{"id":144954,"date":"2018-07-09T06:30:40","date_gmt":"2018-07-08T22:30:40","guid":{"rendered":"\/\/m.iemloyee.com\/?p=144954"},"modified":"2018-07-06T17:09:34","modified_gmt":"2018-07-06T09:09:34","slug":"nat-energy%ef%bc%9a%e5%9f%ba%e4%ba%8e%e7%9f%b3%e6%a6%b4%e7%9f%b3%e5%9e%8b%e5%9b%ba%e4%bd%93%e7%94%b5%e8%a7%a3%e8%b4%a8%e7%9a%84%e7%86%94%e8%9e%8d%e9%94%82%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"\/\/m.iemloyee.com\/?p=144954","title":{"rendered":"Nat. Energy\uff1a\u57fa\u4e8e\u77f3\u69b4\u77f3\u578b\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7194\u878d\u9502\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7528\u4e8e\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u7684\u7535\u6c60\u9700\u8981\u6ee1\u8db3\u9ad8\u529f\u7387\u3001\u9ad8\u5b89\u5168\u6027\u3001\u957f\u5bff\u547d\u548c\u4f4e\u6210\u672c\u7b49\u8981\u6c42\uff0c\u65b0\u4e00\u4ee3\u7535\u7ad9\u5f0f\u50a8\u80fd\u7535\u6c60\u7cfb\u7edf\u4e9f\u5f85\u5f00\u53d1\u3002\u7194\u878d\u91d1\u5c5e\u7535\u6c60\u662f\u5927\u89c4\u6a21\u50a8\u80fd\u7535\u6c60\u7684\u5019\u9009\u65b9\u6848\uff0c\u5728\u8fd9\u4e00\u7c7b\u7535\u6c60\u4f53\u7cfb\u4e2d\uff0c\u5982\u4f55\u964d\u4f4e\u7535\u6c60\u7684\u5de5\u4f5c\u6e29\u5ea6\u3001\u51cf\u5c11\u7535\u6c60\u7684\u6210\u672c\u3001\u63d0\u9ad8\u7535\u6c60\u7684\u53ef\u9760\u6027\u548c\u5b89\u5168\u6027\uff0c\u662f\u7194\u878d\u9502\u7535\u6c60\u53d1\u5c55\u7684\u4e3b\u8981\u6311\u6218\u3002\u672c\u6587\u53d1\u73b0\u77f3\u69b4\u77f3\u578b\u56fa\u4f53\u7535\u89e3\u8d28\u80fd\u591f\u663e\u8457\u964d\u4f4e\u7535\u6c60\u7684\u5de5\u4f5c\u6e29\u5ea6\uff0c\u63d0\u9ad8\u7535\u6c60\u7684\u5bb9\u91cf\u548c\u5b89\u5168\u6027\uff0c\u63d0\u9ad8\u7535\u6c60\u7684\u5e93\u4f26\u6548\u7387\u548c\u5faa\u73af\u5bff\u547d\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u6e05\u534e\u5927\u5b66\u7684\u4f0d\u6656\u548c\u7f8e\u56fd\u65af\u5766\u798f\u5927\u5b66\u7684\u5d14\u5c79\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\uff0c\u62a5\u9053\u4e86\u4e00\u79cd\u7194\u878d\u9502\u8d1f\u6781\uff0c\u7194\u878dSn-Pb\u6216Bi-Pb\u5408\u91d1\u6b63\u6781\u548c\u77f3\u69b4\u77f3\u578bLi6.4<\/sub>La3<\/sub>Zr1.4<\/sub>Ta0.6<\/sub>O12<\/sub>\uff08LLZTO\uff09\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u7ec4\u6210\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u57fa\u7194\u878d\u9502\u7535\u6c60\u3002\u5728240\u2103\u300150\u548c100 mA cm-2<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cLi||LLZTO||Sn-Pb\u548cLi||LLZTO||Bi-Pb\u7535\u6c60\u53ef\u4ee5\u7a33\u5b9a\u5faa\u73af\u7ea6\u4e00\u4e2a\u6708\uff0c\u51e0\u4e4e\u6ca1\u6709\u5bb9\u91cf\u8870\u51cf\uff0c\u5e73\u5747\u5e93\u4ed1\u6548\u7387\u4e3a99.98\uff05\u3002\u540c\u65f6\uff0c\u7535\u6c60\u5177\u6709\u9ad8\u529f\u7387\u80fd\u529b\uff0cLi||LLZTO||Sn-Pb\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u9ad8\u8fbe300 mA cm-2<\/sup>\u65f6\uff0c\u529f\u7387\u5bc6\u5ea6\u4e3a90 mW cm-2<\/sup>\uff0cLi||LLZTO||Sn-Pb\u7535\u6c60\u5728\u7535\u6d41\u5bc6\u5ea6\u9ad8\u8fbe500 mA cm-2<\/sup>\u65f6\uff0c\u529f\u7387\u5bc6\u5ea6\u4e3a175 mW cm-2<\/sup>\u3002\u8fd9\u79cd\u4e2d\u6e29\u7535\u6c60\u6709\u671b\u6210\u4e3a\u9ad8\u5b89\u5168\u6027\u3001\u4f4e\u5efa\u9020\u548c\u7ef4\u62a4\u6210\u672c\u7684\u7535\u7f51\u50a8\u80fd\u7535\u6c60\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>An intermediate temperature garnet-type solid electrolyte-based molten lithium battery for grid energy storage<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Energy<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 Li||LLZTO||<\/strong>\u6db2\u6001\u6b63\u6781\u7535\u6c60\u7684\u793a\u610f\u56fe\u53ca\u5b9e\u7269\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Li||\u56fa\u4f53\u7535\u89e3\u8d28||\u6db2\u6001\u6b63\u6781\u7535\u6c60\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09U\u5f62LLZTO\u7ba1\u7684\u5b9e\u7269\u56fe\uff1b<\/p>\n

