{"id":145734,"date":"2018-07-13T06:30:41","date_gmt":"2018-07-12T22:30:41","guid":{"rendered":"\/\/m.iemloyee.com\/?p=145734"},"modified":"2018-07-13T10:37:11","modified_gmt":"2018-07-13T02:37:11","slug":"adv-energy-mater-%e5%8a%9f%e8%83%bd%e6%80%a7%e8%81%9a%e5%90%88%e7%89%a9%e6%94%b9%e5%96%84%e7%94%b5%e6%9e%81%e4%b8%8e%e5%9b%ba%e6%80%81%e7%94%b5%e8%a7%a3%e8%b4%a8%e7%95%8c%e9%9d%a2%e9%97%ae%e9%a2%98","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=145734","title":{"rendered":"Adv. Energy Mater.: \u529f\u80fd\u6027\u805a\u5408\u7269\u6539\u5584\u7535\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u95ee\u9898"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u5168\u56fa\u6001\u7535\u6c60\u5177\u6709\u80fd\u6e90\u5bc6\u5ea6\u9ad8\uff0c\u5b89\u5168\u6027\u80fd\u597d\u7b49\u4f18\u70b9\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u50a8\u80fd\u88c5\u7f6e\u3002\u9700\u8981\u6307\u51fa\u7684\u662f\u5168\u56fa\u6001\u7535\u6c60\u4ecd\u7136\u5b58\u5728\u4e00\u4e9b\u95ee\u9898\uff0c \u5982\u7535\u6781\u6750\u6599\u4f53\u79ef\u53d8\u5316\u5927\u3001\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\u7535\u963b\u9ad8\u3001\u6d3b\u6027\u6750\u6599\u8d1f\u8f7d\u91cf\u4f4e\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u5dee\u3001\u5b89\u5168\u6027\u80fd\u4f4e\u7b49\u3002\u7531\u4e8e\u5168\u56fa\u6001\u7535\u6c60\u4e2d\u56fa\u6001\u7535\u89e3\u8d28\u4e0e\u7535\u6781\u4e4b\u95f4\u7684\u63a5\u89e6\u662f\u76f4\u63a5\u7684\u7269\u7406\u63a5\u89e6\uff0c\u56e0\u6b64\u754c\u9762\u6d78\u6da6\u6027\u8f83\u5dee\u3002\u4e0d\u7406\u60f3\u7684\u754c\u9762\u6d78\u6da6\u6027\u4e25\u91cd\u5f71\u54cd\u4e86\u5168\u56fa\u6001\u7535\u6c60\u7684\u5bb9\u91cf\uff0c\u8fd9\u79cd\u4e0d\u5229\u5f71\u54cd\u5728\u9ad8\u500d\u7387\u60c5\u51b5\u4e0b\u5c24\u4e3a\u7a81\u51fa\u3002\u540c\u65f6\u7535\u6781-\u7535\u89e3\u8d28\u754c\u9762\u5904\u53d1\u751f\u7684\u526f\u53cd\u5e94\u5bf9\u5168\u56fa\u6001\u7535\u6c60\u7684\u6027\u80fd\u6709\u4e00\u5b9a\u7684\u5f71\u54cd\u3002\u968f\u7740\u7535\u538b\u6216\u6e29\u5ea6\u7684\u5347\u9ad8\uff0c\u526f\u53cd\u5e94\u4f1a\u8fdb\u4e00\u6b65\u964d\u4f4e\u5168\u56fa\u6001\u7535\u6c60\u7684\u5bb9\u91cf\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240<\/strong>\u7684Shi Ji-Lei, Wang Chu-Ru<\/strong>\u548c\u90ed\u7389\u56fd\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u62a5\u9053\u4e86\u7535\u6781-\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u6539\u6027\u7684\u6700\u65b0\u7814\u7a76\u8fdb\u5c55\u3002\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5728NCM\u6b63\u6781\u6750\u6599\u8868\u9762\u5f15\u5165\u805a\u4e19\u70ef\u8148-\u4e01\u4e8c\u70ef(PAB)\u5305\u8986\u5c42\uff0c\u4e0d\u4ec5\u6709\u6548\u6291\u5236\u4e86\u7535\u6c60\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7684\u526f\u53cd\u5e94\uff0c\u800c\u4e14\u6709\u6548\u6539\u5584\u4e86\u7535\u6781-\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u754c\u9762\u63a5\u89e6\u60c5\u51b5\u3002\u7814\u7a76\u53d1\u73b0PAB\u754c\u9762\u6539\u6027\u7684\u5168\u56fa\u6001\u7535\u6c60\u5177\u5907\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff1a\u57283.0 C\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6bd4\u5bb9\u91cf\u53ef\u8fbe99 mAh g-1<\/sup>, \u5faa\u73af400\u5708\u540e\u4ecd\u4fdd\u630175\uff05\u7684\u5bb9\u91cf\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cAmeliorating the Interfacial Problems of Cathode and Solid-State Electrolytes by Interface Modification of Functional Polymers<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Energy Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb<\/strong>\u3011<\/p>\n

