J. Mater. Chem. A, 2017, 5, 13983-13993\uff09\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c<strong>\u6295\u7a3f\u90ae\u7bb1<\/strong><strong>tougao@cailiaoren.com<\/strong>\u3002<\/p>\n<p>\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<strong>cailiaokefu<\/strong>\u3002<\/p>\n<p>\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165<a href=\"\/\/m.iemloyee.com\/25127.html\" target=\"_blank\" rel=\"noopener\"><strong>\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\uff08ZIBs\uff09\u5177\u6709\u4f4e\u6210\u672c\u3001\u5b89\u5168\u3001\u73af\u5883\u53cb\u597d\u7b49\u7279\u70b9\u3002\u76ee\u524d\u7814\u7a76\u7684\u6c34\u7cfbZn\/MnO2\u7535\u6c60\uff0c\u867d\u7136\u5bb9\u91cf\u53ef\u8fbe200 mA h g-1\u4ee5\u4e0a\uff0c\u4f46\u5faa\u73af\u6027\u80fd\u9700\u8981&#8230;<\/p>\n","protected":false},"author":7035,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3411,3412],"class_list":["post-146001","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-3411","tag-3412"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/146001"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7035"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=146001"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/146001\/revisions"}],"predecessor-version":[{"id":146028,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/146001\/revisions\/146028"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=146001"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=146001"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=146001"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}