\uff08c\uff09Li||LLZTO||Sn-Pb\u5408\u91d1\u7535\u6c60\u7684\u5b9e\u7269\u56fe\u3002<\/p>\n

\u56fe<\/strong> 2\u00a0<\/strong>\u5728<\/strong>240<\/strong>\u2103<\/strong>\u4e0b\uff0c<\/strong>Li||LLZTO||Sn-Pb<\/strong>\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u572850 mA cm-2<\/sup>\u4e0b\uff0c\u7b2c1-5\u3001119-120\u5708\u5faa\u73af\u7684\u7535\u538b\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08b\uff09\u7b2c5\u300160\u548c120\u5708\u5faa\u73af\u671f\u95f4\u7684\u5bb9\u91cf-\u7535\u538b\u56fe\uff1b<\/p>\n

\uff08c\uff093.561 g Sn\u548c2.073 g Pb\u4f5c\u4e3a\u6b63\u6781\u6750\u6599\u65f6\uff0c\u7535\u6c60\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u80fd\u91cf\u6548\u7387\u548c\u4f53\u79ef\u5bb9\u91cf\u56fe\uff1b<\/p>\n

\uff08d\uff09\u572850-300 mA cm-2<\/sup>\u4e0b\uff0c\u7535\u6c60\u7684\u7535\u538b\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08e\uff09\u572850 mA cm-2<\/sup>\u4e0b\uff0cLi||LLZTO||Sn-Pb\u7b2c5\u6b21\u5faa\u73af\u7684\u7535\u538b\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08f\uff09Li||LLZTO||Sn-Pb\u7535\u6c60\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u80fd\u91cf\u6548\u7387\u548c\u4f53\u79ef\u5bb9\u91cf\u56fe\u3002<\/p>\n

\u56fe<\/strong> 3\u00a0<\/strong>\u5728<\/strong>240<\/strong>\u2103<\/strong>\u4e0b\uff0c<\/strong>Li||LLZtO||Bi-Pb<\/strong>\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728240\u2103\u4e0b\uff0cLi||LLZTO||Bi-Pb\u7535\u6c60\u7684\u5e93\u4ed1\u6ef4\u5b9a\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728100 mA cm-2<\/sup>\u4e0b\uff0c\u7535\u6c60\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u80fd\u91cf\u6548\u7387\u548c\u4f53\u79ef\u5bb9\u91cf\u4e0e\u5faa\u73af\u6b21\u6570\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