\u56fe-1. \u5168\u56fa\u6001\u7535\u6c60\u5b58\u5728\u7684\u754c\u9762\u95ee\u9898\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u56fe-2. NCM@PAB\u7684\u5f62\u8c8c\u548c\u5143\u7d20\u5206\u5e03\u60c5\u51b5\u8868\u5f81<\/p>\n

\"\"<\/p>\n

(a)-(b) NCM@PAB\u7684\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(TEM)\u56fe\u50cf\uff1b<\/p>\n

(c) NCM@PAB\u7684\u9ad8\u5206\u8fa8\u900f\u5c04\u7535\u5b50\u663e\u5fae\u955c(HRTEM)\u56fe\u50cf\uff1b<\/p>\n

(d)-(j) NCM@PAB\u7684\u5143\u7d20\u5206\u5e03\u56fe\u50cf\u3002<\/p>\n

\u56fe-3. \u6837\u54c1\u7684\u7ed3\u6784\u8868\u5f81<\/p>\n

\"\"<\/p>\n

(a) NCM, NCM@PAB\u7684XRD\u884d\u5c04\u56fe\uff1b<\/p>\n

(b) PAB, NCM, NCM@PAB\u7684\u5085\u91cc\u53f6\u53d8\u6362\u7ea2\u5916(FT-IR)\u5149\u8c31\uff1b<\/p>\n

(c)-(d) NCM, NCM@PAB\u7684EDS\u5143\u7d20\u542b\u91cf\u5206\u6790\u7ed3\u679c\u3002<\/p>\n

\u56fe-4. \u56fa\u6001\u7535\u6c60\u7684\u7535\u5316\u5b66\u6d4b\u8bd5\u66f2\u7ebf<\/p>\n

\"\"<\/p>\n

(a) NCM\u5728\u4e0d\u540c\u626b\u901f\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

(b) \u4ee5NCM\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u7684\u5cf0\u503c\u7535\u6d41\u5bc6\u5ea6\u4e0e\u626b\u901f\u5e73\u65b9\u6839\u4e4b\u95f4\u7684\u51fd\u6570\u5173\u7cfb\u53ca\u5176\u62df\u5408\u66f2\u7ebf\uff1b<\/p>\n

(c) NCM@PAB\u5728\u4e0d\u540c\u626b\u901f\u4e0b\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

(d) \u4ee5NCM@PAB\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u7684\u5cf0\u503c\u7535\u6d41\u5bc6\u5ea6\u4e0e\u626b\u901f\u5e73\u65b9\u6839\u4e4b\u95f4\u7684\u51fd\u6570\u5173\u7cfb\u53ca\u5176\u62df\u5408\u66f2\u7ebf\u3002<\/p>\n

\u56fe-5. \u56fa\u6001\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u66f2\u7ebf<\/p>\n

\"\"<\/p>\n

(a) \u4ee5NCM\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(b) \u4ee5NCM@PAB\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u7684\u6052\u6d41\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

(c) \u4ee5NCM\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u4ece\u7b2c1\u5708\u81f3\u7b2c20\u5708\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684dQ\/dV<\/em>\u5173\u7cfb\u66f2\u7ebf\uff1b<\/p>\n

(d) \u4ee5NCM@PAB\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u4ece\u7b2c1\u5708\u81f3\u7b2c20\u5708\u5145\u7535\u8fc7\u7a0b\u4e2d\u7684dQ\/dV<\/em>\u5173\u7cfb\u66f2\u7ebf\uff1b<\/p>\n

(e) \u4ee5NCM\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u4ece\u7b2c1\u5708\u81f3\u7b2c20\u5708\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684dQ\/dV<\/em>\u5173\u7cfb\u66f2\u7ebf\uff1b<\/p>\n

(f) \u4ee5NCM@PAB\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u4ece\u7b2c1\u5708\u81f3\u7b2c20\u5708\u653e\u7535\u8fc7\u7a0b\u4e2d\u7684dQ\/dV<\/em>\u5173\u7cfb\u66f2\u7ebf\uff1b<\/p>\n

(g) \u4ee5NCM\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u524d20\u5708\u7684\u6c27\u5316-\u8fd8\u539f\u5cf0\uff1b<\/p>\n

(h) \u4ee5NCM@PAB\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u524d20\u5708\u7684\u6c27\u5316-\u8fd8\u539f\u5cf0\u3002<\/p>\n

\u56fe-6. \u7535\u6c60\u7684\u6027\u80fd\u6d4b\u8bd5<\/p>\n

\"\"<\/p>\n

(a) \u4ee5NCM\u4e3a\u6b63\u6781\u3001\u805a\u5408\u7269\u4e3a\u56fa\u6001\u7535\u89e3\u8d28\u7684\u5168\u56fa\u6001\u7535\u6c60\u57280.2-5.0 C\u7535\u6d41\u5bc6\u5ea6\u533a\u95f4\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

(b) \u4ee5NCM@PAB\u4e3a\u6b63\u6781\u3001\u805a\u5408\u7269\u4e3a\u56fa\u6001\u7535\u89e3\u8d28\u7684\u5168\u56fa\u6001\u7535\u6c60\u57280.2-5.0 C\u7535\u6d41\u5bc6\u5ea6\u533a\u95f4\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

(c) \u4ee5NCM\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u5728\u5faa\u73af\u524d\u548c\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u540e\u7684Nyquist\u66f2\u7ebf\uff1b<\/p>\n

(d) \u4ee5NCM@PAB\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u5728\u5faa\u73af\u524d\u548c\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u540e\u7684Nyquist\u66f2\u7ebf\uff1b<\/p>\n

(e) \u7535\u6d41\u5bc6\u5ea6\u4e3a1.0 C\u65f6\uff0c\u4ee5NCM, NCM@PAB\u4e3a\u6b63\u6781\u7684\u5168\u56fa\u6001\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u66f2\u7ebf\u3002<\/p>\n

\u56fe-7. \u5145\u7535\u81f34.3 V\u540eNCM(\u7eff\u8272)\u548cNCM@PAB(\u6a59\u8272)\u7684DSC\u66f2\u7ebf<\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u672c\u6587\u901a\u8fc7\u5728NCM\u6b63\u6781\u6750\u6599\u8868\u9762\u5f15\u5165\u805a\u4e19\u70ef\u8148-\u4e01\u4e8c\u70ef(PAB)\u5305\u8986\u5c42\uff0c\u6709\u6548\u6539\u5584\u4e86\u7535\u6781-\u56fa\u6001\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u754c\u9762\u95ee\u9898\u3002\u7814\u7a76\u53d1\u73b0\uff1aPAB\u8584\u819c\u7684\u5f15\u5165\u4e0d\u4ec5\u53ef\u4ee5\u4fdd\u8bc1\u6b63\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u7684\u826f\u597d\u63a5\u89e6\uff0c\u800c\u4e14\u53ef\u4ee5\u6709\u6548\u6291\u5236\u754c\u9762\u5904\u7684\u526f\u53cd\u5e94\uff1b\u6b63\u6781\u6750\u6599\u8868\u73b0\u51fa\u4f4e\u6781\u5316\u7535\u538b\uff0c\u5168\u56fa\u6001\u7535\u6c60\u8868\u663e\u51fa\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u8be5\u9879\u5de5\u4f5c\u4e3a\u89e3\u51b3\u7535\u6781\u4e0e\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\u95ee\u9898\u63d0\u4f9b\u4e86\u4e00\u79cd\u7b80\u4fbf\u7684\u89e3\u51b3\u65b9\u6848\uff0c\u5e76\u4e14\u53ef\u4ee5\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5176\u5b83\u56fa\u6001\u7535\u6c60\u4f53\u7cfb\u4e2d\u3002<\/p>\n

\u3010\u6587\u732e\u4fe1\u606f<\/strong>\u3011Ameliorating the Interfacial Problems of Cathode and Solid-State Electrolytes by Interface Modification of Functional Polymers\u00a0<\/a>(Adv. Energy. Mater., 2018, DOI: doi.org\/10.1002\/aenm.201801528<\/a>)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u4eba\u7ec4\u97e9\u767e\u5ddd\u7f16\u8f91\uff0c\u5f20\u6770\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>!<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5168\u56fa\u6001\u7535\u6c60\u5177\u6709\u80fd\u6e90\u5bc6\u5ea6\u9ad8\uff0c\u5b89\u5168\u6027\u80fd\u597d\u7b49\u4f18\u70b9\uff0c\u6709\u671b\u5e94\u7528\u4e8e\u4e0b\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u50a8\u80fd\u88c5\u7f6e\u3002\u9700\u8981\u6307\u51fa\u7684\u662f\u5168\u56fa\u6001\u7535\u6c60\u4ecd\u7136\u5b58\u5728\u4e00\u4e9b\u95ee\u9898\uff0c \u5982\u7535\u6781\u6750\u6599\u4f53\u79ef\u53d8\u5316\u5927\u3001\u7535\u6781-…<\/p>\n","protected":false},"author":230,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-145734","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/145734"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=145734"}],"version-history":[{"count":4,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/145734\/revisions"}],"predecessor-version":[{"id":145774,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/145734\/revisions\/145774"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=145734"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=145734"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=145734"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}