\uff08c\uff09\u7535\u6c60\u7684\u7535\u538b\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08d\uff09\u5728100-500 mA cm-2<\/sup>\u4e0b\uff0c\u7535\u6c60\u7684\u7535\u538b\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u56fe<\/strong> 4 Li||LLZTO||Sn-Pb<\/strong>\u548c<\/strong>Li||LLZTO||Bi-Pb<\/strong>\u7535\u6c60\u7684\u51b7\u5374\u540e\u518d\u52a0\u70ed\u542f\u52a8\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u572850 mA cm-2<\/sup>\u5145\u7535\u548c\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cLi||LLZTO||Sn-Pb\u7535\u6c60\u51b7\u53745\u5c0f\u65f6\uff08\u964d\u81f330\u2103\uff09\uff0c\u7136\u540e\u518d\u6b21\u52a0\u70ed\u56de\u5230240\u2103\u7684\u7535\u538b\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728100 mA cm-2<\/sup>\u5145\u7535\u540e\u548c\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cLi||LLZTO||Bi-Pb\u7535\u6c60\u51b7\u53745\u5c0f\u65f6\uff08\u964d\u81f330\u00b0C\uff09\uff0c\u7136\u540e\u518d\u6b21\u56de\u5230240\u00b0C\u7684\u7535\u538b\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u56fe<\/strong> 5 1960<\/strong>\u5e74\u4ee5\u6765\uff0c\u4e0d\u540c<\/strong>LME<\/strong>\u7535\u6c60\u7684\u5de5\u4f5c\u6e29\u5ea6\u6bd4\u8f83\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u57fa\u4e8e\u9ad8\u54c1\u8d28\u7684\u77f3\u69b4\u77f3\u578bLLZTO\u7535\u89e3\u8d28\u7684\u7194\u878d\u9502\u7535\u6c60\uff0c\u5c06LME\u7535\u6c60\u7684\u5de5\u4f5c\u6e29\u5ea6\u964d\u4f4e\u5230240\u00b0C\uff0c\u800c\u7535\u6c60\u7684\u5e73\u5747\u5e93\u4ed1\u6548\u7387\u9ad8\u8fbe99.98\uff05\uff0c\u529f\u7387\u5bc6\u5ea6\u9ad8\u8fbe175 mW cm-2<\/sup>\u3002\u4e0e1960\u5e74\u4ee5\u6765\u62a5\u9053\u7684\u5176\u4ed6\u7194\u878d\u9502\u7535\u6c60\u76f8\u6bd4\uff0cLi||LLZTO||Sn-Pb\u548cLi||LLZTO||Bi-Pb\u7535\u6c60\u7684\u5de5\u4f5c\u6e29\u5ea6\u66f4\u4f4e\u3002\u964d\u4f4e\u5de5\u4f5c\u6e29\u5ea6\uff0c\u53ef\u4ee5\u964d\u4f4e\u7535\u6c60\u6750\u6599\u7684\u6c27\u5316\u548c\u8150\u8680\u901f\u7387\uff0c\u964d\u4f4e\u5bc6\u5c01\u548c\u7535\u7edd\u7f18\u5de5\u827a\u7684\u6210\u672c\u3002Sn-Pb\u548cBi-Pb\u5408\u91d1\u7684\u5bc6\u5ea6\u8f83\u9ad8\uff0cLi||LLZTO||Sn-Pb\u548cLi||LLZTO||Bi-Pb\u7535\u6c60\u7684\u7406\u8bba\u4f53\u79ef\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u8fbe570 Wh l-1<\/sup>\u548c940 Wh l-1<\/sup>\u3002\u56e0\u6b64\uff0c\u56fa\u4f53\u7535\u89e3\u8d28\u57fa\u7194\u878d\u9502\u7535\u6c60\u5177\u6709\u826f\u597d\u7684\u9002\u7528\u6027\u548c\u53ef\u884c\u6027\uff0c\u5176\u4e2dLi||LLZTO||Bi-Pb\u7535\u6c60\uff0c\u5177\u6709\u5e94\u7528\u4e8e\u5927\u89c4\u6a21\u50a8\u80fd\u7cfb\u7edf\u7684\u6f5c\u529b\u3002\u8fd9\u79cd\u57fa\u4e8e\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7194\u878d\u9502\u7535\u6c60\uff0c\u56e0\u5176\u4f4e\u6210\u672c\u548c\u9ad8\u6027\u80fd\u662f\u5927\u89c4\u6a21\u50a8\u80fd\u5e94\u7528\u7684\u6f5c\u5728\u5019\u9009\u8005\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>An intermediate temperature garnet-type solid electrolyte-based molten lithium battery for grid energy storage<\/strong><\/a>\uff08Nat. Energy, 2018, DOI: 10.1038\/s41560-018-0198-9\uff09\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1<\/strong>tougao@cailiaoren.com<\/strong><\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/strong>\u3002<\/p>\n

\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7528\u4e8e\u5927\u89c4\u6a21\u50a8\u80fd\u9886\u57df\u7684\u7535\u6c60\u9700\u8981\u6ee1\u8db3\u9ad8\u529f\u7387\u3001\u9ad8\u5b89\u5168\u6027\u3001\u957f\u5bff\u547d\u548c\u4f4e\u6210\u672c\u7b49\u8981\u6c42\uff0c\u65b0\u4e00\u4ee3\u7535\u7ad9\u5f0f\u50a8\u80fd\u7535\u6c60\u7cfb\u7edf\u4e9f\u5f85\u5f00\u53d1\u3002\u7194\u878d\u91d1\u5c5e\u7535\u6c60\u662f\u5927\u89c4\u6a21\u50a8\u80fd\u7535\u6c60\u7684\u5019\u9009\u65b9\u6848\uff0c\u5728\u8fd9…<\/p>\n","protected":false},"author":7035,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3390,3388,3389],"class_list":["post-144954","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-3390","tag-3388","tag-3389"],"_links":{"self":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/144954"}],"collection":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/users\/7035"}],"replies":[{"embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=144954"}],"version-history":[{"count":3,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/144954\/revisions"}],"predecessor-version":[{"id":145118,"href":"\/\/m.iemloyee.com\/index.php?rest_route=\/wp\/v2\/posts\/144954\/revisions\/145118"}],"wp:attachment":[{"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=144954"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=144954"},{"taxonomy":"post_tag","embeddable":true,"href":"\/\/m.iemloyee.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=144954"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}